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Authors whose works are in public domain in at least one jurisdiction

List of works by Rinaldo Poli

1-(Diphenylphosphinothioyl)-2-[(4-methylphenyl)methoxymethyl]ferrocene

scientific article published on October 20, 2010

A combined parahydrogen and theoretical study of H2 activation by 16-electron d8 ruthenium(0) complexes and their subsequent catalytic behaviour

scientific article published on 16 September 2004

A computational study of the olefin epoxidation mechanism catalyzed by cyclopentadienyloxidomolybdenum(VI) complexes.

scientific article published in February 2010

A two-state computational investigation of methane C--H and ethane C--C oxidative addition to [CpM(PH3)]n+ (M = Co, Rh, Ir; n = 0, 1)

scientific article published on 01 January 2006

ATRP/OMRP/CCT interplay in styrene polymerization mediated by iron(II) complexes: A DFT study of the α-diimine system

scientific article published on 17 November 2014

Ab Initio Study of the Penultimate Effect for the ATRP Activation Step Using Propylene, Methyl Acrylate, and Methyl Methacrylate Monomers

article by Ching Yeh Lin et al published August 2007 in Macromolecules

Accessibility of 17-Electron Structures for Cyclopentadienylchromium(III) Compounds. 1. Experimental Studies on the Dichloride and Dimethyl Compounds

Activation of a (cyclooctadiene) rhodium(I) complex supported by a chiral ferrocenyl phosphine thioether ligand for hydrogenation catalysis: a combined parahydrogen NMR and DFT study

scientific article

Al(OPr i)3-catalysed halogen exchange processes of relevance to atom transfer radical polymerization: the effect depends on the metal electronic structure

scientific article published on 13 October 2004

Amino-phosphanes in RhI-Catalyzed Hydroformylation: Hemilabile Behavior of P,N Ligands under High CO Pressure and Catalytic Properties

An experimental and computational study on the effect of Al(OiPr)3 on atom-transfer radical polymerization and on the catalyst-dormant-chain halogen exchange

scientific article published in April 2005

Anionic Halomolybdate(III) Chemistry. Tetrahydrofuran Loss from [MoX(3)Y(THF)(2)](-) (X, Y = Cl, Br, I), Preparation and Properties of [Mo(3)X(12)](3)(-) (X = Br, I), and Crystal Structure of the Edge-Sharing Trioctahedral [PPh(4)](3)[Mo(3)I(12)].

scientific article published on December 1996

Atom transfer radical polymerization (ATRP) and organometallic mediated radical polymerization (OMRP) of styrene mediated by diaminobis(phenolato)iron(II) complexes: a DFT study.

scientific article published on 3 July 2014

Bis(formylphenolato)cobalt(II)-Mediated Alternating Radical Copolymerization of tert-Butyl 2-Trifluoromethylacrylate with Vinyl Acetate

article published in 2017

Catalyzed Radical Termination in the Presence of Tellanyl Radicals

scientific article

Cobalt(iii) and copper(ii) hydrides at the crossroad of catalysed chain transfer and catalysed radical termination: a DFT study

scholarly article by S. M. Wahidur Rahaman et al published 2016 in Polymer Chemistry

Cobalt-Mediated Radical Coupling (CMRC): An Unusual Route to Midchain-Functionalized Symmetrical Macromolecules

article

Cobalt-mediated radical (co)polymerization of vinyl chloride and vinyl acetate

Cobalt-mediated radical polymerization of acrylonitrile: kinetics investigations and DFT calculations

scientific article published in January 2008

Comparison of Bond Dissociation Energies of Dormant Species Relevant to Degenerative Transfer and Atom Transfer Radical Polymerization

article

Computational study of the spin-forbidden H2oxidative addition to 16-electron Fe(0) complexes

article

Contrasting photochemical and thermal reactivity of Ru(CO)2(PPh3)(dppe) towards hydrogen rationalised by parahydrogen NMR and DFT studies

