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List of works by Vadim Kukushkin

(Isocyano Group π-Hole)⋅⋅⋅[d z2 -MII ] Interactions of (Isocyanide)[MII ] Complexes, in which Positively Charged Metal Centers (d8 -M=Pt, Pd) Act as Nucleophiles

scientific article published on 30 May 2019

1,3-Dipolar Cycloaddition of Nitrones to a Nitrile Functionality in closo-Decaborate Clusters: A Novel Reactivity Mode for the Borylated C≡N Group

1,3-Dipolar cycloaddition of nitrone-type dipoles to uncomplexed and metal-bound substrates bearing the CN triple bond

3-Dialkylamino-1,2,4-triazoles via ZnII-Catalyzed Acyl Hydrazide-Dialkylcyanamide Coupling

scientific article published on 03 July 2018

A Palladium(II) Center Activates Nitrile Ligands toward 1,3-Dipolar Cycloaddition of Nitrones Substantially More than the Corresponding Platinum(II) Center

scientific article published on 11 October 2012

A new family of luminescent compounds: platinum(II) imidoylamidinates exhibiting pH-dependent room temperature luminescence.

scientific article

A novel family of homoleptic copper(i) complexes featuring disubstituted cyanamides: a combined synthetic, structural, and theoretical study

Additions to metal-activated organonitriles

scientific article published on 01 May 2002

Amidines derived from Pt(IV)-mediated nitrile-amino alcohol coupling and their Zn(II)-catalyzed conversion into oxazolines.

scientific article published in April 2003

Amidoximes Provide Facile Platinum(II)-Mediated Oxime–Nitrile Coupling

scientific article published on 08 May 2012

Amidrazone Complexes from a Cascade Platinum(II)-Mediated Reaction between Amidoximes and Dialkylcyanamides

scientific article published on 20 May 2013

An efficient synthesis of phthalocyanines based on an unprecedented double-addition of oximes to phthalonitriles.

scientific article published in November 2004

Anionic halide···alcohol clusters in the solid state

scientific article published on 23 September 2014

Azametallacycles from Ag(I)- or Cu(II)-promoted coupling reactions of dialkylcyanamides with oximes at Pt(II).

scientific article published in March 2001

Bifunctional Reactivity of Amidoximes Observed upon Nucleophilic Addition to Metal-Activated Nitriles

article

Borylated Tetrazoles from Cycloaddition of Azide Anions to Nitrilium Derivatives of closo-Decaborate Clusters

Cleavage of acyclic diaminocarbene ligands at an iridium(iii) center. Recognition of a new reactivity mode for carbene ligands

scientific article published on 29 April 2019

Coordination chemistry of dialkylcyanamides: Binding properties, synthesis of metal complexes, and ligand reactivity

Copper(I)-Catalyzed 1,3-Dipolar Cycloaddition of Ketonitrones to Dialkylcyanamides: A Step toward Sustainable Generation of 2,3-Dihydro-1,2,4-oxadiazoles

scientific article published on 10 April 2017

Copper-mediated imine-nitrile coupling leading to unsymmetric 1,3,5-triazapentadienato complexes containing the incorporated iminoisoindolin-1-one moiety.

scientific article published on 18 August 2008

Coupling of Azomethine Ylides with Nitrilium Derivatives ofcloso-Decaborate Clusters: A Synthetic and Theoretical Study

Coupling of platinated triguanides with platinum-activated nitriles as a novel strategy for generation of dimetallic systems.

scientific article published in April 2015

Dialkylcyanamides are more reactive substrates toward metal-mediated nucleophilic addition than alkylcyanides

article

Dihalomethanes as Bent Bifunctional XB/XB-Donating Building Blocks for Construction of Metal-involving Halogen Bonded Hexagons

scientific article published on 23 October 2019

Diplatinum(III) [Cl2(μ2-amidinate)4] compound derived from air oxidation of mononuclear cis-[PtII(NH3)2(amidine-κ1)2]2+ complex

Direct addition of alcohols to organonitriles activated by ligation to a platinum(IV) center.

