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List of works by Juan Crugeiras

A comparison of the electrophilic reactivities of Zn2+ and acetic acid as catalysts of enolization: imperatives for enzymatic catalysis of proton transfer at carbon

scientific article

Acid-catalysed chlorine transfer from N-chloramines to iodide ion: experimental evidence for a predicted change in mechanism

scientific article published on 22 July 2010

Carbon acidity of the alpha-pyridinium carbon of a pyridoxamine analog.

scientific article published on 26 April 2005

DFT and AIM study of the protonation of nitrous acid and the pKa of nitrous acidium ion.

scientific article

Glycine enolates: the effect of formation of iminium ions to simple ketones on alpha-amino carbon acidity and a comparison with pyridoxal iminium ions

scientific article published on 17 January 2008

Glycine enolates: the large effect of iminium ion formation on alpha-amino carbon acidity

scientific article published in August 2001

Halogen transfer through halogen bonds in halogen-bound ammonia homodimers.

scientific article published on 2 November 2016

Kinetic and thermodynamic barriers to chlorine transfer between amines in aqueous solution.

scientific article published in August 2009

Nucleophilic substitution reactions of N-chloramines: evidence for a change in mechanism with increasing nucleophile reactivity

scientific article published on 31 March 2007

Pyridoxal 5'-phosphate: electrophilic catalyst extraordinaire

scientific article published on 27 July 2009

Structure−Reactivity Relationships and Intrinsic Reaction Barriers for Nucleophile Additions to a Quinone Methide: A Strongly Resonance-Stabilized Carbocation

article

Substituent effects on electrophilic catalysis by the carbonyl group: anatomy of the rate acceleration for PLP-catalyzed deprotonation of glycine.

scientific article

Substituent effects on the thermodynamic stability of imines formed from glycine and aromatic aldehydes: implications for the catalytic activity of pyridoxal-5'-phosphate.

scientific article

The PLP cofactor: lessons from studies on model reactions.

scientific article published on 20 December 2010