List of works - Inmaculada Fernández

A generalization of the base effect on the diastereoselective synthesis of sulfinic and phosphinic esters

An efficient synthesis of both enantiomers of chiral non racemic methylsulfoxides from DAG

Asymmetric Enamide Hydrogenation Using Phosphinite Thioglycosides: Synthesis ofd- andl-Aminoesters Usingd-Sugars as Catalyst Precursors

scientific article published on 29 July 2008

Asymmetric Rhodium-Catalyzed 1,4- and 1,2-Additions of Arylboronic Acids to Activated Ketones in Water at Room Temperature Using a Mixed Sulfur-Olefin Ligand

article

Asymmetric Synthesis of Alkyl and Aryl Sulfinates of DAG: An Improved and General Route to Both Enantiomerically Pure Sulfoxides

Asymmetric Synthesis of Biologically Active Compounds Bearing a Chiral Sulfinyl Group

Asymmetric synthesis of optically pure tert-butyl sulfoxides using the “DAG methodology”

Asymmetric synthesis of the C-3/C-9 fragment of (−) aspicilin

Asymmetric synthesis of the macrolide (−)-aspicilin

Asymmetric synthesis of β-amino-γ-hydroxysulfoxides

Axial chirality control during Suzuki-Miyaura cross-coupling reactions: the tert-butylsulfinyl group as an efficient chiral auxiliary

scientific article

C 2 -Symmetric Bis-Sulfoxide: Highly Diastereoselective 1,4-Addition to Stabilised Michael Acceptors

C2-Symmetric Bis-Sulfoxides: Synthesis of Both Enantiomers and Utilization in Organometallic Chemistry and in Asymmetric Catalysis

C2-Symmetric Bis-Thioglycosides as Useful Ligands in Palladium-Catalyzed Asymmetric Allylic Alkylation: Synthesis of Both Enantiomers Using Natural Sugars as Ligand Precursors

C2-Symmetric Bissulfoxides as Organocatalysts in the Allylation of Benzoyl Hydrazones: Spacer and Concentration Effects

scientific article published on 03 May 2007

C2-Symmetric bis-sulfoxides as chiral ligands in metal catalysed asymmetric diels-alder reactions

C2-Symmetric bis-thioglycosides as new ligands for palladium-catalyzed allylic substitutions

Chiral sulfur derivatives in the allylation of acyl hydrazones: C(2)-symmetric bis-sulfinamides as enhanced chiral organic promoters

scientific article published on 6 August 2010

Clickable iron oxide NPs based on catechol derived ligands: synthesis and characterization

scientific article published on 01 April 2020

Copper-Catalyzed Azide-Alkyne Cycloaddition in the Synthesis of Polydiacetylene: “Click Glycoliposome” as Biosensors for the Specific Detection of Lectins

scientific article published on 12 January 2011

Design, synthesis and biological studies of a library of NK1-Receptor Ligands Based on a 5-arylthiosubstituted 2-amino-4,6-diaryl-3-cyano-4H-pyran core: Switch from antagonist to agonist effect by chemical modification.

scientific article

Dynamic kinetic transformation of sulfinyl chlorides: synthesis of enantiomerically pure C(2)-symmetric bis-sulfoxides

scientific article published in January 2002

Enantiodivergent Approach to Trifluoromethylated Amines: A Concise Route to Both Enantiomeric Analogues of Calcimimetic NPS R-568

article published in 2010

Enantiopure sulforaphane analogues with various substituents at the sulfinyl sulfur: asymmetric synthesis and biological activities

scientific article published on August 2009

Enantioselective Organocatalytic Oxidation of Functionalized Sterically Hindered Disulfides

scientific article published on 07 March 2007

Flexible C2-Symmetric Bis-Sulfoxides as Ligands in Enantioselective 1,4-Addition of Boronic Acids to Electron-Deficient Alkenes

scientific article published on 24 June 2013

General Method for Asymmetric Synthesis of α-Methylsulfinyl Ketones: Application to the Synthesis of Optically Pure Oxisuran and Bioisosteres

scientific article published on 01 January 1997

Glyconanosomes: disk-shaped nanomaterials for the water solubilization and delivery of hydrophobic molecules.

