List of works - George N. Khairallah

A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates.

scientific article

Activation of the C–I and C–OH bonds of 2-iodoethanol by gas phase silver cluster cations yields subvalent silver-iodide and -hydroxide cluster cations

scientific article published on 17 May 2007

C-C bond coupling between the organometallic cations CH3Ag2+, CH3Cu2+ and CH3AgCu+ and allyliodide.

scientific article

C-F bond activation of trifluoroethanol and trifluoroacetic acid catalysed by the dimolybdate anion, [Mo2O6(F)]- †.

scientific article

Competition between cluster fragmentation, C-C bond coupling and C-X bond activation in silver hexynyl cluster cations, [(C(4)H(9)CCAg)(n)Ag](+). Size does matter!

scientific article

Copper mediated decyano decarboxylative coupling of cyanoacetate ligands: Pesci versus Lewis acid mechanism

scientific article published on 01 May 2015

Copper(I)-catalyzed cycloaddition of silver acetylides and azides: incorporation of volatile acetylenes into the triazole core

scientific article

Decarboxylative-Coupling of Allyl Acetate Catalyzed by Group 10 Organometallics, [(phen)M(CH3)]+

article

Fixed-charge labels for simplified reaction analysis: 5-hydroxy-1,2,3-triazoles as byproducts of a copper(I)-catalyzed click reaction

article

Fixed-charge phosphine ligands to explore gas-phase coinage metal-mediated decarboxylation reactions.

scientific article published in May 2013

Formation and characterisation of the silver hydride nanocluster cation [Ag3H2((Ph2 P)2CH2)](+) and its release of hydrogen

scientific article

Fragmentation of the tryptophan cluster [Trp9-2H]2- induced by different activation methods.

scientific article published on November 2010

Gas phase fragmentation of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-: aldehyde structure dictates the nature of the products

scientific article published on 16 July 2009

Gas phase supramolecular cluster ions of deoxyguanosine induced by binding to (2,2':6'2''-terpyridine)-platinum(II) and (diethylenetriamine)-platinum(II).

scientific article published on 19 January 2009

Gas phase synthesis and reactivity of Agn+ and Ag(n-1)H+ cluster cations

scientific article published on 8 July 2005

Gas phase synthesis and reactivity of dimethylaurate

scientific article published on 12 August 2010

Gas phase synthesis, structure and unimolecular reactivity of silver iodide cluster cations, Ag(n)I(m)(+) (n = 2-5, 0 < m < n).

scientific article published on 28 April 2008

Gas-Phase Formation of the Gomberg-Bachmann Magnesium Ketyl

scientific article published on 01 January 2008

Gas-Phase and Computational Study of Identical Nickel- and Palladium-Mediated Organic Transformations Where Mechanisms Proceeding via M(II) or M(IV) Oxidation States Are Determined by Ancillary Ligands

scientific article published on 15 October 2015

Gas-phase VUV photoionisation and photofragmentation of the silver deuteride nanocluster [Ag10D8L6]2+ (L = bis(diphenylphosphino)methane). A joint experimental and theoretical study

scientific article published on 01 October 2015

Gas-phase formation and reactions of radical cations of guanosine, deoxyguanosine and their homodimers and heterodimers

article published in 2011

Gas-phase infrared spectrum and acidity of the radical cation of 9-methylguanine.

scientific article

Gas-phase reactions of [VO2(OH)2]- and [V2O5(OH)]- with methanol: experiment and theory.

scientific article published on 13 August 2012

Gas-phase reactions of aryl radicals with 2-butyne: experimental and theoretical investigation employing the N-methyl-pyridinium-4-yl radical cation

scientific article published on 16 January 2012

Gas-phase structure and reactivity of the keto tautomer of the deoxyguanosine radical cation

scientific article published on 01 October 2015

Gas-phase synthesis and reactivity of binuclear gold hydride cations, (R3PAu)2H+ (R = Me and Ph).

