List of works - Viktoria Däschlein-Gessner

(1R,2R)-N,N'-Diisobutyl-N,N'-dimethyl-cyclo-hexane-1,2-diamine

scientific article published on 2 April 2009

(1R,2R)-N,N'-Dimethyl-cyclo-hexane-1,2-diamine

scientific article published on 12 March 2008

(2,2-Dichloro-vinyl)ferrocene

scientific article published on 28 February 2009

(S)-1,2-Dimethyl-1,1,2-triphenyl-2-(4-piperidiniometh-yl)disilane chloride

scientific article

2-[(2-Hydr-oxy-2,2-diphenyl-ethyl)(meth-yl)amino]-N,N-dimethyl-ethanaminium bromide.

scientific article published on 23 January 2009

A Highly Active Ylide-Functionalized Phosphine for Palladium-Catalyzed Aminations of Aryl Chlorides

scientific article published on 02 January 2019

A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2

scientific article published on 15 June 2020

A precoordination complex of 1,2,3-trimethyl-1,3,5-triazacyclohexane with tert-butyllithium as key intermediate in its methylene group deprotonation

scientific article published in November 2008

Alkali Metal Carbenoids: A Case of Higher Stability of the Heavier Congeners

scientific article

Alkali Metal Chlorine and Bromine Carbenoids: Their Thermal Stability and Structural Properties

scientific article

Assembly of macrocycles by zirconocene-mediated, reversible carbon-carbon bond formation

scientific article published on 7 April 2011

Bridging the Gap between Bisylides and Methandiides: Isolation, Reactivity, and Electronic Structure of an Yldiide

scientific article published on 10 June 2015

Catalytic Transfer Hydrogenation with a Methandiide-Based Carbene Complex: An Experimental and Computational Study.

scientific article published on 25 September 2015

Chiral 2-endo-substituted 9-oxabispidines: novel ligands for enantioselective copper(II)-catalyzed Henry reactions.

scientific article published in November 2009

Cooperative bond activation reactions with carbene complexes

scientific article published on 01 June 2018

Crystal Structures of the Chiral Diamine (R,R)-TMCDA with the Commonly Used Alkyllithium Bases Methyllithium,iso-Propyllithium, andsec-Butyllithium

scientific article published on 27 June 2007

Crystal structures of n-BuLi adducts with (R,R)-TMCDA and the consequences for the deprotonation of benzene.

scientific article

Diphen-yl[(phenyl-sulfan-yl)meth-yl]-λ(5)-phosphane-thione

scientific article

Diphenyl[2-(phenylsulfonyl)propan-2-yl]-λ5-phosphanethione ⬇️

scientific article published on March 14, 2012

Diphenylanthracene Macrocylces from Reductive Zirconocene Coupling: On the Edge of Steric Overload

scientific article published on 02 February 2011

Formation of Specific Configurations at Stereogenic Nitrogen Centers upon Their Coordination to Zinc and Mercury

scientific article published on 25 July 2012

From MonomerictBuLi⋅(R,R)-TMCDA to α-Lithiated (R,R)-TMCDA

scientific article published on 01 January 2007

From the Alkyllithium Aggregate [{(nBuLi)2⋅PMDTA}2] to Lithiated PMDTA

scientific article published on 01 January 2007

Group 9 and 10 Metal Complexes of an Ylide-Substituted Phosphine: Coordination versus Cyclometalation and Oxidative Addition

scientific article published on 05 June 2019

Isolation of a Diylide-Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment.

scientific article

Isolation of the Metalated Ylides [Ph P-C-CN]M (M=Li, Na, K): Influence of the Metal Ion on the Structure and Bonding Situation

scientific article published on 29 January 2019

Isopropyllithium diamine adducts: from a non symmetric aggregate to monomeric i-PrLi·(1R,2R)-N,N,N′,N′-tetraethylcyclohexane-1,2-diamine

scientific article published on 20 May 2008

Lithiation of TMEDA and its higher homologous TEEDA: understanding observed alpha- and beta-deprotonation

scientific article

Mechanistic Insight into Stereoselective Carbolithiation

scientific article published on 03 February 2011

Metal-Ligand Cooperativity in a Methandiide-Derived Iridium Carbene Complex.

scientific article published on 8 January 2016

Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties.