scientific article

Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding

scientific article published on 29 August 2018

Electrophilic-Nucleophilic Dualism of Nickel(II) toward Ni···I Noncovalent Interactions: Semicoordination of Iodine Centers via Electron Belt and Halogen Bonding via σ-Hole.

scientific article published on 25 October 2017

Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2-Amino-1,3-Oxazoles

scientific article published on 02 July 2015

Facile Ni(II)/ketoxime-mediated conversion of organonitriles into imidoylamidine ligands. Synthesis of imidoylamidines and acetyl amides.

scientific article published in November 2003

Facile and Reversible 1,3-Dipolar Cycloaddition of Aryl Ketonitrones to Platinum(II)-Bound Nitriles: Synthetic, Structural, and Theoretical Studies

article by Andreii S. Kritchenkov et al published 29 December 2011 in Organometallics

Facile base-free addition of methanol to PtII-activated nitriles. X-ray structure of a platinum(II) complex bearing unsymmetrical N-bound urea

article

First example of the solid-state thermal cyclometalation of ligated benzophenone imine giving novel luminescent platinum(II) species.

scientific article

Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding

scientific article published on 28 August 2019

Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls

scientific article published on 15 May 2019

Gold-Catalyzed Hydrohydrazidation of Terminal Alkynes

scientific article published on 07 August 2018

Guanidine platinum(II) complexes: synthesis, in vitro antitumor activity, and DNA interactions.

scientific article published on 22 December 2013

Halides Held by Bifurcated Chalcogen-Hydrogen Bonds. Effect of μ(S,N-H)Cl Contacts on Dimerization of Cl(carbene)PdII Species

scientific article published on 28 February 2018

Halogen Bonding Involving Palladium(II) as an XB Acceptor

Hexafluorophosphates of chlorotris(dimethyl sulfide)platinum(II) and bromotris(dimethyl sulfide)platinum(II) ⬇️

scientific article published on October 11, 2003

Hexaiododiplatinate(ii) as a useful supramolecular synthon for halogen bond involving crystal engineering

scientific article published on 01 January 2020

Highly Reactive NiII-Bound Nitrile-Oxime Coupling Intermediates Stabilized by Substituting Conventional Nitriles with a Dialkylcyanamide

Highly Stereoselective 1,3-Dipolar Cycloaddition of Nitrones to (Nitrile)2PtIISpecies Furnishing Diastereomerically Pure 2,3-Dihydro-1,2,4-oxadiazole Ligands

article published in 2011

Iminoacylation. 3. Formation of Platinum(IV)-Based Metallaligands Due to Facile One-End Addition ofvic-Dioximes to Coordinated Organonitriles1-3

scientific article published on 01 January 2000

Interplay between Nitrones and (Nitrile)PdII Complexes: Cycloaddition vs. Complexation Followed by Cyclopalladation and Deoxygenation Reactions

Interplay between nitronates and nitriles accomplished in a PtIV-mediated reaction

Kinetic and mechanistic study of the Pt(II) versus Pt(IV) effect in the platinum-mediated nitrile-hydroxylamine coupling

scientific article published on 01 April 2005

Kinetic and thermodynamic aspects of the regioselective addition of bifunctional hydroxylaminooxime-type HO-nucleophiles to Pt-complexed nitriles

scientific article published on 01 March 2006

Lasagna-type arrays with halide-nitromethane cluster filling. The first recognition of the Hal(-)···HCH2NO2 (Hal = Cl, Br, I) hydrogen bonding.

scientific article published on 22 March 2012

Ligation-Enhanced π-Hole···π Interactions Involving Isocyanides: Effect of π-Hole···π Noncovalent Bonding on Conformational Stabilization of Acyclic Diaminocarbene Ligands

scientific article published on 24 May 2018

Metal-Involving Synthesis and Reactions of Oximes

scientific article published on 9 October 2017

Metal-Mediated and Metal-Catalyzed Reactions of Isocyanides

scientific article published on 05 March 2015

Metal-assisted coupling of oximes and nitriles: a synthetic, structural and theoretical study

Metal-involving generation of aminoheterocycles from N-substituted cyanamides: Toward sustainable chemistry (a Minireview)

Metal-mediated coupling of a coordinated isocyanide and indazoles.

