List of works - Ruben Martin

A Mild and Direct Site-Selective sp2 C-H Silylation of (Poly)Azines

scientific article published on 21 December 2018

A Mild and Ligand-Free Ni-Catalyzed Silylation via C-OMe Cleavage

scientific article published on 28 December 2016

A cheap metal for a "noble" task: preparative and mechanistic aspects of cycloisomerization and cycloaddition reactions catalyzed by low-valent iron complexes

scientific article

A concise enantioselective entry to the synthesis of deoxy-azasugars

scientific article

A general method for the direct alpha-arylation of aldehydes with aryl bromides and chlorides

scientific article published on 01 January 2007

A mild Ni/Cu-catalyzed silylation via C-O cleavage

scientific article published on 03 February 2014

An improved protocol for the Pd-catalyzed alpha-arylation of aldehydes with aryl halides.

scientific article published on 23 September 2008

Back Cover: Nickel-Catalyzed Reductive Amidation of Unactivated Alkyl Bromides (Angew. Chem. Int. Ed. 37/2016)

Base-Mediated Defluorosilylation of C(sp2 )-F and C(sp3 )-F Bonds

scientific article published on 17 January 2019

Catalytic intermolecular dicarbofunctionalization of styrenes with CO2 and radical precursors

scientific article published on 12 July 2017

Combined experimental and theoretical study on the reductive cleavage of inert C-O bonds with silanes: ruling out a classical Ni(0)/Ni(II) catalytic couple and evidence for Ni(I) intermediates.

scientific article

Correction to "Intermediacy of Ni-Ni Species in sp2 C-O Bond Cleavage of Aryl Esters: Relevance in Catalytic C-Si Bond Formation"

scientific article published on 12 December 2019

Cross-coupling of alkyl halides with aryl grignard reagents catalyzed by a low-valent iron complex

scientific article published on 01 July 2004

Cu-Catalyzed Tandem C−N Bond Formation for the Synthesis of Pyrroles and Heteroarylpyrroles

scientific article published on 27 July 2007

Cu-catalyzed mild C(sp2)-H functionalization assisted by carboxylic acids en route to hydroxylated arenes

scientific article published on 14 June 2013

Cycloisomerization of enynes catalyzed by iron(0)-ate complexes

scientific article published in September 2005

Domino cu-catalyzed C--N coupling/hydroamidation: a highly efficient synthesis of nitrogen heterocycles

scientific article published on 01 October 2006

Dual Catalytic Strategy for Forging sp2-sp3 and sp3-sp3 Architectures via β-Scission of Aliphatic Alcohol Derivatives

scientific article published on 30 November 2020

Fe-catalyzed regiodivergent [1,2]-shift of α-aryl aldehydes

scientific article published on 15 August 2013

Forging Amides Through Metal-Catalyzed C-C Coupling with Isocyanates

Forging C-C Bonds Through Decarbonylation of Aryl Ketones

scientific article published on 3 May 2017

Formal γ-alkynylation of ketones via Pd-catalyzed C-C cleavage

scientific article published on 07 November 2012

General approach to glycosidase inhibitors. Enantioselective synthesis of deoxymannojirimycin and swainsonine

scientific article

Intermediacy of Ni-Ni Species in sp2 C-O Bond Cleavage of Aryl Esters: Relevance in Catalytic C-Si Bond Formation

scientific article published on 02 July 2018

Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C-OMe Cleavage.

scientific article published on 22 May 2015

Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

scientific article published on 12 December 2014

Ligand-accelerated Pd-catalyzed ketone γ-arylation via C-C cleavage with aryl chlorides

scientific article published on 14 February 2012

Ligand-free Ni-catalyzed reductive cleavage of inert carbon-sulfur bonds

scientific article published on 18 January 2012

Metal-catalyzed activation of ethers via C-O bond cleavage: a new strategy for molecular diversity.

scientific article

Metal-catalyzed carboxylation of organometallic reagents with carbon dioxide

scientific article published on 01 January 2009

Metal-catalyzed reductive coupling reactions of organic halides with carbonyl-type compounds.