scientific article published on 5 March 2013

Highly diastereoselective formation of C2-symmetric bis-thioglycoside Pd(ii) complexes: the role of the exo anomeric effect

scientific article published on 16 February 2004

Highly diastereoselective oxidation of 2-amino-2-deoxy-1-thio-beta-D-glucopyranosides: synthesis of imino sulfinylglycosides

scientific article published in February 2003

Improved non-covalent biofunctionalization of multi-walled carbon nanotubes using carbohydrate amphiphiles with a butterfly-like polyaromatic tail

article by Mohyeddin Assali et al published 26 October 2010 in Nano Research

Michael Additions of .alpha.-Sulfinyl and .alpha.-Sulfonyl Carbanions: The Unprecedented Reaction of .beta.-Keto Sulfoxides and .beta.-Keto Sulfones with Highly Stabilized Michael Acceptors

article

Mixed S/P Ligands from Carbohydrates: Synthesis and Utilization in Asymmetric Catalysis

Monodentate phosphites with carbohydrate substituents and their application in rhodium catalysed asymmetric hydrosilylation reactions

N-isopropylsulfinylimines as useful intermediates in the synthesis of chiral amines: expeditive asymmetric synthesis of the calcimimetic (+)-NPS R-568.

scientific article published on 23 December 2007

NMR study on the stabilization and chiral discrimination of sulforaphane enantiomers and analogues by cyclodextrins.

scientific article published on 16 December 2017

Non-covalent functionalization of carbon nanotubes with glycolipids: glyconanomaterials with specific lectin-affinity

P/S ligands derived from carbohydrates in Rh-catalyzed hydrosilylation of ketones

scientific article published on 14 November 2011

Phosphinite Thioglycosides Derived from Natural d-Sugars as Useful P/S Ligands for the Synthesis of Both Enantiomers in Palladium-Catalyzed Asymmetric Substitution

Proline-coated gold nanoparticles as a highly efficient nanocatalyst for the enantioselective direct aldol reaction in water

scholarly article in RSC Advances, vol. 3 no. 12, 2013

Pyrene-tagged carbohydrate-based mixed P/S ligand: spacer effect on the Rh(i)-catalyzed hydrogenation of methyl α-acetamidocinnamate

scientific article published on 29 June 2017

Recent Developments in the Synthesis and Utilization of Chiral Sulfoxides

scientific article published on 01 September 2003

Stereoselective addition of alpha-sulfinyl carbanions to N-p-tolylsulfinylketimines: synthesis of optically pure 1,2,2'-trialkyl-2-aminoethanols

scientific article

Steric Tuning of Sulfinamide/Sulfoxides as Chiral Ligands with C1, Pseudo-meso, and Pseudo-C2 Symmetries: Application in Rhodium(I)-Mediated Arylation

scientific article published on 31 July 2019

Studies on the diastereoselective oxidation of 1-thio-β-D-glucopyranosides: synthesis of the usually less favoured R(S) sulfoxide as a single diastereoisomer.

scientific article published in February 2015

Sulfinamide Phosphinates as Chiral Catalysts for the Enantioselective Organocatalytic Reduction of Imines.

scientific article

Sulforaphane homologues: Enantiodivergent synthesis of both enantiomers, activation of the Nrf2 transcription factor and selective cytotoxic activity

scientific article published on 16 September 2014

Sulfur–Sulfur-Based Ligands Derived fromD-Sugars: Synthesis of PdII Complexes, Application in Palladium-Catalyzed Allylic Alkylation for the Synthesis of Both Members of Enantiomer Pairs, and Structural Studies

Supramolecular Diversity through Click Chemistry: Switching from Nanomicelles to 1D-Nanotubes and Tridimensional Hydrogels

Synthesis and non-covalent functionalization of carbon nanotubes rings: new nanomaterials with lectin affinity

scientific article published on 5 February 2013

Synthesis of 1D-glyconanomaterials by a hybrid noncovalent-covalent functionalization of single wall carbon nanotubes: a study of their selective interactions with lectins and with live cells.

scientific article published on 4 November 2015

Tailoring carbon nanotube surfaces with glyconanorings: new bionanomaterials with specific lectin affinity

scientific article published on 02 June 2009

The Isopropyl- andtert-Butylsulfinyl Groups in Asymmetric Synthesis: A Comparative Study

