List of works - Alexander F. Khlebnikov

1-(2H-Azirine-2-carbonyl)benzotriazoles: building blocks for the synthesis of pyrrole-containing heterocycles

scientific article published on 01 March 2020

2 H-Azirines as C-C Annulation Reagents in Cu-Catalyzed Synthesis of Furo[3,2- c]quinolone Derivatives

scientific article published on 07 May 2019

2-Diazoacetyl-2 H-azirines: Source of a Variety of 2 H-Azirine Building Blocks with Orthogonal and Domino Reactivity

scientific article published on 16 July 2018

2H-Azirine-2-carbonyl Azides: Preparation and Use as N-Heterocyclic Building Blocks

scientific article published on 06 March 2020

A Convergent Route to Enantiomerically Pure Higher [n?2]Triangulanedimethanol Derivatives and [n]Triangulanes (n?7)

scientific article published on 01 December 2004

A novel approach to 5H-pyrazino[2,3-b]indoles via annulation of 3-diazoindolin-2-imines with 2H-azirines or 5-alkoxyisoxazoles under Rh(ii) catalysis

scientific article published on 6 December 2017

A novel strategy for the synthesis of 3-(N-heteryl)pyrrole derivatives

scientific article

A novel strategy for the synthesis of thermally stable and apoptosis-inducing 2,3-dihydroazetes.

scientific article published on 19 April 2016

A simple approach to pyrrolylimidazole derivatives by azirine ring expansion with imidazolium ylides.

scientific article published in September 2014

An aza cyclopropylcarbinyl-homoallyl radical rearrangement-radical cyclization cascade. Synthesis of dibenzoimidazoazepine and oxazepine derivatives

scientific article published on 02 June 2011

An efficient approach to azirino and pyrrolo-fused dibenzazepines. Conformations of substituted dibenzo[c,f]pyrrolo[1,2-a]azepines

scientific article published on 04 April 2011

Azirine-containing dipeptides and depsipeptides: synthesis, transformations and antibacterial activity

scientific article published on 10 November 2020

Azirinium ylides from α-diazoketones and 2H-azirines on the route to 2H-1,4-oxazines: three-membered ring opening vs 1,5-cyclization.

scientific article

Bisaziridine tetracarboxylates as building blocks in the stereoselective synthesis of C60-fullerene diads and dumbbell-like bis-C60-fullerene triads

scientific article published on 30 June 2011

Chiral macrocyclic aliphatic oligoimines derived from trans-1,2-diaminocyclohexane

scientific article published on 01 January 2007

Cu(I)-NHC-Catalyzed (2 + 3)-Annulation of Tetramic Acids with 2H-Azirines: Stereoselective Synthesis of Functionalized Hexahydropyrrolo[3,4-b]pyrroles.

scientific article published on 14 August 2015

Cu(II)-catalyzed domino reaction of 2H-azirines with diazotetramic and diazotetronic acids. Synthesis of 2-substituted 2H-1,2,3-triazoles.

scientific article published in September 2013

Dibenzoxazepinium ylides: facile access and 1,3-dipolar cycloaddition reactions

scientific article published on 01 February 2009

Domino reactions of 2H-azirines with acylketenes from furan-2,3-diones: Competition between the formation of ortho-fused and bridged heterocyclic systems

scientific article

Electrophilic cyclization of aryldiacetylenes in the synthesis of functionalized enediynes fused to a heterocyclic core

scientific article published on 15 September 2014

Facile access to 2-acyloxy-, aryloxy- and alkenyloxy-2H-azirines via an SN2'-SN2' cascade in 2-halo-2H-azirines.

scientific article published on 17 April 2018

Fe(II)-Catalyzed Isomerization of 4-Vinylisoxazoles into Pyrroles.

scientific article

Fe(II)-Catalyzed isomerization of 5-chloroisoxazoles to 2H-azirine-2-carbonylchlorides as a key stage in the synthesis of pyrazole-nitrogen heterocycle dyads.

scientific article published on 15 February 2018

Fe(II)/Au(I) Relay Catalyzed Propargylisoxazole to Pyridine Isomerization: Access to 6-Halonicotinates.