scientific article published on 6 June 2014

Mild ArI-catalyzed C(sp²)-H or C(sp³)-H functionalization/C-O formation: an intriguing catalyst-controlled selectivity switch

scientific article published on 25 August 2014

Myth or reality? Fixation of carbon dioxide into complex organic matter under mild conditions

scientific article published on 12 May 2011

N-Heterocyclic carbene dichotomy in Pd-catalyzed acylation of aryl chlorides via C-H bond functionalization

scientific article published on 03 October 2012

Ni(I)-Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers

scientific article published on 10 June 2020

Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2.

scientific article

Ni-Catalyzed Borylation of Aryl Fluorides via C-F Cleavage.

scientific article published on 23 September 2015

Ni-Catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2

scientific article published on 18 May 2015

Ni-Catalyzed Regioselective Hydrocarboxylation of Alkynes with CO2 by Using Simple Alcohols as Proton Sources.

scientific article published on 8 July 2015

Ni-Catalyzed Site-Selective Dicarboxylation of 1,3-Dienes with CO2.

scientific article

Ni-Catalyzed Stannylation of Aryl Esters via C-O Bond Cleavage

scientific article published on 10 February 2017

Ni-Catalyzed Stereoselective Arylation of Inert C–O bonds at Low Temperatures

article

Ni-catalyzed Reductive Deaminative Arylation at sp3 Carbon Centers

scientific article published on 29 March 2019

Ni-catalyzed Umpolung Arylation of Ambiphilic a-Bromo Boronic Esters

scientific article published on 15 February 2018

Ni-catalyzed carboxylation of C(sp2)- and C(sp3)-O bonds with CO2.

scientific article published on 9 January 2014

Ni-catalyzed direct carboxylation of benzyl halides with CO2

scientific article published on 14 January 2013

Ni-catalyzed direct reductive amidation via C-O bond cleavage.

scientific article

Ni-catalyzed reduction of inert C-O bonds: a new strategy for using aryl ethers as easily removable directing groups

scientific article published on 15 September 2010

Nickel-Catalyzed Carboxylation of Benzylic C-N Bonds with CO2

scientific article published on 16 March 2016

Nickel-Catalyzed Chemo-, Regio- and Diastereoselective Bond Formation through Proximal C-C Cleavage of Benzocyclobutenones

scientific article published on 11 June 2015

Nickel-Catalyzed Reductive Amidation of Unactivated Alkyl Bromides

scientific article

Nickel-catalyzed enantioselective C-C bond formation through C(sp2)-O cleavage in aryl esters

scientific article published on 4 February 2015

Nickel‐Catalyzed Decarbonylative CH Coupling Reactions: A Strategy for Preparing Bis(heteroaryl) Backbones ⬇️

scholarly article by Arkaitz Correa et al published 3 January 2013 in Angewandte Chemie International Edition

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

scientific article

Palladium-catalyzed direct carboxylation of aryl bromides with carbon dioxide

scientific article published on 01 November 2009

Pd-Catalyzed Kumada−Corriu Cross-Coupling Reactions at Low Temperatures Allow the Use of Knochel-type Grignard Reagents

article

Pd-catalyzed intramolecular acylation of aryl bromides via C-H functionalization: a highly efficient synthesis of benzocyclobutenones.

scientific article published in January 2010

Preparation, structure, and reactivity of nonstabilized organoiron compounds. Implications for iron-catalyzed cross coupling reactions

scientific article published in July 2008

Remote sp2 C-H Carboxylation via Catalytic 1,4-Ni Migration with CO2

scientific article published on 10 September 2020

Ring-closing metathesis of chiral allylamines. Enantioselective synthesis of (2S,3R,4S)-3,4-dihydroxyproline.

scientific article published in October 2002

Sequential copper-catalyzed vinylation/cyclization: an efficient synthesis of functionalized oxazoles

scientific article published on 17 November 2007

Site-Selective 1,2-Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis

scientific article published on 03 February 2020

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water.