The Isopropylsulfinyl Group: A Useful Chiral Controller for the Asymmetric Aziridination of Sulfinylimines and the Organocatalytic Allylation of Hydrazones

scientific article published on 01 March 2005

Unprecedented base effect on the synthesis of chiral phosphinate esters: A new route to P-chiral phosphine oxides of high enantiomeric purity

‘ClickCarb’: modular sugar based ligands via click chemistry

article by Noureddine Khiar et al published January 2012 in Tetrahedron Letters

“Sulfolefin”: Highly modular mixed S/Olefin ligands for enantioselective Rh-catalyzed 1,4-addition

scientific article published on 26 January 2012

“Sulfolefin”: a mixed sulfinamido-olefin ligand in enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones

article

List of works by Inmaculada Fernández

A generalization of the base effect on the diastereoselective synthesis of sulfinic and phosphinic esters

An efficient synthesis of both enantiomers of chiral non racemic methylsulfoxides from DAG

Asymmetric Enamide Hydrogenation Using Phosphinite Thioglycosides: Synthesis ofd- andl-Aminoesters Usingd-Sugars as Catalyst Precursors

Asymmetric Rhodium-Catalyzed 1,4- and 1,2-Additions of Arylboronic Acids to Activated Ketones in Water at Room Temperature Using a Mixed Sulfur-Olefin Ligand

Asymmetric Synthesis of Alkyl and Aryl Sulfinates of DAG: An Improved and General Route to Both Enantiomerically Pure Sulfoxides

Asymmetric Synthesis of Biologically Active Compounds Bearing a Chiral Sulfinyl Group

Asymmetric synthesis of optically pure tert-butyl sulfoxides using the “DAG methodology”

Asymmetric synthesis of the C-3/C-9 fragment of (−) aspicilin

Asymmetric synthesis of the macrolide (−)-aspicilin

Asymmetric synthesis of β-amino-γ-hydroxysulfoxides

Axial chirality control during Suzuki-Miyaura cross-coupling reactions: the tert-butylsulfinyl group as an efficient chiral auxiliary

C 2 -Symmetric Bis-Sulfoxide: Highly Diastereoselective 1,4-Addition to Stabilised Michael Acceptors

C2-Symmetric Bis-Sulfoxides: Synthesis of Both Enantiomers and Utilization in Organometallic Chemistry and in Asymmetric Catalysis

C2-Symmetric Bis-Thioglycosides as Useful Ligands in Palladium-Catalyzed Asymmetric Allylic Alkylation: Synthesis of Both Enantiomers Using Natural Sugars as Ligand Precursors

C2-Symmetric Bissulfoxides as Organocatalysts in the Allylation of Benzoyl Hydrazones: Spacer and Concentration Effects

C2-Symmetric bis-sulfoxides as chiral ligands in metal catalysed asymmetric diels-alder reactions

C2-Symmetric bis-thioglycosides as new ligands for palladium-catalyzed allylic substitutions

Chiral sulfur derivatives in the allylation of acyl hydrazones: C(2)-symmetric bis-sulfinamides as enhanced chiral organic promoters

Clickable iron oxide NPs based on catechol derived ligands: synthesis and characterization

Copper-Catalyzed Azide-Alkyne Cycloaddition in the Synthesis of Polydiacetylene: “Click Glycoliposome” as Biosensors for the Specific Detection of Lectins

Design, synthesis and biological studies of a library of NK1-Receptor Ligands Based on a 5-arylthiosubstituted 2-amino-4,6-diaryl-3-cyano-4H-pyran core: Switch from antagonist to agonist effect by chemical modification.

Dynamic kinetic transformation of sulfinyl chlorides: synthesis of enantiomerically pure C(2)-symmetric bis-sulfoxides

Enantiodivergent Approach to Trifluoromethylated Amines: A Concise Route to Both Enantiomeric Analogues of Calcimimetic NPS R-568

Enantiopure sulforaphane analogues with various substituents at the sulfinyl sulfur: asymmetric synthesis and biological activities

Enantioselective Organocatalytic Oxidation of Functionalized Sterically Hindered Disulfides

Flexible C2-Symmetric Bis-Sulfoxides as Ligands in Enantioselective 1,4-Addition of Boronic Acids to Electron-Deficient Alkenes

General Method for Asymmetric Synthesis of α-Methylsulfinyl Ketones: Application to the Synthesis of Optically Pure Oxisuran and Bioisosteres

Glyconanosomes: disk-shaped nanomaterials for the water solubilization and delivery of hydrophobic molecules.

