List of works - Daniele Leonori

7.22 Oxidation of Carbon–Boron Bonds

A dual photoredox-nickel strategy for remote functionalization via iminyl radicals: radical ring-opening-arylation, -vinylation and -alkylation cascades

scientific article published on 27 June 2019

A photochemical dehydrogenative strategy for aniline synthesis

scientific article published on 05 August 2020

A unified approach to mechanistic aspects of photochemical vapor generation

Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides

scientific article published on 01 February 2020

An Experimental and in Situ IR Spectroscopic Study of the Lithiation–Substitution of N-Boc-2-phenylpyrrolidine and -piperidine: Controlling the Formation of Quaternary Stereocenters

scientific article published on 07 March 2012

Asymmetric Synthesis of Tertiary Alcohols and Thiols via Nonstabilized Tertiary α-Oxy- and α-Thio-Substituted Organolithium Species

scientific article

Asymmetric Synthesis of Tertiary Alcohols and Thiols via Nonstabilized Tertiary α-Oxy- and α-Thio-Substituted Organolithium Species

scientific article published on 7 August 2017

Asymmetric addition of chiral boron-ate complexes to cyclic iminium ions

article

Asymmetric substitutions of 2-lithiated N-boc-piperidine and N-Boc-azepine by dynamic resolution

scientific article published in April 2010

Concise Synthesis of (+)-allo-Kainic Acid via MgI2-Mediated Tandem Aziridine Ring Opening–Formal [3 + 2] Cycloaddition

scientific article published on 02 August 2013

De Novo Synthesis of the Bacterial 2-Amino-2,6-Dideoxy Sugar Building Blocks d-Fucosamine, d-Bacillosamine, and d-Xylo-6-deoxy-4-ketohexosamine

scientific article published on 06 September 2012

De novo synthesis of D- and L-fucosamine containing disaccharides

scientific article published on 14 February 2013

Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds

scientific article published on 6 July 2016

Direct Preparation of 7-Allyl- and 7-Arylindolines

Divergent Strain-Release Amino-Functionalization of [1.1.1]Propellane with Electrophilic Nitrogen-Radicals

scientific article published on 31 January 2020

Dual Catalysis: Combination of Photocatalytic Aerobic Oxidation and Metal Catalyzed Alkynylation Reactions-CC Bond Formation Using Visible Light

scientific article published on 16 March 2012

Dynamic resolution of N-Boc-2-lithiopiperidine

scientific article published on 08 August 2008

Enantiospecific sp(2)-sp(3) coupling of secondary and tertiary boronic esters

scientific article published on 8 June 2014

Frontispiece: Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

scholarly article by Jacob Davies et al published 22 August 2018 in Chemistry—A European Journal

Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

scientific article published on 06 July 2018

Lithiation–Borylation Methodology and Its Application in Synthesis

scientific article published on 29 September 2014

Lithium-Boron Chemistry: A Synergistic Strategy in Modern Synthesis

Photoinduced Remote Functionalisations by Iminyl Radical Promoted C-C and C-H Bond Cleavage Cascades.

scientific article published on 8 November 2017

Photoinduced Remote Functionalisations by Iminyl Radical Promoted C−C and C−H Bond Cleavage Cascades

Photoinduced Remote Functionalization of Amides and Amines Using Electrophilic Nitrogen Radicals

Photoinduced decarboxylative azidation of cyclic amino acids

scientific article published on 01 February 2019

Photoredox Imino Functionalizations of Olefins

scientific article published on 31 August 2017

Photoredox Imino Functionalizations of Olefins

Photoredox Synthesis of Arylhydroxylamines from Carboxylic Acids and Nitrosoarenes

Practical and regioselective amination of arenes using alkyl amines

scientific article published on 22 April 2019

Reaction of Nitrogen-Radicals with Organometallics Under Ni-Catalysis: N-Arylations and Amino-Functionalization Cascades

Reaction of Nitrogen‐Radicals with Organometallics Under Ni‐Catalysis: N‐Arylations and Amino‐Functionalization Cascades

Reagent-Controlled Lithiation–Borylation

Regioselective and stereoselective copper(I)-promoted allylation and conjugate addition of N-Boc-2-lithiopyrrolidine and N-Boc-2-lithiopiperidine

scientific article published in June 2010

Stereocontrolled Synthesis of 1,5-Stereogenic Centers through Three-Carbon Homologation of Boronic Esters

scientific article published on 15 July 2014

Stereospecific Coupling of Boronic Esters with N-Heteroaromatic Compounds

scientific article published on 21 August 2015

Stereospecific Couplings of Secondary and Tertiary Boronic Esters

scientific article published on 20 November 2014

Stereospecific conversion of alcohols into pinacol boronic esters using lithiation–borylation methodology with pinacolborane

scientific article published on 01 April 2014

Synthesis and kinetic resolution of N-Boc-2-arylpiperidines

scientific article published on 01 September 2014

Synthesis of 1-substituted tetrahydroisoquinolines by lithiation and electrophilic quenching guided by in situ IR and NMR spectroscopy and application to the synthesis of salsolidine, carnegine and laudanosine.

scientific article published on 15 May 2013

Synthesis of 2-Arylpiperidines by Palladium Couplings of Aryl Bromides with Organozinc Species Derived from Deprotonation ofN-Boc-Piperidine

scientific article published on 07 August 2008

Synthesis of Arylamines via Aminium Radicals

Synthesis of Arylamines via Aminium Radicals.

scientific article

The barrier to enantiomerization and dynamic resolution of N-Boc-2-lithiopiperidine and the effect of TMEDA

scientific article published on 06 August 2009

The first calcium-catalysed Nazarov cyclisation

scientific article published on 01 December 2014

The interplay of polar effects in controlling the selectivity of radical reactions

scientific article published in 2022

Visible light mediated azomethine ylide formation—photoredox catalyzed [3+2] cycloadditions ⬇️

scientific article published on July 27, 2011

Visible-Light-Mediated 5-exo -dig Cyclizations of Amidyl Radicals

scholarly article by Daniel Fernandez Reina et al published 6 February 2017 in European Journal of Organic Chemistry

Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions

scientific article published on 28 September 2015

Visible-Light-Mediated Reactions of Electrophilic Radicals with Vinyl and Allyl Trifluoroborates

scholarly article by Daniel Fernandez Reina et al published 17 May 2017 in ACS Catalysis

Visible-Light-Mediated Synthesis of Amidyl Radicals: Transition-Metal-Free Hydroamination and N-Arylation Reactions.

scientific article published on 21 June 2016

List of works by Daniele Leonori

7.22 Oxidation of Carbon–Boron Bonds

A dual photoredox-nickel strategy for remote functionalization via iminyl radicals: radical ring-opening-arylation, -vinylation and -alkylation cascades

A photochemical dehydrogenative strategy for aniline synthesis

A unified approach to mechanistic aspects of photochemical vapor generation

Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides

An Experimental and in Situ IR Spectroscopic Study of the Lithiation–Substitution of N-Boc-2-phenylpyrrolidine and -piperidine: Controlling the Formation of Quaternary Stereocenters

Asymmetric Synthesis of Tertiary Alcohols and Thiols via Nonstabilized Tertiary α-Oxy- and α-Thio-Substituted Organolithium Species

Asymmetric Synthesis of Tertiary Alcohols and Thiols via Nonstabilized Tertiary α-Oxy- and α-Thio-Substituted Organolithium Species

Asymmetric addition of chiral boron-ate complexes to cyclic iminium ions

Asymmetric substitutions of 2-lithiated N-boc-piperidine and N-Boc-azepine by dynamic resolution

Concise Synthesis of (+)-allo-Kainic Acid via MgI2-Mediated Tandem Aziridine Ring Opening–Formal [3 + 2] Cycloaddition

