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List of works by Rian D. Dewhurst

1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group.

scientific article

A New Perspective on Borane Chemistry: the Nucleophilicity of the B-H Bonding Pair Electrons

article

A facile and selective route to remarkably inert monocyclic NHC-stabilized boriranes

scientific article published on 01 January 2015

A linear, anionic dimetalloborylene complex

scientific article published on 01 January 2008

A mercury bis(tricarbido) complex: [Hg{C triple bond C-C triple bond W(CO)2Tp}2(dmso)4](dmso)2 (Tp = hydrotrispyrazolylborate).

scientific article published on 9 November 2004

A trimetallic gold boride complex with a fluxional gold-boron bond

scientific article published on 01 January 2009

Alkylideneborate zwitterions and C-C coupling by atypical diboration of electron-rich alkynes.

scientific article published on 27 October 2017

Ambient-temperature isolation of a compound with a boron-boron triple bond

scientific article

Base-stabilized boryl and cationic haloborylene complexes of iron

scientific article published on 19 August 2013

Bond-strengthening π backdonation in a transition-metal π-diborene complex

scientific article published on 09 December 2012

Borido complexes via intermetallic metalloborylene transfer

scientific article published on 01 August 2011

Boron-Metallated Borirenes and Bis(Borirenes).

scientific article

Boron: Its Role in Energy-Related Processes and Applications

scientific article published on 18 October 2019

Boryl-functionalized σ-alkynyl and vinylidene rhodium complexes: synthesis and electronic properties.

scientific article published on 20 December 2013

Bottleable Neutral Analogues of [B2 H5 ]- as Versatile and Strongly Binding η2 Donor Ligands

scientific article published on 14 March 2018

CO2 Binding and Splitting by Boron-Boron Multiple Bonds

scientific article published on 14 April 2018

Carbene-induced synthesis of the first borironium cations using the [(η(5)-C5Me5)Fe(CO)2](-) anion as an unlikely leaving group

scientific article published on 29 October 2015

Cascades of catalytic selectivity

scientific article published on 01 April 2014

Closely related yet different: a borylene and its dimer are non-interconvertible but connected through reactivity.

scientific article published on 4 January 2018

Complete and partial 1,2-additions across transition metal-boron double bonds

scientific article published on 30 June 2014

Controlled homocatenation of boron on a transition metal

scientific article published on 17 June 2012

Correlations and Contrasts in Homo- and Heteroleptic Cyclic (Alkyl)(amino)carbene-Containing Pt(0) Complexes.

scientific article published on 4 August 2015

CuOTf-mediated intramolecular diborene hydroarylation

scientific article published on 20 October 2017

Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation.

scientific article published on April 2008

Cyclization of a 1,4-diborabutadiene ligand with both atoms of CO

scientific article published on 27 February 2015

DFT Studies of Dimerization Reactions of Boroles

scientific article

Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base

scientific article published on 24 November 2015

Desymmetrizing Electron-Deficient Diboranes(4): Diverse Products and Their Reactivity.

scientific article published on 12 August 2016

Dialumination of unsaturated species with a reactive bis(cyclopentadienyl) dialane

scientific article

Diboryldiborenes: π-Conjugated B4 Chains Isoelectronic to the Butadiene Dication

scientific article published on 15 July 2018

Dicyclohexyl(2',4',6'-triisopropylbiphenyl-2-yl)phosphine-dichlorophenylborane

scientific article published on 17 October 2009

Direct hydroboration of B=B bonds: a mild strategy for the proliferation of B-B bonds

scientific article published on 19 February 2014

Ditopic ambiphilicity of an anionic dimetalloborylene complex

scientific article published on 31 January 2013

Diverse reactions of N-heterocyclic carbenes with an alkynylborane and isolation of a reactive zwitterionic borataallene

scientific article published on 04 November 2013

Dynamic, Reversible Oxidative Addition of Highly Polar Bonds to a Transition Metal

scientific article published on 29 November 2016

Electron-Precise Coordination Modes of Boron-Centered Ligands

scientific article published on 01 July 2010

Electronic and ligand properties of annelated normal and abnormal (mesoionic) N-heterocyclic carbenes: a theoretical study.