scientific article published on 2 June 2006

Gas-phase synthesis and reactivity of the lithium acetate enolate anion, -CH2CO2Li

scientific article published in January 2009

Gas-phase synthesis of [Ag4H]+ and its mediation of the C--C coupling of allyl bromide

scientific article published in January 2005

Gas-phase synthesis of the homo and hetero organocuprate anions [MeCuMe]-, [EtCuEt]-, and [MeCuR]-.

scientific article published in January 2008

Gold-Mediated CI Bond Activation of Iodobenzene

scientific article published on 16 February 2012

Halide-ion-templated Ag8Cu6 rhombic dodecahedrons: synthesis, structure and reactivity of [Ag8Cu6(CCtBu)12X]BF4 (X = Cl, Br)

scientific article published on 01 April 2013

Interaction of cisplatin and analogue Pt(en)Cl2 with the copper metallo-chaperone Atox1.

scientific article published in August 2013

Interaction of cisplatin and analogues with a Met-rich protein site.

scientific article published on 26 November 2008

Intercluster Reactions Show That (CH3)2S+CH2CO2H is a Better Methyl Cation Donor Than (CH3)3N+CH2CO2H

scientific article published on 01 January 2011

Internal Energy Deposition in Dielectric Barrier Discharge Ionization is Significantly Lower than in Direct Analysis in Real-Time Mass Spectrometry

scientific article published in 2017

Leishmania beta-1,2-mannan is assembled on a mannose-cyclic phosphate primer.

scholarly article

Letter: Silver mediated ester bond formation in the gas phase: substrate structure is important.

scientific article

Letter: intercluster chemistry of protonated and sodiated betaine dimers upon collision induced dissociation and electron induced dissociation.

scientific article published in January 2008

Ligand-induced substrate steering and reshaping of [Ag2(H)](+) scaffold for selective CO2 extrusion from formic acid

scientific article published on 06 June 2016

MR1 presents microbial vitamin B metabolites to MAIT cells

scientific article

Mass spectrometric and computational studies on the reaction of aromatic peroxyl radicals with phenylacetylene using the distonic radical ion approach.

scientific article published on 23 April 2014

Molecular salt effects in the gas phase: tuning the kinetic basicity of [HCCLiCl]⁻ and [HCCMgCl₂]⁻ by LiCl and MgCl₂.

scientific article published on 30 July 2014

Mononuclear metavanadate catalyses gas phase oxidation of methanol to formaldehyde employing dioxygen as the terminal oxidant

scientific article published on 01 November 2006

Nitrogen adduction by three coordinate group 10 organometallic cations: platinum is favoured over nickel and palladium

scientific article published on 01 July 2011

Radical Formation in the Gas-Phase Ozonolysis of Deprotonated Cysteine

scientific article published on 3 September 2015

Reaction of Aromatic Peroxyl Radicals with Alkynes: A Mass Spectrometric and Computational Study Using the Distonic Radical Ion Approach

article

Seleniranium Ions Undergo π-Ligand Exchange via an Associative Mechanism in the Gas Phase.

scientific article

Structure and unimolecular chemistry of protonated sulfur betaines, (CH3)2S+(CH2)nCO2H (n = 1 and 2)

scientific article published on 28 February 2011

Synthesis, Structural Characterization, and Gas-Phase Unimolecular Reactivity of the Silver Hydride Nanocluster [Ag3((PPh2)2CH2)3(μ3-H)](BF4)2

scientific article published on 03 July 2014

Synthesis, structural elucidation, and biochemical analysis of immunoactive glucuronosyl diacylglycerides of mycobacteria and corynebacteria

scientific article published on 30 January 2013

Synthesis, structure and gas-phase reactivity of a silver hydride complex [Ag3{(PPh2)2CH2}3(μ3-H)(μ3-Cl)]BF4.

scientific article

The effective temperature of ions stored in a linear quadrupole ion trap mass spectrometer.

