List of works - Shigeyoshi Inoue

1,2-Disilacyclobut-2-enes: donor-free four-membered cyclic silenes from reaction of disilenides with vinylbromides

scientific article published on 01 January 2008

A Stable Neutral Compound with an Aluminum-Aluminum Double Bond

scientific article

A Tin Analogue of Carbenoid: Isolation and Reactivity of a Lithium Bis(imidazolin-2-imino)stannylenoid

scientific article published on 21 April 2016

A cyclic germadicarbene ("germylone") from germyliumylidene

scientific article published on 25 March 2013

A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom

scientific article published on 31 May 2013

A dihydrodisilene transition metal complex from an N-heterocyclic carbene-stabilized silylene monohydride

scientific article published on 22 November 2013

A facile access to a novel NHC-stabilized silyliumylidene ion and C-H activation of phenylacetylene

scientific article published in October 2014

A fragile zwitterionic phosphasilene as a transfer agent of the elusive parent phosphinidene (:PH).

scientific article

A monotopic aluminum telluride with an Al=Te double bond stabilized by N-heterocyclic carbenes

scientific article published on 27 November 2015

A neutral tetraphosphacyclobutadiene ligand in cobalt(I) complexes

scientific article published on 4 December 2014

Activation of elemental sulfur by aluminum dihydride: isolation of mono- and bis(hydrogensulfide) complexes of aluminum

scientific article published on 22 April 2014

Advances in Phosphasilene Chemistry.

scientific article published on 5 April 2017

Advances in the development of complexes that contain a group 13 element chalcogen multiple bond

scientific article published on 24 May 2016

An Air-Stable Heterobimetallic Si2 M2 Tetrahedral Cluster

scientific article published on 20 February 2020

An Efficient Zinc‐Catalyzed Dehydration of Primary Amides to Nitriles ⬇️

scientific article published on September 29, 2011

An Isolable Bis-Silylene Oxide (“Disilylenoxane”) and Its Metal Coordination ⬇️

scientific article published on September 8, 2010

An NHC-Stabilized Silicon Analogue of Acylium Ion: Synthesis, Structure, Reactivity, and Theoretical Studies

scientific article published on 24 April 2015

An acyclic imino-substituted silylene: synthesis, isolation, and its facile conversion into a zwitterionic silaimine

scientific article published on 18 July 2012

An elusive hydridoaluminum(I) complex for facile C-H and C-O bond activation of ethers and access to its isolable hydridogallium(I) analogue: syntheses, structures, and theoretical studies

scientific article published on 26 June 2014

An unsymmetric substituted digermylene with a Ge(I)-Ge(I) bond and synthesis of a germylene-stannylene with a Ge(I)-Sn(I) bond

scientific article published on 23 March 2009

An ylide-like phosphasilene and striking formation of a 4π-electron, resonance-stabilized 2,4-disila-1,3-diphosphacyclobutadiene.

scientific article published on 15 February 2011

Applications of N-heterocyclic imines in main group chemistry.

scientific article

Aromatic ylide-stabilized carbocyclic silylene.

scientific article published in September 2011

Bis(silylenyl)- and bis(germylenyl)-substituted ferrocenes: synthesis, structure, and catalytic applications of bidentate silicon(II)-cobalt complexes

scientific article published on 4 May 2012

Bis-N-heterocyclic carbene (NHC) stabilized η6-arene iron(0) complexes: synthesis, structure, reactivity, and catalytic activity

scientific article published on 20 November 2013

CO2 Fixation and Catalytic Reduction by a Neutral Aluminum Double Bond

scientific article published on 28 June 2019

Catalytic CO2 Reduction with Boron- and Aluminum Hydrides

scientific article published on 30 September 2019

Cationic Complexes of Boron and Aluminum: An Early 21st Century Viewpoint

scientific article published on 10 December 2018

Chalcogen-atom transfer and exchange reactions of NHC-stabilized heavier silaacylium ions

