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List of works by William J. Evans

(N2)3- radical chemistry via trivalent lanthanide salt/alkali metal reduction of dinitrogen: new syntheses and examples of (N2)2- and (N2)3- complexes and density functional theory comparisons of closed shell Sc3+, Y3+, and Lu3+ versus 4f(9) Dy3+.

scientific article published on 4 January 2011

A Monometallic f Element Complex of Dinitrogen: (C5Me5)3U(η-N2)

scientific article published on November 26, 2003

A N2(3-) radical-bridged terbium complex exhibiting magnetic hysteresis at 14 K.

scientific article published on 19 August 2011

A Room-Temperature Stable Y(II) Aryloxide: Using Steric Saturation to Kinetically Stabilize Y(II) Complexes

scientific article published on 12 February 2020

A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes

scientific article published on 10 September 2020

A crystallizable f-element tuck-in complex: the tuck-in tuck-over uranium metallocene [(C5Me5)U{mu-eta(5):eta(1):eta(1)-C5Me3(CH2)2}(mu-H)2U(C5Me5)2].

scientific article

A half-sandwich organometallic single-ion magnet with hexamethylbenzene coordinated to the Dy(III) ion

scientific article published on 01 October 2014

Analysis of uranium azide and nitride complexes by atmospheric pressure chemical ionization mass spectrometry

scientific article

Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium

scientific article published on 5 November 2009

Bismuth Coordination Chemistry with Allyl, Alkoxide, Aryloxide, and Tetraphenylborate Ligands and the {[2,6-(Me2NCH2)2C6H3]2Bi}+ Cation

scientific article published on December 30, 2010

Bismuth-based cyclic synthesis of 3,5-di-tert-butyl-4-hydroxybenzoic acid via the oxyarylcarboxy dianion, (O2CC6H2(t)Bu2O)2-.

scientific article published in February 2014

C-H bond activation through steric crowding of normally inert ligands in the sterically crowded gadolinium and yttrium (C5Me5)3M complexes

scholarly article

Chelate-Free Synthesis of the U(II) Complex, [(C5H3(SiMe3)2)3U]1–, Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs

scientific article published on 05 September 2018

Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.

scientific article published in June 2002

Cocrystallization of (μ-S2)2- and (μ-S)2- and formation of an [η2-S3N(SiMe3)2] ligand from chalcogen reduction by (N2)2- in a bimetallic yttrium amide complex

scientific article published on 28 August 2014

Comparative Reactivity of Sterically Crowded nf3 (C5Me5)3Nd and (C5Me5)3U Complexes with CO: Formation of a Nonclassical Carbonium Ion versus an f Element Metal Carbonyl Complex

scientific article published on November 12, 2003

Comparisons of lanthanide/actinide +2 ions in a tris(aryloxide)arene coordination environment

scientific article

Completing the series of +2 ions for the lanthanide elements: synthesis of molecular complexes of Pr2+, Gd2+, Tb2+, and Lu2+.

scientific article

Coordination Chemistry of Samarium Diiodide with Ethers Including the Crystal Structure of Tetrahydrofuran-Solvated Samarium Diiodide, SmI2(THF)5

article

Coordination and reductive chemistry of tetraphenylborate complexes of trivalent rare earth metallocene cations, [(C5Me5)2Ln][(μ-Ph)2BPh2].

scientific article published on 25 March 2011

Covalency in Americium(III) Hexachloride.

scientific article

Crystal structure of the [(THF)Cs(μ-η5:η5-Cp')3Yb] n oligomer

scientific article published on 23 June 2020

Density functional theory and X-ray analysis of the structural variability in η5,η5,η1-tris(ring) rare earth/actinide tetramethylpyrrolyl complexes, (C5Me5)2M(NC4Me4).

scientific article

Differentiating Chemically Similar Lewis Acid Sites in Heterobimetallic Complexes: The Rare-Earth Bridged Hydride (C5Me5)2Ln(μ-H)2Ln′(C5Me5)2 and Tuckover Hydride (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln′(C5Me5) Systems

Dinitrogen Reduction, Sulfur Reduction, and Isoprene Polymerization via Photochemical Activation of Trivalent Bis(cyclopentadienyl) Rare-Earth-Metal Allyl Complexes

article

Dinitrogen reduction by TmII, DyII, and NdII with simple amide and aryloxide ligands

scientific article

Dinitrogen reduction via photochemical activation of heteroleptic tris(cyclopentadienyl) rare-earth complexes

scientific article published in March 2013

Electrocatalytic H2O Reduction with f-Elements: Mechanistic In-sight and Overpotential Tuning in a Series of Lanthanide Complexes

scientific article published on 29 January 2018

Electrochemical studies of tris(cyclopentadienyl)thorium and uranium complexes in the +2, +3, and +4 oxidation states

scientific article published on 07 May 2021

Electronic structures of organometallic complexes of f elements LXXXIII: First comparison of experimental and calculated (on the basis of density functional theory) polarized Raman spectra of an oriented organometallic single crystal: Tris(pentameth

scientific article published on 24 April 2014

End-On Bridging Dinitrogen Complex of Scandium.

scientific article published on 28 September 2017

Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum

scientific article published on 26 July 2019

Evaluating Electron-Transfer Reactivity of Complexes of Actinides in +2 and +3 Oxidation States by using EPR Spectroscopy

scientific article published on 23 January 2020

Evaluating the electronic structure of formal LnII ions in LnII(C5H4SiMe3)31- using XANES spectroscopy and DFT calculations

scientific article published on 30 June 2017

Expanding Thorium Hydride Chemistry Through Th²⁺, Including the Synthesis of a Mixed-Valent Th⁴⁺/Th³⁺ Hydride Complex

scientific article published on 15 March 2016

Expanding Yttrium Bis(trimethylsilylamide) Chemistry Through the Reaction Chemistry of (N2)2–, (N2)3–, and (NO)2– Complexes

scientific article published on October 4, 2012

Expanding dinitrogen reduction chemistry to trivalent lanthanides via the LnZ3/alkali metal reduction system: evaluation of the generality of forming Ln2(mu-eta2:eta2-N2) complexes via LnZ3/K.

scientific article published in November 2004

Expanding rare-earth oxidation state chemistry to molecular complexes of holmium(II) and erbium(II).

scientific article published on 14 May 2012

Expanding the Chemistry of Molecular U(2+) Complexes: Synthesis, Characterization, and Reactivity of the {[C5 H3 (SiMe3 )2 ]3 U}(-) Anion.

scientific article published on 4 December 2015

Expanding the LnZ(3)/alkali-metal reduction system to organometallic and heteroleptic precursors: formation of dinitrogen derivatives of lanthanum

scientific article published in October 2004

Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI2(THF)2 Precursors (Ln = Sm, Eu, Yb)

scientific article published on 10 July 2019

Facile bismuth-oxygen bond cleavage, C-H activation, and formation of a monodentate carbon-bound oxyaryl dianion, (C₆H₂(t)Bu₂-3,5-O-4)²⁻.

scientific article published on 18 March 2011

Facile syntheses of unsolvated UI3 and tetramethylcyclopentadienyl uranium halides.

scientific article

Flexibility in the coordination chemistry of the 2,3-dimethylindolide ligand with potassium, yttrium, and samarium

scientific article

Formation of a bridging planar trimethylenemethane dianion from a neopentyl precursor via sequential beta-alkyl elimination and C-H activation

scientific article published in February 2005

Formation of the End-on Bound Lanthanide Dinitrogen Complexes, [(R2N)3Ln-N=N-Ln(NR2)3]2-, from Divalent [(R2N)3Ln]1- Salts (R = SiMe3)

scientific article published on 29 March 2020

Giant coercivity and high magnetic blocking temperatures for N23- radical-bridged dilanthanide complexes upon ligand dissociation

scientific article published on 15 December 2017

Identification of the +2 oxidation state for uranium in a crystalline molecular complex, [K(2.2.2-cryptand)][(C5H4SiMe3)3U].

scientific article published on 28 August 2013

Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {NpII[C5H3(SiMe3)2]3}1–

scientific article published on 05 June 2018

Identification of the Formal +2 Oxidation State of Plutonium: Synthesis and Characterization of {PuII[C5H3(SiMe3)2]3}.

scientific article published on 24 February 2017

Importance of energy level matching for bonding in Th(3+)-Am(3+) actinide metallocene amidinates, (C(5)Me(5))(2)[(i)PrNC(Me)N(i)Pr]An

scientific article published on November 2010

In search of tris(trimethylsilylcyclopentadienyl) thorium

scientific article published on 29 October 2019

Influence of an inner-sphere K+ ion on the magnetic behavior of N2(3-) radical-bridged dilanthanide complexes isolated using an external magnetic field

scientific article

Insertion of CO2 and COS into Bi-C bonds: reactivity of a bismuth NCN pincer complex of an oxyaryl dianionic ligand, [2,6-(Me2NCH2)2C6H3]Bi(C6H2(t)Bu2O).

scientific article published on 10 May 2013

Insertion, Isomerization, and Cascade Reactivity of the Tethered Silylalkyl Uranium Metallocene (η5-C5Me4SiMe2CH2-κC)2U

scientific article published on February 18, 2011

Insights into the Mechanism of Reaction of [(C5Me5)2SmII(thf)2] with CO2 and COS by DFT Studies

scientific article published on 09 May 2012

Investigating metal size effects in the Ln2(mu-eta2:eta2-N2) reduction system: reductive reactivity with complexes of the largest and smallest trivalent lanthanide ions, La3+ and Lu3+.

scientific article published in March 2009

Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb).

scientific article published in May 2017

Isolation of (CO)1- and (CO2)1- radical complexes of rare earths via Ln(NR2)3/K reduction and [K2(18-crown-6)2]2+ oligomerization

scientific article published on 28 March 2012

Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La2+ and Ce2+ are four electron reductants.

scientific article

Isolation of U(ii) compounds using strong donor ligands, C5Me4H and N(SiMe3)2, including a three-coordinate U(ii) complex

scientific article published on 01 February 2019

Isolation of a Square-Planar Th(III) Complex: Synthesis and Structure of [Th(OC6H2tBu2-2,6-Me-4)4]1

scientific article published on 31 July 2019

Isolation of a radical dianion of nitrogen oxide (NO)(2-).

scientific article published on 27 June 2010

Isolation of dysprosium and yttrium complexes of a three-electron reduction product in the activation of dinitrogen, the (N2)3- radical

scientific article published in August 2009

Isolation of reactive Ln(ii) complexes with C5H4Me ligands (CpMe) using inverse sandwich countercations: synthesis and structure of [(18-crown-6)K(μ-CpMe)K(18-crown-6)][CpMe3LnII] (Ln = Tb, Ho)

scientific article published on 01 December 2018

Lanthanide metallocene complexes of the 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinato Ligand, (hpp)1-.

scientific article published in December 2008

Lanthanide versus actinide reactivity in the formation of sterically crowded [(C(5)Me(5))(3)ML(n)] nitrile and isocyanide complexes

scientific article published in January 2010

Lanthanum and alkali metal coordination chemistry of the bis(dimethylphenylsilyl)amide ligand

scientific article published on 01 April 2006

Ligand Effects in the Synthesis of Ln2+ Complexes by Reduction of Tris(cyclopentadienyl) Precursors Including C–H Bond Activation of an Indenyl Anion

article

Magnetic susceptibility of uranium complexes

scientific article published on 19 August 2014

Metal versus Ligand Reduction in Ln3+ Complexes of a Mesitylene-Anchored Tris(Aryloxide) Ligand.

scientific article published on 19 February 2018

Methyl displacements from cyclopentadienyl ring planes in sterically crowded (C5Me5)3M complexes

scientific article

Molecular octa-uranium rings with alternating nitride and azide bridges

scientific article

Multi-electron reduction from alkyl/hydride ligand combinations in U4+ complexes

scientific article

Muscle wasting in cancer cachexia: clinical implications, diagnosis, and emerging treatment strategies

scientific article published on January 2011

NH3 and (NH2)1- as ligands in yttrium metallocene chemistry.

scientific article published on 21 March 2018

Neutron Diffraction Study of [Nd(AlMe4 )3 ]⋅0.5 Al2 Me6 at 100 K: The First Detailed Look at a Bridging Methyl Group with a Trigonal-Bipyramidal Carbon Atom

scientific article published on 01 May 1998

Nitric oxide insertion reactivity with the bismuth-carbon bond: formation of the oximate anion, [ON=(C6H2tBu2O)]-, from the oxyaryl dianion, (C6H2tBu2O)2-.

scientific article published on 22 September 2014

Organolanthanide-based synthesis of 1,2,3-triazoles from nitriles and diazo compounds

scientific article

Organolutetium vinyl and tuck-over complexes via C-H bond activation

scientific article published in November 2006

Perspectives on Neutron Scattering in Lanthanide-Based Single-Molecule Magnets and a Case Study of the Tb2(μ-N2) System

Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb).

scientific article published on 23 May 2016

Planar trimethylenemethane dianion chemistry of lanthanide metallocenes: synthesis, structure, density functional theory analysis, and reactivity of [(C5Me5)2Ln]2[mu-eta3:eta3-C(CH2)(3] Complexes

scientific article

Raman spectroscopy of the N-N bond in rare earth dinitrogen complexes

scientific article

Rare‐Earth Metal(II) Aryloxides: Structure, Synthesis, and EPR Spectroscopy of [K(2.2.2‐cryptand)][Sc(OC 6 H 2 t Bu 2 ‐2,6‐Me‐4) 3 ]

scientific article published on 08 November 2018

Reaction chemistry of the U(3+) metallocene amidinate (C(5)Me(5))(2)[(i)PrNC(Me)N(i)Pr]U including the isolation of a uranium complex of a monodentate acetate.

scientific article

Reactivity of (C5Me5)3LaL(x) complexes: synthesis of a tris(pentamethylcyclopentadienyl) complex with two additional ligands, (C5Me5)3La(NCCMe3)2.

scientific article published in February 2009

Reactivity of Complexes of 4fn5d1 and 4fn+1 Ln2+ Ions with Cyclooctatetraene

article

Reactivity of Ln(II) Complexes Supported by (C5H4Me)1– Ligands with THF and PhSiH3: Isolation of Ring-Opened, Bridging Alkoxyalkyl, Hydride, and Silyl Products

Reactivity of organothorium complexes with TEMPO.

scientific article published on 29 July 2014

Record High Single-Ion Magnetic Moments Through 4f(n)5d(1) Electron Configurations in the Divalent Lanthanide Complexes [(C5H4SiMe3)3Ln]⁻.

scientific article published on 13 July 2015

Reduction chemistry of the mixed ligand metallocene [(C5Me5)(C8H8)U]2(μ-C8H8) with bipyridines

article

Reduction of Dinitrogen with an Yttrium Metallocene Hydride Precursor, [(C5Me5)2YH]2

scientific article published on October 22, 2010

Reduction of dinitrogen to planar bimetallic M2(mu-eta 2:eta 2-N2) complexes of Y, Ho, Tm, and Lu using the K/Ln[N(SiMe3)2]3 reduction system

scientific article published in January 2004

Reductive coupling of acetonitrile by uranium and thorium hydride complexes to give cyanopentadienyl dianion (C6N3H7)2-.

scientific article

Reductive reactivity of the organolanthanide hydrides, [(C5Me5)2LnH]x, leads to ansa-allyl cyclopentadienyl (eta(5)-C5Me4CH2-C5Me4CH2-eta(3))2- and trianionic cyclooctatetraenyl (C8H7)3- ligands.

scientific article

Samarium versus aluminium Lewis acidity in a mixed alkyl carboxylate complex related to alkylaluminium activation in diene polymerization catalysis

scientific article published on 21 October 2005

Scandium and yttrium metallocene borohydride complexes: comparisons of (BH4)1- vs. (BPh4)1- coordination and reactivity.

scientific article

Sigma bond metathesis with pentamethylcyclopentadienyl ligands in sterically crowded (C5Me5)3M complexes

scientific article published on 13 May 2010

Slow Magnetic Relaxation in a Dysprosium Ammonia Metallocene Complex

scientific article

Small-Scale Metal-Based Syntheses of Lanthanide Iodide, Amide, and Cyclopentadienyl Complexes as Analogues for Transuranic Reactions.

scientific article published on 15 September 2017

Solid-state 139La and 15N NMR spectroscopy of lanthanum-containing metallocenes

scientific article published on October 2006

Solution Synthesis, Structure, and CO2 Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe3 )2 ]3 }.

scientific article

Solution Synthesis, Structure, and CO2 Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe3 )2 ]3 }−

Stabilization of U(III) to Oxidation and Hydrolysis by Encapsulation Using 2.2.2-Cryptand

scientific article published on 23 November 2020

Strong exchange and magnetic blocking in N₂³⁻-radical-bridged lanthanide complexes

scientific article published on 22 May 2011

Structural complexity in the rare earth metallocene hydride complexes, [(C₅Me₅)₂LnH]₂.

scientific article published in November 2014

Structural, spectroscopic, and theoretical comparison of traditional vs recently discovered Ln(2+) ions in the [K(2.2.2-cryptand)][(C5H4SiMe3)3Ln] complexes: the variable nature of Dy(2+) and Nd(2+).

scientific article

Structure, Magnetism, and Multi-electron Reduction Reactivity of the Inverse Sandwich Reduced Arene La2+ Complex [{[C5H3(SiMe3)2]2La}2(μ-η6:η6-C6H6)]1–

Structure, reactivity, and density functional theory analysis of the six-electron reductant, [(C5Me5)2U]2(mu-eta6:eta6-C6H6), synthesized via a new mode of (C5Me5)3M reactivity

scientific article published in November 2004

Synthesis and Insertion Chemistry of Mixed Tether Uranium Metallocene Complexes

scientific article published on October 9, 2012

Synthesis and Reactivity of Organosamarium Diarylpnictide Complexes: Cleavage Reactions of Group 15 E−E and E−C Bonds by Samarium(II)

scientific article published on July 17, 1996

Synthesis and Reduction of Bimetallic Methyl-Bridged Rare-Earth Metal Complexes, [(C5H4SiMe3)2Ln(μ-CH3)]2 (Ln = Y, Tb, Dy)

scientific article published on 07 January 2019

Synthesis and Structure of the First Molecular Thulium(II) Complex:[TmI2(MeOCH2CH2OMe)3]

article

Synthesis and crystallographic characterization of di-phenyl-amide rare-earth metal complexes Ln(NPh2)3(THF)2 and [(Ph2N)2 Ln(μ-NPh2)]2

scientific article published on 14 August 2020

Synthesis and reactivity of a silylalkyl double tuck-in uranium metallocene [(eta(5):eta(1)-C(5)Me(4)SiMe(2)CH(2))(2)U] and its conversion to bis(tethered) metallocenes

scientific article published in January 2010

Synthesis and reactivity of bis(tetramethylcyclopentadienyl) yttrium metallocenes including the reduction of Me(3)SiN(3) to [(Me(3)Si)(2)N](-) with [(C(5)Me(4)H)(2)Y(THF)](2)(mu-eta(2):eta(2)-N(2)).

scientific article published in July 2010

Synthesis and reductive chemistry of bimetallic and trimetallic rare-earth metallocene hydrides with (C 5 H 4 SiMe 3 ) 1− ligands

article

Synthesis and structure of polymeric networks of silver hexafluoroacetylacetonate complexes of THF, toluene, and vinyltrimethylsilane

scientific article

Synthesis of (C5Me5)2(C5Me4H)UMe, (C5Me5)2(C5H5)UMe, and (C5Me5)2UMe[CH(SiMe3)2] from cationic metallocenes for the evaluation of sterically induced reduction.

scientific article published on 9 October 2008

Synthesis of (O2CEPh)1- ligands (E = S, Se) by CO2 insertion into lanthanide chalcogen bonds and their utility in forming crystallographically characterizable organoaluminum complexes [Me2Al(mu-O2CEPh)]2.

scientific article published in January 2006

Synthesis of Ln(II)-in-Cryptand Complexes by Chemical Reduction of Ln(III)-in-Cryptand Precursors: Isolation of a Nd(II)-in-Cryptand Complex

scientific article published on 22 May 2020

Synthesis of Zirconium Aryloxide Complexes Containing Pendent Vinyl Groups

scientific article published on March 22, 1999

Synthesis of a crystalline molecular complex of Y2+, [(18-crown-6)K][(C5H4SiMe3)3Y].

scientific article published on 16 September 2011

Synthesis of a thorium tuck-in complex, [(eta(5):eta(1)-C(5)Me(4)CH(2))(eta(5)-C(5)Me(5))Th{iPrNC(Me)NiPr}], by C-H bond activation initiated by (C(5)Me(5))(-).

scientific article published in November 2009

Synthesis of air-stable, volatile uranium(IV) and (VI) compounds and their gas-phase conversion to uranium oxide films

scientific article published on 23 December 2014

Synthesis of heteroleptic uranium (mu-eta(6):eta(6)-C6H6)2- sandwich complexes via facile displacement of (eta(5)-C5Me5)1- by ligands of lower hapticity and their conversion to heteroleptic bis(imido) compounds

scientific article published in December 2009

Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2.

scientific article published on 19 July 2017

Synthesis of the (N2)3- radical from Y2+ and its protonolysis reactivity to form (N2H2)2- via the Y[N(SiMe3)2]3/KC8 reduction system.

scientific article published in March 2011

Synthesis of uranium-in-cryptand complexes

article

Synthesis, Structure, and Magnetism of Tris(amide) {Ln[N(SiMe3)2]3}1- Complexes of the Non-Traditional +2 Lanthanide Ions.

scientific article published on 28 February 2018

Synthesis, Structure, and Reactivity of the Ethyl Yttrium Metallocene, (C5Me5)2Y(CH2CH3), Including Activation of Methane

scientific article

Synthesis, Structure, and Reactivity of the Sterically Crowded Th3+ Complex (C5Me5)3Th Including Formation of the Thorium Carbonyl, [(C5Me5)3Th(CO)][BPh4].

scientific article

Synthesis, structure, and 15N NMR studies of paramagnetic lanthanide complexes obtained by reduction of dinitrogen

scientific article published in December 2006

Synthesis, structure, and density functional theory analysis of a scandium dinitrogen complex, [(C(5)Me(4)H)(2)Sc](2)(mu-eta(2):eta(2)-N(2)).

scientific article published on August 2010

Synthesis, structure, and ligand-based reduction reactivity of trivalent organosamarium benzene chalcogenolate complexes (C(5)Me(5))(2)Sm(EPh)(THF) and [(C(5)Me(5))(2)Sm(mu-EPh)](2).

scientific article published in June 2005

Synthesis, structure, and magnetism of an f element nitrosyl complex, (C5Me4H)3UNO.

scientific article published on 23 December 2011

Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C5H3(SiMe3)2]3Th}1- anion containing thorium in the formal +2 oxidation state.

scientific article published on 3 November 2014

Synthesis, structure, and reactivity of heterometallic polyhydride complexes of rhenium with yttrium and lutetium

article

Synthetic utility of [(C5Me5)2Ln][(mu-Ph)2BPh] in accessing [(C5Me5)2LnR]x unsolvated alkyl lanthanide metallocenes, complexes with high C-H activation reactivity

scientific article

Tethered Olefin Studies of Alkene versus Tetraphenylborate Coordination and Lanthanide Olefin Interactions in Metallocenes

scientific article published on April 30, 2003

Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C5Me4H)3Ln] Complexes

The Importance of a Single Methyl Group in Determining the Reaction Chemistry of Pentamethylcyclopentadienyl Cyclooctatetraenyl Uranium Metallocenes

scientific article published on March 14, 2011

The Trivalent Neodymium Complex [(C5 Me5 )3 Nd] Is a One-Electron Reductant!

scientific article published on 01 June 1999

Thorium Metallocene Cation Chemistry: Synthesis and Characterization of the Bent [(C5Me5)2Th(C6H5)(THF)][BPh4] and the Parallel Ring [(C5Me5)2Th(NCR)5][BPh4]2 (R = Me, Ph) Complexes

scholarly article by Ryan R. Langeslay et al published 31 January 2018 in Organometallics

Trialkylboron/lanthanide metallocene hydride chemistry: polydentate bridging of (HBEt3)- to lanthanum

scientific article published in August 2005

Trimethylsilyl versus Bis(trimethylsilyl) Substitution in Tris(cyclopentadienyl) Complexes of La, Ce, and Pr: Comparison of Structure, Magnetic Properties, and Reactivity

Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons

Tris(polyalkylcyclopentadienyl) complexes: the elusive [(η5-C5R5)2M(η1-C5R5)] structure and trihapto cyclopentadienyl coordination involving a methyl substituent.

scientific article

Trivalent [(C5Me5)2(THF)Ln]2(mu-eta2:eta2-N2) complexes as reducing agents including the reductive homologation of CO to a ketene carboxylate, (mu-eta4-O2C-C=C=O)2-.

scientific article published in November 2006

Unprecedented Bending and Rearrangement of f-Element Sandwich Complexes Induced by Superbulky Cyclooctatetraenide Ligands

scientific article published on 07 January 2011

Uranium metallocene complexes of the 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinato ligand, (hpp)(-).

scientific article published in January 2010

Using Diamagnetic Yttrium and Lanthanum Complexes to Explore Ligand Reduction and C–H Bond Activation in a Tris(aryloxide)mesitylene Ligand System

scientific article published on 24 September 2018

Utility of Arylamido Ligands in Yttrium and Lanthanide Chemistry1

scientific article published on September 11, 1996

Utility of Lithium in Rare-Earth Metal Reduction Reactions to Form Nontraditional Ln2+ Complexes and Unusual [Li(2.2.2-cryptand)]1+ Cations

scientific article

Utility of anhydrous neodymium nitrate as a precursor to extended organoneodymium nitrate networks

scientific article

Utility of neodymium diiodide as a reductant in ketone coupling reactions

scientific article published on 01 June 2003

Varying the Lewis base coordination of the Y2N2 core in the reduced dinitrogen complexes {[(Me3Si)2N]2(L)Y}2(μ-η2:η2-N2) (L = benzonitrile, pyridines, triphenylphosphine oxide, and trimethylamine N-oxide).

scientific article published on 3 July 2012

Yttrium metallocene borane chemistry: isolation of 9-BBN substitution and coordination complexes in a single crystal, {(C(5)Me(5))(2)Y[eta(3)-C(3)H(4)(BC(8)H(14))]} and {(C(5)Me(5))(2)Y(micro-H)(2)BC(8)H(14)}

scientific article published on 26 September 2007

[(C5Me5)2U][(mu-Ph)2BPh2] as a four electron reductant

scientific article published on 25 August 2005

[Am(C5 Me4 H)3 ]: An Organometallic Americium Complex

scientific article published on 25 July 2019