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List of works by Carsten Krebs

A 2.8 Å Fe-Fe separation in the Fe2(III/IV) intermediate, X, from Escherichia coli ribonucleotide reductase

scientific article

A New Microbial Pathway for Organophosphonate Degradation Catalyzed by Two Previously Misannotated Non-Heme-Iron Oxygenases

scientific article published on 07 March 2019

A Paramagnetic Copper(III) Complex Containing an Octahedral CuIIIS6 Coordination Polyhedron

scientific article published on 01 February 1999

A Triangular Iron(III) Complex Potentially Relevant to Iron(III)-Binding Sites in Ferreascidin

article

A catalytic di-heme bis-Fe(IV) intermediate, alternative to an Fe(IV)=O porphyrin radical

scholarly article

A consensus mechanism for Radical SAM-dependent dehydrogenation? BtrN contains two [4Fe-4S] clusters

scientific article published on May 2010

A coupled dinuclear iron cluster that is perturbed by substrate binding in myo-inositol oxygenase

scientific article (publication date: 2 May 2006)

A long-lived, substrate-hydroxylating peroxodiiron(III/III) intermediate in the amine oxygenase, AurF, from Streptomyces thioluteus ⬇️

scientific article published on September 2009

A manganese(IV)/iron(III) cofactor in Chlamydia trachomatis ribonucleotide reductase

scientific article published on May 2007

A manganese(IV)/iron(IV) intermediate in assembly of the manganese(IV)/iron(III) cofactor of Chlamydia trachomatis ribonucleotide reductase

scientific article published on 6 July 2007

A mixed-valent Fe(II)Fe(III) species converts cysteine to an oxazolone/thioamide pair in methanobactin biosynthesis

scientific article published in 2022

A radically different mechanism for S-adenosylmethionine-dependent methyltransferases

scientific article

A role for iron in an ancient carbonic anhydrase

scientific article published on 7 December 2003

A short Fe-Fe distance in peroxodiferric ferritin: control of Fe substrate versus cofactor decay?

scientific article published in January 2000

Ability of tetrahydrobiopterin analogues to support catalysis by inducible nitric oxide synthase: formation of a pterin radical is required for enzyme activity

scientific article published in November 2003

Active Site Threonine Facilitates Proton Transfer during Dioxygen Activation at the Diiron Center of Toluene/ o -Xylene Monooxygenase Hydroxylase

scientific article

An Unusual Ferryl Intermediate and Its Implications for the Mechanism of Oxacyclization by the Loline-Producing Iron(II)- and 2-Oxoglutarate-Dependent Oxygenase, LolO

scientific article published on 2 July 2024

Analysis of RNA Methylation by Phylogenetically Diverse Cfr Radical S-Adenosylmethionine Enzymes Reveals an Iron-Binding Accessory Domain in a Clostridial Enzyme

scientific article published on 12 July 2019

Aromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations

scientific article

AurF from Streptomyces thioluteus and a possible new family of manganese/iron oxygenases

scientific article

Biochemical and Spectroscopic Characterization of Overexpressed Fuscoredoxin from Escherichia coli

scholarly article by Alice S. Pereira et al published June 1999 in Biochemical and Biophysical Research Communications

Biogenesis of iron-sulfur clusters in photosystem I: holo-NfuA from the cyanobacterium Synechococcus sp. PCC 7002 rapidly and efficiently transfers [4Fe-4S] clusters to apo-PsaC in vitro

scientific article published on 11 August 2008

Branched activation- and catalysis-specific pathways for electron relay to the manganese/iron cofactor in ribonucleotide reductase from Chlamydia trachomatis

scientific article published on 26 July 2008

CD and MCD of CytC3 and taurine dioxygenase: role of the facial triad in alpha-KG-dependent oxygenases

scientific article published on 30 October 2007

Cfr and RlmN contain a single [4Fe-4S] cluster, which directs two distinct reactivities for S-adenosylmethionine: methyl transfer by SN2 displacement and radical generation