article

Coordination Chemistry Inside Polymeric Nanoreactors: Interparticle Metal Exchange and Ionic Compound Vectorization in Phosphine-Functionalized Amphiphilic Polymer Latexes

scientific article published on 22 March 2016

Coordination Chemistry inside Polymeric Nanoreactors: Metal Migration and Cross-Exchange in Amphiphilic Core-Shell Polymer Latexes

scientific article published on 22 January 2016

Coordination chemistry of diphenylphosphinoferrocenylthioethers on cyclooctadiene and norbornadiene rhodium(I) platforms

scientific article published on 22 August 2012

Coordinatively Labile 18-Electron Arene Ruthenium Iminophosphonamide Complexes

scientific article

Core-shell nanoreactors for efficient aqueous biphasic catalysis

scientific article

Crystal structure of penta-carbon-yl(2,2-di-fluoro-propane-thio-ato-κ)manganese(I)

scientific article published on 02 April 2019

Dihydrogen to dihydride isomerization mechanism in [(C5Me5)FeH2(Ph2PCH2CH2PPh2)]+ through the experimental and theoretical analysis of kinetic isotope effects

scientific article published in December 2006

Double [3 + 2]-dimerisation cascade synthesis of bis(triazolyl)bisphosphanes, a new scaffold for bidentate bisphosphanes

scientific article published on 01 July 2015

Effect of Head-to-Head Addition in Vinyl Acetate Controlled Radical Polymerization: Why Is Co(acac)2-Mediated Polymerization so Much Better?

Effect of electron donors on the radical polymerization of vinyl acetate mediated by [Co(acac)2]: degenerative transfer versus reversible homolytic cleavage of an organocobalt(III) complex

scientific article published in January 2007

Effect of the nature of the metal atom on hydrogen bonding and proton transfer to [Cp*MH3(dppe)]: tungsten versus molybdenum

scientific article published in January 2008

Effective Cobalt-Mediated Radical Coupling (CMRC) of Poly(vinyl acetate) and Poly(N-vinylpyrrolidone) (Co)polymer Precursors

article

Electronic and steric ligand effects in the radical polymerization of vinyl acetate mediated by beta-ketoiminate complexes of cobalt(II).

scientific article

Experimental (IR, Raman) and computational analysis of a series of PtBr(2) derivatives: vibrational coupling in the coordinated ethylene and Pt-Br modes

scientific article published on 01 June 2009

Experimental and computational studies of hydrogen bonding and proton transfer to [Cp*Fe(dppe)H].

scientific article published in January 2005

Fluoroalkyl Pentacarbonylmanganese(I) Complexes as Initiators for the Radical (co)Polymerization of Fluoromonomers

scientific article published on 08 February 2020

Fluoroalkyl Radical Generation by Homolytic Bond Dissociation in Pentacarbonylmanganese Derivatives

scientific article published on 13 December 2018

Formation and Possible Reactions of Organometallic Intermediates with Active Copper(I) Catalysts in ATRP

article

Formation and structure of a sterically protected molybdenum hydride complex with a 15-electron configuration: [(1,2,4-C5H2tBu3)Mo(PMe3)2H]+

scientific article published on 01 January 2007

H(+)/AuPPh(3)(+) Exchange for the Hydride Complexes CpMoH(CO)(2)(L) (L = PMe(3), PPh(3), CO). Formation and Structure of [Cp(CO)(2)(PMe(3))Mo(AuPPh(3))(2)](+)[BF(4)](-)

scientific article published on 01 July 1997

Hemilability of phosphine-thioether ligands coordinated to trinuclear Mo3S4 cluster and its effect on hydrogenation catalysis

scholarly article by Artem L. Gushchin et al published 2018 in New Journal of Chemistry

High oxidation state organometallic chemistry in aqueous media: new opportunities for catalysis and electrocatalysis

scientific article published in January 2004

Homolytic bond strengths and formation rates in half-sandwich chromium alkyl complexes: relevance for controlled radical polymerization

scientific article published on 01 January 2008

Hydrogen bonding to carbonyl hydride complex Cp*Mo(PMe(3))(2)(CO)H and its role in proton transfer

scientific article published on 11 January 2010

Interaction of half-sandwich alkylmolybdenum(III) complexes with B(C6F5)3. The X-ray structure of [CpMo(η4-C4H6)(μ-Cl)(μ-CH2)(O)MoCp][CH3B(C6F5)3]