scientific article published on 9 November 2017

Coinage metal complexes of NHC-stabilized silyliumylidene ions

article

Conversion of a disilenide into a silene: silyl-anion-substituted silene by a sila-Peterson-type reaction from an sp2-type silyl anion

scientific article published on 01 January 2007

Correction: Facile rotation around a silicon-phosphorus double bond enabled through coordination to tungsten

scientific article published on 26 June 2015

Disilene-Silylene Interconversion: A Synthetically Accessible Acyclic Bis(silyl)silylene

scientific article published on 09 August 2019

Electron-rich N-heterocyclic silylene (NHSi)-iron complexes: synthesis, structures, and catalytic ability of an isolable hydridosilylene-iron complex

scientific article published on 22 April 2013

Experimental Realisation of Elusive Multiple-Bonded Aluminium Compounds: A New Horizon in Aluminium Chemistry

scientific article published on 21 September 2018

Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines.

scientific article published on 30 August 2016

Facile access to silicon-functionalized bis-silylene titanium(II) complexes

scientific article published on 10 September 2012

Facile rotation around a silicon-phosphorus double bond enabled through coordination to tungsten

scientific article published in June 2015

Formation of N-heterocyclic, donor-stabilized borenium ions.

scientific article

Formation of a donor-stabilized tetrasilacyclobutadiene dication by a Lewis acid assisted reaction of an N-heterocyclic chloro silylene

scientific article published on 11 May 2011

Formation of an imino-stabilized cyclic tin(II) cation from an amino(imino)stannylene

scientific article published on 12 March 2015

From Si(II) to Si(IV) and Back: Reversible Intramolecular Carbon-Carbon Bond Activation by an Acyclic Iminosilylene

scientific article published on 6 June 2017

From a zwitterionic phosphasilene to base stabilized silyliumylidene-phosphide and bis(silylene) complexes

scientific article published on 13 November 2013

From elusive thio- and selenosilanoic acids to copper(i) complexes with intermolecular SiE → Cu–O–Si coordination modes (E = S, Se)

scientific article published on 01 June 2013

Heavier Carbonyl Olefination: The Sila-Wittig Reaction

scientific article published on 09 October 2019

Hydrosilylation of Alkynes by Ni(CO)3-Stabilized Silicon(II) Hydride

scientific article published on 21 November 2011

Isolable anion radical of blue disilene (tBu2MeSi)2Si=Si(SiMetBu2)2 formed upon one-electron reduction: synthesis and characterization

scientific article

Isolable silylene anion radical: structural characteristics in the solid state and in solution

scientific article published on 19 April 2007

Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines

scientific article published on 9 August 2016

Isolation of a germanium(II) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand

scientific article published on 26 May 2015

Isolation of a three-coordinate boron cation with a boron-sulfur double bond

scientific article published on 16 October 2014

Isolation of an N-Heterocyclic Carbene Complex of a Borasilene

scientific article published on 26 July 2019

Isolierung schwer fassbarer Komplexe mit einer Aluminium-Element-Mehrfachbindung: Am Horizont zeichnet sich eine neue Aluminiumchemie ab

scientific article published on 21 September 2018

Lewis base-stabilized silyliumylidene ions in transition metal coordination chemistry

scientific article published on 09 April 2020

Metal-free activation of EH3 (E = P, As) by an ylide-like silylene and formation of a donor-stabilized arsasilene with a HSi=AsH subunit

scientific article published in December 2010

N-Heterocyclic Carbene-Stabilized Germanium and Tin Analogues of Heavier Nitriles: Synthesis, Reactivity, and Catalytic Application

scientific article published on 10 September 2019

NHC-Stabilised Silyliumylidene Ions

scientific article published on 05 March 2019

NHC-Stabilized Silyl-Substituted Chlorosilylene

scientific article published on 11 November 2019

NHC-stabilized silyl-substituted silyliumylidene ions

scientific article published on 01 July 2019

NHCs in Main Group Chemistry

scientific article published on 03 July 2018

New route to access an acyl-functionalized phosphasilene and a four-membered Si-P-C-O heterocycle

