List of works - Leonardo Degennaro

A Study of Graphene-Based Copper Catalysts: Copper(I) Nanoplatelets for Batch and Continuous-Flow Applications

scientific article published on 13 August 2019

A direct and sustainable synthesis of tertiary butyl esters enabled by flow microreactors

scientific article

A greener and efficient access to substituted four- and six-membered sulfur-bearing heterocycles.

scientific article published in June 2017

A stereospecific synthesis of oxazolinyloxiranes

scientific article published on 01 May 2001

Azetidine-Borane Complexes: Synthesis, Reactivity, and Stereoselective Functionalization

scientific article published on 30 July 2018

Enantioselective carbolithiation of S-alkenyl-N-aryl thiocarbamates: kinetic and thermodynamic control

scientific article published on 01 February 2015

Exploiting a "Beast" in Carbenoid Chemistry: Development of a Straightforward Direct Nucleophilic Fluoromethylation Strategy

scientific article

Flow Microreactor Technology for Taming Highly Reactive Chloroiodomethyllithium Carbenoid: Direct and Chemoselective Synthesis of α-Chloroaldehydes

scientific article published on 10 April 2020

Harnessing the ortho-directing ability of the azetidine ring for the regioselective and exhaustive functionalization of arenes.

scientific article published on 5 August 2014

Highly Chemoselective NH- and O-Transfer to Thiols Using Hypervalent Iodine Reagents: Synthesis of Sulfonimidates and Sulfonamides

scientific article published on 13 April 2018

Lithiation of N-alkyl-(o-tolyl)aziridine: stereoselective synthesis of isochromans.

scientific article published in August 2009

Modular and Chemoselective Strategy for the Direct Access to α-Fluoroepoxides and Aziridines via the Addition of Fluoroiodomethyllithium to Carbonyl-Like Compounds

scientific article published on 02 January 2019

Nitrogen Stereodynamics and Complexation Phenomena as Key Factors in the Deprotonative Dynamic Resolution of Alkylideneaziridines: A Spectroscopic and Computational Study.

scientific article

Nitrogen dynamics and reactivity of chiral aziridines: generation of configurationally stable aziridinyllithium compounds

scientific article published on 04 April 2011

One-pot preparation of piperazines by regioselective ring-opening of non-activated arylaziridines

scientific article published on 30 January 2012

Oxazolinyloxiranyllithium-mediated stereoselective synthesis of alpha-epoxy-beta-amino acids

scientific article published on 01 July 2003

Pharmaceutical development of novel lactate-based 6-fluoro-l-DOPA formulations

scientific article published on 4 October 2016

Recent advances in the stereoselective synthesis of aziridines.

scientific article published on 13 May 2014

Regioselective functionalization of 2-arylazetidines: evaluating the ortho-directing ability of the azetidinyl ring and the α-directing ability of the N-substituent

scientific article published on 06 January 2014

Stereocontrolled lithiation/trapping of chiral 2-alkylideneaziridines: investigation into the role of the aziridine nitrogen stereodynamics

scientific article published on 01 November 2014

Stereoselective synthesis of novel 4,5-epoxy-1,2-oxazin-6-ones and alpha,beta-epoxy-gamma-amino acids from beta-lithiated oxazolinyloxiranes and nitrones

scientific article published on 01 October 2006

Stereospecific beta-lithiation of oxazolinyloxiranes: synthesis of alpha,beta-epoxy-gamma-butyrolactones

scientific article published on 01 May 2002

Straightforward access to 4-membered sulfurated heterocycles: introducing a strategy for the single and double functionalization of thietane 1-oxide.

scientific article published in April 2014

Straightforward chemo- and stereoselective fluorocyclopropanation of allylic alcohols: exploiting the electrophilic nature of the not so elusive fluoroiodomethyllithium

scientific article published on 01 July 2019

Synthesis of 1,2,3,4-tetrahydroisoquinolines by microreactor-mediated thermal isomerization of laterally lithiated arylaziridines

scientific article

Synthesis of Sulfinamidines and Sulfinimidate Esters by Transfer of Nitrogen to Sulfenamides

scientific article published on 28 August 2020

Synthesis of Sulfonimidamides from Sulfenamides via an Alkoxy-amino-λ6 -sulfanenitrile Intermediate

scientific article published on 28 August 2019

Synthesis of functionalized arylaziridines as potential antimicrobial agents.

scientific article published on 4 August 2014

Transfer of Electrophilic NH Using Convenient Sources of Ammonia: Direct Synthesis of NH Sulfoximines from Sulfoxides

scientific article published on 29 April 2016

List of works by Leonardo Degennaro

A Study of Graphene-Based Copper Catalysts: Copper(I) Nanoplatelets for Batch and Continuous-Flow Applications

A direct and sustainable synthesis of tertiary butyl esters enabled by flow microreactors

A greener and efficient access to substituted four- and six-membered sulfur-bearing heterocycles.

A stereospecific synthesis of oxazolinyloxiranes

Azetidine-Borane Complexes: Synthesis, Reactivity, and Stereoselective Functionalization

Enantioselective carbolithiation of S-alkenyl-N-aryl thiocarbamates: kinetic and thermodynamic control

Exploiting a "Beast" in Carbenoid Chemistry: Development of a Straightforward Direct Nucleophilic Fluoromethylation Strategy

Flow Microreactor Technology for Taming Highly Reactive Chloroiodomethyllithium Carbenoid: Direct and Chemoselective Synthesis of α-Chloroaldehydes

Harnessing the ortho-directing ability of the azetidine ring for the regioselective and exhaustive functionalization of arenes.

Highly Chemoselective NH- and O-Transfer to Thiols Using Hypervalent Iodine Reagents: Synthesis of Sulfonimidates and Sulfonamides

Lithiation of N-alkyl-(o-tolyl)aziridine: stereoselective synthesis of isochromans.

Modular and Chemoselective Strategy for the Direct Access to α-Fluoroepoxides and Aziridines via the Addition of Fluoroiodomethyllithium to Carbonyl-Like Compounds

Nitrogen Stereodynamics and Complexation Phenomena as Key Factors in the Deprotonative Dynamic Resolution of Alkylideneaziridines: A Spectroscopic and Computational Study.

Nitrogen dynamics and reactivity of chiral aziridines: generation of configurationally stable aziridinyllithium compounds

One-pot preparation of piperazines by regioselective ring-opening of non-activated arylaziridines

Oxazolinyloxiranyllithium-mediated stereoselective synthesis of alpha-epoxy-beta-amino acids

Pharmaceutical development of novel lactate-based 6-fluoro-l-DOPA formulations

Recent advances in the stereoselective synthesis of aziridines.

Regioselective functionalization of 2-arylazetidines: evaluating the ortho-directing ability of the azetidinyl ring and the α-directing ability of the N-substituent

Stereocontrolled lithiation/trapping of chiral 2-alkylideneaziridines: investigation into the role of the aziridine nitrogen stereodynamics

Stereoselective synthesis of novel 4,5-epoxy-1,2-oxazin-6-ones and alpha,beta-epoxy-gamma-amino acids from beta-lithiated oxazolinyloxiranes and nitrones

Stereospecific beta-lithiation of oxazolinyloxiranes: synthesis of alpha,beta-epoxy-gamma-butyrolactones

Straightforward access to 4-membered sulfurated heterocycles: introducing a strategy for the single and double functionalization of thietane 1-oxide.

Straightforward chemo- and stereoselective fluorocyclopropanation of allylic alcohols: exploiting the electrophilic nature of the not so elusive fluoroiodomethyllithium

Synthesis of 1,2,3,4-tetrahydroisoquinolines by microreactor-mediated thermal isomerization of laterally lithiated arylaziridines

Synthesis of Sulfinamidines and Sulfinimidate Esters by Transfer of Nitrogen to Sulfenamides

Synthesis of Sulfonimidamides from Sulfenamides via an Alkoxy-amino-λ6 -sulfanenitrile Intermediate

Synthesis of functionalized arylaziridines as potential antimicrobial agents.

Transfer of Electrophilic NH Using Convenient Sources of Ammonia: Direct Synthesis of NH Sulfoximines from Sulfoxides