Investigation of the [Cp*Mo(PMe3)3H]n+ (n = 0, 1) redox pair: dynamic processes on very different time scales.

scientific article published in January 2009

Key Role of Intramolecular Metal Chelation and Hydrogen Bonding in the Cobalt-Mediated Radical Polymerization ofN-Vinyl Amides

scientific article published on 21 August 2012

Kinetico-mechanistic information about alkene hydroamination with aniline in bromide-rich ionic media: importance of solvolysis

scientific article published on 17 May 2011

Kinetics and mechanism of the proton transfer to CpFe(dppe)H: absence of a direct protonation at the metal site

scientific article published in September 2003

Ligand adducts of bis(acetylacetonato)iron(II): a 1H NMR study

scientific article published on 17 October 2011

Mechanistic diversity in acetophenone transfer hydrogenation catalyzed by ruthenium iminophosphonamide complexes

scientific article published on 09 January 2020

Mechanistic insights into the cobalt-mediated radical polymerization (CMRP) of vinyl acetate with cobalt(III) adducts as initiators

scientific article published in January 2008

Mechanistic insights into β-oxygen atom transfer in olefinepoxidation mediated by W(vi) complexes and H2O2

scientific article published on 07 December 2011

Mononuclear and Binuclear Cyclopentadienyl Oxo Molybdenum and Tungsten Complexes: Syntheses and Applications in Olefin Epoxidation Catalysis

Nature of Cp*MoO2+ in water and intramolecular proton-transfer mechanism by stopped-flow kinetics and density functional theory calculations

scientific article published on 10 April 2007

New Phenomena in Organometallic-Mediated Radical Polymerization (OMRP) and Perspectives for Control of Less Active Monomers

scientific article published on 4 March 2015

Olefin epoxidation by H2O2/MeCN catalysed by cyclopentadienyloxidotungsten(VI) and molybdenum(VI) complexes: experiments and computations

scientific article published in August 2010

Open-Shell Organometallics as a Bridge between Werner-Type and Low-Valent Organometallic Complexes. The Effect of the Spin State on the Stability, Reactivity, and Structure

scientific article

Organic Salts and Merrifield Resin Supported [PMO] (M = Mo or W) as Catalysts for Adipic Acid Synthesis

scientific article published on 21 February 2019

Origin of Activity in Cu-, Ru-, and Os-Mediated Radical Polymerization

article

Overview of cobalt-mediated radical polymerization: Roots, state of the art and future prospects

Oxidation-promoted activation of a ferrocene C-H bond by a rhodium complex

scientific article published on 01 May 2013

Oxygen-Triggered Switchable Polymerization for the One-Pot Synthesis of CO2 -Based Block Copolymers from Monomer Mixtures

scientific article published on 21 August 2019

Parahydrogen studies of H2 addition to Ir(I) complexes containing chiral phosphine-thioether ligands: implications for catalysis

scientific article published on 26 April 2006

Pd(I) phosphine carbonyl and hydride complexes implicated in the palladium-catalyzed oxo process.

scientific article published on 16 July 2008

Polymorph of {2-[(2-hydroxyethyl)iminiomethyl]phenolato-kappaO}dioxido{2-[(2-oxidoethyl)iminomethyl]phenolato-kappa3O,N,O'}molybdenum(VI)

scientific article published on 22 January 2008

Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis.

scientific article published on 13 March 2013

Radical polymerization of styrene controlled by half-sandwich Mo(III)/Mo(IV) couples: all basic mechanisms are possible.