scientific article published on 20 April 2013

The role of peroxyl radicals in polyester degradation--a mass spectrometric product and kinetic study using the distonic radical ion approach

scientific article published on 11 March 2015

Two Spin-State Reactivity in the Activation and Cleavage of CO2 by [ReO2](.).

scientific article published on 11 May 2016

Unimolecular Chemistry of Doubly Protonated Zwitterionic Clusters

scientific article published on 07 April 2011

Using distonic radical ions to probe the chemistry of key combustion intermediates: the case of the benzoxyl radical anion.

scientific article published on 20 March 2013

Watson-Crick Base Pair Radical Cation as a Model for Oxidative Damage in DNA.

scientific article published on 19 June 2017

sp-sp3 coupling reactions of alkynylsilver cations, RC≡CAg2+ (R = Me and Ph) with allyliodide

scientific article published in July 2013

List of works by George N. Khairallah

A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates.

Activation of the C–I and C–OH bonds of 2-iodoethanol by gas phase silver cluster cations yields subvalent silver-iodide and -hydroxide cluster cations

C-C bond coupling between the organometallic cations CH3Ag2+, CH3Cu2+ and CH3AgCu+ and allyliodide.

C-F bond activation of trifluoroethanol and trifluoroacetic acid catalysed by the dimolybdate anion, [Mo2O6(F)]- †.

Competition between cluster fragmentation, C-C bond coupling and C-X bond activation in silver hexynyl cluster cations, [(C(4)H(9)CCAg)(n)Ag](+). Size does matter!

Copper mediated decyano decarboxylative coupling of cyanoacetate ligands: Pesci versus Lewis acid mechanism

Copper(I)-catalyzed cycloaddition of silver acetylides and azides: incorporation of volatile acetylenes into the triazole core

Decarboxylative-Coupling of Allyl Acetate Catalyzed by Group 10 Organometallics, [(phen)M(CH3)]+

Fixed-charge labels for simplified reaction analysis: 5-hydroxy-1,2,3-triazoles as byproducts of a copper(I)-catalyzed click reaction

Fixed-charge phosphine ligands to explore gas-phase coinage metal-mediated decarboxylation reactions.

Formation and characterisation of the silver hydride nanocluster cation [Ag3H2((Ph2 P)2CH2)](+) and its release of hydrogen

Fragmentation of the tryptophan cluster [Trp9-2H]2- induced by different activation methods.

Gas phase fragmentation of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-: aldehyde structure dictates the nature of the products

Gas phase supramolecular cluster ions of deoxyguanosine induced by binding to (2,2':6'2''-terpyridine)-platinum(II) and (diethylenetriamine)-platinum(II).

Gas phase synthesis and reactivity of Agn+ and Ag(n-1)H+ cluster cations

Gas phase synthesis and reactivity of dimethylaurate

Gas phase synthesis, structure and unimolecular reactivity of silver iodide cluster cations, Ag(n)I(m)(+) (n = 2-5, 0 < m < n).

Gas-Phase Formation of the Gomberg-Bachmann Magnesium Ketyl

Gas-Phase and Computational Study of Identical Nickel- and Palladium-Mediated Organic Transformations Where Mechanisms Proceeding via M(II) or M(IV) Oxidation States Are Determined by Ancillary Ligands

Gas-phase VUV photoionisation and photofragmentation of the silver deuteride nanocluster [Ag10D8L6]2+ (L = bis(diphenylphosphino)methane). A joint experimental and theoretical study

Gas-phase formation and reactions of radical cations of guanosine, deoxyguanosine and their homodimers and heterodimers

Gas-phase infrared spectrum and acidity of the radical cation of 9-methylguanine.

Gas-phase reactions of [VO2(OH)2]- and [V2O5(OH)]- with methanol: experiment and theory.

Gas-phase reactions of aryl radicals with 2-butyne: experimental and theoretical investigation employing the N-methyl-pyridinium-4-yl radical cation

Gas-phase structure and reactivity of the keto tautomer of the deoxyguanosine radical cation

Gas-phase synthesis and reactivity of binuclear gold hydride cations, (R3PAu)2H+ (R = Me and Ph).