scientific article published on 18 November 2011

Characterization of Lipoyl Synthase from Mycobacterium tuberculosis

scientific article published on 3 February 2016

Characterization of RimO, a new member of the methylthiotransferase subclass of the radical SAM superfamily

scientific article published on October 2009

Characterization of quinolinate synthases from Escherichia coli, Mycobacterium tuberculosis, and Pyrococcus horikoshii indicates that [4Fe-4S] clusters are common cofactors throughout this class of enzymes

scientific journal article

Characterization of the cofactor composition of Escherichia coli biotin synthase

scientific article published in February 2004

ChlR protein of Synechococcus sp. PCC 7002 is a transcription activator that uses an oxygen-sensitive [4Fe-4S] cluster to control genes involved in pigment biosynthesis

scientific article

Circular dichroism, magnetic circular dichroism, and variable temperature variable field magnetic circular dichroism studies of biferrous and mixed-valent myo-inositol oxygenase: insights into substrate activation of O2 reactivity

scientific article published on 15 October 2013

Conversion of 3Fe-4S to 4Fe-4S Clusters in Native Pyruvate Formate-Lyase Activating Enzyme: Mössbauer Characterization and Implications for Mechanism

scientific article published in 2000

Conversion of fatty aldehydes to alka(e)nes and formate by a cyanobacterial aldehyde decarbonylase: cryptic redox by an unusual dimetal oxygenase

scientific article

Coordination of adenosylmethionine to a unique iron site of the [4Fe-4S] of pyruvate formate-lyase activating enzyme: a Mössbauer spectroscopic study

scientific article published in February 2002

Cryoreduction of the NO-adduct of taurine:alpha-ketoglutarate dioxygenase (TauD) yields an elusive {FeNO}(8) species

scientific article published on April 2010

Cyanobacterial alkane biosynthesis further expands the catalytic repertoire of the ferritin-like 'di-iron-carboxylate' proteins

scientific article

Demonstration by 2H ENDOR spectroscopy that myo-inositol binds via an alkoxide bridge to the mixed-valent diiron center of myo-inositol oxygenase

scientific article

Detection of formate, rather than carbon monoxide, as the stoichiometric coproduct in conversion of fatty aldehydes to alkanes by a cyanobacterial aldehyde decarbonylase

scientific article

Dioxygen Reactivity of Mononuclear Heme and Copper Components Yielding A High-Spin Heme−Peroxo−Cu Complex

article

Diphthamide biosynthesis requires an organic radical generated by an iron-sulphur enzyme

scientific article

Direct nitration and azidation of aliphatic carbons by an iron-dependent halogenase

scientific article

Direct spectroscopic and kinetic evidence for the involvement of a peroxodiferric intermediate during the ferroxidase reaction in fast ferritin mineralization

scientific article

Direct spectroscopic detection of a C-H-cleaving high-spin Fe(IV) complex in a prolyl-4-hydroxylase

scholarly article

Direct spectroscopic evidence for a high-spin Fe(IV) intermediate in tyrosine hydroxylase

scientific article

Drop-on-demand sample delivery for studying biocatalysts in action at X-ray free-electron lasers

scientific article

EXAFS spectroscopic evidence for an Fe=O unit in the Fe(IV) intermediate observed during oxygen activation by taurine:alpha-ketoglutarate dioxygenase

scientific article published in July 2004

Efficient delivery of long-chain fatty aldehydes from the Nostoc punctiforme acyl-acyl carrier protein reductase to its cognate aldehyde-deformylating oxygenase

scientific article published on 22 January 2015

Electronic Structure of the Ferryl Intermediate in the α-Ketoglutarate Dependent Non-Heme Iron Halogenase SyrB2: Contributions to H Atom Abstraction Reactivity

scientific article published on 29 March 2016

Electronic structure analysis of the oxygen-activation mechanism by Fe(II)- and α-ketoglutarate (αKG)-dependent dioxygenases

scientific article

Elucidation of the Fe(IV)=O intermediate in the catalytic cycle of the halogenase SyrB2.