scientific article published on 23 October 2013

Electronic and structural effects of stepwise borylation and quaternization on borirene aromaticity

scientific article published on 24 January 2013

Engineering a Small HOMO-LUMO Gap and Intramolecular C-H Borylation by Diborene/Anthracene Orbital Intercalation

scientific article

Evidence for extensive single-electron-transfer chemistry in boryl anions: isolation and reactivity of a neutral borole radical

scientific article published on 09 April 2014

Exclusive π Encapsulation of Light Alkali Metal Cations by a Neutral Molecule

scientific article published on 11 September 2015

Fashionably late: synthesis and characterization of transition-metal-fluoroborylene complexes

scientific article published on 01 May 2010

Fundamental Differences between Group 8 Metals: Unexpected Oxidation State Preferences and Mechanisms in Ruthenium Borylene Complex Formation.

scientific article

Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.

scientific article published on 12 October 2016

Generation of a carbene-stabilized bora-borylene and its insertion into a C-H bond

scientific article published on 04 November 2011

Heterobimetallic C3 complexes through silylpropargylidyne desilylation

scientific article published on 01 January 2004

Hydridoborylene complexes and di-, tri-, and tetranuclear borido complexes with hydride ligands

scientific article published on 11 November 2013

Identification of a Lead Candidate in the Search for Carbene-Stabilised Homoaromatics

scientific article published on 02 October 2015

Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron.

scientific article published on 8 July 2016

Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs).

scientific article published in January 2007

Iridium tricarbido complexes via transmetallation with tricarbidomercurials.

scientific article published on 10 March 2009

Isolation and Characterization of Crystalline, Neutral Diborane(4) Radicals

scientific article published on 21 June 2018

Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst-Free Spontaneous Cyclopropanation Step at 0 °C.

scientific article

Isolation of diborenes and their 90°-twisted diradical congeners.

scientific article

Lewis Acid Binding and Transfer as a Versatile Experimental Gauge of the Lewis Basicity of Fe(0) , Ru(0) , and Pt(0) Complexes

scientific article published on 11 November 2015

Lewis-Base-Induced Disproportionation of a Dialane

scientific article published on 18 July 2018

Low-coordinate boride ligands: a true trimetalloborane

scientific article published on 01 January 2009

Maximizing coordinative and electronic unsaturation: three-coordinate dicationic platinum complexes.

scientific article published on 31 January 2013

Metal-free binding and coupling of carbon monoxide at a boron-boron triple bond.

scientific article

Metal-only Lewis pairs by reversible insertion of ruthenium and osmium fragments into metal-boron double bonds

scientific article published on 12 March 2014

Metal-only Lewis pairs with transition metal lewis bases

scientific article published on 22 May 2012

Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex

scientific article published on 15 March 2016

Mild synthesis of diboryldiborenes by diboration of B-B triple bonds

scientific article published on 11 June 2019

Monohaloboryls (BHX-) as bridging ligands: observable dinuclear σ-(halo)boranyl intermediates in the synthesis of metalloborylenes

scientific article published on 20 January 2012

Monomeric 16-Electron π-Diborene Complexes of Zn(II) and Cd(II).

scientific article published on 26 July 2017

Multiple complexation of CO and related ligands to a main-group element

scientific article published in June 2015

Neutral zero-valent s-block complexes with strong multiple bonding

article

New outcomes of Lewis base addition to diboranes(4): electronic effects override strong steric disincentives

scientific article published on 14 March 2016

Nitrogen fixation and reduction at boron

scientific article published in February 2018

Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor

scientific article published on 4 August 2017

Observation of elementary steps in the catalytic borane dehydrocoupling reaction

scientific article published on 15 June 2012

One-pot, room-temperature conversion of dinitrogen to ammonium chloride at a main-group element

scientific article published on 14 September 2020

Photoionization and pyrolysis of a 1,4-azaborinine: retro-hydroboration in the cation and identification of novel organoboron ring systems

scientific article published on 26 June 2014

Planar four-coordinate boron: a single, flat boron atom as a ligand for four metals

scientific article published on 17 January 2012

Platinum complexes containing pyramidalized germanium and tin dihalide ligands bound through σ,σ M=E multiple bonds

scientific article published on 30 October 2014

Platinum trans-Bis(borirene) complexes displaying coplanarity and communication across a platinum metal center.

scientific article

Quaternizing diboranes(4): highly divergent outcomes and an inorganic Wagner-Meerwein rearrangement

scientific article

Reaction of Dihalodiboranes(4) with a N-Heterocyclic Silylene: Facile Construction of 1-Aryl-2-Silyl-1,2-Diboraindanes

scientific article published on 13 June 2017

Reactions of Digallanes with p- and d-Block Lewis Bases: Adducts, Bis(gallyl) Complexes, and Naked Ga+ as Ligand

scientific article published on 08 June 2018

Reactivity of Lewis basic platinum complexes towards fluoroboranes

scientific article published on 15 May 2013

Reductive borylene-CO coupling with a bulky arylborylene complex.

scientific article published on 25 July 2013

Regioselective Catalytic and Stepwise Routes to Bulky, Functional-Group-Appended, and Luminescent 1,2-Azaborinines.

scientific article

Release of Isonitrile- and NHC-Stabilized Borylenes from Group VI Terminal Borylene Complexes

scientific article published on 2 March 2018

Reversible sigma-borane-to-borylene transformation: a little something for everyone

scientific article published on 01 January 2009

Selective mono- and dimetallation of a group 3 sandwich complex

scientific article published on 26 July 2019

Silver(I) and thallium(I) cations as unsupported bridges between two metal bases

scientific article published on 06 November 2014

Simple solution-phase syntheses of tetrahalodiboranes(4) and their labile dimethylsulfide adducts

scientific article published on 01 July 2017

Single, Double, Triple Bonds and Chains: The Formation of Electron‐Precise BB Bonds ⬇️

scientific article published on January 30, 2013

Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum

scientific article

Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes

scientific article published on 17 September 2019

Strongly Phosphorescent Transition Metal π-Complexes of Boron-Boron Triple Bonds.

scientific article

Synthesis and Trapping of Iminoboranes by M=B/C=N Bond Metathesis.

scientific article

Synthesis of Functionalized 1,4-Azaborinines by the Cyclization of Di-tert-butyliminoborane and Alkynes

scientific article published on 10 June 2016

Synthesis of cyclic diborenes with unprecedented cis-configuration

scientific article published on 11 September 2015

Synthesis of the first heteroaryl-substituted boryl complexes: strong stabilizing effects of boron-aryl π-conjugation

scientific article published on 09 March 2015

Tetraiododiborane(4) (B2 I4 ) is a Polymer Based on sp3 Boron in the Solid State

scientific article published on 30 January 2020

Theoretical strategies toward stabilization of singlet remote N-heterocyclic carbenes.

scientific article

Toward Transition-Metal-Templated Construction of Arylated B4 Chains by Dihydroborane Dehydrocoupling

scientific article published on 30 October 2019

Transition metal borylene complexes

scientific article published on 12 February 2013

Transition metals as Lewis bases: “Z-type” boron ligands and metal-to-boron dative bonding ⬇️

scientific article published on November 29, 2010

Transition-Metal π-Ligation of a Tetrahalodiborane

scientific article

Trihapto ligation of a borirene to a single metal atom: a heterocyclic analogue of the η³-cyclopropenyl ligand

scientific article published on 06 May 2014

Two-Dimensional, but not Flat: An All-Boron Graphene with a Corrugated Structure.

scientific article published on 17 March 2016

Unexpected luminescence behavior of coinage metal π-diborene complexes

scientific article published on 06 February 2015

Unprecedented Borane, Diborane(3), Diborene, and Borylene Ligands via Pt-Mediated Borane Dehydrogenation

scientific article published on 22 December 2015

Unprecedented oxidative addition and metal-only Lewis pair chemistry of antimony trihalides

scientific article published on 09 December 2014

Unsupported boron–carbon σ-coordination to platinum as an isolable snapshot of σ-bond activation

scientific article published in Nature Communications

sp2–sp3 diboranes: astounding structural variability and mild sources of nucleophilic boron for organic synthesis

scientific article published on 01 June 2015

trans-[Pt(BCat')Me(PCy3)2]: an experimental case study of reductive elimination processes in Pt-Boryls through associative mechanisms

scientific article published on 07 September 2011

{N',N''-Bis[2,6-bis-(1-methyl-ethyl)phen-yl]-N,N-dimethyl-guanidinato-κN',N''}dibromido-borane

scientific article published on 13 February 2010

Übergangsmetall-π-Komplexierung eines Tetrahalogendiborans

σ-Donor-σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt(0) and Pb(II) fragments

scientific article published on 19 September 2012

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