Gas-phase synthesis and reactivity of the lithium acetate enolate anion, -CH2CO2Li

Gas-phase synthesis of [Ag4H]+ and its mediation of the C--C coupling of allyl bromide

Gas-phase synthesis of the homo and hetero organocuprate anions [MeCuMe]-, [EtCuEt]-, and [MeCuR]-.

Gold-Mediated CI Bond Activation of Iodobenzene

Halide-ion-templated Ag8Cu6 rhombic dodecahedrons: synthesis, structure and reactivity of [Ag8Cu6(CCtBu)12X]BF4 (X = Cl, Br)

Interaction of cisplatin and analogue Pt(en)Cl2 with the copper metallo-chaperone Atox1.

Interaction of cisplatin and analogues with a Met-rich protein site.

Intercluster Reactions Show That (CH3)2S+CH2CO2H is a Better Methyl Cation Donor Than (CH3)3N+CH2CO2H

Internal Energy Deposition in Dielectric Barrier Discharge Ionization is Significantly Lower than in Direct Analysis in Real-Time Mass Spectrometry

Leishmania beta-1,2-mannan is assembled on a mannose-cyclic phosphate primer.

Letter: Silver mediated ester bond formation in the gas phase: substrate structure is important.

Letter: intercluster chemistry of protonated and sodiated betaine dimers upon collision induced dissociation and electron induced dissociation.

Ligand-induced substrate steering and reshaping of [Ag2(H)](+) scaffold for selective CO2 extrusion from formic acid

MR1 presents microbial vitamin B metabolites to MAIT cells

Mass spectrometric and computational studies on the reaction of aromatic peroxyl radicals with phenylacetylene using the distonic radical ion approach.

Molecular salt effects in the gas phase: tuning the kinetic basicity of [HCCLiCl]⁻ and [HCCMgCl₂]⁻ by LiCl and MgCl₂.

Mononuclear metavanadate catalyses gas phase oxidation of methanol to formaldehyde employing dioxygen as the terminal oxidant

Nitrogen adduction by three coordinate group 10 organometallic cations: platinum is favoured over nickel and palladium

Radical Formation in the Gas-Phase Ozonolysis of Deprotonated Cysteine

Reaction of Aromatic Peroxyl Radicals with Alkynes: A Mass Spectrometric and Computational Study Using the Distonic Radical Ion Approach

Seleniranium Ions Undergo π-Ligand Exchange via an Associative Mechanism in the Gas Phase.

Structure and unimolecular chemistry of protonated sulfur betaines, (CH3)2S+(CH2)nCO2H (n = 1 and 2)

Synthesis, Structural Characterization, and Gas-Phase Unimolecular Reactivity of the Silver Hydride Nanocluster [Ag3((PPh2)2CH2)3(μ3-H)](BF4)2

Synthesis, structural elucidation, and biochemical analysis of immunoactive glucuronosyl diacylglycerides of mycobacteria and corynebacteria

Synthesis, structure and gas-phase reactivity of a silver hydride complex [Ag3{(PPh2)2CH2}3(μ3-H)(μ3-Cl)]BF4.

The effective temperature of ions stored in a linear quadrupole ion trap mass spectrometer.

The role of peroxyl radicals in polyester degradation--a mass spectrometric product and kinetic study using the distonic radical ion approach

Two Spin-State Reactivity in the Activation and Cleavage of CO2 by [ReO2](.).

Unimolecular Chemistry of Doubly Protonated Zwitterionic Clusters

Using distonic radical ions to probe the chemistry of key combustion intermediates: the case of the benzoxyl radical anion.

Watson-Crick Base Pair Radical Cation as a Model for Oxidative Damage in DNA.

sp-sp3 coupling reactions of alkynylsilver cations, RC≡CAg2+ (R = Me and Ph) with allyliodide