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List of works by Gérard Jaouen

(N-Succinimidyl 4-pentynoate)(hexacarbonyldicobalt): a transition-metal carbonyl complex having similar uses to the Bolton-Hunter reagent

scientific article published on 01 January 1991

(η6-Arene) ruthenium(ii) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels–Alder reaction in water

scientific article published on 20 April 2010

4-(3-Methoxy-phen-oxy)butyric acid

scientific article published on 19 March 2009

4-Benchrotrenyl Pyrylium Salts as Protein Organometallic Labelling Reagents

A Novel and Mild Metal-Exchange Reaction in the Organometallic Cyclopentadienyl Series: 1,1‘-Diaryl 2-Cymantrenyl 1-Butene as an Example

scientific article published in 2000

A [3]ferrocenophane polyphenol showing a remarkable antiproliferative activity on breast and prostate cancer cell lines

scientific article

A facile route to Cr(CO)5(CX) (X  S, Se) complexes

A fast route to the potential biological reagent (η5-C5H4COOH)Re(CO)3 from [NH4] [ReO4]

A ferrocenyl derivative of hydroxytamoxifen elicits an estrogen receptor-independent mechanism of action in breast cancer cell lines

scientific article

A new application of bioorganometallics: the first simultaneous triple assay by the carbonylmetalloimmunoassay (CMIA) method

A new bioorthogonal cross-linker with alkyne and hydrazide end groups for chemoselective ligation. Application to antibody labelling

A new efficient route to chiral 1,3-disubstituted ferrocenes: application to the syntheses of (R(p))- and (S(p))-17alpha-[(3'-formylferrocenyl)ethynyl]estradiol

scientific article

A new generation of ferrociphenols leads to a great diversity of reactive metabolites, and exhibits remarkable antiproliferative properties

scientific article published on 16 November 2017

A new optically pure half-sandwich Cp–Ru diphosphine complex with a chiral metal centre, (S)-Ru(η5-C5H5)(EPHOS)Cl {EPHOS is (+)-(1R,2S)-2-[(diphenylphosphino)methylamino]-1-phenylpropyl diphenylphosphinite}

scientific article published on 31 October 2002

A new series of ferrocifen derivatives, bearing two aminoalkyl chains, with strong antiproliferative effects on breast cancer cells

A series of unconjugated ferrocenyl phenols: prospects as anticancer agents

scientific article published on May 2006

A short route to cyclopentadienyltricarbonylrhenium substituted derivatives

A variable-temperature 13C NMR study of (η5-C5H5)2Mo2(CO)4 complexes of chiral alkynes derived from a terpene or a hormonal steroid: interconversion of diastereomers via exchange of terminal and semi-bridging carbonyls

Acces a des complexes du Cr et Mn a ligands isocyanures N-α carbonyles. proprietes et exemples d'utilisation de ces coordinats inhabituels

Access to 11β-ethynyl-androst-5-ene

Addition of aryllithiums to an 11-oxo-steroid

article

Affinity labelling of estradiol receptor by ferrocenyl tagging of estradiol 17α-position

Alkylation selective de substituants aromatiques actives par un greffon chrome carbonyle

article published in 1979

An organometallic route for the preparation of ring-substituted 2-aryl-propanoic and -butanoic acids

An organometallic substitute for the radioactive Bolton–Hunter reagent

Analytical potential of near-infrared fourier transform Raman spectra in the detection of solid transition metal carbonyl steroid hormones

Anodic properties of diarylethene derivatives having organometallic piano-stool tags

article

Antibacterial properties and mode of action of new triaryl butene citrate compounds.

scientific article

Antiplasmodial activity of iron(II) and ruthenium(II) organometallic complexes against Plasmodium falciparum blood parasites.

scientific article

Antiproliferative effect of ferrocifen drug candidates on malignant pleural mesothelioma cell lines

Are the 11-oxo-steroids really so hindered towards organometallic compounds?

scientific article

Arsenic-Based Drugs: From Fowler’s Solution to Modern Anticancer Chemotherapy

article published in 2010

Asymmetric biochemical reduction, acylation and hydrolysis in the (diene)Fe(CO)3 series: Experimental results and molecular modelling studies

article published in 1993

Attachment of amino acid derivatives to tungsten carbonyl complexes via four component condensations

Atypical Lone Pair-π Interaction with Quinone Methides in a Series of Imido-Ferrociphenol Anticancer Drug Candidates

scientific article published on 14 May 2019

Atypical McMurry cross-coupling reactions leading to a new series of potent antiproliferative compounds bearing the key [ferrocenyl-ene-phenol] motif.

scientific article

Binding of Biotin to Gold Surfaces Functionalized by Self-Assembled Monolayers of Cystamine and Cysteamine: Combined FT-IRRAS and XPS Characterization

scientific article published on 01 March 2001

Biological evaluation of twenty-eight ferrocenyl tetrasubstituted olefins: cancer cell growth inhibition, ROS production and hemolytic activity

scientific article published on 27 May 2011

Bioorganometallic Chemistry: Structural Diversity of Organometallic Complexes with Bioligands and Molecular Recognition Studies of Several Supramolecular Hosts with Biomolecules, Alkali-Metal Ions, and Organometallic Pharmaceuticals