scientific article published on 26 June 2014

Observation of a thermally accessible triplet state resulting from rotation around a main-group π bond

scientific article published on 20 August 2015

Oxidation reactions of a versatile, two-coordinate, acyclic iminosiloxysilylene

scientific article published on 12 May 2020

Parent heavy methylenes: chemical tricks to access isolable complexes of elusive H2E: species (E=Ge and Sn).

scientific article published on 4 May 2011

Phosphinosilylenes as a novel ligand system for heterobimetallic complexes

scientific article published on 14 March 2016

Precise Activation of Ammonia and Carbon Dioxide by an Iminodisilene

Reaction of an N-heterocyclic carbene-stabilized silicon(II) monohydride with alkynes: [2+2+1] cycloaddition versus hydrogen abstraction

scientific article published on 20 November 2014

Reactivity of an NHC-stabilized pyramidal hydrosilylene with electrophilic boron sources

scientific article published on 01 April 2019

Reductive cleavage of P4 by iron(i) centres: synthesis and structural characterisation of Fe2(P2)2 complexes with two bridging P22− ligands

Silicon and Oxygen's Bond of Affection: An Acyclic Three-Coordinate Silanone and Its Transformation to an Iminosiloxysilylene

scientific article published on 3 November 2017

Silicon-containing formal 4π-electron four-membered ring systems: antiaromatic, aromatic, or nonaromatic?

scientific article published on 24 April 2012

Silylated silicon-carbonyl complexes as mimics of ubiquitous transition-metal carbonyls

scientific article published on 19 October 2020

Small Molecule Activation by Two-Coordinate Acyclic Silylenes

scientific article published on 28 July 2020

Stable cyclic silenes from reaction of disilenides with carboxylic acid chlorides

scientific article published on 01 January 2007

Steering S-H and N-H bond activation by a stable n-heterocyclic silylene: different addition of H(2)S, NH(3), and organoamines on a silicon(II) ligand versus its Si(II)-->Ni(CO)(3) complex

scientific article published in March 2010

Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium

scientific article published in March 2012

Synthesis of mixed silylene-carbene chelate ligands from N-heterocyclic silylcarbenes mediated by nickel

scientific article

Synthesis, characterization and reactivity of an imidazolin-2-iminato aluminium dihydride

scientific article published in March 2014

Systematic Study of N-Heterocyclic Carbene Coordinate Hydrosilylene Transition-Metal Complexes.

scientific article published on 7 August 2017

Taming the germyliumylidene [CIGe:]+ and germathionium [CIGe=S]+ ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene

scientific article published in December 2012

The Quest for Stable Silaaldehydes: Synthesis and Reactivity of a Masked Silacarbonyl

scientific article published on 20 December 2018

The elusive silyliumylidene [ClSi:]+ and silathionium [ClSi=S]+ cations stabilized by bis(iminophosphorane) chelate ligand

scientific article published on 10 September 2012

The isolable cation radical of disilene: synthesis, characterization, and a reversible one-electron redox system

scientific article published on 19 April 2008

Three-Coordinate Boron(III) and Diboron(II) Dications

scientific article published on 7 February 2018

Transition Metal Carbonyl Complexes of an N-Heterocyclic Carbene Stabilized Silyliumylidene Ion

scientific article published on 22 October 2019

Twist of a Silicon-Silicon Double Bond: Selective Anti-Addition of Hydrogen to an Iminodisilene.

scientific article published on 22 June 2017

List of works by Shigeyoshi Inoue

1,2-Disilacyclobut-2-enes: donor-free four-membered cyclic silenes from reaction of disilenides with vinylbromides

A Stable Neutral Compound with an Aluminum-Aluminum Double Bond

A Tin Analogue of Carbenoid: Isolation and Reactivity of a Lithium Bis(imidazolin-2-imino)stannylenoid

A cyclic germadicarbene ("germylone") from germyliumylidene

A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom

A dihydrodisilene transition metal complex from an N-heterocyclic carbene-stabilized silylene monohydride

A facile access to a novel NHC-stabilized silyliumylidene ion and C-H activation of phenylacetylene

A fragile zwitterionic phosphasilene as a transfer agent of the elusive parent phosphinidene (:PH).