scientific article

Enzymatic C–H activation by metal–superoxo intermediates

Escherichia coli L-serine deaminase requires a [4Fe-4S] cluster in catalysis

scientific article

Escherichia coli lipoyl synthase binds two distinct [4Fe-4S] clusters per polypeptide

scientific article published in September 2004

Escherichia coli quinolinate synthetase does indeed harbor a [4Fe-4S] cluster

scientific article published in May 2005

Evidence That the β Subunit of Chlamydia trachomatis Ribonucleotide Reductase Is Active with the Manganese Ion of Its Manganese(IV)/Iron(III) Cofactor in Site 1

scientific article

Evidence for C-H cleavage by an iron-superoxide complex in the glycol cleavage reaction catalyzed by myo-inositol oxygenase

scientific article

Evidence for Modulation of Oxygen Rebound Rate in Control of Outcome by Iron(II)- and 2-Oxoglutarate-Dependent Oxygenases

scientific article published on 16 September 2019

Evidence for a Di-μ-oxo Diamond Core in the Mn(IV)/Fe(IV) Activation Intermediate of Ribonucleotide Reductase from Chlamydia trachomatis.

scientific article

Evidence for a catalytically and kinetically competent enzyme-substrate cross-linked intermediate in catalysis by lipoyl synthase

scientific article published on 10 July 2014

Evidence for a high-spin Fe(IV) species in the catalytic cycle of a bacterial phenylalanine hydroxylase

scientific article

Evidence for basic ferryls in cytochromes P450.

scientific article published on September 2006

Evidence for hydrogen abstraction from C1 of taurine by the high-spin Fe(IV) intermediate detected during oxygen activation by taurine:alpha-ketoglutarate dioxygenase (TauD).

scientific article published in October 2003

Evidence for only oxygenative cleavage of aldehydes to alk(a/e)nes and formate by cyanobacterial aldehyde decarbonylases

scientific article published on 24 September 2012

Evidence for the slow reaction of hypoxia-inducible factor prolyl hydroxylase 2 with oxygen

scientific article

Evidence for two ferryl species in chloroperoxidase compound II.

scientific article published in May 2006

Evidence that the fosfomycin-producing epoxidase, HppE, is a non-heme-iron peroxidase

scientific article

Exchange Coupling in an Isostructural Series of Face-Sharing Bioctahedral Complexes [LM(II)(&mgr;-X)(3)M(II)L]BPh(4) (M = Mn, Fe, Co, Ni, Zn; X = Cl, Br; L = 1,4,7-Trimethyl-1,4,7-triazacyclononane).

scientific article published on June 1997

Exchange and Double-Exchange Phenomena in Linear Homo- and Heterotrinuclear Nickel(II,III,IV) Complexes Containing Six μ2-Phenolato or μ2-Thiophenolato Bridging Ligands

scholarly article by Thomas Beissel et al published January 1996 in Journal of the American Chemical Society

Exchange coupling constant J of peroxodiferric reaction intermediates determined by Mössbauer spectroscopy

scientific article published on 27 April 2002

Experimental Correlation of Substrate Position with Reaction Outcome in the Aliphatic Halogenase, SyrB2.

scientific article published on 19 May 2015

Facile electron transfer during formation of cluster X and kinetic competence of X for tyrosyl radical production in protein R2 of ribonucleotide reductase from mouse

scientific article published in January 2002

First Step in Catalysis of the Radical S-Adenosylmethionine Methylthiotransferase MiaB Yields an Intermediate with a [3Fe-4S]0-Like Auxiliary Cluster

scientific article published on 16 January 2020

Formation and function of the Manganese(IV)/Iron(III) cofactor in Chlamydia trachomatis ribonucleotide reductase

scientific article published on December 2008

Formation of Fe(III)Fe(IV) Species from the Reaction between a Diiron(II) Complex and Dioxygen: Relevance to Ribonucleotide Reductase Intermediate X

article

Formation of a Pterin Radical in the Reaction of the Heme Domain of Inducible Nitric Oxide Synthase with Oxygen†