Bioorganometallics: Future Trends in Drug Discovery, Analytical Chemistry, and Catalysis†,‡

scholarly article by Elizabeth A. Hillard & Gérard Jaouen published 10 January 2011 in Organometallics

Boron trifluoride promoted addition of aryllithiums to estrone benzyl ether

article

Carbonyl metallo immuno assay: a new application for Fourier transform infrared spectroscopy

scientific article published on 01 November 1999

Carbonylmetalloimmunoassay (CMIA) a new type of non-radioisotopic immunoassay

scientific article published on 01 April 1992

Cobalt and molybdenum carbonyl clusters in immunology. Synthesis and binding properties of mycotoxin derivatives of zearalenone

scholarly article by Michel Gruselle et al published January 1989 in Journal of Organometallic Chemistry

Comparative Oxidative Addition of Transition-Metal Iodocyclopentadienyl Complexes (η5-C5H4-I)MLn(M = Re, Mn, Fe) with a Palladium(0) Complex: Relevance to the Efficiency of Catalytic Reactions

article

Comparative toxicity of [3]ferrocenophane and ferrocene moieties on breast cancer cells

article

Comparison of two means of attachment of an organometallic acid on gold surfaces by combining X-ray photoelectron spectroscopy and IR reflection spectroscopy

article

Conducteurs organiques ternaires: Nouvelle methode de synthese d'ions radicaux entre sels de se ou p et tcnq

Conséquences de la substitution de carbonyles par des ligands donneurs dans les complexes dérivés du benchrotrène

article published in 1973

Contribution a l'etude des metaux asymetriques

Contribution a l'etude des metaux asymetriques—II

Contribution a lietude des metallocenes

Corrigendum to “Site-selective and covalent labelling of the cysteine-containing peptide glutathione with a ferrocenyl group”

scholarly article published in Tetrahedron Letters

Covalent and Selective Labeling of Proteins with Heavy Metals. Synthesis, X-ray Structure, and Reactivity Studies ofN-Succinimidyl andN-Sulfosuccinimidyl Ester Organotungsten Complexes

Crystal structures of [(η5-C5H4COOH)W(CO)3R] (R=Me, I)

Cyclopentadienyl Iron Dicarbonyl (η1-N-Phthalimidato) Complexes Containing an Isothiocyanate Function: Synthesis and Application to Protein Side-Chain Selective Labeling

scientific article published on 01 July 1997

Cyclopentadienyl transfer reaction: thermal reaction between Re2(CO)10 and a series of cyclopentadienyl transition metal complexes

Cysteine-Specific, Covalent Anchoring of Transition Organometallic Complexes to the Protein Papain from Carica papaya

scientific article published on 01 January 2007

Deciphering the activation sequence of ferrociphenol anticancer drug candidates.

scientific article published on 11 April 2012

Decomplexation of Cyclopentadienylmanganese Tricarbonyls under Very Mild Conditions: A Novel Route to Substituted Cyclopentadienes and Their Application in Organometallic Synthesis

Design of a New Multifunctionalized PAMAM Dendrimer with Hydrazide-Terminated Spacer Arm Suitable for Metal−Carbonyl Multilabeling of Aldehyde-Containing Molecules

Diastereoselectivity in the bakers yeast reduction of [1-2H](sorbaldehyde)Fe(CO)3

Dicyclopentadienylnickel: A problematical reagent in cluster synthesis

Direct Synthesis of Tricarbonyl(cyclopentadienyl)rhenium and Tricarbonyl(cyclopentadienyl)technetium Units from Ferrocenyl Moieties− Preparation of 17α-Ethynylestradiol Derivatives Bearing a Tricarbonyl(cyclopentadienyl)technetium Group

scholarly article by Stéphane Masi et al published May 2004 in European Journal of Inorganic Chemistry

Dose effect activity of ferrocifen-loaded lipid nanocapsules on a 9L-glioma model.

scientific article published on 23 May 2009

Déprotonation des allylbenzènes chrometricarbonyle en milieu basique. Etude RMN 1H et 13C et réeactivité des anions allyliques: influence électronique et stérique du groupement chrometricarbonyle

Dérivés hydrosilylés des complexes (η-arène) tricarbonylchrome, de type (η C6R6)(CO)2Cr(H)SiHPh2; liaison à 2 électrons/3 centres, Cr—H—Si

Effect of substituents on the structure and catalytic activity of arene chromium tricarbonyls

Effect of the amino chain length and the transformation into citric acid salts of aryl-diphenyl-butenes and ferrocenyl-diphenyl-butenes bearing two dimethylaminoalkyl chains on their antimicrobial activities.

scientific article published on 4 October 2013

Efficacy of a novel ferrocenyl diaryl butene citrate compound as a biocide for preventing healthcare-associated infections

article

Efficient new constructs against triple negative breast cancer cells: synthesis and preliminary biological study of ferrocifen-SAHA hybrids and related species.

scientific article published on November 2013

Electrochemical Microbead-Based Immunoassay Using an (η5-Cyclopentadienyl)tricarbonylmanganese Redox Marker Bound to Bovine Serum Albumin

scientific article published on 01 January 2006

Electrochemical attachment of a conjugated amino–ferrocifen complex onto carbon and metal surfaces