scientific article published on 16 August 2017

Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins

scientific article published on 02 October 2019

Site-Selective Ni-Catalyzed Reductive Coupling of α-Haloboranes with Unactivated Olefins

scientific article published on 28 September 2018

Site-Selective, Remote sp3 C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis

scientific article published on 06 June 2019

Stereoselective Base-Catalyzed 1,1-Silaboration of Terminal Alkynes

scientific article published on 16 December 2019

Stereoselective Synthesis of 2-Acetamido-1,2-dideoxyallonojirimycin (DAJNAc), a New Potent Hexosaminidase Inhibitor

scientific article published on 26 June 2013

Switchable Site-Selective Catalytic Carboxylation of Allylic Alcohols with CO2.

scientific article published on 2 May 2017

Synergistic palladium-catalyzed C(sp3)-H activation/C(sp3)-O bond formation: a direct, step-economical route to benzolactones

scientific article published on 31 October 2011

Transition-Metal-Catalyzed Carboxylation Reactions with Carbon Dioxide

scientific article published on 02 October 2018

Visible-Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts.

scientific article

Walking Metals for Remote Functionalization.

scientific article published on 8 February 2018

sp3 C-H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts

scientific article published on 17 September 2018

List of works by Ruben Martin

A Mild and Direct Site-Selective sp2 C-H Silylation of (Poly)Azines

A Mild and Ligand-Free Ni-Catalyzed Silylation via C-OMe Cleavage

A cheap metal for a "noble" task: preparative and mechanistic aspects of cycloisomerization and cycloaddition reactions catalyzed by low-valent iron complexes

A concise enantioselective entry to the synthesis of deoxy-azasugars

A general method for the direct alpha-arylation of aldehydes with aryl bromides and chlorides

A mild Ni/Cu-catalyzed silylation via C-O cleavage

An improved protocol for the Pd-catalyzed alpha-arylation of aldehydes with aryl halides.

Back Cover: Nickel-Catalyzed Reductive Amidation of Unactivated Alkyl Bromides (Angew. Chem. Int. Ed. 37/2016)

Base-Mediated Defluorosilylation of C(sp2 )-F and C(sp3 )-F Bonds

Catalytic intermolecular dicarbofunctionalization of styrenes with CO2 and radical precursors

Combined experimental and theoretical study on the reductive cleavage of inert C-O bonds with silanes: ruling out a classical Ni(0)/Ni(II) catalytic couple and evidence for Ni(I) intermediates.

Correction to "Intermediacy of Ni-Ni Species in sp2 C-O Bond Cleavage of Aryl Esters: Relevance in Catalytic C-Si Bond Formation"

Cross-coupling of alkyl halides with aryl grignard reagents catalyzed by a low-valent iron complex

Cu-Catalyzed Tandem C−N Bond Formation for the Synthesis of Pyrroles and Heteroarylpyrroles

Cu-catalyzed mild C(sp2)-H functionalization assisted by carboxylic acids en route to hydroxylated arenes

Cycloisomerization of enynes catalyzed by iron(0)-ate complexes

Domino cu-catalyzed C--N coupling/hydroamidation: a highly efficient synthesis of nitrogen heterocycles

Dual Catalytic Strategy for Forging sp2-sp3 and sp3-sp3 Architectures via β-Scission of Aliphatic Alcohol Derivatives

Fe-catalyzed regiodivergent [1,2]-shift of α-aryl aldehydes

Forging Amides Through Metal-Catalyzed C-C Coupling with Isocyanates

Forging C-C Bonds Through Decarbonylation of Aryl Ketones

Formal γ-alkynylation of ketones via Pd-catalyzed C-C cleavage

General approach to glycosidase inhibitors. Enantioselective synthesis of deoxymannojirimycin and swainsonine

Intermediacy of Ni-Ni Species in sp2 C-O Bond Cleavage of Aryl Esters: Relevance in Catalytic C-Si Bond Formation

Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C-OMe Cleavage.

Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

Ligand-accelerated Pd-catalyzed ketone γ-arylation via C-C cleavage with aryl chlorides

Ligand-free Ni-catalyzed reductive cleavage of inert carbon-sulfur bonds

Metal-catalyzed activation of ethers via C-O bond cleavage: a new strategy for molecular diversity.

