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List of works by Lawrence Que Jr.

Acid pKa Dependence in O-O Bond Heterolysis of a Nonheme FeIII-OOH Intermediate To Form a Potent FeV═O Oxidant with Heme Compound I-Like Reactivity

scientific article published on 26 September 2019

Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds.

scientific article

Activation of a Non-Heme FeIII -OOH by a Second FeIII to Hydroxylate Strong C-H Bonds: Possible Implications for Soluble Methane Monooxygenase

scientific article published on 09 May 2019

Alkane Hydroxylation by a Nonheme Iron Catalyst that Challenges the Heme Paradigm for Oxygenase Action

scientific article published on 05 December 2007

Bio-inspired Nonheme Iron Oxidation Catalysis: Involvement of Oxoiron(V) Oxidants in Cleaving Strong C-H Bonds

scientific article published on 01 August 2019

Carboxylate Structural Effects on the Properties and Proton-Coupled Electron Transfer Reactivity of [CuO2CR]2+ Cores

scientific article published on 11 November 2019

Characterization of the Fleeting Hydroxoiron(III) Complex of the Pentadentate TMC-py Ligand.

scientific article

CmlI N-Oxygenase Catalyzes the Final Three Steps in Chloramphenicol Biosynthesis without Dissociation of Intermediates

scientific article published on 20 August 2017

Correction to Characterization of the Fleeting Hydroxoiron(III) Complex of the Pentadentate TMC-py Ligand.

scientific article

Crystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better Oxidant

scientific article published on 28 June 2018

Detection of a transient FeV(O)(OH) species involved in olefin oxidation by a bio-inspired non-haem iron catalyst

scientific article published on 20 July 2018

Diiron monooxygenases in natural product biosynthesis

scientific article published on 19 March 2018

Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes

scientific article

Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation

scientific article

Facile Conversion of syn -[FeIV (O)(TMC)]2+ into the anti Isomer via Meunier's Oxo-Hydroxo Tautomerism Mechanism

scientific article published on 17 January 2019

Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III).

scientific article published on 9 June 2017

Fast O2 binding at dicopper complexes containing Schiff-base dinucleating ligands

scientific article

High-Energy-Resolution Fluorescence-Detected X-ray Absorption of the Q Intermediate of Soluble Methane Monooxygenase.

scientific article published on 14 November 2017

High-Resolution EXAFS Provides Evidence for a Longer Fe•••Fe Distance in the Q Intermediate of Methane Monooxygenase

article

Ligand Topology Effects on Olefin Oxidations by Bio-Inspired [FeII(N2Py2)] Catalysts

scientific article published on 01 September 2006

Mimicking class Ib Mn2 ribonucleotide reductase: a MnII2 complex and its reaction with superoxide.

scientific article published on 22 November 2017

Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.

scientific article

NMR Reveals That a Highly Reactive Nonheme FeIV =O Complex Retains Its Six-Coordinate Geometry and S=1 State in Solution

scientific article published on 27 June 2019

Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity

scientific article

O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding

scientific article published on July 2006

Octahedral iron(iv)-tosylimido complexes exhibiting single electron-oxidation reactivity

scientific article published on 20 August 2019

Olefin-dependent discrimination between two nonheme HO-FeV=O tautomeric species in catalytic H2O2 epoxidations

scientific article published in January 2009

On the Lewis Acidity of the Oxoiron(IV) Unit in a Tetramethylcyclam Complex

scientific article published on 2 December 2017

Oxoiron(IV) Tetramethylcyclam Complexes with Axial Carboxylate Ligands: Effect of Tethering the Carboxylate on Reactivity

scientific article published on 3 March 2017

Oxygen Atom Exchange between H2O and Non-Heme Oxoiron(IV) Complexes: Ligand Dependence and Mechanism

scientific article published on 08 June 2016

Privileged Role of Thiolate as the Axial Ligand in Hydrogen Atom Transfer Reactions by Oxoiron(IV) Complexes in Shaping the Potential Energy Surface and Inducing Significant H-Atom Tunneling

scientific article published on 28 November 2017

Sc (or HClO) Activation of a Nonheme Fe-OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene

scientific article published on 17 April 2018

Sc3+-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O2 to Generate a Complex with an FeIV2(μ-O)2 Core

scientific article published on 19 February 2020

Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-oxo Intermediate

scientific article published on 20 February 2018

Spectroscopic and Reactivity Comparisons between Nonheme Oxoiron(IV) and Oxoiron(V) Species Bearing the Same Ancillary Ligand

scientific article published on 11 September 2019

Structural implications of the paramagnetically shifted NMR signals from pyridine H atoms on synthetic nonheme FeIV=O complexes

scientific article published on 06 June 2019

The Two Faces of Tetramethylcyclam in Iron Chemistry: Distinct Fe-O-M Complexes Derived from [FeIV(Oanti/syn)(TMC)]2+ Isomers

scientific article

The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: bioinspired non-heme iron catalysts containing cis-labile exchangeable sites

scientific article

Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C-H Bonds with Stereoretention.

scientific article published on 24 November 2015

Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis

scientific article

Tyrosinase-like reactivity in a Cu(III)2(mu-O)2 species.

scientific article

Unprecedented (μ-1,1-Peroxo)diferric Structure for the Ambiphilic Orange Peroxo Intermediate of the Nonheme N-Oxygenase CmlI.

scientific article published on 4 July 2017