A monotopic aluminum telluride with an Al=Te double bond stabilized by N-heterocyclic carbenes

A neutral tetraphosphacyclobutadiene ligand in cobalt(I) complexes

Activation of elemental sulfur by aluminum dihydride: isolation of mono- and bis(hydrogensulfide) complexes of aluminum

Advances in Phosphasilene Chemistry.

Advances in the development of complexes that contain a group 13 element chalcogen multiple bond

An Air-Stable Heterobimetallic Si2 M2 Tetrahedral Cluster

An Efficient Zinc‐Catalyzed Dehydration of Primary Amides to Nitriles ⬇️

An Isolable Bis-Silylene Oxide (“Disilylenoxane”) and Its Metal Coordination ⬇️

An NHC-Stabilized Silicon Analogue of Acylium Ion: Synthesis, Structure, Reactivity, and Theoretical Studies

An acyclic imino-substituted silylene: synthesis, isolation, and its facile conversion into a zwitterionic silaimine

An elusive hydridoaluminum(I) complex for facile C-H and C-O bond activation of ethers and access to its isolable hydridogallium(I) analogue: syntheses, structures, and theoretical studies

An unsymmetric substituted digermylene with a Ge(I)-Ge(I) bond and synthesis of a germylene-stannylene with a Ge(I)-Sn(I) bond

An ylide-like phosphasilene and striking formation of a 4π-electron, resonance-stabilized 2,4-disila-1,3-diphosphacyclobutadiene.

Applications of N-heterocyclic imines in main group chemistry.

Aromatic ylide-stabilized carbocyclic silylene.

Bis(silylenyl)- and bis(germylenyl)-substituted ferrocenes: synthesis, structure, and catalytic applications of bidentate silicon(II)-cobalt complexes

Bis-N-heterocyclic carbene (NHC) stabilized η6-arene iron(0) complexes: synthesis, structure, reactivity, and catalytic activity

CO2 Fixation and Catalytic Reduction by a Neutral Aluminum Double Bond

Catalytic CO2 Reduction with Boron- and Aluminum Hydrides

Cationic Complexes of Boron and Aluminum: An Early 21st Century Viewpoint

Chalcogen-atom transfer and exchange reactions of NHC-stabilized heavier silaacylium ions

Coinage metal complexes of NHC-stabilized silyliumylidene ions

Conversion of a disilenide into a silene: silyl-anion-substituted silene by a sila-Peterson-type reaction from an sp2-type silyl anion

Correction: Facile rotation around a silicon-phosphorus double bond enabled through coordination to tungsten

Disilene-Silylene Interconversion: A Synthetically Accessible Acyclic Bis(silyl)silylene

Electron-rich N-heterocyclic silylene (NHSi)-iron complexes: synthesis, structures, and catalytic ability of an isolable hydridosilylene-iron complex

Experimental Realisation of Elusive Multiple-Bonded Aluminium Compounds: A New Horizon in Aluminium Chemistry

Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines.

Facile access to silicon-functionalized bis-silylene titanium(II) complexes

Facile rotation around a silicon-phosphorus double bond enabled through coordination to tungsten

Formation of N-heterocyclic, donor-stabilized borenium ions.

