List of works - Daniel A Singleton

"Concerted" transition state, stepwise mechanism. Dynamics effects in C2-C6 enyne allene cyclizations

scientific article published on June 2005

13C and (2)H kinetic isotope effects and the mechanism of Lewis acid-catalyzed ene reactions of formaldehyde.

scientific article

13C and 2H kinetic isotope effects and the mechanism of bromination of 1-pentene under synthetic conditions

scientific article published on 01 July 1999

A few molecules can control the enantiomeric outcome. Evidence supporting absolute asymmetric synthesis using the Soai asymmetric autocatalysis

scientific article published on 01 November 2003

A new form of kinetic isotope effect. Dynamic effects on isotopic selectivity and regioselectivity

scientific article

Bond Memory in Dynamically Determined Stereoselectivity

scientific article published on 20 December 2019

Carbometalations of simple alkenes with allyldibromoborane

scientific article published on 01 August 1999

Comment on "Activation of methane to CH3 +: A selective industrial route to methanesulfonic acid"

scientific article published on 01 May 2019

Competition between reaction and intramolecular energy redistribution in solution: observation and nature of nonstatistical dynamics in the ozonolysis of vinyl ethers

scientific article published on 15 August 2011

Concert along the Edge: Dynamics and the Nature of the Border between General and Specific Acid-Base Catalysis

scientific article published on 5 April 2017

Control elements in dynamically determined selectivity on a bifurcating surface

scientific article published on 11 October 2008

Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution

scientific article published on 21 October 2016

Controlling Selectivity by Controlling the Path of Trajectories

scientific article

Cycloalkenylboranes as Highly Reactive and Selective Diels-Alder Dienophiles. A Simple Synthesis of Bridgehead Bicyclic Alcohols

scientific article published on 01 April 1997

Deuterium kinetic isotope effects and the mechanism of the bacterial luciferase reaction

scientific article published on 01 February 1998

Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene

scientific article published on June 2006

Dynamic origin of the stereoselectivity of a nucleophilic substitution reaction

scientific article published on 27 April 2012

Dynamically Complex [6+4] and [4+2] Cycloadditions in the Biosynthesis of Spinosyn A

scientific article published on 24 February 2016

Dynamics and a unified understanding of competitive [2,3]- and [1,2]-sigmatropic rearrangements based on a study of ammonium ylides

scientific article published on 28 February 2014

Dynamics and the Regiochemistry of Nitration of Toluene

scientific article published on 30 October 2016

Dynamics and the failure of transition state theory in alkene hydroboration

scientific article

Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents.

scientific article published on 20 September 2010

Enantioselective synthesis without discrete optically active additives

scientific article published on 01 August 2002

Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing

scientific article published on 18 January 2012

Exo-selective Diels-Alder reactions of vinylazepines. Origin of divergent stereoselectivity in Diels-Alder reactions of vinylazepines, vinylpiperideines, and vinylcycloalkenes

scientific article published in November 2003

Experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl radical from intramolecular 12C/13C kinetic isotope effects.

scientific article published on September 2010

Failure and Redemption of Statistical and Nonstatistical Rate Theories in the Hydroboration of Alkenes

scientific article published on 13 October 2017

Ir-Catalyzed ortho-Borylation of Phenols Directed by Substrate-Ligand Electrostatic Interactions: A Combined Experimental/in Silico Strategy for Optimizing Weak Interactions

scientific article published on 28 April 2017

Isotope effect, mechanism, and origin of catalysis in the decarboxylation of mandelylthiamin

scientific article

Isotope effects and heavy-atom tunneling in the Roush allylboration of aldehydes

scientific article published on 16 April 2012

Isotope effects and the mechanism of allylic hydroxylation of alkenes with selenium dioxide

scientific article published on 01 November 2000

Isotope effects and the mechanism of an electron-transfer-catalyzed Diels-Alder reaction

scientific article published in September 2002

Isotope effects and the mechanism of epoxidation of cyclohexenone with tert-butyl hydroperoxide

scientific article published on 3 July 2007

Isotope effects and the nature of enantioselectivity in the shi epoxidation. The importance of asynchronicity