scientific article published on 01 November 1999

Four-electron oxidation of p-hydroxylaminobenzoate to p-nitrobenzoate by a peroxodiferric complex in AurF from Streptomyces thioluteus

scientific article

Freeze-quench (57)Fe-Mössbauer spectroscopy: trapping reactive intermediates

scientific article

Function of the diiron cluster of Escherichia coli class Ia ribonucleotide reductase in proton-coupled electron transfer

scientific article published on 31 May 2013

Functional mimic of dioxygen-activating centers in non-heme diiron enzymes: mechanistic implications of paramagnetic intermediates in the reactions between diiron(II) complexes and dioxygen

scientific article

Further Insights into the Spectroscopic Properties, Electronic Structure, and Kinetics of Formation of the Heme−Peroxo−Copper Complex [(F8TPP)FeIII−(O22-)−CuII(TMPA)]+

article

Further characterization of Cys-type and Ser-type anaerobic sulfatase maturating enzymes suggests a commonality in the mechanism of catalysis

scientific article published on 16 April 2013

Generation of a Mixed-Valent Fe(III)Fe(IV) Form of Intermediate Q in the Reaction Cycle of Soluble Methane Monooxygenase, an Analog of Intermediate X in Ribonucleotide Reductase R2 Assembly

scientific article published in 1998

Geometric and electronic structure of the Mn(IV)Fe(III) cofactor in class Ic ribonucleotide reductase: correlation to the class Ia binuclear non-heme iron enzyme

scientific article

High-resolution iron X-ray absorption spectroscopic and computational studies of non-heme diiron peroxo intermediates

scientific article published on 22 October 2019

Highly Variable π-Bonding in the Interaction of Iron(II) Porphyrinates with Nitrite

article

Human calprotectin is an iron-sequestering host-defense protein

scientific article published on 24 August 2015

Hybrid radical-polar pathway for excision of ethylene from 2-oxoglutarate by an iron oxygenase

scientific article published on 24 September 2021

Hydrogen Donation but not Abstraction by a Tyrosine (Y68) during Endoperoxide Installation by Verruculogen Synthase (FtmOx1)

scientific article published on 12 June 2019

Identification of FX in the heliobacterial reaction center as a [4Fe-4S] cluster with an S = 3/2 ground spin state

scientific article

Importance of the maintenance pathway in the regulation of the activity of Escherichia coli ribonucleotide reductase

scientific article published on 4 March 2008

In vitro characterization of AtsB, a radical SAM formylglycine-generating enzyme that contains three [4Fe-4S] clusters

scientific article published on 18 June 2008

Installation of the Ether Bridge of Lolines by the Iron- and 2-Oxoglutarate-Dependent Oxygenase, LolO: Regio- and Stereochemistry of Sequential Hydroxylation and Oxacyclization Reactions.

scientific article published on 14 March 2018

Iron-sulfur cluster engineering provides insight into the evolution of substrate specificity among sulfonucleotide reductases.

scientific article published on 9 November 2011

IscA, an alternate scaffold for Fe-S cluster biosynthesis

scientific article published in November 2001

IscU as a Scaffold for Iron−Sulfur Cluster Biosynthesis: Sequential Assembly of [2Fe-2S] and [4Fe-4S] Clusters in IscU†

scientific article published on 01 July 2000

Kinetic dissection of the catalytic mechanism of taurine:alpha-ketoglutarate dioxygenase (TauD) from Escherichia coli

scientific article published in June 2005

Magnetic exchange coupling in a nearly linear iron(III)nickel(II)nickel(II)iron(III) complex

article

Mechanism of Rapid Electron Transfer during Oxygen Activation in the R2 Subunit ofEscherichiacoliRibonucleotide Reductase. 1. Evidence for a Transient Tryptophan Radical

article

Mechanism of Rapid Electron Transfer during Oxygen Activation in the R2 Subunit ofEscherichiacoliRibonucleotide Reductase. 2. Evidence for and Consequences of Blocked Electron Transfer in the W48F Variant

article

Mechanism of Taurine: α-Ketoglutarate Dioxygenase (TauD) fromEscherichia coli

article

Mechanism of the C5 Stereoinversion Reaction in the Biosynthesis of Carbapenem Antibiotics

scientific article

Metal-free class Ie ribonucleotide reductase from pathogens initiates catalysis with a tyrosine-derived dihydroxyphenylalanine radical

article published in the Proceedings of the National Academy of Sciences of the United States of America