De Novo Synthesis of the Bacterial 2-Amino-2,6-Dideoxy Sugar Building Blocks d-Fucosamine, d-Bacillosamine, and d-Xylo-6-deoxy-4-ketohexosamine

De novo synthesis of D- and L-fucosamine containing disaccharides

Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds

Direct Preparation of 7-Allyl- and 7-Arylindolines

Divergent Strain-Release Amino-Functionalization of [1.1.1]Propellane with Electrophilic Nitrogen-Radicals

Dual Catalysis: Combination of Photocatalytic Aerobic Oxidation and Metal Catalyzed Alkynylation Reactions-CC Bond Formation Using Visible Light

Dynamic resolution of N-Boc-2-lithiopiperidine

Enantiospecific sp(2)-sp(3) coupling of secondary and tertiary boronic esters

Frontispiece: Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry

Lithiation–Borylation Methodology and Its Application in Synthesis

Lithium-Boron Chemistry: A Synergistic Strategy in Modern Synthesis

Photoinduced Remote Functionalisations by Iminyl Radical Promoted C-C and C-H Bond Cleavage Cascades.

Photoinduced Remote Functionalisations by Iminyl Radical Promoted C−C and C−H Bond Cleavage Cascades

Photoinduced Remote Functionalization of Amides and Amines Using Electrophilic Nitrogen Radicals

Photoinduced Remote Functionalization of Amides and Amines Using Electrophilic Nitrogen Radicals

Photoinduced decarboxylative azidation of cyclic amino acids

Photoredox Imino Functionalizations of Olefins

Photoredox Imino Functionalizations of Olefins

Photoredox Synthesis of Arylhydroxylamines from Carboxylic Acids and Nitrosoarenes

Practical and regioselective amination of arenes using alkyl amines

Reaction of Nitrogen-Radicals with Organometallics Under Ni-Catalysis: N-Arylations and Amino-Functionalization Cascades

Reaction of Nitrogen‐Radicals with Organometallics Under Ni‐Catalysis: N‐Arylations and Amino‐Functionalization Cascades

Reagent-Controlled Lithiation–Borylation

Regioselective and stereoselective copper(I)-promoted allylation and conjugate addition of N-Boc-2-lithiopyrrolidine and N-Boc-2-lithiopiperidine

Stereocontrolled Synthesis of 1,5-Stereogenic Centers through Three-Carbon Homologation of Boronic Esters

Stereospecific Coupling of Boronic Esters with N-Heteroaromatic Compounds

Stereospecific Couplings of Secondary and Tertiary Boronic Esters

Stereospecific conversion of alcohols into pinacol boronic esters using lithiation–borylation methodology with pinacolborane

Synthesis and kinetic resolution of N-Boc-2-arylpiperidines

Synthesis of 1-substituted tetrahydroisoquinolines by lithiation and electrophilic quenching guided by in situ IR and NMR spectroscopy and application to the synthesis of salsolidine, carnegine and laudanosine.

Synthesis of 2-Arylpiperidines by Palladium Couplings of Aryl Bromides with Organozinc Species Derived from Deprotonation ofN-Boc-Piperidine

Synthesis of Arylamines via Aminium Radicals

Synthesis of Arylamines via Aminium Radicals.

The barrier to enantiomerization and dynamic resolution of N-Boc-2-lithiopiperidine and the effect of TMEDA

The first calcium-catalysed Nazarov cyclisation

The interplay of polar effects in controlling the selectivity of radical reactions

Visible light mediated azomethine ylide formation—photoredox catalyzed [3+2] cycloadditions ⬇️

Visible-Light-Mediated 5-exo -dig Cyclizations of Amidyl Radicals

Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions

Visible-Light-Mediated Reactions of Electrophilic Radicals with Vinyl and Allyl Trifluoroborates

Visible-Light-Mediated Synthesis of Amidyl Radicals: Transition-Metal-Free Hydroamination and N-Arylation Reactions.