scientific article published in May 2005

Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations

scientific article published in December 2003

Isotope effects and the nature of stereo- and regioselectivity in hydroaminations of vinylarenes catalyzed by palladium(ii)-diphosphine complexes

scientific article published on 01 July 2004

Isotope effects, dynamic matching, and solvent dynamics in a Wittig reaction. Betaines as bypassed intermediates

scientific article published on 12 September 2014

Isotope effects, dynamics, and the mechanism of solvolysis of aryldiazonium cations in water

scientific article published in March 2005

Isotope-induced desymmetrization can mimic isotopic perturbation of equilibria. On the symmetry of bromonium ions and hydrogen bonds

scientific article published on 10 October 2011

Labelling and determination of the energy in reactive intermediates in solution enabled by energy-dependent reaction selectivity

scientific article published in January 2018

Mechanism and origin of enantioselectivity in the Rh2(OAc)(DPTI)3-catalyzed cyclopropenation of alkynes

scientific article published in May 2005

Mechanism and origin of stereoselectivity in Lewis acid catalyzed [2 + 2] cycloadditions of ketenes with aldehydes

scientific article published on 01 May 2002

Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism

scientific article

Mechanistic Studies of Formal Thioboration Reactions of Alkynes

scientific article

Minimum Energy Structure of Hydridotris(pyrazolyl)borato Iridium(V) Tetrahydride Is Not aC3vCapped Octahedron

scientific article published on 01 October 2001

Newtonian kinetic isotope effects. Observation, prediction, and origin of heavy-atom dynamic isotope effects

scientific article published on June 2009

Outer-sphere direction in iridium C-H borylation

scientific article published on 3 July 2012

Phenomenon of optical self-purification of chiral non-racemic compounds

scientific article published on 13 September 2007

Racing carbon atoms. Atomic motion reaction coordinates and structural effects on Newtonian kinetic isotope effects

scientific article published on October 2012

Reaction removal of polychlorinated biphenyls from transformer oil: treatment of contaminated oil with poly(ethylene glycol)/potassium hydroxide

scientific article published on 01 August 1985

Reactions of Alkynyldihaloboranes with 1,3-Dienes. 1,4-Alkynylborations and Stepwise Diels-Alder Reactions

scientific article published on 01 April 1997

Recrossing and dynamic matching effects on selectivity in a Diels-Alder reaction

scientific article published on January 2009

The normal range for secondary Swain-Schaad exponents without tunneling or kinetic complexity

scientific article published on 01 March 2005

Transition-state geometry measurements from (13)c isotope effects. The experimental transition state for the epoxidation of alkenes with oxaziridines

scientific article published on February 2009

Vibrationally Hot and Cold Triplets. Sensitizer-Dependent Dynamics and Localized Vibrational Promotion of a Di-π-methane Rearrangement

scientific article published on 12 November 2020

List of works by Daniel A Singleton

"Concerted" transition state, stepwise mechanism. Dynamics effects in C2-C6 enyne allene cyclizations

13C and (2)H kinetic isotope effects and the mechanism of Lewis acid-catalyzed ene reactions of formaldehyde.

13C and 2H kinetic isotope effects and the mechanism of bromination of 1-pentene under synthetic conditions

A few molecules can control the enantiomeric outcome. Evidence supporting absolute asymmetric synthesis using the Soai asymmetric autocatalysis

A new form of kinetic isotope effect. Dynamic effects on isotopic selectivity and regioselectivity

Bond Memory in Dynamically Determined Stereoselectivity

Carbometalations of simple alkenes with allyldibromoborane

Comment on "Activation of methane to CH3 +: A selective industrial route to methanesulfonic acid"

Competition between reaction and intramolecular energy redistribution in solution: observation and nature of nonstatistical dynamics in the ozonolysis of vinyl ethers

Concert along the Edge: Dynamics and the Nature of the Border between General and Specific Acid-Base Catalysis