scientific article

Radical polymerization of vinyl acetate with bis(tetramethylheptadionato)cobalt(II): coexistence of three different mechanisms

scientific article

Rational synthesis and characterization of the mixed-metal organometallic polyoxometalates [Cp*Mo(x)W(6-x)O18]- (x = 0, 1, 5, 6)

scientific article published on 27 April 2012

Reductive Termination of Cyanoisopropyl Radicals by Copper(I) Complexes and Proton Donors: Organometallic Intermediates or Coupled Proton-Electron Transfer?

scientific article published on 16 April 2019

Relationship between one-electron transition-metal reactivity and radical polymerization processes.

scientific article

Reversible-Deactivation Radical Polymerization of Methyl Methacrylate and Styrene Mediated by Alkyl Dithiocarbamates and Copper Acetylacetonates

Rh(I) coordination chemistry of chiral alpha-aminophosphine(eta6-arene)chromium tricarbonyl ligands

scientific article published in April 2003

Rhodium nanoparticles stabilized by ferrocenyl-phosphine ligands: synthesis and catalytic styrene hydrogenation

scientific article published on 01 May 2019

Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study

scientific article published on 26 April 2019

Solvent-dependent dihydrogen/dihydride stability for [Mo(CO)(Cp*)H(2)(PMe(3))(2)](+)[BF(4)](-) determined by multiple solvent...anion...cation non-covalent interactions

scientific article published in January 2010

Speciation of [Cp*(2)M(2)O(5)] in polar and donor solvents.

scientific article

Spin forbidden chemical reactions of transition metal compounds. New ideas and new computational challenges

scientific article published on 01 January 2003

Studies on organometallic hetero-multiple-bridged molecules. Part 7. Synthesis and properties of dichalcogenide-bridged complexes of rhenium(I) and the crystal and molecular structures of the diphenyl ditelluride-bridged complex, [Re2Br2(CO)6(Te2Ph2)

scholarly article by Fausto Calderazzo et al published 1981 in Dalton transactions RSC

Switchable Polymerization Triggered by Fast and Quantitative Insertion of Carbon Monoxide into Cobalt-Oxygen Bonds

scientific article published on 18 February 2020

Synthesis and Characterization of the Most Active Copper ATRP Catalyst Based on Tris[(4-dimethylaminopyridyl)methyl]amine

scientific article published on 10 January 2018

Synthesis of S-Alkyl Phosphinocarbodithioates with Switch between P(III) and P(V) Derivatives

scientific article published on 17 July 2019

Synthesis of beta-P,N aminophosphines and coordination chemistry to Pd(II). X-ray structures of [PdCl2(Ph2PCH(Ph)NHPh-kappaP,kappaN)] and PdCl(eta3-C3H5)(Ph2PCH2CH(Ph)NHPh-kappaP)].

scientific article

Synthesis, coordination to Rh(I), and hydroformylation catalysis of new beta-aminophosphines bearing a dangling nitrogen group: an unusual inversion of a Rh-coordinated P center

scientific article

Synthesis, structure, and electrochemical properties of sterically protected molybdenum trihydride redox pairs: a paramagnetic "stretched" dihydrogen complex?

scientific article published on 01 January 2007

The Pt-Catalyzed Ethylene Hydroamination by Aniline: A Computational Investigation of the Catalytic Cycle

scientific article published on October 6, 2010

The Reductive Elimination of Methane fromansa-Hydrido(methyl)metallocenes of Molybdenum and Tungsten: Application of Hammond’s Postulate to Two-State Reactions

The radical trap in atom transfer radical polymerization need not be thermodynamically stable. A study of the MoX(3)(PMe(3))(3) catalysts

scientific article

The reaction of M(CO)3(Ph2PCH2CH2PPh2) (M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products

scientific article published on 25 August 2004

Theoretical investigation of the spin crossover transition states of the addition of methane to a series of Group 6 metallocenes using minimum energy crossing points

article

Tris(1,1,1,5,5,5-hexa-fluoro-2,4-pentane-dionato-κO,O')molybdenum(III).

scientific article published on 13 February 2010

Tris(bis(trimethylsilyl)amido)samarium: X-ray structure and DFT study

scientific article published in October 2003

chalcogenide low-valent metal complexes

article