Formation of a donor-stabilized tetrasilacyclobutadiene dication by a Lewis acid assisted reaction of an N-heterocyclic chloro silylene

Formation of an imino-stabilized cyclic tin(II) cation from an amino(imino)stannylene

From Si(II) to Si(IV) and Back: Reversible Intramolecular Carbon-Carbon Bond Activation by an Acyclic Iminosilylene

From a zwitterionic phosphasilene to base stabilized silyliumylidene-phosphide and bis(silylene) complexes

From elusive thio- and selenosilanoic acids to copper(i) complexes with intermolecular SiE → Cu–O–Si coordination modes (E = S, Se)

Heavier Carbonyl Olefination: The Sila-Wittig Reaction

Hydrosilylation of Alkynes by Ni(CO)3-Stabilized Silicon(II) Hydride

Isolable anion radical of blue disilene (tBu2MeSi)2Si=Si(SiMetBu2)2 formed upon one-electron reduction: synthesis and characterization

Isolable silylene anion radical: structural characteristics in the solid state and in solution

Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines

Isolation of a germanium(II) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand

Isolation of a three-coordinate boron cation with a boron-sulfur double bond

Isolation of an N-Heterocyclic Carbene Complex of a Borasilene

Isolierung schwer fassbarer Komplexe mit einer Aluminium-Element-Mehrfachbindung: Am Horizont zeichnet sich eine neue Aluminiumchemie ab

Lewis base-stabilized silyliumylidene ions in transition metal coordination chemistry

Metal-free activation of EH3 (E = P, As) by an ylide-like silylene and formation of a donor-stabilized arsasilene with a HSi=AsH subunit

N-Heterocyclic Carbene-Stabilized Germanium and Tin Analogues of Heavier Nitriles: Synthesis, Reactivity, and Catalytic Application

NHC-Stabilised Silyliumylidene Ions

NHC-Stabilized Silyl-Substituted Chlorosilylene

NHC-stabilized silyl-substituted silyliumylidene ions

NHCs in Main Group Chemistry

New route to access an acyl-functionalized phosphasilene and a four-membered Si-P-C-O heterocycle

Observation of a thermally accessible triplet state resulting from rotation around a main-group π bond

Oxidation reactions of a versatile, two-coordinate, acyclic iminosiloxysilylene

Parent heavy methylenes: chemical tricks to access isolable complexes of elusive H2E: species (E=Ge and Sn).

Phosphinosilylenes as a novel ligand system for heterobimetallic complexes

Precise Activation of Ammonia and Carbon Dioxide by an Iminodisilene

Reaction of an N-heterocyclic carbene-stabilized silicon(II) monohydride with alkynes: [2+2+1] cycloaddition versus hydrogen abstraction

Reactivity of an NHC-stabilized pyramidal hydrosilylene with electrophilic boron sources

Reductive cleavage of P4 by iron(i) centres: synthesis and structural characterisation of Fe2(P2)2 complexes with two bridging P22− ligands

Silicon and Oxygen's Bond of Affection: An Acyclic Three-Coordinate Silanone and Its Transformation to an Iminosiloxysilylene

Silicon-containing formal 4π-electron four-membered ring systems: antiaromatic, aromatic, or nonaromatic?

Silylated silicon-carbonyl complexes as mimics of ubiquitous transition-metal carbonyls

Small Molecule Activation by Two-Coordinate Acyclic Silylenes

Stable cyclic silenes from reaction of disilenides with carboxylic acid chlorides

Steering S-H and N-H bond activation by a stable n-heterocyclic silylene: different addition of H(2)S, NH(3), and organoamines on a silicon(II) ligand versus its Si(II)-->Ni(CO)(3) complex

Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium

Synthesis of mixed silylene-carbene chelate ligands from N-heterocyclic silylcarbenes mediated by nickel

Synthesis, characterization and reactivity of an imidazolin-2-iminato aluminium dihydride

Systematic Study of N-Heterocyclic Carbene Coordinate Hydrosilylene Transition-Metal Complexes.