scientific article

Metal-mediated coupling of amino acid esters with isocyanides leading to new chiral acyclic aminocarbene complexes

scientific article published on 01 November 2014

Metal-mediated cyanamide–hydroxyguanidine coupling

Metal-mediated reactions between dialkylcyanamides and acetamidoxime generate unusual (nitrosoguanidinate)nickel(ii) complexes.

scientific article published on 21 July 2017

Microwave-Assisted and PdII-Mediated Nitrile-Oxime Coupling

Nature of the Nucleophilic Oxygenation Reagent Is Key to Acid-Free Gold-Catalyzed Conversion of Terminal and Internal Alkynes to 1,2-Dicarbonyls

scientific article published on 31 December 2019

NiII-mediated coupling between iminoisoindolinones and nitriles leading to unsymmetrical 1,3,5-triazapentadienato complexes.

scientific article

Nickel(II) complexes featuring dialkylcyanamide ligands: Synthetic and structural studies

scholarly article by Elena V. Andrusenko et al published November 2014 in Inorganica Chimica Acta

Nitrile−Amidine Coupling at Pt(IV) and Pt(II) Centers. An Easy Entry to Imidoylamidine Complexes

scientific article published on 01 July 2005

Novel (cyanamide)Zn(II) complexes and zinc(ii)-mediated hydration of the cyanamide ligands.

scientific article

Novel reactivity mode of hydroxamic acids: a metalla-pinner reaction

scientific article published on 01 June 2002

Novel tailoring reaction for two adjacent coordinated nitriles giving platinum 1,3,5-triazapentadiene complexes.

scientific article published in December 2008

One-end nucleophilic addition of di- and triamines to PtIV-coordinated nitriles as an entry to (amidine)PtIV complexes bearing pendant NH2-groups

article

Oxidation of Pt-bound bis-hydroxylamine as a novel route to unexplored dinitrosoalkane ligated species.

scientific article

Oxygen Atom Transfer as Key To Reverse Regioselectivity in the Gold(I)-Catalyzed Generation of Aminooxazoles from Ynamides

scientific article published on 28 December 2020

Photoinduced synthesis and electrochemical properties of new ruthenium(mono)bipyridine dialkylcyanamide and propiononitrile complexes

Platinum Complexes with Chelating Acyclic Aminocarbene Ligands Work as Catalysts for Hydrosilylation of Alkynes

scientific article published on 24 January 2018

Platinum(II)-Complexed Tetrahydroimidazo[1,2-b][1,2,4]oxadiazoles Derived from Metal-Mediated 1,3-Dipolar Cycloaddition. Novel Type of Heterocycles, Which Do Not Exist without the Metal Center

Platinum(IV)-Mediated Nitrile-Amidoxime Coupling Reactions: Insights into the Mechanism for the Generation of 1,2,4-Oxadiazoles

Platinum(iv)-mediated coupling of dione monoximes and nitriles: a novel reactivity pattern of the classic oxime-based chelating ligands

Pop-the-cork strategy in synthetic utilization of imines: stabilization by complexation and activation via liberation of the ligated species.

scientific article published in June 2003

PtII-Mediated 1,3-Dipolar Cycloaddition of OxazolineN-Oxides to Nitriles as a Key Step to Dihydrooxazolo-1,2,4-oxadiazoles

scientific article published on 29 August 2007

PtII-Mediated Nitrile−Tetramethylguanidine Coupling as a Key Step for a Novel Synthesis of 1,6-Dihydro-1,3,5-triazines○

scientific article published on 01 February 2007

Reactions of platinum(iv)-bound nitriles with isomeric nitroanilines: addition vs. substitution

scientific article published on 01 November 2012

Reactivity of Pt- and Pd-bound nitriles towards nitrile oxides and nitrones: substitution vs. cycloaddition.

scientific article

Reduction of (imine)Pt(IV) to (imine)Pt(II) Complexes with Carbonyl-Stabilized Phosphorus Ylides

scientific article published on 01 March 2001

Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[MII ] (d8  M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile

scientific article published on 14 February 2019

Reversion of Structure-Activity Relationships of Antitumor Platinum Complexes by Acetoxime but Not Hydroxylamine Ligands

scientific article published on 18 October 2006

Selective Nucleophilic Oxygenation of Palladium-Bound Isocyanide Ligands: Route to Imine Complexes That Serve as Efficient Catalysts for Copper-/Phosphine-Free Sonogashira Reactions