Metal-catalyzed carboxylation of organometallic reagents with carbon dioxide

Metal-catalyzed reductive coupling reactions of organic halides with carbonyl-type compounds.

Mild ArI-catalyzed C(sp²)-H or C(sp³)-H functionalization/C-O formation: an intriguing catalyst-controlled selectivity switch

Myth or reality? Fixation of carbon dioxide into complex organic matter under mild conditions

N-Heterocyclic carbene dichotomy in Pd-catalyzed acylation of aryl chlorides via C-H bond functionalization

Ni(I)-Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers

Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2.

Ni-Catalyzed Borylation of Aryl Fluorides via C-F Cleavage.

Ni-Catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2

Ni-Catalyzed Regioselective Hydrocarboxylation of Alkynes with CO2 by Using Simple Alcohols as Proton Sources.

Ni-Catalyzed Site-Selective Dicarboxylation of 1,3-Dienes with CO2.

Ni-Catalyzed Stannylation of Aryl Esters via C-O Bond Cleavage

Ni-Catalyzed Stereoselective Arylation of Inert C–O bonds at Low Temperatures

Ni-catalyzed Reductive Deaminative Arylation at sp3 Carbon Centers

Ni-catalyzed Umpolung Arylation of Ambiphilic a-Bromo Boronic Esters

Ni-catalyzed carboxylation of C(sp2)- and C(sp3)-O bonds with CO2.

Ni-catalyzed direct carboxylation of benzyl halides with CO2

Ni-catalyzed direct reductive amidation via C-O bond cleavage.

Ni-catalyzed reduction of inert C-O bonds: a new strategy for using aryl ethers as easily removable directing groups

Nickel-Catalyzed Carboxylation of Benzylic C-N Bonds with CO2

Nickel-Catalyzed Chemo-, Regio- and Diastereoselective Bond Formation through Proximal C-C Cleavage of Benzocyclobutenones

Nickel-Catalyzed Reductive Amidation of Unactivated Alkyl Bromides

Nickel-catalyzed enantioselective C-C bond formation through C(sp2)-O cleavage in aryl esters

Nickel‐Catalyzed Decarbonylative CH Coupling Reactions: A Strategy for Preparing Bis(heteroaryl) Backbones ⬇️

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Palladium-catalyzed direct carboxylation of aryl bromides with carbon dioxide

Pd-Catalyzed Kumada−Corriu Cross-Coupling Reactions at Low Temperatures Allow the Use of Knochel-type Grignard Reagents

Pd-catalyzed intramolecular acylation of aryl bromides via C-H functionalization: a highly efficient synthesis of benzocyclobutenones.

Preparation, structure, and reactivity of nonstabilized organoiron compounds. Implications for iron-catalyzed cross coupling reactions

Remote sp2 C-H Carboxylation via Catalytic 1,4-Ni Migration with CO2

Ring-closing metathesis of chiral allylamines. Enantioselective synthesis of (2S,3R,4S)-3,4-dihydroxyproline.

Sequential copper-catalyzed vinylation/cyclization: an efficient synthesis of functionalized oxazoles

Site-Selective 1,2-Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water.

Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins

Site-Selective Ni-Catalyzed Reductive Coupling of α-Haloboranes with Unactivated Olefins

Site-Selective, Remote sp3 C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis

Stereoselective Base-Catalyzed 1,1-Silaboration of Terminal Alkynes

Stereoselective Synthesis of 2-Acetamido-1,2-dideoxyallonojirimycin (DAJNAc), a New Potent Hexosaminidase Inhibitor

Switchable Site-Selective Catalytic Carboxylation of Allylic Alcohols with CO2.

Synergistic palladium-catalyzed C(sp3)-H activation/C(sp3)-O bond formation: a direct, step-economical route to benzolactones

Transition-Metal-Catalyzed Carboxylation Reactions with Carbon Dioxide

Visible-Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts.

Walking Metals for Remote Functionalization.

sp3 C-H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts