List of works - Miguel Ángel Ruiz

A Triply Bonded Dimolybdenum Hydride Complex with Acid, Base and Radical Activity

A Versatile and Unprecedented Triply Bonded Dimolybdenum Carbonyl Anion

A thiophosphinidene complex as a vehicle in phosphinidene transmetalation: easy formation and cleavage of a P-S bond.

scientific article published on 12 October 2011

Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex

scientific article published on 10 January 2018

Activation of H-H and H-O bonds at phosphorus with diiron complexes bearing pyramidal phosphinidene ligands.

scientific article published in March 2012

Alkenyl Derivatives of the Unsaturated Dimolybdenum Hydride Complex [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2]

Aurophilic self-assembly of a Mo4Au2 phosphinidene complex with an unprecedented H-shaped planar metal core

scientific article published on 9 August 2008

C-C and C-N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives

scientific article published on 04 August 2017

C-X bond formation and cleavage in the reactions of the ditungsten hydride complex [W2(η5-C5H5)2(H)(μ-PCy2)(CO)2] with small molecules having multiple C-X bonds (X = C, N, O).

scientific article published on 20 July 2011

Carbene- and Carbyne-like Behavior of the Mo−P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand

scientific article published on 04 July 2007

Chemical and Structural Effects of Bulkness on Bent-Phosphinidene Bridges: Synthesis and Reactivity of the Diiron Complex [Fe2Cp2{μ-P(2,4,6-C6H2tBu3)}(μ-CO)(CO)2]

Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)].

scientific article published on 27 February 2017

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

scientific article

Chemistry of the oxophosphinidene ligand. 2. Reactivity of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) toward electrophiles based on elements different from carbon.

scientific article published on 17 November 2010

Chemistry of the phosphinidene oxide ligand.

scientific article published in October 2004

Coordination and Dehydrogenation of Diphosphine-Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative

scientific article published on 12 November 2019

Cycloaddition Reactions of the Phosphinidene-Bridged Complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)] with Diazoalkanes and Other Heterocumulenes

scientific article published on 06 October 2016

Cyclopentadienyl and related complexes of the group 6 elements having metal–metal triple bonds: Synthesis, structure, bonding and reactivity

Dehydrogenation, Methyl Elimination and Insertion Reactions of the Agostic Methyl-Bridged Complex [Mo2 Cp2 (μ-κ1 :η2 -CH3 )(μ-Pt Bu2 )(μ-CO)]

scientific article published on 30 May 2018

Dimolybdenum cyclopentadienyl complexes with bridging chalcogenophosphinidene ligands.

scientific article published on 3 July 2012

Dimolybdenum−Tin Derivatives of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] and HSnR3(R = Ph, Bu): Bridging versus Terminal Coordination of the Triorganostannyl Group

Diphosphorus-bridged heterometallic anions and hydrides derived from reactions of complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− with precursors of 16-electron metal carbonyl fragments

E-H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

scientific article published on 7 February 2018

Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo-Re Complex. A Platform Combining Nucleophilic and Electrophilic Features

scientific article published on 06 July 2020

Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo2(η5-C5H5)(μ-κ1:κ1,η5-PC5H4)(η6-C6H3tBu3)(CO)2(PMe3)]

scientific article published on 08 October 2015

Enhanced nucleophilic behavior of a dimolybdenum phosphinidene complex: multicomponent reactions with activated alkenes and alkynes in the presence of CO or CNXyl

scientific article published on 23 May 2011

From coordinated oxophosphinidene to O,O,P-bound arylhypophosphite(2-) to build a singular Mo2Sn2O4P2 metallocycle

scientific article published on 29 January 2008

Gold(I) and related heterometallic derivatives of dimolybdenum complexes with asymmetric phosphinidene bridges

scientific article published on 5 September 2014

Heterometallic derivatives of [Fe2Cp2(μ-PCy)(μ-CO)(CO)2]: rational synthesis of polynuclear complexes from neutral precursors having pyramidal-phosphinidene bridges.

scientific article published on 20 July 2011

Heterometallic derivatives of the unsaturated ditungsten hydride [W2(η(5)-C5H5)2(H)(μ-PCy2)(CO)2]

scientific article published on 03 June 2013

High yield synthesis and reactivity of a phosphinidene bridged dimolybdenum complex

scientific article published on 01 December 2002

Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2](-).

scientific article published in November 2014

Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4

Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes

scientific article published on 01 March 2016

Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo₂(η⁵-C₅H₅)₂(μ-CH₂R)(μ-PCy₂)(CO)₂] (R = H, Ph) with isocyanides and secondary phosphines.

scientific article published on 4 April 2014

Low-temperature N-O bond cleavage and reversible N-P bond formation processes in the reactions of the unsaturated anions [M2(η5-C5H5)2(μ-PCy2)(μ-CO)2]- (M = Mo, W) with the nitrosyl complex [Re(η5-C5H4Me)(CO)2(NO)]+.

scientific article published on 13 March 2013

Low-temperature N-O bond cleavage in nitrosyl ligands induced by the unsaturated dimolybdenum anion [Mo2(eta(5)-C5H5)2(mu-PPh2)(mu-CO)2]-.

scientific article published in October 2009

Low-temperature N-O bond cleavage of nitrogen monoxide in heterometallic carbonyl complexes. An experimental and theoretical study.

scientific article published on 18 October 2008

Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo2(η5-C5H5)2(μ-R)(μ-PCy2)(CO)2] (R = Me, CH2Ph, Ph) with CO and NO

Mild N–O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center

scientific article published on 03 November 2015

Mild P-P bond cleavage in the methyldiphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] to give novel phosphide-bridged trinuclear derivatives

scientific article published on 10 October 2014

Mild P4Activation To Give an Anionic Diphosphorus Complex with a Dual Binding Ability at a Single P Site

scientific article published on 27 January 2011

M−P versus MM Bonds as Protonation Sites in the Organophosphide-Bridged Complexes [M2Cp2(μ-PR2)(μ-PR‘2)(CO)2], (M = Mo, W; R, R‘ = Ph, Et, Cy)†

scientific article published on 01 August 2006

N-O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W)

scientific article published on 21 November 2018

Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO)2{E,P-EP(O)(2,4,6-C6H2tBu3)}]−(E = O, S)

scientific article published on 01 November 2014

One-step synthesis and P-H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

scientific article published on 01 October 2019

Oxidation reactions of the phosphinidene oxide ligand.

scientific article

P-N and N-Mo Bond Formation Processes in the Reactions of a Pyramidal Phosphinidene-Bridged Dimolybdenum Complex with Diazoalkanes and Organic Azides

scientific article published on 21 May 2020

P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.

scientific article published on 8 June 2015

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes)(CO)2] (Mes = 2,4,6-C6H2tBu3).

scientific article

Phosphinidene-bridged binuclear complexes

article published in 2017

Proton induced P–H and Mo–H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(µ-H)(µ-PHR)(CO)4] (R = Cy, 2,4,6-C6H2R′3; R′ = H, Me,tBu)

scientific article published on 15 November 2004

Reactions of the Tetrafluoroborate Complex [Mo2Cp2(κ2-F2BF2)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P)

scientific article published on 20 June 2012

Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite Ligand

scientific article published on 16 April 2014

Reactions of the Unsaturated Hydroxo Complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N)

scientific article published on 18 September 2012

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with electrophiles based on p-block elements

scientific article published on 01 December 2012

Reactions of the unsaturated complex [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PEt(2))(2)(CO)(2)] with [Au(PR(3))](+) cations: kinetic preference of the Mo-P bonds as the site of attack of the gold(I) electrophile.

scientific article published in October 2009

Reactivity of [Mn2(.mu.-H)2(CO)6(.mu.-tedip)] (tedip = (EtO)2POP(OEt)2) with Group 11 Alkynyl Compounds. X-ray Structures of [Ag2Mn4(.mu.-H)6(CO)12(.mu.-tedip)2] and [AuMn4(.mu.-H)5(CO)12(.mu.-tedip)2]

Reactivity of the 30-electron dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]− towards β,γ-unsaturated organic halides: Alkenyl, allenyl and alkoxycarbyne derivatives

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]− Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Donor Ability and Dynamics of the P2 Ligand

scientific article published on 24 September 2012

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− toward Phosphorus- and Transition Metal-Based Electrophiles

scientific article published on 09 July 2013

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward 17- and 16-Electron Metal Carbonyl Fragments: Rational Synthesis of Electron-Deficient Heterometallic Clusters

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward P-Donor Bidentate Ligands and Unsaturated N-Containing Organic Molecules

Reactivity of the unsaturated dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]− towards electrophiles based on p- and d-block elements

Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(CO)2]: Migratory Behavior and Methylidyne Derivatives

Reply to the ‘Comment on “Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−”’ by M. Green, Dalton Transactions, 2018, 47, DOI: 10.1039/C8DT00044A

scientific article published on 01 May 2018

Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

scientific article published on 01 August 2013

Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands.

scientific article

Structure and Bonding in the Unsaturated Hydride- and Hydrocarbyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-X)(μ-PCy2)(CO)2] (X = H, CH3, CH2Ph, Ph). Evidence for the Presence of α-Agostic and π-Bonding Interactions†

Structure and dynamics of heterometallic clusters derived from addition of metal carbonyl fragments to the unsaturated hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

scientific article published on 25 October 2017

Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity

scientific article published on 06 December 2011

Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex.

scientific article

Synthesis and Decarbonylation Reactions of Diiron Cyclopentadienyl Complexes with Bent-Phosphinidene Bridges

article published in 2011

Synthesis and Decarbonylation Reactions of the Triiron Phosphinidene Complex [Fe3Cp3(μ-H)(μ3-PPh)(CO)4]: Easy Cleavage and Formation of P–H and Fe–Fe Bonds

scientific article published on 07 October 2011

Synthesis of the triply-bonded dimolybdenum anions [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PA(2))(mu-CO)(2)](-) (A = Cy, Et, Ph, OEt): unsaturated hydride and carbyne derivatives.

scientific article published on 31 July 2009

Ten-electron coordination and reactivity of an arylphosphinidene ligand.

scientific article published in October 2003

Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study.

scientific article

Tetranuclear phosphide- and phosphinidene-bridged derivatives of the diphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2].

scientific article published on 11 February 2015

The carbaborane group η5-C2B9H9Me2as a spectator and non-spectator ligand in di- and tri-metal complex chemistry: X-ray crystal structures of [PPh4][Co2W(µ3-CPh)(CO)8(η5-C2B9H9Me2)].1/2CH2Cl2, [NEt4][FeW(µ-CC6H3Me2-2,6)(CO)5-(η5-C2B9H9Me2)], and

article published in 1987

The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2](-): an entry to the chemistry of unsaturated nitrosyl complexes.

scientific article published in August 2016

Trapping of hemiquinone radicals at Mo and P sites by phosphide-bridged dimolybdenum species: chemistry of complexes [Mo2(eta5-C5H5)2(OC6H4OH)(mu-PR2)(CO)4] and [Mo2(eta5-C5H5)2{mu-PR(OC6H4OH)}(CO)4]- (R = Cy, Ph)

scientific article published on 01 November 2006

List of works by Miguel Ángel Ruiz

A Triply Bonded Dimolybdenum Hydride Complex with Acid, Base and Radical Activity

A Versatile and Unprecedented Triply Bonded Dimolybdenum Carbonyl Anion

A thiophosphinidene complex as a vehicle in phosphinidene transmetalation: easy formation and cleavage of a P-S bond.

Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex

Activation of H-H and H-O bonds at phosphorus with diiron complexes bearing pyramidal phosphinidene ligands.

Alkenyl Derivatives of the Unsaturated Dimolybdenum Hydride Complex [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2]

Aurophilic self-assembly of a Mo4Au2 phosphinidene complex with an unprecedented H-shaped planar metal core

C-C and C-N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives

C-X bond formation and cleavage in the reactions of the ditungsten hydride complex [W2(η5-C5H5)2(H)(μ-PCy2)(CO)2] with small molecules having multiple C-X bonds (X = C, N, O).

Carbene- and Carbyne-like Behavior of the Mo−P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand

Chemical and Structural Effects of Bulkness on Bent-Phosphinidene Bridges: Synthesis and Reactivity of the Diiron Complex [Fe2Cp2{μ-P(2,4,6-C6H2tBu3)}(μ-CO)(CO)2]

Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)].

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R*}(CO)(2)](-) (M = Mo, W; R* = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

Chemistry of the oxophosphinidene ligand. 2. Reactivity of the anionic complexes [MCp{P(O)R*}(CO)(2)](-) (M = Mo, W; R* = 2,4,6-C(6)H(2)(t)Bu(3)) toward electrophiles based on elements different from carbon.

Chemistry of the phosphinidene oxide ligand.

Coordination and Dehydrogenation of Diphosphine-Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative

Cycloaddition Reactions of the Phosphinidene-Bridged Complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)] with Diazoalkanes and Other Heterocumulenes

Cyclopentadienyl and related complexes of the group 6 elements having metal–metal triple bonds: Synthesis, structure, bonding and reactivity

Dehydrogenation, Methyl Elimination and Insertion Reactions of the Agostic Methyl-Bridged Complex [Mo2 Cp2 (μ-κ1 :η2 -CH3 )(μ-Pt Bu2 )(μ-CO)]

Dimolybdenum cyclopentadienyl complexes with bridging chalcogenophosphinidene ligands.

Dimolybdenum−Tin Derivatives of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] and HSnR3(R = Ph, Bu): Bridging versus Terminal Coordination of the Triorganostannyl Group

Diphosphorus-bridged heterometallic anions and hydrides derived from reactions of complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− with precursors of 16-electron metal carbonyl fragments

E-H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo-Re Complex. A Platform Combining Nucleophilic and Electrophilic Features

Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo2(η5-C5H5)(μ-κ1:κ1,η5-PC5H4)(η6-C6H3tBu3)(CO)2(PMe3)]

Enhanced nucleophilic behavior of a dimolybdenum phosphinidene complex: multicomponent reactions with activated alkenes and alkynes in the presence of CO or CNXyl

From coordinated oxophosphinidene to O,O,P-bound arylhypophosphite(2-) to build a singular Mo2Sn2O4P2 metallocycle

Gold(I) and related heterometallic derivatives of dimolybdenum complexes with asymmetric phosphinidene bridges

Heterometallic derivatives of [Fe2Cp2(μ-PCy)(μ-CO)(CO)2]: rational synthesis of polynuclear complexes from neutral precursors having pyramidal-phosphinidene bridges.

Heterometallic derivatives of the unsaturated ditungsten hydride [W2(η(5)-C5H5)2(H)(μ-PCy2)(CO)2]

High yield synthesis and reactivity of a phosphinidene bridged dimolybdenum complex

Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2](-).

Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4

Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes

Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo₂(η⁵-C₅H₅)₂(μ-CH₂R)(μ-PCy₂)(CO)₂] (R = H, Ph) with isocyanides and secondary phosphines.

Low-temperature N-O bond cleavage and reversible N-P bond formation processes in the reactions of the unsaturated anions [M2(η5-C5H5)2(μ-PCy2)(μ-CO)2]- (M = Mo, W) with the nitrosyl complex [Re(η5-C5H4Me)(CO)2(NO)]+.

Low-temperature N-O bond cleavage in nitrosyl ligands induced by the unsaturated dimolybdenum anion [Mo2(eta(5)-C5H5)2(mu-PPh2)(mu-CO)2]-.

Low-temperature N-O bond cleavage of nitrogen monoxide in heterometallic carbonyl complexes. An experimental and theoretical study.

Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo2(η5-C5H5)2(μ-R)(μ-PCy2)(CO)2] (R = Me, CH2Ph, Ph) with CO and NO

Mild N–O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center

Mild P-P bond cleavage in the methyldiphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] to give novel phosphide-bridged trinuclear derivatives

Mild P4Activation To Give an Anionic Diphosphorus Complex with a Dual Binding Ability at a Single P Site

M−P versus MM Bonds as Protonation Sites in the Organophosphide-Bridged Complexes [M2Cp2(μ-PR2)(μ-PR‘2)(CO)2], (M = Mo, W; R, R‘ = Ph, Et, Cy)†

N-O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W)

Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO)2{E,P-EP(O)(2,4,6-C6H2tBu3)}]−(E = O, S)

One-step synthesis and P-H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

Oxidation reactions of the phosphinidene oxide ligand.

P-N and N-Mo Bond Formation Processes in the Reactions of a Pyramidal Phosphinidene-Bridged Dimolybdenum Complex with Diazoalkanes and Organic Azides

P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes*)(CO)2] (Mes* = 2,4,6-C6H2tBu3).

Phosphinidene-bridged binuclear complexes

Proton induced P–H and Mo–H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(µ-H)(µ-PHR)(CO)4] (R = Cy, 2,4,6-C6H2R′3; R′ = H, Me,tBu)

Reactions of the Tetrafluoroborate Complex [Mo2Cp2(κ2-F2BF2)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P)

Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite Ligand

Reactions of the Unsaturated Hydroxo Complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N)

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with electrophiles based on p-block elements

Reactions of the unsaturated complex [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PEt(2))(2)(CO)(2)] with [Au(PR(3))](+) cations: kinetic preference of the Mo-P bonds as the site of attack of the gold(I) electrophile.

Reactivity of [Mn2(.mu.-H)2(CO)6(.mu.-tedip)] (tedip = (EtO)2POP(OEt)2) with Group 11 Alkynyl Compounds. X-ray Structures of [Ag2Mn4(.mu.-H)6(CO)12(.mu.-tedip)2] and [AuMn4(.mu.-H)5(CO)12(.mu.-tedip)2]

Reactivity of the 30-electron dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]− towards β,γ-unsaturated organic halides: Alkenyl, allenyl and alkoxycarbyne derivatives

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]− Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Donor Ability and Dynamics of the P2 Ligand

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− toward Phosphorus- and Transition Metal-Based Electrophiles

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward 17- and 16-Electron Metal Carbonyl Fragments: Rational Synthesis of Electron-Deficient Heterometallic Clusters

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward P-Donor Bidentate Ligands and Unsaturated N-Containing Organic Molecules

Reactivity of the unsaturated dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]− towards electrophiles based on p- and d-block elements

Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(CO)2]: Migratory Behavior and Methylidyne Derivatives

Reply to the ‘Comment on “Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−”’ by M. Green, Dalton Transactions, 2018, 47, DOI: 10.1039/C8DT00044A

Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands.

Structure and Bonding in the Unsaturated Hydride- and Hydrocarbyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-X)(μ-PCy2)(CO)2] (X = H, CH3, CH2Ph, Ph). Evidence for the Presence of α-Agostic and π-Bonding Interactions†

Structure and dynamics of heterometallic clusters derived from addition of metal carbonyl fragments to the unsaturated hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity

Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex.

Synthesis and Decarbonylation Reactions of Diiron Cyclopentadienyl Complexes with Bent-Phosphinidene Bridges

Synthesis and Decarbonylation Reactions of the Triiron Phosphinidene Complex [Fe3Cp3(μ-H)(μ3-PPh)(CO)4]: Easy Cleavage and Formation of P–H and Fe–Fe Bonds

Synthesis of the triply-bonded dimolybdenum anions [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PA(2))(mu-CO)(2)](-) (A = Cy, Et, Ph, OEt): unsaturated hydride and carbyne derivatives.

Ten-electron coordination and reactivity of an arylphosphinidene ligand.

Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study.

Tetranuclear phosphide- and phosphinidene-bridged derivatives of the diphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2].

The carbaborane group η5-C2B9H9Me2as a spectator and non-spectator ligand in di- and tri-metal complex chemistry: X-ray crystal structures of [PPh4][Co2W(µ3-CPh)(CO)8(η5-C2B9H9Me2)].1/2CH2Cl2, [NEt4][FeW(µ-CC6H3Me2-2,6)(CO)5-(η5-C2B9H9Me2)], and

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

Chemistry of the oxophosphinidene ligand. 2. Reactivity of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) toward electrophiles based on elements different from carbon.

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes)(CO)2] (Mes = 2,4,6-C6H2tBu3).