Molecular basis for enantioselective herbicide degradation imparted by aryloxyalkanoate dioxygenases in transgenic plants

scientific article published on 17 June 2019

Mössbauer and EPR Characterization of theS=9/2Mixed-Valence Fe(II)Fe(III) Cluster in the Cryoreduced R2 Subunit ofEscherichia coliRibonucleotide Reductase

scientific article published in 2000

Mössbauer spectroscopy of Fe/S proteins

scientific article

Neelaredoxin, an iron-binding protein from the syphilis spirochete, Treponema pallidum, is a superoxide reductase.

scientific article published in September 2000

NifS-mediated assembly of [4Fe-4S] clusters in the N- and C-terminal domains of the NifU scaffold protein.

scientific article published in October 2005

Non-Heme Diiron Model Complexes Can Mediate Direct NO Reduction: Mechanistic Insight into Flavodiiron NO Reductases

scientific article published on 03 October 2018

Non-heme Fe(IV)-oxo intermediates

scientific article

Non-heme High-Spin {FeNO}6-8 Complexes: One Ligand Platform Can Do It All

scientific article published on 30 August 2018

Novel Approaches for the Accumulation of Oxygenated Intermediates to Multi-Millimolar Concentrations

scientific article published on January 2013

Nuclear Resonance Vibrational Spectroscopic Definition of the Facial Triad FeIV═O Intermediate in Taurine Dioxygenase: Evaluation of Structural Contributions to Hydrogen Atom Abstraction

scientific article published on 26 October 2020

O(2)-evolving chlorite dismutase as a tool for studying O(2)-utilizing enzymes.

scientific article published on 13 February 2012

O-H Activation by an Unexpected Ferryl Intermediate during Catalysis by 2-Hydroxyethylphosphonate Dioxygenase

scientific article published on 16 January 2017

Organophosphonate-degrading PhnZ reveals an emerging family of HD domain mixed-valent diiron oxygenases

scientific article

Oxygen activation by a mixed-valent, diiron(II/III) cluster in the glycol cleavage reaction catalyzed by myo-inositol oxygenase

scientific article (publication date: 2 May 2006)

Peroxide Activation for Electrophilic Reactivity by the Binuclear Non-heme Iron Enzyme AurF.

scientific article

Radical-translocation intermediates and hurdling of pathway defects in "super-oxidized" (Mn(IV)/Fe(IV)) Chlamydia trachomatis ribonucleotide reductase.

scientific article published on 04 December 2012

Rapid Reduction of the Diferric-Peroxyhemiacetal Intermediate in Aldehyde-Deformylating Oxygenase by a Cyanobacterial Ferredoxin: Evidence for a Free-Radical Mechanism

scientific article published on 2 September 2015

Rapid and quantitative activation of Chlamydia trachomatis ribonucleotide reductase by hydrogen peroxide

scientific article published on 22 March 2008

Rapid freeze-quench 57Fe Mössbauer spectroscopy: monitoring changes of an iron-containing active site during a biochemical reaction

scientific article published in February 2005

Rational reprogramming of the R2 subunit of Escherichia coli ribonucleotide reductase into a self-hydroxylating monooxygenase.

scientific article published in July 2001

Reaction of cytochrome P450BM3 and peroxynitrite yields nitrosyl complex

scientific article published on 14 April 2007

Reconstitution of ThiC in thiamine pyrimidine biosynthesis expands the radical SAM superfamily

scientific article

RlmN and AtsB as models for the overproduction and characterization of radical SAM proteins

scientific article published in January 2012

Spectroscopic Characterization of a Novel Tetranuclear Fe Cluster in an Iron−Sulfur Protein Isolated fromDesulfovibrio desulfuricans†

article published in 1998

Spectroscopic Evidence for the Two C-H-Cleaving Intermediates of Aspergillus nidulans Isopenicillin N Synthase

scientific article published on 18 May 2016

Spectroscopic and Electrochemical Characterization of the Iron–Sulfur and Cobalamin Cofactors of TsrM, an Unusual Radical S-Adenosylmethionine Methylase

scientific article published on 03 March 2016

Spectroscopic and computational evaluation of the structure of the high-spin Fe(IV)-oxo intermediates in taurine: alpha-ketoglutarate dioxygenase from Escherichia coli and its His99Ala ligand variant

scientific article published on 24 April 2007

Spectroscopic evidence for a high-spin Br-Fe(IV)-oxo intermediate in the alpha-ketoglutarate-dependent halogenase CytC3 from Streptomyces

scientific article published on 16 October 2007

Spectroscopic studies on the [4Fe-4S] cluster in adenosine 5'-phosphosulfate reductase from Mycobacterium tuberculosis.

scientific article

Spectroscopic, steady-state kinetic, and mechanistic characterization of the radical SAM enzyme QueE, which catalyzes a complex cyclization reaction in the biosynthesis of 7-deazapurines

scientific journal article

Stalking intermediates in oxygen activation by iron enzymes: motivation and method

scientific article

Stereochemical and Mechanistic Investigation of the Reaction Catalyzed by Fom3 from Streptomyces fradiae, a Cobalamin-Dependent Radical S-Adenosylmethionine Methylase ⬇️

scientific article published on 09 August 2018

Steric Enforcement of cis-Epoxide Formation in the Radical C-O-Coupling Reaction by Which (S)-2-Hydroxypropylphosphonate Epoxidase (HppE) Produces Fosfomycin

scientific article published on 11 December 2019

Stoichiometric Production of Hydrogen Peroxide and Parallel Formation of Ferric Multimers through Decay of the Diferric−Peroxo Complex, the First Detectable Intermediate in Ferritin Mineralization†

article

Structural Basis for Assembly of the Mn IV /Fe III Cofactor in the Class Ic Ribonucleotide Reductase from Chlamydia trachomatis

scientific article

Structural Basis for Superoxide Activation of Flavobacterium johnsoniae Class I Ribonucleotide Reductase and for Radical Initiation by its Dimanganese Cofactor.

scientific article published on 2 April 2018

Structural analysis of the Mn(IV)/Fe(III) cofactor of Chlamydia trachomatis ribonucleotide reductase by extended X-ray absorption fine structure spectroscopy and density functional theory calculations

scientific article published on 21 October 2008

Structural and Spectroscopic Characterization of a High-Spin {FeNO}(6) Complex with an Iron(IV)-NO(-) Electronic Structure

scientific article

Structural and spectroscopic analyses of the sporulation killing factor biosynthetic enzyme SkfB, a bacterial AdoMet radical sactisynthase

scientific article published in Journal of Biological Chemistry

Structural basis for tRNA methylthiolation by the radical SAM enzyme MiaB

scientific article published on 15 September 2021

Structural characterization of the peroxodiiron(III) intermediate generated during oxygen activation by the W48A/D84E variant of ribonucleotide reductase protein R2 from Escherichia coli

scientific article published in November 2003

Structure of a Ferryl Mimic in the Archetypal Iron(II)- and 2-(Oxo)-glutarate-Dependent Dioxygenase, TauD

scientific article published on 02 October 2019

Substrate activation by iron superoxo intermediates

scientific article

Substrate positioning controls the partition between halogenation and hydroxylation in the aliphatic halogenase, SyrB2.