Stepwise assembly of unsymmetrical supramolecular arrays containing porphyrins and coordination compounds

scientific article published on 01 April 2000

Structure-Directing Weak Interactions with 1,4-Diiodotetrafluorobenzene Convert One-Dimensional Arrays of [MII(acac)2] Species into Three-Dimensional Networks

Structure-directing sulfur...metal noncovalent semicoordination bonding

scientific article published on 21 May 2020

Supramolecular Assembly of Metal Complexes by (Aryl)I⋯dz2[PtII] Halogen Bond

scientific article published on 02 April 2020

Synthesis of (1,2,4-Oxadiazole)palladium(II) Complexes by [2 + 3] Cycloaddition of Nitrile Oxides to Organonitriles in the Presence of PdCl2

Synthesis of the First Family of Platinum(IV) Complexes with Phosphorus Ylide Ligands

Synthesis, X-ray diffraction structures, spectroscopic properties, and in vitro antitumor activity of isomeric (1H-1,2,4-triazole)Ru(III) complexes.

scientific article published on September 2003

Synthesis, characterization, and cytotoxic activity of novel potentially pH-sensitive nonclassical platinum(II) complexes featuring 1,3-dihydroxyacetone oxime ligands.

scientific article published on 27 September 2011

The (Dioximate)NiII/I2 System: Ligand Oxidation and Binding Modes of Triiodide Species

scientific article published on 06 February 2020

The first example of linkage isomerism for pyrazole ligands in platinum complexes

The first examples of metal-mediated addition of a phosphorus imine to nitriles; the preparation and X-ray crystal structures of [PtCl4{NHC(Et)NPPh3}2] and [PtCl2(EtCN){NHC(Et)NPPh3}]

article

The halogen bond with isocyano carbon reduces isocyanide odor

scientific article published on 10 June 2020

The metalla-Pinner reaction between Pt(IV)-bound nitriles and alkylated oxamic and oximic forms of hydroxamic acids.

scientific article published on 23 July 2004

Theoretical study of chemo-, regio-, and stereoselectivity in 1,3-dipolar cycloadditions of nitrones and nitrile oxides to free and Pt-bound bifunctional dipolarophiles

scientific article published on 12 May 2007

Trinuclear (aminonitrone)ZnII complexes as key intermediates in zinc(ii)-mediated generation of 1,2,4-oxadiazoles from amidoximes and nitriles

Tris-isocyanide copper(I) complexes: Synthetic, structural, and theoretical study

Tuning of redox potentials for the design of ruthenium anticancer drugs -- an electrochemical study of [trans-RuCl(4)L(DMSO)](-) and [trans-RuCl(4)L(2)](-) complexes, where L = imidazole, 1,2,4-triazole, indazole.

scientific article

Unexpectedly efficient activation of push–pull nitriles by a PtII center toward dipolar cycloaddition of Z-nitrones

scientific article published on 09 March 2011

Unsymmetrical NiII–Imidoylamidine Complexes Derived from a Novel Oxime-Mediated Single-Pot Reaction of Nitriles

scientific article published on 01 January 2007

Unusual reaction between (nitrile)Pt complexes and pyrazoles: substitution proceeds via metal-mediated nitrile-pyrazole coupling followed by elimination of the nitrile

scientific article published on 01 June 2006

Zinc(II)-mediated nitrile-amidoxime coupling gives new insights into H⁺-assisted generation of 1,2,4-oxadiazoles.

scientific article

[2 + 3] cycloaddition of nitrones to platinum-bound organonitriles: effect of metal oxidation state and of nitrile substituent.

scientific article

trans-Dichlorobis(piperidine-1-carbonitrile)platinum(II)

π-Hole···dz2[PtII] Interactions with Electron-Deficient Arenes Enhance the Phosphorescence of PtII-Based Luminophores

scientific article published on 09 June 2020

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