scientific article published on 28 April 2017

Fe(II)/Et3N-Relay-catalyzed domino reaction of isoxazoles with imidazolium salts in the synthesis of methyl 4-imidazolylpyrrole-2-carboxylates, its ylide and betaine derivatives

scientific article published on 24 September 2015

Intramolecular cycloaddition of azomethine ylides, from imines of O-acylsalicylic aldehyde and ethyl diazoacetate, to ester carbonyl--experimental and DFT computational study

scientific article published on 21 June 2012

Isoxazole Strategy for the Synthesis of 2,2'-Bipyridine Ligands: Symmetrical and Unsymmetrical 6,6'-Binicotinates, 2,2'-Bipyridine-5-carboxylates, and Their Metal Complexes

scientific article published on 04 March 2019

Isoxazole Strategy for the Synthesis of α-Aminopyrrole Derivatives

scientific article published on 20 August 2019

Isoxazolium N-ylides and 1-oxa-5-azahexa-1,3,5-trienes on the way from isoxazoles to 2H-1,3-oxazines

scientific article published on 14 August 2014

Metal/organo relay catalysis in a one-pot synthesis of methyl 4-aminopyrrole-2-carboxylates from 5-methoxyisoxazoles and pyridinium ylides

scientific article published in October 2015

Metalated Ir(III) Complexes Based on the Luminescent Diimine Ligands: Synthesis and Photophysical Study

scientific article published on 29 May 2018

NHC as the Guiding Factor in a Copper-Catalyzed Intramolecular C Arylation of Pyrrolylimidazolium Salts: Synthesis of Luminescent Heterotetracyclic Frameworks

scientific article published on 21 December 2016

Non-pericyclic cycloaddition of gem-difluorosubstituted azomethine ylides to the C[double bond, length as m-dash]O bond: computational study and synthesis of fluorinated oxazole derivatives

scientific article

Nonconcerted cycloaddition of 2H-azirines to acylketenes: a route to N-bridgehead heterocycles

scientific article published on 18 October 2011

Novel 3-(1H-indol-3-yl)-2-[3-(4-methoxyphenyl)ureido]propanamides as selective agonists of human formyl-peptide receptor 2

scientific article published on 13 December 2014

Novel homogeneous photocatalyst for oxygen to hydrogen peroxide reduction in aqueous media

scientific article published on 25 June 2019

PEG-modified aziridines for stereoselective synthesis of water-soluble fulleropyrrolidines

scientific article published on 01 November 2019

Photocurrent in Multilayered Assemblies of Porphyrin-Fullerene Covalent Dyads: Evidence for Channels for Charge Transport.

scientific article

Pseudopericyclic 1,5- versus Pericyclic 1,4- and 1,6-Electrocyclization in Electron-Poor 4-Aryl-2-azabuta-1,3-dienes: Indole Synthesis from 2H-Azirines and Diazo Compounds

scientific article published on 09 December 2014

Regiodivergent Synthesis of Butenolide-Based α- and β-Amino Acid Derivatives via Base-Controlled Azirine Ring Expansion

scientific article published on 31 March 2020

Relative Reactivity of Benzothiophene-Fused Enediynes in the Bergman Cyclization

scientific article published on 5 February 2018

Rh(II)-Catalyzed Ring Expansion of Pyrazoles with Diazocarbonyl Compounds as a Method for the Preparation of 1,2-Dihydropyrimidines

scientific article published on 28 June 2018

Rh(II)-Catalyzed Transannulation of 1,2,4-Oxadiazole Derivatives with 1-Sulfonyl-1,2,3-triazoles: Regioselective Synthesis of 5-Sulfonamidoimidazoles

scientific article published on 27 August 2018

Ring-Closing Metathesis of Co2(CO)6-Alkyne Complexes for the Synthesis of 11-Membered Dienediynes: Overcoming Thermodynamic Barriers.