scientific article published on 06 October 2009

Substrate-Triggered Formation of a Peroxo-Fe2(III/III) Intermediate during Fatty Acid Decarboxylation by UndA

scientific article published on 10 September 2019

Substrate-triggered addition of dioxygen to the diferrous cofactor of aldehyde-deformylating oxygenase to form a diferric-peroxide intermediate

scientific article published on 09 October 2013

Substrate-triggered formation and remarkable stability of the C-H bond-cleaving chloroferryl intermediate in the aliphatic halogenase, SyrB2

scientific article published on May 2009

SufR coordinates two [4Fe-4S]2+, 1+ clusters and functions as a transcriptional repressor of the sufBCDS operon and an autoregulator of sufR in cyanobacteria

scientific article published on 7 September 2007

Synthetic Model Complex of the Key Intermediate in Cytochrome P450 Nitric Oxide Reductase

scientific article published on 09 January 2019

The COMBREX project: design, methodology, and initial results

scientific article

The Fe2 (NO)2 Diamond Core: A Unique Structural Motif In Non-Heme Iron-NO Chemistry

scientific article published on 23 October 2019

The Ferroxidase Reaction of Ferritin Reveals a Diferric μ-1,2 Bridging Peroxide Intermediate in Common with Other O2-Activating Non-Heme Diiron Proteins†

scientific article published in 1999

The RicAFT (YmcA-YlbF-YaaT) complex carries two [4Fe-4S]2+ clusters and may respond to redox changes

scientific article published on 15 March 2017

The active form of Chlamydia trachomatis ribonucleotide reductase R2 protein contains a heterodinuclear Mn(IV)/Fe(III) cluster with S = 1 ground state

scientific article published on 27 May 2007

The biosynthesis of methanobactin.

scientific article

The first direct characterization of a high-valent iron intermediate in the reaction of an alpha-ketoglutarate-dependent dioxygenase: a high-spin FeIV complex in taurine/alpha-ketoglutarate dioxygenase (TauD) from Escherichia coli

scientific article

The manganese(IV)/iron(III) cofactor of Chlamydia trachomatis ribonucleotide reductase: structure, assembly, radical initiation, and evolution

scientific article

Toward a mechanistic and physiological understanding of a ferredoxin:disulfide reductase from the domains Archaea and Bacteria

scientific article published on 02 May 2018

Two Distinct Mechanisms for C-C Desaturation by Iron(II)- and 2-(Oxo)glutarate-Dependent Oxygenases: Importance of α-Heteroatom Assistance

scientific article published on 04 June 2018

Two distinct mechanisms of inactivation of the class Ic ribonucleotide reductase from Chlamydia trachomatis by hydroxyurea: implications for the protein gating of intersubunit electron transfer

scientific article

Two interconverting Fe(IV) intermediates in aliphatic chlorination by the halogenase CytC3

Two-Color Valence-to-Core X-ray Emission Spectroscopy Tracks Cofactor Protonation State in a Class I Ribonucleotide Reductase

scientific article published on 04 September 2018

Unusual Synthetic Pathway for an {Fe(NO)2}(9) Dinitrosyl Iron Complex (DNIC) and Insight into DNIC Electronic Structure via Nuclear Resonance Vibrational Spectroscopy

scientific article published on 20 May 2016

Use of a chemical trigger for electron transfer to characterize a precursor to cluster X in assembly of the iron-radical cofactor of Escherichia coli ribonucleotide reductase

scientific article

Valence-Delocalized Diiron(II,III) Cores Supported by Carboxylate-Only Bridging Ligands

article published in 2000

Vanadyl as a Stable Structural Mimic of Reactive Ferryl Intermediates in Mononuclear Nonheme-Iron Enzymes.

scientific article published on 29 September 2017

Visualizing the Reaction Cycle in an Iron(II)- and 2-(Oxo)-glutarate-Dependent Hydroxylase

scientific article published on 20 August 2017

YfaE, a ferredoxin involved in diferric-tyrosyl radical maintenance in Escherichia coli ribonucleotide reductase

scientific article published on 20 September 2007

myo-Inositol oxygenase: a radical new pathway for O(2) and C-H activation at a nonheme diiron cluster

scientific article

α-Amine Desaturation of d-Arginine by the Iron(II)- and 2-(Oxo)glutarate-Dependent l-Arginine 3-Hydroxylase, VioC

scientific article published on 07 November 2018

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