Adding Rubidium and Cesium to the Homologous Series of Alkali Metal Compounds of (Trimethylsilyl)methanides and 2,2,6,6-Tetramethylpiperidides

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Adding Rubidium and Cesium to the Homologous Series of Alkali Metal Compounds of (Trimethylsilyl)methanides and 2,2,6,6-Tetramethylpiperidides (Eur. J. Inorg. Chem. 18/2012)

Alkali-Metal-Mediated Manganation: A Method for Directly Attaching Manganese(II) Centers to Aromatic Frameworks

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Alkali-Metal-Mediated Manganation: A Method for Directly Attaching Manganese(II) Centers to Aromatic Frameworks

Alkali-metal-mediated manganationII of functionalized arenes and applications of ortho-manganated products in Pd-catalyzed cross-coupling reactions with iodobenzene.

scientific article published on January 2008

Bis[(trimethylsilyl)methyl]manganese: Structural Variations of Its Solvent-Free and TMEDA-, Pyridine-, and Dioxane-Complexed Forms

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Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran

scientific article published on 23 May 2010

Combining Neopentyllithium with Potassium tert-Butoxide: Formation of an Alkane-Soluble Lochmann-Schlosser Superbase

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Cover Picture: Alkali-Metal-Mediated Manganation(II) of Functionalized Arenes and Applications ofortho-Manganated Products in Pd-Catalyzed Cross-Coupling Reactions with Iodobenzene (Chem. Eur. J. 1/2008)

Cover Picture: Direct CH Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes (Angew. Chem. Int. Ed. 18/2009)

Crossing Organolithium Compounds with Organolithium Compounds: Molecular Squares and a Cage-Encapsulating Reaction

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Crossing Organolithium Compounds with Organolithium Compounds: Molecular Squares and a Cage-Encapsulating Reaction

Die Reaktion von Neopentyllithium mit Kalium-tert -butoxid: Bildung einer alkanlöslichen Lochmann-Schlosser-Superbase

Direct C-H metalation with chromium(II) and iron(II): transition-metal host/benzenediide guest magnetic inverse-crown complexes.

scientific article published on January 2009

Direct CH Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes

Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs.Si-O bond cleavage.

scientific article published on 20 April 2009

Homo- and Heteroleptic Hypersilylcuprates— Valuable Reagents for the Synthesis of Molecular Compounds with a Cu−Si Bond

Innentitelbild: Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases (Angew. Chem. 42/2008)

Inside Cover: Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases (Angew. Chem. Int. Ed. 42/2008)

Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane

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Manganese(ii)–lithium and –sodium inverse crown ether (ICE) complexes

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Monometalated tribenzotriquinacene: exo and endo coordination of sodium and potassium with a rigid bowl-shaped hydrocarbon anion

scientific article published on 01 July 2014

Multistep Self-Assembly of Heteroleptic Magnesium and Sodium−Magnesium Benzamidinate Complexes

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N-Heterocyclic-Carbene-Induced Monomerization of Sterically Encumbered Dialkylmagnesium and Dialkylmanganese Polymers

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N-Heterocyclic-Carbene-Induced Monomerization of Sterically Encumbered Dialkylmagnesium and Dialkylmanganese Polymers (Eur. J. Inorg. Chem. 30/2011)

New insights into addition reactions of dialkylzinc reagents to trifluoromethyl ketones: structural authentication of a beta-hydride elimination product containing a tetranuclear zinc chain

scientific article published on 10 September 2009

Polysubstituted ferrocenes as tunable redox mediators.

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Potassium-alkyl magnesiates: synthesis, structures and Mg–H exchange applications of aromatic and heterocyclic substrates

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Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

scientific article published on 30 September 2009

Remote functionalisation via sodium alkylamidozincate intermediates: access to unusual fluorenone and pyridyl ketone reactivity patterns

scientific article published on 24 February 2011

Sodium-Mediated Manganation: Direct Mono- and Dimanganation of Benzene and Synthesis of a Transition-Metal Inverse-Crown Complex

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Sodium-Mediated Manganation: Direct Mono- and Dimanganation of Benzene and Synthesis of a Transition-Metal Inverse-Crown Complex

Structural Elucidation of tmeda-Solvated Alkali Metal Diphenylamide Complexes

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Structural Motifs of Alkali Metal Superbases in Non-coordinating Solvents

scientific article published on 09 November 2020

Structural and magnetic insights into the trinuclear ferrocenophane and unexpected hydrido inverse crown products of alkali-metal-mediated manganation(II) of ferrocene

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Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like Mg3(2,5-fur-di-yl)3 substructure.

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Structural elaboration of the surprising ortho-zincation of benzyl methyl ether

scientific article published on 20 January 2010

Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone

scientific article published on 4 December 2012

Structural insights into mono-amido tris-alkyl potassium aluminates

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Structural variations within group 1 (Li-Cs)+ (2,2,6,6-tetramethyl-1-piperidinyloxy)- complexes made via metallic reduction of the nitroxyl radical.

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Structurally Engineered Deprotonation/Alumination of THF and THTP with Retention of Their Cycloanionic Structures

Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures

scientific article published on December 2010

Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines

scientific article published on 16 May 2008

Synthesis and Structure of a Potassium Potassiochromate: A Bis-Chromium(II) Molecule Held Together by Near-Square-Planar Potassium−Ligand Bridges†

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Synthesis and Structures of [(Trimethylsilyl)methyl]sodium and -potassium with Bi- and Tridentate N-Donor Ligands

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Synthesis of an alkylmagnesium amide and interception of a ring-opened isomer of the important utility amide 2,2,6,6-tetramethylpiperidide (TMP)

Synthesis of peracetylated d-galactopyranosylidene dihalides

Synthesis, Structural Elucidation, and Diffusion-Ordered NMR Studies of Homoleptic Alkyllithium Magnesiates: Donor-Controlled Structural Variations in Mixed-Metal Chemistry

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Taming the shrew: [TMEDALi-Zn(C2H4)2L] as a model compound for anionic ethene polymerisation

The Preparation of Tetramethyl 1,1′,3,3′-Ruthenocenetetracarboxylate and Tetramethyl 1,1′,3,3′-Osmocenetetracarboxylate, and a Simplified Synthesis for Tetramethyl 1,1′,3,3′-Ferrocenetetracarboxylate

The hetero-cubane structures of the heavy alkali metal tert-amyloxides [MOCMe2Et]4 (M = K, Rb, Cs)

scientific article published on 01 September 2018

Titelbild: Direct CH Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes (Angew. Chem. 18/2009)

Towards the Next Generation of Lochmann-Schlosser Superbases: A Potassium Neopentyl/Alkoxy Aggregate used in the Tetra-Functionalization of Ferrocene

scientific article published on 12 March 2018

Tuning the Basicity of Synergic Bimetallic Reagents: Switching the Regioselectivity of the Direct Dimetalation of Toluene from 2,5- to 3,5-Positions

Tuning the basicity of synergic bimetallic reagents: switching the regioselectivity of the direct dimetalation of toluene from 2,5- to 3,5-positions

scientific article published on January 2008

Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

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Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?

scientific article published on 2 September 2009