Electrochemical parameters and techniques in drug development, with an emphasis on quinones and related compounds

scientific article published on 10 April 2008

Electron counting in square-pyramidal organo-transition-metal carbides: can a carbon atom be a vertex of a closo octahedral M5C cluster

Electronic and steric factors for elimination reactions in carbenium ions derived from (17.beta.-ethynylestradiol)M2L6 complexes (M2L6 = Co2(CO)6, Mo2Cp2(CO)4). X-ray structure of [Mo2Cp2(CO)4(.mu.-CH.tplbond.CC19H25O)]+ BF4-

article published in 1990

Enzymatic generation of planar chirality in the (arene)tricarbonylchromium series

Estradiols Modified by Metal Carbonyl Clusters as Suicide Substrates for the Study of Receptor Proteins: Application to the Estradiol Receptor

Estrogen derivatives of transition metal carbonyl clusters for analytical detection enhancement

Evaluation of bactericidal and fungicidal activity of ferrocenyl or phenyl derivatives in the diphenyl butene series

Evaluation of cytotoxic properties of organometallic ferrocifens on melanocytes, primary and metastatic melanoma cell lines

scientific article published on 3 August 2008

Evaluation of the carbonyl metallo immunoassay (CMIA) for the determination of traces of the herbicide atrazine

article published in 2003

Evidence for Targeting Thioredoxin Reductases with Ferrocenyl Quinone Methides. A Possible Molecular Basis for the Antiproliferative Effect of Hydroxyferrocifens on Cancer Cells

scientific article published on 28 October 2014

FACS analysis of oxidative stress induced on tumour cells by SERMs

FT-IR observation of covalent labelling of lysozyme crystals by organometallic complexes of transition metals

scientific article

Facile route to ferrocifen, 1-[4-(2-dimethylaminoethoxy)]-1-(phenyl-2-ferrocenyl-but-1-ene), first organometallic analogue of tamoxifen, by the McMurry reaction

article by Siden Top et al published August 1997 in Journal of Organometallic Chemistry

Facile synthesis and strong antiproliferative activity of disubstituted diphenylmethylidenyl-[3]ferrocenophanes on breast and prostate cancer cell lines

Ferrocene-Mediated Proton-Coupled Electron Transfer in a Series of Ferrocifen-Type Breast-Cancer Drug Candidates

scholarly article by Elizabeth A. Hillard et al published January 2006 in Angewandte Chemie International Edition

Ferrocenyl Quinone Methide-Thiol Adducts as New Antiproliferative Agents: Synthesis, Metabolic Formation from Ferrociphenols, and Oxidative Transformation

scientific article

Ferrocenyl catechols: synthesis, oxidation chemistry and anti-proliferative effects on MDA-MB-231 breast cancer cells.

scientific article published on 17 May 2012

Ferrocenyl chalcone difluoridoborates inhibit HIV-1 integrase and display low activity towards cancer and endothelial cells.

scientific article

Ferrocenyl compounds possessing protected phenol and thiophenol groups: Synthesis, X-ray structure, and in vitro biological effects against breast cancer

Ferrocenyl flavonoid-induced morphological modifications of endothelial cells and cytotoxicity against B16 murine melanoma cells

Ferrocenyl hydroxytamoxifen: a prototype for a new range of oestradiol receptor site-directed cytotoxics

Ferrocenyl quinone methides as strong antiproliferative agents: formation by metabolic and chemical oxidation of ferrocenyl phenols.

scientific article published on January 2009

Ferrocifen derivatives that induce senescence in cancer cells: selected examples

scientific article published on 6 September 2014

Ferrocifen type anti cancer drugs

scientific article

Ferrocifens and Ferrocifenols as New Potential Weapons against Breast Cancer

Ferrole-estradiol complex as a test for receptor dimerization

First anti-oestrogen in the cyclopentadienyl rhenium tricarbonyl series. Synthesis and study of antiproliferative effects

scholarly article by Gérard Jaouen et al published 2001 in Chemical Communications

First attachment of the stable organometallic moiety 〚Re(CO) 3 (η 5 -C 5 H 4 –C≡C–)〛 at position 11ß of oestradiol. Biochemical behaviour of the complex

First carbonyl metallo immunoassay in the environmental area: application to the herbicide chlortoluron

Foreword for the ISBOMC’06 special issue

Foreword to the special JOMC issue on bioorganometallic chemistry

Formation de liaison CC par couplage réducteur d'ions carbéniums arène chrome tricarbonyle

Fourier transform infrared spectroscopic method for the quantitative trace analysis of transition-metal carbonyl-labeled bioligands

scientific article published on 01 October 1991

Functionalisations of estrone benzyl ether at the 11 and 12 positions

Functionalized cationic (η6-arene)ruthenium(II) complexes for site-specific and covalent anchoring to papain from papaya latex. Synthesis, X-ray structures and reactivity studies

Further insights into hydrophobic interactions between ferrocenyl-tamoxifen drugs and non-polar molecular architectures at electrode surfaces

article by Omar Mertins et al published October 2009 in Journal of Electroanalytical Chemistry

Heteronuclear organotransition-metal clusters: rational syntheses and fluxional behavior

Improved addition of organolithium reagents to hindered and/or enolisable ketones

article

Improved addition of phenyllithium to hindered ketones by the use of non-polar media

article

Improved synthesis of a protected 11-oxoestrone

scientific article published on 01 December 1995

In vitro inhibitory properties of ferrocene-substituted chalcones and aurones on bacterial and human cell cultures.

scientific article published on 12 January 2012

Influence des substituants sur l'activite catalytique des composes arene-chrome tricarbonyle, mise en evidence de l'imfortance d'un α-heteroatome (O, N)

article

Infrared immunoassay

scientific article published on August 1989

Inhibition and photo-deinhibition of glutathione (S)-transferase activity by an organometallic complex: (S)-[3-CpFe(CO)2(η1-N-succinimidato)]glutathione

Inhibition of ectopic glioma tumor growth by a potent ferrocenyl drug loaded into stealth lipid nanocapsules

scientific article published on 16 May 2014

Intracellular Localization of an Osmocenyl-Tamoxifen Derivative in Breast Cancer Cells Revealed by Synchrotron Radiation X-ray Fluorescence Nanoimaging

scientific article published on 06 February 2019

Introduction of a planar chirality onto steroid substrates: synthesis of (S) and (R)-2′-formylcymantrenyl-17α-ethynylestradiols using (S) and (R)-1-formyl-2-iodo-cymantrenes

Isolation of fac-[Re(CO)3(HMPA)3][BF4]. Structural characterization of a key cationic intermediate in the exchange reaction between [Re(CO)6][BF4] and acetylferrocene. Implications in radiopharmaceutical chemistry

Labeling of proteins by organometallic complexes of rhenium(I). Synthesis and biological activity of the conjugates

scientific article published on 01 November 1993

Labelling and binding of poly-(l-lysine) to functionalised gold surfaces. Combined FT-IRRAS and XPS characterisation

scientific article published on 01 August 2001

Labelling of biologically active molecules with a cyclohexadiene tricarbonyl iron unit

Les ions α-carbéniums benchrotréniques: mode de génération, exemples d'utilisation a la préparation d'amines, d'éthers et au contrôle stéréochimique lors d'attaques nucléophiles

Lipid nanocapsules loaded with an organometallic tamoxifen derivative as a novel drug-carrier system for experimental malignant gliomas.

scientific article

Local delivery of ferrociphenol lipid nanocapsules followed by external radiotherapy as a synergistic treatment against intracranial 9L glioma xenograft.

scientific article

Mechanism of Reduction of Cymantrene (Tricarbonyl η5-Cyclopentadienylmanganese) and Its Methyl Carboximidate Derivative

article published in 2001

Modification of the estrogenic properties of diphenols by the incorporation of ferrocene. Generation of antiproliferative effects in vitro

scientific article published on June 2005

Modulation de la reactivite vis a vis du borohydrure de sodium d'acetophenones complexees par une gamme de groupes Cr(CO)2L

Molecular mechanism of action of 2-ferrocenyl-1,1-diphenylbut-1-ene on HL-60 leukemia cells.

scientific article published on 25 August 2014

Molecular recognition of avidin on biotin-functionalized gold surfaces detected by FT-IRRAS and use of metal carbonyl probes

scientific article

Mono et dinitrosation en position benzylique des complexes du benz'ene chrometricarbonyle. Synth'ese directe d'oximes et d'hydroximates

NMR structural and dynamic study of a carbenium ion with a steroidal substituent [Mo2Cp2(CO)4(.mu.-HC:CC19H24O]+BF4-

Nanoparticles loaded with ferrocenyl tamoxifen derivatives for breast cancer treatment

scientific article

Nature of the stabilization of a carbenium ion adjacent to two organometallic groups. [Mo2Cp2(CO)4(.mu.-FcCHC:C(CH2)2CH3]+, BF4-: x-ray structure and NMR dynamic investigation

New Ortho-Directing Group for Lithiation: Use of a Methoxy−Imino Auxiliary for the Synthesis of Chiral Ortho-Substituted Acetyl- and Propionylferrocenes

New Synthetic Pathways ofcis- ortrans-Hydroxytamoxifen Derivatives with in Situ Formed [Cp*Rh(solvent)3]2+Complexes: Kinetic and Thermodynamic Control, Including a Novel, Intramolecular N-π Rearrangement, and Relative Binding Affinities of the η6Co

New and efficient routes to CpRe(CO)3 substituted steroids

New and efficient synthesis of CpRe(CO)3 substituted steroids

New applications of carbonylmetalloimmunoassay (CMIA): a non-radioisotopic approach to cortisol assay

scientific article published on 01 May 1994

New paradigms for synthetic pathways inspired by bioorganometallic chemistry

Novel redox label for proteins

Optimization of Two Fourier Transform Infrared Least-Squares Multivariate Analysis Methods for the Simultaneous Quantitation of Mixtures of Three Metal-Carbonyl Complexes in the Picomole Range

article by Michèle Salmain et al published November 1998 in Applied Spectroscopy

Organo-transition metal clusters: rational approaches to synthesis, structure, fluxionality, and reactivity

Organometallic Antitumor Compounds: Ferrocifens as Precursors to Quinone Methides

scientific article published on 14 July 2015

Organometallic SERMs (selective estrogen receptor modulators): Cobaltifens, the (cyclobutadiene)cobalt analogues of hydroxytamoxifen

scholarly article by Kirill Nikitin et al published February 2010 in Journal of Organometallic Chemistry

Organometallic analogues of tamoxifen: Effect of the amino side-chain replacement by a carbonyl ferrocenyl moiety in hydroxytamoxifen

Organometallic cyclic polyphenols derived from 1,2-(alpha-keto tri or tetra methylene) ferrocene show strong antiproliferative activity on hormone-independent breast cancer cells.

scientific article published on 8 July 2010

Organometallic derivatives of estradiol as bioligands: targetted binding of the estradiol receptor

scientific article

Organometallic derivatives of peptides: Application to peptide receptor analysis

Organometallic diphenols: The importance of the organometallic moiety on the expression of a cytotoxic effect on breast cancer cells

Organometallic estrogens: synthesis, interaction with lamb uterine estrogen receptor, and detection by infrared spectroscopy

scientific article published on 01 September 1988

Osmocenyl-tamoxifen derivatives target the thioredoxin system leading to a redox imbalance in Jurkat cells.

scientific article published on 13 April 2016

Oxidative Sequence of a Ruthenocene-Based Anticancer Drug Candidate in a Basic Environment

Oxidative metabolism of ferrocene analogues of tamoxifen: characterization and antiproliferative activities of the metabolites.

scientific article published on 16 April 2015

Phthalimido-ferrocidiphenol cyclodextrin complexes: Characterization and anticancer activity.

scientific article

Platinum(II) and technetium(I) complexes anchored to ethynylestradiol: a way to drug targeting and delivery

Preparation and characterization of poly(amidoamine) dendrimers functionalized with a rhenium carbonyl complex and PEG as new IR probes for carbonyl metallo immunoassay

scholarly article by Jan-Martin Heldt et al published December 2004 in Journal of Organometallic Chemistry

Preparation et etude des proprietes electroniques et chimiques de ligands isocyanures fonctionnels cncor coordines au chrome et au manganese

Pressure-tuning infrared and solution Raman spectroscopic studies of 17β-estradiol and several A-ring and 17α-ethynylestradiol derivatives

Pro-oxidant properties of AZT and other thymidine analogues in macrophages: implication of the azido moiety in oxidative stress

scientific article

Problemes de stereoselectivite en serie du benchrotrene: Reduction d' indanones chrome tricarbonyle á et β Substituees endo et exo par les borohydrures de sodium et de potassium. Stereospecificite de la reaction et applications synthetiques

Production of specific antibodies and development of a non-isotopic immunoassay for carbamazepine by the carbonyl metallo-immunoassay (CMIA) method

scientific article published on 01 October 1995

Purification of gaseous CO from Fe(CO)5 traces formed in steel storage cylinders

article published in 2001

Quantitative Analysis of Mixtures of Metal–Carbonyl Complexes by Fourier-Transform Infrared Spectroscopy: Application to the Simultaneous Double Immunoassay of Antiepileptic Drugs by the Nonisotopic Carbonyl Metalloimmunoassay Method

scientific article published on 01 November 1996

Quantitative IR Analysis in the Picomole Range of Organometallic-Labeled Biomolecules in KBr Disks

Quantitative analyses of ROS and RNS production in breast cancer cell lines incubated with ferrocifens.

scientific article published on 6 May 2014

Reaction of [Re(CO)6]+ cation with cyclopentadienylthallium derivatives. Formation of cyclopentadienylrheniumtricarbonyl derivatives via [Re(CO)3L3]+ (L=solvent)

Reaction of hen egg white lysozyme with Fischer-type metallocarbene complexes. Characterization of the conjugates and determination of the metal complex binding sites

scientific article published in October 2001

Reactions of eq,eq-Re2(CO)8(MeCN)2 with phenylacetylene and α-ethynylestradiol. A new synthesis of acetylide complexes

Reactivity and antiproliferative activity of ferrocenyl-tamoxifen adducts with cyclodextrins against hormone-independent breast-cancer cell lines.

scientific article published in January 2008

Rearrangement of 2,5-Bis(silylated)-N-Boc Pyrroles into the Corresponding 2,4-Species

scientific article published on 01 November 2009

Recent Analytical Applications of Molecular Spectroscopy in Bioorganometallic Chemistry—Part I: Metal Carbonyls

Recent Applications of Molecular Spectroscopy in Bioorganometallic Chemistry–Part 2: Ferrocenes and Other Organometallic Complexes

Reduction par le borohydrure de sodium d'indanones chrome tricarbonyle endo substituees en α et β. Position de l'etat de transition et facteurs

Reduction par le borohydrure de sodium d'indanones chrome tricarbonyle exo substituees en α et β. position de l'etat de transition et facteurs

Role of aromatic substituents on the antiproliferative effects of diphenyl ferrocenyl butene compounds

scientific article

Régioselectivité de la propargylation, par des ions carbéniums organométalliques, d'aromatiques polysubstitués; application aux dérivés du zéranol

Selective estrogen receptor modulators in the ruthenocene series. Synthesis and biological behavior.

scientific article

Selective estrogen-receptor modulators (SERMs) in the cyclopentadienylrhenium tricarbonyl series: synthesis and biological behaviour.

scientific article

Selective functionalization of crown ethers via arene chromium tricarbonyl complexes

Selectivity in the propargylation of polyfunctional amines by (propargylium)-Co2(CO)6+ and -(C5H5)2Mo2(CO)4+

Side-chain selective and covalent labelling of proteins by organometallic complexes of heavy transition metals. Possible application in radio-crystallography of proteins

scientific article published on 01 November 1998

Side-chain selective and covalent labelling of proteins with transition organometallic complexes. Perspectives in biology

Site-selective and covalent labelling of the cysteine-containing peptide glutathione with a ferrocenyl group

Site-specific conjugation of metal carbonyl dendrimer to antibody and its use as detection reagent in immunoassay.

scientific article

Small Structural Differences between Two Ferrocenyl Diphenols Determine Large Discrepancies of Reactivity and Biological Effects

scientific article published on 24 September 2019

Solution- and crystal-phase covalent modification of lysozyme by a purpose-designed organoruthenium complex. A MALDI-TOF MS study of its metal binding sites

scientific article published in January 2004

Specific binding of a biotinylated, metallocarbonyl-labelled dendrimer to immobilized avidin detected by diffuse-reflectance infrared Fourier transform spectroscopy

Specific binding of avidin to biotin immobilised on modified gold surfaces

Spectres de vibration du benzoate de methyle chrome dicarbonyle thiocarbonyle

article

Spectres de vibration et champs de force de valence de quelques composes π benzoate de methyle Cr(CO)3−nLn

article

Stabilisation of carbenium ions species by two different adjacent organometallic moieties: synthesis, NMR study and synthetic application

article published in 1989

Stopping a chromium carousel: X-ray crystallographic and variable-temperature13C n. m. r. studies on dicarbonyl(hexaethylbenzene)-thiocarbonylchromium(0) and related complexes

article published in 1983

Structural and biological investigation of ferrocene-substituted 3-methylidene-1,3-dihydro-2H-indol-2-ones

scientific article

Structural and chemical aspects of metal stabilized N-acyl isocyanide groups (MCNCOR)

scientific article published in 1978

Structure cristalline et moleculaire du tricarbonyl (1,2,3,4,5,6-η-3-ethylendo-7-phenyl-1,3,5 cycloheptatriene) chrome

Structures of zearalenone and zearalanone in solution: A high-field NMR and molecular modelling study

Studies on organometallic selective estrogen receptor modulators. (SERMs) Dual activity in the hydroxy-ferrocifen series

Sulfhydryl-selective, covalent labeling of biomolecules with transition metallocarbonyl complexes. Synthesis of (eta5-C5H5)M(CO)3(eta1-N-maleimidato) (M = Mo, W), X-ray structure, and reactivity studies

scientific article published in September 2005

Surface grafting of a π-conjugated amino-ferrocifen drug

Synthese directe de composes areniques bis-chrome tricarbonyles

Synthese directe de phenylpyruvates chrome tricarbonyle. Influences de la substitution sur la nature cetonique ou enolique des produits isoles, et du groupement Cr(CO)3 sur l'equilibre tautomere

Syntheses, crystal structures and DNMR studies on the mixed clusters CpNiFe(CO)3(RC.tplbond.CR')M [M = CpNi, Co(CO)3, Mo(CO)2Cp]: some comments on the acetylene rotation process

Synthesis and Antiproliferative Effects of [3]Ferrocenophane Transposition Products and Pinacols Obtained from McMurry Cross-Coupling Reactions

Synthesis and Structural Characterization of Ferrocenyl-Substituted Aurones, Flavones, and Flavonols

Synthesis and Structural Characterization of Neutral and Cationic Alkylaluminum Complexes Based on Bidentate Aminophenolate Ligands

Synthesis and Structure Activity Relationship of Organometallic Steroidal Androgen Derivatives

Synthesis and Structure of a Four-Coordinate Aluminum Alkyl Cation/HB(C6F5)3Salt: Implication in a B(C6F5)3-Catalyzed Hydroalumination Reaction of Benzophenone or Benzaldehyde

scholarly article by Samuel Dagorne et al published September 2004 in Organometallics

Synthesis and antiproliferative activity of (Z + E)-1-[4-(2-(cyclopentadienyltricarbonylmanganese)-2-oxo-ethoxy)phenyl]-1,2-di(p-hydroxyphenyl)-but-1-ene against breast cancer cells

Synthesis and antiproliferative activity of hydroxyferrocifen hybrids against triple-negative breast cancer cells

scientific article

Synthesis and antiproliferative evaluation of ferrocenyl and cymantrenyl triaryl butene on breast cancer cells. Biodistribution study of the corresponding technetium-99m tamoxifen conjugate

Synthesis and biodistribution of [99mTc]-N-[4-nitro-3-trifluoromethyl-phenyl] cyclopentadienyltricarbonyltechnetium carboxamide, a nonsteroidal antiandrogen flutamide derivative

scientific article published on 12 February 2010

Synthesis and biological activity of ferrocenyl derivatives of the non-steroidal antiandrogens flutamide and bicalutamide

Synthesis and biological evaluation of novel ferrocenyl curcuminoid derivatives

scientific article published on 11 January 2011

Synthesis and characterization of new ferrocenyl compounds with different alkyl chain lengths and functional groups to target breast cancer cells

Synthesis and crystal structure of [(η5-C5H5)2Ti(η2-COR)B(C6H5)3CN]

Synthesis and reactivity of a transition metal-carbonyl imidoester designed for the selective and covalent labelling of biological macromolecules

scholarly article by Stéphanie Blanalt et al published September 1996 in Tetrahedron Letters

Synthesis and receptor binding of polynuclear organometallic estradiol derivatives

scientific article published on 01 January 1988

Synthesis and structure of four-coordinate dimethyl aluminium complexes incorporating new N,O-chelating arylamido ligands

Synthesis and structure-activity relationships of ferrocenyl tamoxifen derivatives with modified side chains

scientific article

Synthesis and structure-activity relationships of the first ferrocenyl-aryl-hydantoin derivatives of the nonsteroidal antiandrogen nilutamide

scientific article

Synthesis of 17α-4-amino- and 4-iodophenylestradiols

Synthesis of CpFe(CO)(L) complexes of hydantoin anions (Cp = eta5-C5H5, L = CO, PPh3), and the use of the 5,5-diphenylhydantoin anion complexes as tracers in the nonisotopic immunoassay CMIA of this antiepileptic drug

scientific article published on May 1999

Synthesis of N-functionalized 2,2′-dipyridylamine ligands, complexation to ruthenium (II) and anchoring of complexes to papain from papaya latex

Synthesis of Optically Pureo-Formylcyclopentadienyl Metal Complexes of 17α-Ethynylestradiol. Recognition of the Planar Chirality by the Estrogen Receptor

Synthesis of Rhenium Carbonyl Complexes Bearing Substituted Pyrrolyl Ligands

scholarly article by Jean-Hugues Mirebeau et al published July 2008 in Organometallics

Synthesis of benzyl- and benzhydrylferrocenes via Friedel–Crafts alkylation of ferrocene. Access to ferrocenyl bisphenols with high affinities for estrogen receptors

article published in 2004

Synthesis of cobalt carbonyl complexes of cortisol and testosterone. Study of their recognition by specific polyclonal antibodies

scientific article published on 01 November 1993

Synthesis of cyclopentadienyltricarbonylrhenium substituted benzhydryl species and oestrogen receptor binding properties

Synthesis of cyclopentadienyltricarbonylrhenium(I) carboxylic acid from perrhenate

Synthesis of cytotoxic ferrocenyl flavones via a ferricenium-mediated 1,6-oxidative cyclization

scientific article published on 16 June 2010

Synthesis of metal-carbonyl-dendrimer-antibody immunoconjugates: towards a new format for carbonyl metallo immunoassay.

scientific article published in April 2004

Synthesis of methyl vinyl sulfides: The role of boron trifluoride in promoting a Horner-Wittig type reaction

Synthesis of oximes from (arene)Cr(CO)3complexes by nitrosation at the benzylic position

Synthesis of the First Ferrocenyl Derivatives of Curcuminoids

Synthesis of the new organometallic carboxylic acid complexes [η5-C5H4COOH)M(CO)nMe] (M  Mo, n = 3; M  Fe, n = 2 and their potential as bioconjugates

Synthesis of the pentacarbonyl(chalcocarbonyl)chromium(0) complexes, Cr(CO)5(CX) (X = S, Se)

Synthesis of tritium-labeled (3)-O-(3-hydroxypropyl)-17α-estradiol chromium tricarbonyl: The first radioactive transition metal carbonyl steroid hormone

Synthesis, Characterization, and Antiproliferative Activities of Novel Ferrocenophanic Suberamides against Human Triple-Negative MDA-MB-231 and Hormone-Dependent MCF-7 Breast Cancer Cells

Synthesis, Characterization, and Biological Properties of Osmium-Based Tamoxifen Derivatives - Comparison with Their Homologues in the Iron and Ruthenium Series

scholarly article by Hui Zhi Shirley Lee et al published 11 August 2015 in European Journal of Inorganic Chemistry

Synthesis, X-ray structure and chemical properties of 17α-ferrocenylestradiol

Synthesis, biochemical properties and molecular modelling studies of organometallic specific estrogen receptor modulators (SERMs), the ferrocifens and hydroxyferrocifens: evidence for an antiproliferative effect of hydroxyferrocifens on both hormone

scientific article

Synthesis, cytotoxicity, and COMPARE analysis of ferrocene and [3]ferrocenophane tetrasubstituted olefin derivatives against human cancer cells

scientific article published on December 2010

Synthesis, oxidation chemistry and cytotoxicity studies on ferrocene derivatives of diethylstilbestrol

scientific article

Synthesis, receptor binding, molecular modeling, and proliferative assays of a series of 17alpha-arylestradiols

scientific article published on June 2003

Synthetic and mechanistic pathways of cis and trans-hydroxytamoxifen drug derivatives reacting with Cp*Rh complexes that involve η1-N, η2-N,O, η1-O, and η6 bonding modes, via a novel N-π rearrangement; relative binding affinities and computer dockin

scientific article published on December 2010

Synthetic pathways for selective introduction of a dicobalt hexacarbonyl cluster into a polyfunctional molecule: Methotrexate

Synthetic strategy for organometallic complexes of rhenium with exceptionally high affinity for the oestradiol receptor; their potential use as imaging and therapeutic agents

scholarly article by Siden Top et al published 1994 in Journal of the Chemical Society. Chemical communications

Synthèse asymétrique d'alcools benchrotréniques par voie microbiologique

Synthèses photochimiques diastéréosélectives de complexes à liaison fer-métal du groupe 14

Tamoxifen derivatives for delivery of the antitumoral (DACH)Pt group: selective synthesis by McMurry coupling, and biochemical behaviour

scientific article published in August 2003

Targeted therapy vs. DNA-adduct formation-guided design: thoughts about the future of metal-based anticancer drugs ⬇️

scientific article published on May 22, 2012

The N-benzoyl isocyanide group: A .pi.-acceptor ligand similar to carbon monoxide and a new route to optically active chromium(0) complexes

article published in 1979

The Use of Glycidol to Introduce Aldehyde Functions Into Proteins – Application to the Fluorescent Labelling of Bovine Serum Albumin and Avidin

The effect of protic electron donor aromatic substituents on ferrocenic and [3]ferrocenophanic anilines and anilides: Some aspects of structure–activity relationship studies on organometallic compounds with strong antiproliferative effects

The effect of replacing carbonyl groups by other ligands on the catalytic properties of arenechromium carbonyl complexes

The effect of transition metal benzyl and propargyl species on the behavior of steroidal hormones

The first organo-tungsten pyrylium salt and structural characterization of its pseudobase

The first organometallic derivative of 11β-ethynylestradiol, a potential high-affinity marker for the estrogen receptor

article published in 2000

The first titanocenyl dichloride moiety vectorised by a selective estrogen receptor modulator (SERM). Synthesis and preliminary biochemical behaviour

The influence of phenolic hydroxy substitution on the electron transfer and anti-cancer properties of compounds based on the 2-ferrocenyl-1-phenyl-but-1-ene motif

scientific article published on 28 September 2007

The in vivo performance of ferrocenyl tamoxifen lipid nanocapsules in xenografted triple negative breast cancer.

scientific article published on 15 June 2013

The length of the bridging chain in ansa-metallocenes influences their antiproliferative activity against triple negative breast cancer cells (TNBC)

scientific article published on 01 August 2016

The presence of a ferrocenyl unit on an estrogenic molecule is not always sufficient to generate in vitro cytotoxicity.

scientific article published on November 2006

The reaction of tertiary phosphines with tropylium chromium tricarbonyl tetrafluoroborate

The replacement of a phenol group by an aniline or acetanilide group enhances the cytotoxicity of 2-ferrocenyl-1,1-diphenyl-but-l-ene compounds against breast cancer cells

The use of high affinity binding bioligands modified by transition metal carbonyl moieties

article published in 1989

Transition metal (‘Fischer-type’) carbene complexes as protein labelling reagents

Transition metal carbonyl labeling of proteins. A novel approach to a solid-phase two-site immunoassay using Fourier transform infrared spectroscopy

scientific article published on 01 November 1992

Transition metal carbonyl oestrogen receptor assay

Transition metal-carbonyl labeling of biotin and avidin for use in solid-phase carbonyl metallo immunoassay (CMIA).

scientific article

Treatment of 9L gliosarcoma in rats by ferrociphenol-loaded lipid nanocapsules based on a passive targeting strategy via the EPR effect

scientific article published on 21 June 2011

Tricarbonyl[3-(η5-cyclopentadienylcarbonylamino)propionic acid]rhenium

scholarly article by A. Bennouna et al published 15 April 1997 in Acta Crystallographica Section C: Crystal Structure Communications

Use of Fourier Transform Infrared Spectroscopy for the Simultaneous Quantitative Detection of Metal Carbonyl Tracers Suitable for Multilabel Immunoassays

scientific article published on 01 January 1993

Use of Heavy-Metal Clusters in the Design of N-Succinimidyl Ester Acylation Reagents for Side-Chain-Specific Labeling of Proteins

scientific article published on 01 July 1999

Versatile use of hindered oxalates for the stereoselective preparation of novel 11-modified androst-5-ene derivatives

scientific article published in April 2004

X-ray absorption spectroscopy studies of the adducts formed between cytotoxic gold compounds and two major serum proteins

scientific article published on 24 December 2010

[eta 5-Cyclopentadienyl]metal tricarbonyl pyrylium salts: novel reagents for the specific conjugation of proteins with transition organometallic labels

scientific article published in November 1994

“Biochemical resolution and generation of planar chirality in formyl substituted (diene)Fe(CO)3 complexes”

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