Control elements in dynamically determined selectivity on a bifurcating surface

Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution

Controlling Selectivity by Controlling the Path of Trajectories

Cycloalkenylboranes as Highly Reactive and Selective Diels-Alder Dienophiles. A Simple Synthesis of Bridgehead Bicyclic Alcohols

Deuterium kinetic isotope effects and the mechanism of the bacterial luciferase reaction

Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene

Dynamic origin of the stereoselectivity of a nucleophilic substitution reaction

Dynamically Complex [6+4] and [4+2] Cycloadditions in the Biosynthesis of Spinosyn A

Dynamics and a unified understanding of competitive [2,3]- and [1,2]-sigmatropic rearrangements based on a study of ammonium ylides

Dynamics and the Regiochemistry of Nitration of Toluene

Dynamics and the failure of transition state theory in alkene hydroboration

Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents.

Enantioselective synthesis without discrete optically active additives

Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing

Exo-selective Diels-Alder reactions of vinylazepines. Origin of divergent stereoselectivity in Diels-Alder reactions of vinylazepines, vinylpiperideines, and vinylcycloalkenes

Experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl radical from intramolecular 12C/13C kinetic isotope effects.

Failure and Redemption of Statistical and Nonstatistical Rate Theories in the Hydroboration of Alkenes

Ir-Catalyzed ortho-Borylation of Phenols Directed by Substrate-Ligand Electrostatic Interactions: A Combined Experimental/in Silico Strategy for Optimizing Weak Interactions

Isotope effect, mechanism, and origin of catalysis in the decarboxylation of mandelylthiamin

Isotope effects and heavy-atom tunneling in the Roush allylboration of aldehydes

Isotope effects and the mechanism of allylic hydroxylation of alkenes with selenium dioxide

Isotope effects and the mechanism of an electron-transfer-catalyzed Diels-Alder reaction

Isotope effects and the mechanism of epoxidation of cyclohexenone with tert-butyl hydroperoxide

Isotope effects and the nature of enantioselectivity in the shi epoxidation. The importance of asynchronicity

Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations

Isotope effects and the nature of stereo- and regioselectivity in hydroaminations of vinylarenes catalyzed by palladium(ii)-diphosphine complexes

Isotope effects, dynamic matching, and solvent dynamics in a Wittig reaction. Betaines as bypassed intermediates

Isotope effects, dynamics, and the mechanism of solvolysis of aryldiazonium cations in water

Isotope-induced desymmetrization can mimic isotopic perturbation of equilibria. On the symmetry of bromonium ions and hydrogen bonds

Labelling and determination of the energy in reactive intermediates in solution enabled by energy-dependent reaction selectivity

Mechanism and origin of enantioselectivity in the Rh2(OAc)(DPTI)3-catalyzed cyclopropenation of alkynes

Mechanism and origin of stereoselectivity in Lewis acid catalyzed [2 + 2] cycloadditions of ketenes with aldehydes

Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism

Mechanistic Studies of Formal Thioboration Reactions of Alkynes

Minimum Energy Structure of Hydridotris(pyrazolyl)borato Iridium(V) Tetrahydride Is Not aC3vCapped Octahedron

Newtonian kinetic isotope effects. Observation, prediction, and origin of heavy-atom dynamic isotope effects

Outer-sphere direction in iridium C-H borylation

Phenomenon of optical self-purification of chiral non-racemic compounds

Racing carbon atoms. Atomic motion reaction coordinates and structural effects on Newtonian kinetic isotope effects

Reaction removal of polychlorinated biphenyls from transformer oil: treatment of contaminated oil with poly(ethylene glycol)/potassium hydroxide

Reactions of Alkynyldihaloboranes with 1,3-Dienes. 1,4-Alkynylborations and Stepwise Diels-Alder Reactions

Recrossing and dynamic matching effects on selectivity in a Diels-Alder reaction

The normal range for secondary Swain-Schaad exponents without tunneling or kinetic complexity

Transition-state geometry measurements from (13)c isotope effects. The experimental transition state for the epoxidation of alkenes with oxaziridines

Vibrationally Hot and Cold Triplets. Sensitizer-Dependent Dynamics and Localized Vibrational Promotion of a Di-π-methane Rearrangement