scientific article published on 27 February 2017

Methandiide as a Non-Innocent Ligand in Carbene Complexes: From the Electronic Structure to Bond Activation Reactions and Cooperative Catalysis

scientific article published on 22 July 2014

On the structure and ambiphilicity of a sulfonyl substituted α-chloro lithium base

scientific article published on 01 March 2014

One-Pot Ugi/Aza-Michael Synthesis of Highly Substituted 2,5-Diketopiperazines with Anti-Proliferative Properties

scientific article published on 11 December 2012

Palladium Complexes Based on Ylide-Functionalized Phosphines (YPhos): Broadly Applicable High-Performance Precatalysts for the Amination of Aryl Halides at Room Temperature

scientific article published on 28 February 2020

Preparation and Isolation of a Chiral Methandiide and Its Application as Cooperative Ligand in Bond Activation

scientific article published on 8 December 2015

Preparation of aminomethyl functionalised silanes via an α-lithiated amine: From their synthesis, stability and crystal structures to stereochemical issues ⬇️

scientific article published on February 3, 2012

Preparation of “Si-Centered” Chiral Silanes by Direct α-Lithiation of Methylsilanes

scientific article published on 01 April 2010

Reactivity of Stabilized Li/Cl Carbenoids towards Lewis Base Adducts of BH3: B-H Bond Activation versus Carbene Dimerization

scientific article published on 29 July 2013

Remote sensing of in-use heavy-duty diesel trucks.

scientific article published on November 2006

Selective Dehydrocoupling of Phosphines by Lithium Chloride Carbenoids

scientific article published on 21 October 2014

Selective Vinyl C−H Lithiation ofcis-Stilbenes

scientific article published on 01 March 2009

Si-H activation by means of metal ligand cooperation in a methandiide derived carbene complex.

scientific article published on 25 August 2015

Stability and reactivity control of carbenoids: recent advances and perspectives

scientific article published on 08 August 2016

Structure Formation Principles and Reactivity of Organolithium Compounds

scientific article published on 01 January 2009

Substitution Effects on the Formation of T-Shaped Palladium Carbene and Thioketone Complexes from Li/Cl Carbenoids

scientific article published on 24 March 2014

Synthesis and bonding in carbene complexes of an unsymmetrical dilithio methandiide: a combined experimental and theoretical study

scientific article published on 21 October 2013

Synthesis and stability of Li/Cl carbenoids based on bis(iminophosphoryl)methanes

scientific article published on 01 October 2014

Synthesis ofP-Stereogenic Compounds via Kinetic Deprotonation and Dynamic Thermodynamic Resolution of Phosphine Sulfides: Opposite Sense of Induction Using (−)-Sparteine

scientific article published on 01 October 2010

Taming Metal/Fluorine Carbenoids

scientific article published in December 2016

Tetrahedral versus Planar Four-Coordinate Carbon: A Sulfonyl-Substituted Methandiide

scientific article published on 26 July 2012

The Bonding Situation in Metalated Ylides

scientific article published on 25 January 2017

Total synthesis and absolute configuration of the guaiane sesquiterpene englerin A.

scientific article published in January 2009

Towards the Preparation of Stable Cyclic Amino(ylide)Carbenes

scientific article published on 12 February 2020

Transition metal borylene complexes ⬇️

scientific article published on February 12, 2013

Transition metal–free ketene formation from carbon monoxide through isolable ketenyl anions

scientific article published on 23 December 2022

Unexpected direct dilithiation of a prochiral phosphine borane

scientific article published on 20 May 2010

Using Ylide Functionalization to Stabilize Boron Cations

scientific article published on 10 February 2017

Versatile Modes of Cooperative B-H Bond Activation Reactions in Ruthenium-Carbene Complexes: Addition, Ring-Opening and Insertion

scientific article published on 18 January 2018

Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis

scientific article published on 25 June 2018

Ylide‐Functionalization via Metalated Ylides: Synthesis and Structural Properties

scientific article published on 15 May 2019

List of works by Viktoria Däschlein-Gessner

(1R,2R)-N,N'-Diisobutyl-N,N'-dimethyl-cyclo-hexane-1,2-diamine

(1R,2R)-N,N'-Dimethyl-cyclo-hexane-1,2-diamine

(2,2-Dichloro-vinyl)ferrocene

(S)-1,2-Dimethyl-1,1,2-triphenyl-2-(4-piperidiniometh-yl)disilane chloride

2-[(2-Hydr-oxy-2,2-diphenyl-ethyl)(meth-yl)amino]-N,N-dimethyl-ethanaminium bromide.

A Highly Active Ylide-Functionalized Phosphine for Palladium-Catalyzed Aminations of Aryl Chlorides

A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2

A precoordination complex of 1,2,3-trimethyl-1,3,5-triazacyclohexane with tert-butyllithium as key intermediate in its methylene group deprotonation

Alkali Metal Carbenoids: A Case of Higher Stability of the Heavier Congeners

Alkali Metal Chlorine and Bromine Carbenoids: Their Thermal Stability and Structural Properties

Assembly of macrocycles by zirconocene-mediated, reversible carbon-carbon bond formation

Bridging the Gap between Bisylides and Methandiides: Isolation, Reactivity, and Electronic Structure of an Yldiide

Catalytic Transfer Hydrogenation with a Methandiide-Based Carbene Complex: An Experimental and Computational Study.

Chiral 2-endo-substituted 9-oxabispidines: novel ligands for enantioselective copper(II)-catalyzed Henry reactions.

Cooperative bond activation reactions with carbene complexes

Crystal Structures of the Chiral Diamine (R,R)-TMCDA with the Commonly Used Alkyllithium Bases Methyllithium,iso-Propyllithium, andsec-Butyllithium

Crystal structures of n-BuLi adducts with (R,R)-TMCDA and the consequences for the deprotonation of benzene.

Diphen-yl[(phenyl-sulfan-yl)meth-yl]-λ(5)-phosphane-thione

Diphenyl[2-(phenylsulfonyl)propan-2-yl]-λ5-phosphanethione ⬇️

Diphenylanthracene Macrocylces from Reductive Zirconocene Coupling: On the Edge of Steric Overload

Formation of Specific Configurations at Stereogenic Nitrogen Centers upon Their Coordination to Zinc and Mercury

From MonomerictBuLi⋅(R,R)-TMCDA to α-Lithiated (R,R)-TMCDA

From the Alkyllithium Aggregate [{(nBuLi)2⋅PMDTA}2] to Lithiated PMDTA

Group 9 and 10 Metal Complexes of an Ylide-Substituted Phosphine: Coordination versus Cyclometalation and Oxidative Addition

Isolation of a Diylide-Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment.

Isolation of the Metalated Ylides [Ph P-C-CN]M (M=Li, Na, K): Influence of the Metal Ion on the Structure and Bonding Situation

Isopropyllithium diamine adducts: from a non symmetric aggregate to monomeric i-PrLi·(1R,2R)-N,N,N′,N′-tetraethylcyclohexane-1,2-diamine

Lithiation of TMEDA and its higher homologous TEEDA: understanding observed alpha- and beta-deprotonation

Mechanistic Insight into Stereoselective Carbolithiation

Metal-Ligand Cooperativity in a Methandiide-Derived Iridium Carbene Complex.

Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties.

Methandiide as a Non-Innocent Ligand in Carbene Complexes: From the Electronic Structure to Bond Activation Reactions and Cooperative Catalysis

On the structure and ambiphilicity of a sulfonyl substituted α-chloro lithium base

One-Pot Ugi/Aza-Michael Synthesis of Highly Substituted 2,5-Diketopiperazines with Anti-Proliferative Properties

Palladium Complexes Based on Ylide-Functionalized Phosphines (YPhos): Broadly Applicable High-Performance Precatalysts for the Amination of Aryl Halides at Room Temperature

Preparation and Isolation of a Chiral Methandiide and Its Application as Cooperative Ligand in Bond Activation

Preparation of aminomethyl functionalised silanes via an α-lithiated amine: From their synthesis, stability and crystal structures to stereochemical issues ⬇️

Preparation of “Si-Centered” Chiral Silanes by Direct α-Lithiation of Methylsilanes

Reactivity of Stabilized Li/Cl Carbenoids towards Lewis Base Adducts of BH3: B-H Bond Activation versus Carbene Dimerization

Remote sensing of in-use heavy-duty diesel trucks.

Selective Dehydrocoupling of Phosphines by Lithium Chloride Carbenoids

Selective Vinyl C−H Lithiation ofcis-Stilbenes

Si-H activation by means of metal ligand cooperation in a methandiide derived carbene complex.

Stability and reactivity control of carbenoids: recent advances and perspectives

Structure Formation Principles and Reactivity of Organolithium Compounds

Substitution Effects on the Formation of T-Shaped Palladium Carbene and Thioketone Complexes from Li/Cl Carbenoids

Synthesis and bonding in carbene complexes of an unsymmetrical dilithio methandiide: a combined experimental and theoretical study

Synthesis and stability of Li/Cl carbenoids based on bis(iminophosphoryl)methanes

Synthesis ofP-Stereogenic Compounds via Kinetic Deprotonation and Dynamic Thermodynamic Resolution of Phosphine Sulfides: Opposite Sense of Induction Using (−)-Sparteine

Taming Metal/Fluorine Carbenoids

Tetrahedral versus Planar Four-Coordinate Carbon: A Sulfonyl-Substituted Methandiide

The Bonding Situation in Metalated Ylides

Total synthesis and absolute configuration of the guaiane sesquiterpene englerin A.

Towards the Preparation of Stable Cyclic Amino(ylide)Carbenes

Transition metal borylene complexes ⬇️

Transition metal–free ketene formation from carbon monoxide through isolable ketenyl anions

Unexpected direct dilithiation of a prochiral phosphine borane

Using Ylide Functionalization to Stabilize Boron Cations

Versatile Modes of Cooperative B-H Bond Activation Reactions in Ruthenium-Carbene Complexes: Addition, Ring-Opening and Insertion

Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis

Ylide‐Functionalization via Metalated Ylides: Synthesis and Structural Properties