Highly diastereoselective formation of C2-symmetric bis-thioglycoside Pd(ii) complexes: the role of the exo anomeric effect

Highly diastereoselective oxidation of 2-amino-2-deoxy-1-thio-beta-D-glucopyranosides: synthesis of imino sulfinylglycosides

Improved non-covalent biofunctionalization of multi-walled carbon nanotubes using carbohydrate amphiphiles with a butterfly-like polyaromatic tail

Michael Additions of .alpha.-Sulfinyl and .alpha.-Sulfonyl Carbanions: The Unprecedented Reaction of .beta.-Keto Sulfoxides and .beta.-Keto Sulfones with Highly Stabilized Michael Acceptors

Mixed S/P Ligands from Carbohydrates: Synthesis and Utilization in Asymmetric Catalysis

Monodentate phosphites with carbohydrate substituents and their application in rhodium catalysed asymmetric hydrosilylation reactions

N-isopropylsulfinylimines as useful intermediates in the synthesis of chiral amines: expeditive asymmetric synthesis of the calcimimetic (+)-NPS R-568.

NMR study on the stabilization and chiral discrimination of sulforaphane enantiomers and analogues by cyclodextrins.

Non-covalent functionalization of carbon nanotubes with glycolipids: glyconanomaterials with specific lectin-affinity

P/S ligands derived from carbohydrates in Rh-catalyzed hydrosilylation of ketones

Phosphinite Thioglycosides Derived from Natural d-Sugars as Useful P/S Ligands for the Synthesis of Both Enantiomers in Palladium-Catalyzed Asymmetric Substitution

Proline-coated gold nanoparticles as a highly efficient nanocatalyst for the enantioselective direct aldol reaction in water

Pyrene-tagged carbohydrate-based mixed P/S ligand: spacer effect on the Rh(i)-catalyzed hydrogenation of methyl α-acetamidocinnamate

Recent Developments in the Synthesis and Utilization of Chiral Sulfoxides

Stereoselective addition of alpha-sulfinyl carbanions to N-p-tolylsulfinylketimines: synthesis of optically pure 1,2,2'-trialkyl-2-aminoethanols

Steric Tuning of Sulfinamide/Sulfoxides as Chiral Ligands with C1, Pseudo-meso, and Pseudo-C2 Symmetries: Application in Rhodium(I)-Mediated Arylation

Studies on the diastereoselective oxidation of 1-thio-β-D-glucopyranosides: synthesis of the usually less favoured R(S) sulfoxide as a single diastereoisomer.

Sulfinamide Phosphinates as Chiral Catalysts for the Enantioselective Organocatalytic Reduction of Imines.

Sulforaphane homologues: Enantiodivergent synthesis of both enantiomers, activation of the Nrf2 transcription factor and selective cytotoxic activity

Sulfur–Sulfur-Based Ligands Derived fromD-Sugars: Synthesis of PdII Complexes, Application in Palladium-Catalyzed Allylic Alkylation for the Synthesis of Both Members of Enantiomer Pairs, and Structural Studies

Supramolecular Diversity through Click Chemistry: Switching from Nanomicelles to 1D-Nanotubes and Tridimensional Hydrogels

Synthesis and non-covalent functionalization of carbon nanotubes rings: new nanomaterials with lectin affinity

Synthesis of 1D-glyconanomaterials by a hybrid noncovalent-covalent functionalization of single wall carbon nanotubes: a study of their selective interactions with lectins and with live cells.

Tailoring carbon nanotube surfaces with glyconanorings: new bionanomaterials with specific lectin affinity

The Isopropyl- andtert-Butylsulfinyl Groups in Asymmetric Synthesis: A Comparative Study

The Isopropylsulfinyl Group: A Useful Chiral Controller for the Asymmetric Aziridination of Sulfinylimines and the Organocatalytic Allylation of Hydrazones

Unprecedented base effect on the synthesis of chiral phosphinate esters: A new route to P-chiral phosphine oxides of high enantiomeric purity

‘ClickCarb’: modular sugar based ligands via click chemistry

“Sulfolefin”: Highly modular mixed S/Olefin ligands for enantioselective Rh-catalyzed 1,4-addition

“Sulfolefin”: a mixed sulfinamido-olefin ligand in enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones