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List of works by Hansjörg Grützmacher

"Naked" phosphanediide chains and their fragmentation into diphosphene radical anions

scientific article published on 01 August 2004

(L)2 C2 P2 : Dicarbondiphosphide Stabilized by N-Heterocyclic Carbenes or Cyclic Diamido Carbenes

scientific article

1,3,4-Azadiphospholides as building blocks for scorpionate and bidentate ligands in multinuclear complexes

scientific article published on 05 June 2020

2,4,6-Tri(hydroxy)-1,3,5-triphosphinine, P3 C3 (OH)3 : The Phosphorus Analogue of Cyanuric Acid.

scientific article

A Biologically Inspired Organometallic Fuel Cell (OMFC) That Converts Renewable Alcohols into Energy and Chemicals

scientific article published on 01 September 2010

A Convenient Synthesis of 1,2,4- and 1,3,4-Azadiphospholes

scientific article published on 31 August 2016

A Diolefin Diamide Rhodium(I) Complex and Its One-Electron Oxidation Resulting in a Two-Center, Three-Electron Rh-N Bond

article

A Low-Valent Iron Imido Heterocubane Cluster: Reversible Electron Transfer and Catalysis of Selective C-C Couplings

scientific article published on 7 September 2015

A Low-Valent Iron Imido Heterocubane Cluster: Reversible Electron Transfer and Catalysis of Selective C-C Couplings

A Monomeric d9 -Rhodium(0) Complex

scientific article published on 01 June 1998

A Planar Ti2 P2 Core Assembled by Reductive Decarbonylation of - O-C≡P and P-P Radical Coupling

scientific article published on 15 March 2017

A Room Temperature Stable Distonic Radical Cation

scientific article published on 10 September 2020

A Scandium-Stabilized Diisophosphaethynolate Ligand: [OCPPCO]4.

scientific article published on 29 November 2017

A Simple Preparation of Photoactive Glass Surfaces Allowing Coatings via the "Grafting-from" Method

scientific article published on 22 July 2016

A Stable Aminyl Radical Coordinated to Cobalt.

scientific article

A highly efficient waterborne photoinitiator for visible-light-induced three-dimensional printing of hydrogels

scientific article published on 10 January 2018

A homogeneous transition metal complex for clean hydrogen production from methanol-water mixtures

scientific article published on 10 March 2013

A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones

scientific article published on 15 November 2018

A stable aminyl radical metal complex

scientific article

A stable phosphanyl phosphaketene and its reactivity

A synthetic cycle for the ruthenium-promoted formation of 1H-phosphindoles from phosphaalkynes

scientific article published on 01 November 2006

A tetracoordinated rhodium aminyl radical complex

scientific article published on 01 May 2006

Alkylating agents stronger than alkyl triflates

scientific article published in October 2004

All-in-One Cellulose Nanocrystals for 3D Printing of Nanocomposite Hydrogels

scientific article published on 20 December 2017

Amine olefin rhodium(I) complexes: pKa and NH bond strength

scientific article published in November 2004

Amino olefin nickel(i) and nickel(0) complexes as dehydrogenation catalysts for amine boranes

scholarly article by Matthias Vogt et al published 2011 in Chemical Science

An In-Depth Mechanistic Study of Ru Catalysed Aqueous Methanol Dehydrogenation and Prospects for Future Catalyst Design

scientific article published on 18 July 2019

An isolable magnesium diphosphaethynolate complex.

scientific article published on 15 December 2017

Annulated 1,3,4-Azadiphospholides: Heterocycles with Widely Tunable Optical Properties

scientific article

Bent Phosphaallenes With "Hidden" Lone Pairs as Ligands

scientific article published on 15 May 2019

Binding of Specialty Phosphines to Metals: Synthesis, Structure, and Solution Calorimetry of the Phosphirane Complex [PtMe2(iPrBABAR-Phos)2]

Bis(mesitoyl)phosphinic acid: photo-triggered release of metaphosphorous acid in solution

scientific article published on 19 July 2016

Bisacylphosphane oxides as photo-latent cytotoxic agents and potential photo-latent anticancer drugs

scientific article published on 12 April 2019

Bismesitoylphosphinic Acid (BAPO-OH): A Ligand for Copper Complexes and Four-Electron Photoreductant for the Preparation of Copper Nanomaterials

scientific article published on 16 May 2018

Bismesitoylphosphinic Acid (BAPO-OH): A Ligand for Copper Complexes and Four-Electron Photoreductant for the Preparation of Copper Nanomaterials

Borane-Stabilized Isomeric Dimers of the Phosphaethynolate Anion

scientific article published on 18 September 2017

Borane-Stabilized Isomeric Dimers of the Phosphaethynolate Anion

Carbene insertion into a P-H bond: parent phosphinidene-carbene adducts from PH3 and bis(phosphinidene)mercury complexes

scientific article published on 30 June 2015

Catalyzed dehydrogenative coupling of primary alcohols with water, methanol, or amines

scientific article published on 01 January 2009

Chemoselective methoxycarbonylation of terminal alkynes catalyzed by Pd(II)-TROPP complexes

scientific article published on 8 June 2010

Chiral Olefins as Steering Ligands in Asymmetric Catalysis

scientific article published on 01 January 2008

Chiral phosphane alkenes (PALs): simple synthesis, applications in catalysis, and functional hemilability

scientific article published on 01 July 2006

Cooperating ligands in catalysis

scientific article published on 01 January 2008

Coordination chemistry of phosphanyl amino acids: solid state and solution structures of neutral and cationic rhodium complexes

scientific article published on 29 November 2005

Correction to "DFT Provides Insight into the Additive-Free Conversion of Aqueous Methanol to Dihydrogen Catalyzed by [Ru(tropdad)]: Importance of the (Electronic) Flexibility of the Diazadiene Moiety"

scholarly article published in Journal of the American Chemical Society

Coulomb repulsion versus cycloaddition: formation of anionic four-membered rings from sodium phosphaethynolate, Na(OCP)

scientific article published on 24 October 2013

Cyaarside (CAs− ) and 1,3-Diarsaallendiide (AsCAs2− ) Ligands Coordinated to Uranium and Generated via Activation of the Arsaethynolate Ligand (OCAs− )

scholarly article by Christopher J. Hoerger et al published 9 January 2019 in Angewandte Chemie

Cyaarside (CAs− ) and 1,3-Diarsaallendiide (AsCAs2− ) Ligands Coordinated to Uranium and Generated via Activation of the Arsaethynolate Ligand (OCAs− )

scientific article published on 09 January 2019

Cyclo-oligomerization of isocyanates with Na(PH2) or Na(OCP) as "P-" anion sources

scientific article

DFT Provides Insight into the Additive-Free Conversion of Aqueous Methanol to Dihydrogen Catalyzed by [Ru(trop2dad)]: Importance of the (Electronic) Flexibility of the Diazadiene Moiety

scholarly article by Vivek Sinha et al published 14 September 2018 in Journal of the American Chemical Society

DFT Provides Insight into the Additive-Free Conversion of Aqueous Methanol to Dihydrogen Catalyzed by [Ru(tropdad)]: Importance of the (Electronic) Flexibility of the Diazadiene Moiety

scientific article published in 2018

Deoxygenative Fluorination of Phosphine Oxides: A General Route to Fluorinated Organophosphorus(V) Compounds and Beyond

scientific article published on 27 August 2020

Diamido rhodates(1-)

scientific article published on 01 October 2005

Dibenzophosphasemibullvalene

scientific article published on 01 August 2003

Diolefins with an ether/thioether functionality as ligands in the coordination sphere of Ni and Rh

scientific article published on 01 December 2015

Direct Access to Inversely Polarized Phosphaalkenes from Elemental Phosphorus or Polyphosphides

Direct Amidation of Aldehydes with Primary Amines under Mild Conditions Catalyzed by Diolefin-Amine-RhIComplexes

article

Domino rhodium/palladium-catalyzed dehydrogenation reactions of alcohols to acids by hydrogen transfer to inactivated alkenes

scientific article published in March 2010

Electromeric rhodium radical complexes

scientific article

Elucidating the thermal decomposition of dimethyl methylphosphonate by vacuum ultraviolet (VUV) photoionization: pathways to the PO radical, a key species in flame-retardant mechanisms

scientific article

Enabling the synthesis of homogeneous or Janus hairy nanoparticles through surface photoactivation

scientific article from 2018

Ethanol as hydrogen donor: highly efficient transfer hydrogenations with rhodium(I) amides

scientific article

Facile Access to NaOC≡As and Its Use as an Arsenic Source To Form Germylidenylarsinidene Complexes

scientific article published on 2 May 2017

Facile Access to NaOC≡As and Its Use as an Arsenic Source To Form Germylidenylarsinidene Complexes

scientific article published on 23 May 2017

Facile Phenylphosphinidene Transfer Reactions from Carbene-Phosphinidene Zinc Complexes

scientific article

Finding a soft spot for vanadium: a P-bound OCP ligand

scientific article published on 03 May 2019

Formation of a Uranium-Bound η1-Cyaphide (CP–) Ligand via Activation and C–O Bond Cleavage of Phosphaethynolate (OCP–)

scholarly article by Christopher J. Hoerger et al published 3 October 2017 in Organometallics

From 0 to II in One-Electron Steps: A Series of Ruthenium Complexes Supported by TropPPh2.

scientific article published on 25 August 2016

From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene

scientific article published on 3 March 2016

From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene.

scientific article published on 3 March 2016

From an Fe2P3 complex to FeP nanoparticles as efficient electrocatalysts for water-splitting

scientific article published on 17 September 2018

From the parent phosphinidene-carbene adduct NHC = PH to cationic P4-rings and P2-cycloaddition products

scientific article published on 23 September 2015

Front Cover: Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious (Chem. Eur. J. 21/2018)

Gelatin Type A from Porcine Skin Used as Co-Initiator in a Radical Photo-Initiating System

scientific article published on 18 November 2019

Heteroatom stabilized carbenium ions

scientific article (publication date: July 1997)

Heterolytic splitting of hydrogen with rhodium(I) amides

scientific article published on 01 October 2005

High-resolution EPR spectroscopic investigations of a homologous set of d9-cobalt(0), d9-rhodium(0), and d9-iridium(0) complexes

scientific article published in February 2002

Highly Efficient Base-Free Dehydrogenation of Formic Acid at Low Temperature

scientific article published on 15 August 2018

Homogeneously catalysed conversion of aqueous formaldehyde to H2 and carbonate

scientific article

Hydrogenolysis of Polysilanes Catalyzed by Low Valent Nickel Complexes

scientific article published on 12 February 2020

In vitro Implementation of Photopolymerizable Hydrogels as a Potential Treatment of Intracranial Aneurysms

scientific article published on 03 April 2020

In-plane bishomoaromaticity in tetranitrogen dianions: solid-state, solution, and electronic structures

scientific article published on 01 April 2005

Insertion of sodium phosphaethynolate, Na[OCP], into a zirconium-benzyne complex.

scientific article published on 21 April 2017

Inside Back Cover: A Stable Aminyl Radical Coordinated to Cobalt (Chem. Eur. J. 28/2017)

scholarly article by Rafael E. Rodríguez-Lugo et al published 29 March 2017 in Chemistry—A European Journal

Insights into metal-ligand hydrogen transfer: a square-planar ruthenate complex supported by a tetradentate amino-amido-diolefin ligand

scientific article published on 13 April 2016

Ion Dynamics in Confined Spaces: Sodium Ion Mobility in Icosahedral Container Molecules

article

Ion Dynamics in Confined Spaces: Sodium Ion Mobility in Icosahedral Container Molecules

scientific article published in September 2010

Is the phosphaethynolate anion, (OCP)(-), an ambident nucleophile? A spectroscopic and computational study

scientific article published on 3 March 2014

Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion.

scientific article published on 4 January 2016

Isolation of a Highly Persistent Diphosphanyl Radical: The Phosphorus Analogue of a Hydrazyl This work was supported by the ETH Zürich and Swiss National Science Foundation

scientific article published on 01 February 2001

Isomerization and fragmentation reactions of gaseous dimethyl phenylarsane radical cations and methyl phenylarsenium cations. A study by tandem mass spectrometry and density functional theory calculations

scientific article published on 01 January 2006

Isomerization and fragmentation reactions of gaseous phenylarsane radical cations and phenylarsanyl cations. A study by tandem mass spectrometry and theoretical calculations

scientific article published on 30 January 2006

L3 C3 P3 : Tricarbontriphosphide Tricyclic Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes

scientific article

L3 C3 P3 : Tricarbontriphosphide Tricyclic Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes

Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious

Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex; The Innocent, the Guilty, and the Suspicious

scientific article published on 17 January 2018

Lithium Oligophosphanediides in the Li/PhPCl2 System

article

Low-Valent Iron Mono-Diazadiene Compounds: Electronic Structure and Catalytic Application

Low-Valent Iron(I) Amido Olefin Complexes as Promotors for Dehydrogenation Reactions

scholarly article by Crispin Lichtenberg et al published 12 March 2015 in Angewandte Chemie International Edition

Low-valent homobimetallic Rh complexes: influence of ligands on the structure and the intramolecular reactivity of Rh-H intermediates

scientific article published on 08 July 2019

Main Group Element Analogues of Carbenes, Olefins, and Small Rings

Making the true "CP" ligand

scientific article published on 01 September 2006

Making the unconventional μ-P bridging binding mode more conventional in phosphinine complexes

scientific article published on 21 January 2019

Mechanisms of cyaphide (C[triple bond]P(-)) formation

scientific article published on 01 January 2007

Metalloenzyme-inspired catalysis: selective oxidation of primary alcohols with an iridium-aminyl-radical complex.

scientific article

Metal–Ligand Cooperation in the Catalytic Dehydrogenative Coupling (DHC) of Polyalcohols to Carboxylic Acid Derivatives ⬇️

scientific article published on September 7, 2011

Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P- into a P-P bond

scientific article published on 01 March 2019

Mono- and Dinuclear Neutral and Cationic Iron(II) Compounds Supported by an Amidinato-diolefin Ligand: Characterization and Catalytic Application

Multidentate Phosphanyl Phosphinines: Synthesis and Properties

scientific article published on 15 May 2018

N-Heterocyclic Carbene Stabilized Dicarbondiphosphides: Strong Neutral Four-Membered Heterocyclic 6π-Electron Donors

scientific article published on 29 January 2020

N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism

scientific article published on 08 April 2016

N-Heterocyclic carbene phosphaketene adducts as precursors to carbene-phosphinidene adducts and a rearranged π-system.

scientific article

Nanoparticle Cookies Derived from Metal-Organic Frameworks: Controlled Synthesis and Application in Anode Materials for Lithium-Ion Batteries

scientific article published on 7 March 2016

Nanoreactor Based on Macroporous Single Crystals of Metal-Organic Framework

scientific article published on 4 September 2016

Niedervalente Eisen(I)-Amido-Olefinkomplexe als Promotoren von Dehydrierungsreaktionen

Nitrosobenzene as a hydrogen acceptor in rhodium catalysed dehydrogenation reactions of alcohols: synthesis of aldehydes and azoxybenzenes ⬇️

scientific article published on 03 October 2012

Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols

scientific article published on 22 December 2015

O-O bond activation in heterobimetallic peroxides: synthesis of the peroxide [LNi(mu,eta2:eta2-O2)K] and its conversion into a bis(mu-hydroxo) nickel zinc complex

scientific article published in January 2009

Odd-electron bonds and biradicals in main group element chemistry

scientific article published on 01 November 2002

Olefins as steering ligands for homogeneously catalyzed hydrogenations

scientific article published in September 2004

Oxidative formation of phosphinyl radicals from a trigonal pyramidal terminal phosphide Rh(i) complex, with an unusually long Rh-P bond

scientific article published on 20 February 2017

PH3 as a Phosphorus Source for Phosphinidene-Carbene Adducts and Phosphinidene-Transition Metal Complexes

scientific article published on 01 January 2016

Phosphaketenes as building blocks for the synthesis of triphospha heterocycles

scientific article published on 23 July 2014

Phosphanyl Cyanophosphide Salts: Versatile PCN Building Blocks

scientific article published on 03 June 2019

Phosphination of carbon monoxide: a simple synthesis of sodium phosphaethynolate (NaOCP)

scientific article published on 15 July 2011

Phosphorous-functionalized bis(acyl)phosphane oxides for surface modification

scientific article published on 04 April 2012

Probing Phosphorus Nitride (P≡N) and Other Elusive Species Formed upon Pyrolysis of Dimethyl Phosphoramidate

scientific article

Reactivity of an All-Ferrous Iron-Nitrogen Heterocubane under Reductive and Oxidative Conditions

scientific article published on 16 September 2015

Redox-triggered reversible interconversion of a monocyclic and a bicyclic phosphorus heterocycle

scientific article published on 19 May 2014

Remarkable stability of a molecular ruthenium complex in PEM water electrolysis

Rhodium(0) metalloradicals in binuclear C-H activation

scientific article

Ru(II)-hydride-trop complexes: X-ray single-crystal determination and quantum-chemical calculations

scientific article published on 8 November 2013

Ruthenium mediated halogenation of white phosphorus: synthesis and reactivity of the unprecedented P4Cl2 moiety

scientific article published on 01 March 2019

Salen supported Al-O-C[triple bond, length as m-dash]P and Ga-P[double bond, length as m-dash]C[double bond, length as m-dash]O complexes

scientific article published on 01 March 2019

Simple Synthesis of Functionalized 2-Phosphanaphthalenes

scientific article published on 30 March 2018

Simple one-pot syntheses of water-soluble bis(acyl)phosphane oxide photoinitiators and their application in surfactant-free emulsion polymerization

scientific article published on 4 February 2015

Snowballing radical generation leads to ultrahigh molecular weight polymers

scientific article

Sodium compounds of the benzophenone dianion (diphenyloxidomethanide).

scientific article published on 22 November 2005

Sodium oligophosphanediide ions in the PhPCl2/Na system: syntheses and structural characterization

scientific article published on 01 August 2003

Sodium phosphaethynolate as a building block for heterocycles

scientific article published on 22 January 2014

Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX- (E = As, P, and N; X = S and O) Anions.

scientific article published on 7 June 2017

Spin density distribution in mononuclear Rh(0) complexes: A combined experimental and DFT study

Star-shaped Polymers through Simple Wavelength-Selective Free-Radical Photopolymerization.

scientific article published on 31 August 2017

Stereochemical control of the redox potential of tetracoordinate rhodium complexes

scientific article published on 01 May 2004

Synthesis and Characterization of Gold(I) Complexes of Dibenzotropylidene-Functionalized NHC Ligands (Trop-NHCs)

Synthesis and Characterization of Ion Pairs between Alkaline Metal Ions and Anionic Anti-Aromatic and Aromatic Hydrocarbons with π-Conjugated Central Seven- and Eight-Membered Rings

scientific article published on 15 October 2020

Synthesis and characterization of terminal [Re(XCO)(CO)2(triphos)] (X=N, P): isocyanate versus phosphaethynolate complexes

scientific article published on 28 September 2012

Synthesis and structure of [Na11(OtBu)10(OH)]: 1H NMR shift of a hydroxide ion encapsulated in a 21-vertex alcoholate cage

scientific article published in December 2003

Synthesis of P2C2O2 and P2CO via NHC-mediated coupling of the phosphaethynolate anion

scientific article published on 01 November 2017

Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy

scientific article published on 01 May 2006

Synthesis of new bis(acyl)phosphane oxide photoinitiators for the surface functionalization of cellulose nanocrystals

scientific article published on 18 January 2016

Synthesis of γ-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-γ-CyD) serving as multiple photoinitiator and crosslinking agent

scientific article published on 01 April 2020

Synthesis, structure, and reactivity of a stabilized phosphiranylium salt

scientific article published on July 2010

The Chemistry of the 2-Phosphaethynolate Anion

scientific article published on 20 November 2018

The Organometallic Chemistry of Rh-, Ir-, Pd-, and Pt-Based Radicals: Higher Valent Species

article

The Underlying Chemistry to Formation of Phosphoryl Radicals from Organophosphorus Compounds - A Missing Puzzle Piece in the Flame Chemistry

scientific article published on 19 May 2020

The reactivity of acyl chlorides towards sodium phosphaethynolate, Na(OCP): a mechanistic case study.

scientific article published on 17 June 2016

Thermodynamic and kinetic data for adduct formation, cis-trans isomerization and redox reactions of ML4 complexes: a case study with rhodium- and iridium-tropp complexes in d8, d9 and d10 valence electron configurations (tropp=dibenzotropylidene pho

scientific article

Transient Dipnictyl Analogues of Acrylamides, R-E=E'-CONR2 , and a Related Diphosphadigalletane from Na[OCP] and (R2 N)2 ECl (E, E'=P, As, Ga)

scientific article published on 18 February 2019

Trends in the Periodic System: the mass spectrum of dimethylphenyl phosphane and a comparison of the gas phase reactivity of dimethylphenyl pnictogene radical cations C(6)H(5)E(CH(3))(2)(*+), (E = N, P, As)(dagger).

scientific article published in January 2009

Trends in the reactions of gaseous phenyl pnictogen radical cations C6H5EH2*+ (E = N, P, As).

scientific article published on 30 May 2008

Trigonal pyramids: alternative ground-state structures for sixteen-electron complexes

scientific article published on 01 August 2006

Tropad: a new ligand for the synthesis of water-stable paramagnetic [16+1]-electron rhodium and iridium complexes.

scientific article published in August 2003

Unexpected Photodegradation of a Phosphaketenyl-Substituted Germyliumylidene Borate Complex

scientific article published on 13 March 2017

Unexpected Photodegradation of a Phosphaketenyl-Substituted Germyliumylidene Borate Complex.

scientific article published on 13 March 2017

Unprecedented Bifunctional Chemistry of Bis(acyl)phosphane Oxides in Aqueous and Alcoholic Media

scientific article published on 12 June 2019

Using the diphosphanyl radical as a potential spin label: effect of motion on the EPR spectrum of an R1(R2)P--PR1 radical

scientific article published in May 2005

Very Stable Phosphiranes

scientific article published on 01 June 1999

Zero-Valent Amino-Olefin Cobalt Complexes as Catalysts for Oxygen Atom Transfer Reactions from Nitrous Oxide

scientific article published on 9 November 2016

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