scientific article published on 18 May 2015

Selective Cu-Catalyzed Intramolecular Annulation of 3-Aryl/Heteryl-2-(diazoacetyl)-1H-pyrroles: Synthesis of Benzo/Furo/Thieno[e]-Fused 1H-Indol-7-oles and Their Transformations

scientific article published on 26 July 2019

Selective transannular ring transformations in azirino-fused eight-membered O,N- or S,N-heterocycles

scientific article published on 17 October 2005

Stereoselective cycloaddition of dibenzoxazepinium ylides to acetylenes and fullerene C60. Conformational behavior of 3-aryldibenzo[b,f]pyrrolo[1,2-d][1,4]oxazepine systems

scientific article published on August 2010

Switchable Synthesis of Pyrroles and Pyrazines via Rh(II)-Catalyzed Reaction of 1,2,3-Triazoles with Isoxazoles: Experimental and DFT Evidence for the 1,4-Diazahexatriene Intermediate

scientific article

Syntheses and properties of enantiomerically pure higher (n > or = 7) [n-2]triangulanedimethanols and sigma-[n]helicenes

scientific article

Synthesis and spectroscopic and electrochemical properties of an axially symmetric fullerene-porphyrin dyad with a rigid pyrrolo[3,4-c]pyrrole spacer

scientific article published on 21 February 2013

Synthesis of 1,2-Dihydropyrimidine-2-carboxylates via Regioselective Addition of Rhodium(II) Carbenoids to 2H-Azirine-2-carbaldimines

scientific article published on 13 November 2017

Synthesis of 1-(2-Aminovinyl)indoles and 1,3'-Biindoles by Reaction of 2,2-Diaryl-Substituted 2 H-Azirines with α-Imino Rh(II) Carbenoids

scientific article published on 31 January 2019

Synthesis of 2-(Di/tri/tetraazolyl)-2 H-azirine-2-carboxylates by Halogen Substitution: Evidence for an S2'-S2' Cascade Mechanism

scientific article published on 18 October 2018

Synthesis of 3-Alkoxy-4-Pyrrolin-2-ones via Rhodium(II)-Catalyzed Denitrogenative Transannulation of 1H-1,2,3-Triazoles with Diazo Esters

scientific article published on 07 October 2020

Synthesis of Bi-, Ter-, and Quaterpyridinecarboxylates via Propargylisoxazole-Pyridine Rearrangement

scientific article published on 08 April 2020

Synthesis of Isoxazole- and Oxazole-4-carboxylic Acids Derivatives by Controlled Isoxazole-Azirine-Isoxazole/Oxazole Isomerization

scientific article published on 07 November 2019

Synthesis of Pyrrolotriazoloisoquinoline Frameworks by Intramolecular Cu-Mediated or Free Radical Arylation of Triazoles

scientific article

Synthesis of new porphyrin-fullerene dyads capable of forming charge-separated states on a microsecond lifetime scale

scientific article

The First Enantiomerically Pure Triangulane (M)-Trispiro

scientific article published on 01 December 1999

The first enantiomerically pure [n]triangulanes and analogues: sigma-[n]helicenes with remarkable features

scientific article published in February 2002

Thiazol-4-one derivatives from the reaction of monosubstituted thioureas with maleimides: structures and factors determining the selectivity and tautomeric equilibrium in solution.

scientific article published on 29 November 2016

[2 + 1 + 1] Assembly of spiro β-lactams by Rh(ii)-catalyzed reaction of diazocarbonyl compounds with azirines/isoxazoles

scientific article published on 01 July 2019

List of works by Alexander F. Khlebnikov

1-(2H-Azirine-2-carbonyl)benzotriazoles: building blocks for the synthesis of pyrrole-containing heterocycles

2 H-Azirines as C-C Annulation Reagents in Cu-Catalyzed Synthesis of Furo[3,2- c]quinolone Derivatives

2-Diazoacetyl-2 H-azirines: Source of a Variety of 2 H-Azirine Building Blocks with Orthogonal and Domino Reactivity

2H-Azirine-2-carbonyl Azides: Preparation and Use as N-Heterocyclic Building Blocks

A Convergent Route to Enantiomerically Pure Higher [n?2]Triangulanedimethanol Derivatives and [n]Triangulanes (n?7)

A novel approach to 5H-pyrazino[2,3-b]indoles via annulation of 3-diazoindolin-2-imines with 2H-azirines or 5-alkoxyisoxazoles under Rh(ii) catalysis

A novel strategy for the synthesis of 3-(N-heteryl)pyrrole derivatives

A novel strategy for the synthesis of thermally stable and apoptosis-inducing 2,3-dihydroazetes.

A simple approach to pyrrolylimidazole derivatives by azirine ring expansion with imidazolium ylides.

An aza cyclopropylcarbinyl-homoallyl radical rearrangement-radical cyclization cascade. Synthesis of dibenzoimidazoazepine and oxazepine derivatives

An efficient approach to azirino and pyrrolo-fused dibenzazepines. Conformations of substituted dibenzo[c,f]pyrrolo[1,2-a]azepines

Azirine-containing dipeptides and depsipeptides: synthesis, transformations and antibacterial activity

Azirinium ylides from α-diazoketones and 2H-azirines on the route to 2H-1,4-oxazines: three-membered ring opening vs 1,5-cyclization.

Bisaziridine tetracarboxylates as building blocks in the stereoselective synthesis of C60-fullerene diads and dumbbell-like bis-C60-fullerene triads

Chiral macrocyclic aliphatic oligoimines derived from trans-1,2-diaminocyclohexane

Cu(I)-NHC-Catalyzed (2 + 3)-Annulation of Tetramic Acids with 2H-Azirines: Stereoselective Synthesis of Functionalized Hexahydropyrrolo[3,4-b]pyrroles.

Cu(II)-catalyzed domino reaction of 2H-azirines with diazotetramic and diazotetronic acids. Synthesis of 2-substituted 2H-1,2,3-triazoles.

Dibenzoxazepinium ylides: facile access and 1,3-dipolar cycloaddition reactions

Domino reactions of 2H-azirines with acylketenes from furan-2,3-diones: Competition between the formation of ortho-fused and bridged heterocyclic systems

Electrophilic cyclization of aryldiacetylenes in the synthesis of functionalized enediynes fused to a heterocyclic core

Facile access to 2-acyloxy-, aryloxy- and alkenyloxy-2H-azirines via an SN2'-SN2' cascade in 2-halo-2H-azirines.

Fe(II)-Catalyzed Isomerization of 4-Vinylisoxazoles into Pyrroles.

Fe(II)-Catalyzed isomerization of 5-chloroisoxazoles to 2H-azirine-2-carbonylchlorides as a key stage in the synthesis of pyrazole-nitrogen heterocycle dyads.

Fe(II)/Au(I) Relay Catalyzed Propargylisoxazole to Pyridine Isomerization: Access to 6-Halonicotinates.

Fe(II)/Et3N-Relay-catalyzed domino reaction of isoxazoles with imidazolium salts in the synthesis of methyl 4-imidazolylpyrrole-2-carboxylates, its ylide and betaine derivatives

Intramolecular cycloaddition of azomethine ylides, from imines of O-acylsalicylic aldehyde and ethyl diazoacetate, to ester carbonyl--experimental and DFT computational study

Isoxazole Strategy for the Synthesis of 2,2'-Bipyridine Ligands: Symmetrical and Unsymmetrical 6,6'-Binicotinates, 2,2'-Bipyridine-5-carboxylates, and Their Metal Complexes

Isoxazole Strategy for the Synthesis of α-Aminopyrrole Derivatives

Isoxazolium N-ylides and 1-oxa-5-azahexa-1,3,5-trienes on the way from isoxazoles to 2H-1,3-oxazines

Metal/organo relay catalysis in a one-pot synthesis of methyl 4-aminopyrrole-2-carboxylates from 5-methoxyisoxazoles and pyridinium ylides

Metalated Ir(III) Complexes Based on the Luminescent Diimine Ligands: Synthesis and Photophysical Study

NHC as the Guiding Factor in a Copper-Catalyzed Intramolecular C Arylation of Pyrrolylimidazolium Salts: Synthesis of Luminescent Heterotetracyclic Frameworks

Non-pericyclic cycloaddition of gem-difluorosubstituted azomethine ylides to the C[double bond, length as m-dash]O bond: computational study and synthesis of fluorinated oxazole derivatives

Nonconcerted cycloaddition of 2H-azirines to acylketenes: a route to N-bridgehead heterocycles

Novel 3-(1H-indol-3-yl)-2-[3-(4-methoxyphenyl)ureido]propanamides as selective agonists of human formyl-peptide receptor 2

Novel homogeneous photocatalyst for oxygen to hydrogen peroxide reduction in aqueous media

PEG-modified aziridines for stereoselective synthesis of water-soluble fulleropyrrolidines

Photocurrent in Multilayered Assemblies of Porphyrin-Fullerene Covalent Dyads: Evidence for Channels for Charge Transport.

Pseudopericyclic 1,5- versus Pericyclic 1,4- and 1,6-Electrocyclization in Electron-Poor 4-Aryl-2-azabuta-1,3-dienes: Indole Synthesis from 2H-Azirines and Diazo Compounds

Regiodivergent Synthesis of Butenolide-Based α- and β-Amino Acid Derivatives via Base-Controlled Azirine Ring Expansion

Relative Reactivity of Benzothiophene-Fused Enediynes in the Bergman Cyclization

Rh(II)-Catalyzed Ring Expansion of Pyrazoles with Diazocarbonyl Compounds as a Method for the Preparation of 1,2-Dihydropyrimidines

Rh(II)-Catalyzed Transannulation of 1,2,4-Oxadiazole Derivatives with 1-Sulfonyl-1,2,3-triazoles: Regioselective Synthesis of 5-Sulfonamidoimidazoles

Ring-Closing Metathesis of Co2(CO)6-Alkyne Complexes for the Synthesis of 11-Membered Dienediynes: Overcoming Thermodynamic Barriers.

Selective Cu-Catalyzed Intramolecular Annulation of 3-Aryl/Heteryl-2-(diazoacetyl)-1H-pyrroles: Synthesis of Benzo/Furo/Thieno[e]-Fused 1H-Indol-7-oles and Their Transformations

Selective transannular ring transformations in azirino-fused eight-membered O,N- or S,N-heterocycles

Stereoselective cycloaddition of dibenzoxazepinium ylides to acetylenes and fullerene C60. Conformational behavior of 3-aryldibenzo[b,f]pyrrolo[1,2-d][1,4]oxazepine systems

Switchable Synthesis of Pyrroles and Pyrazines via Rh(II)-Catalyzed Reaction of 1,2,3-Triazoles with Isoxazoles: Experimental and DFT Evidence for the 1,4-Diazahexatriene Intermediate

Syntheses and properties of enantiomerically pure higher (n > or = 7) [n-2]triangulanedimethanols and sigma-[n]helicenes

Synthesis and spectroscopic and electrochemical properties of an axially symmetric fullerene-porphyrin dyad with a rigid pyrrolo[3,4-c]pyrrole spacer

Synthesis of 1,2-Dihydropyrimidine-2-carboxylates via Regioselective Addition of Rhodium(II) Carbenoids to 2H-Azirine-2-carbaldimines

Synthesis of 1-(2-Aminovinyl)indoles and 1,3'-Biindoles by Reaction of 2,2-Diaryl-Substituted 2 H-Azirines with α-Imino Rh(II) Carbenoids

Synthesis of 2-(Di/tri/tetraazolyl)-2 H-azirine-2-carboxylates by Halogen Substitution: Evidence for an S2'-S2' Cascade Mechanism

Synthesis of 3-Alkoxy-4-Pyrrolin-2-ones via Rhodium(II)-Catalyzed Denitrogenative Transannulation of 1H-1,2,3-Triazoles with Diazo Esters

Synthesis of Bi-, Ter-, and Quaterpyridinecarboxylates via Propargylisoxazole-Pyridine Rearrangement

Synthesis of Isoxazole- and Oxazole-4-carboxylic Acids Derivatives by Controlled Isoxazole-Azirine-Isoxazole/Oxazole Isomerization

Synthesis of Pyrrolotriazoloisoquinoline Frameworks by Intramolecular Cu-Mediated or Free Radical Arylation of Triazoles

Synthesis of new porphyrin-fullerene dyads capable of forming charge-separated states on a microsecond lifetime scale

The First Enantiomerically Pure Triangulane (M)-Trispiro

The first enantiomerically pure [n]triangulanes and analogues: sigma-[n]helicenes with remarkable features

Thiazol-4-one derivatives from the reaction of monosubstituted thioureas with maleimides: structures and factors determining the selectivity and tautomeric equilibrium in solution.

[2 + 1 + 1] Assembly of spiro β-lactams by Rh(ii)-catalyzed reaction of diazocarbonyl compounds with azirines/isoxazoles