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List of works by Brian M. Hoffman

13C ENDOR Spectroscopy of Lipoxygenase-Substrate Complexes Reveals the Structural Basis for C-H Activation by Tunneling

scientific article published on 25 January 2017

A mixed-valent Fe(II)Fe(III) species converts cysteine to an oxazolone/thioamide pair in methanobactin biosynthesis

scientific article published in 2022

A structurally-characterized peroxomanganese(iv) porphyrin from reversible O2 binding within a metal-organic framework.

scientific article published on 14 December 2017

Across the tree of life, radiation resistance is governed by antioxidant Mn2+, gauged by paramagnetic resonance.

scientific article

Active-Site Controlled, Jahn-Teller Enabled Regioselectivity in Reductive S-C Bond Cleavage of <i>S</i>-Adenosylmethionine in Radical SAM Enzymes

scientific article published on 29 December 2020

An Engineered Glutamate in Biosynthetic Models of Heme-Copper Oxidases Drives Complete Product Selectivity by Tuning the Hydrogen-Bonding Network

scientific article published on 19 January 2021

Beyond fossil fuel-driven nitrogen transformations

scientific article published in Science

Correction to "High-Resolution ENDOR Spectroscopy Combined with Quantum Chemical Calculations Reveals the Structure of Nitrogenase Janus Intermediate E4(4H)"

scientific article published on 10 December 2019

Critical computational analysis illuminates the reductive-elimination mechanism that activates nitrogenase for N reduction

article published in the Proceedings of the National Academy of Sciences of the United States of America

Cu+-specific CopB transporter: Revising P1B-type ATPase classification.

scientific article published on 12 February 2018

ENDOR Characterization of (N2)FeII(μ-H)2FeI(N2)-: A Spectroscopic Model for N2 Binding by the Di-μ-hydrido Nitrogenase Janus Intermediate

scientific article published on 17 September 2018

ENDOR characterization of an iron-alkene complex provides insight into a corresponding organometallic intermediate of nitrogenase.

scientific article published on 30 June 2017

EPR/ENDOR and Theoretical Study of the Jahn-Teller-Active [HIPTN3N]MoVL Complexes (L = N-, NH).

scientific article published in June 2017

Electron Redistribution within the Nitrogenase Active Site FeMo-Cofactor During Reductive Elimination of H<sub>2</sub> to Achieve N≡N Triple-Bond Activation

scientific article published on 16 December 2020

Energy Transduction in Nitrogenase

scientific article published on 10 August 2018

Formation and Electronic Structure of an Atypical CuA Site

scientific article published on 07 March 2019

High-Resolution ENDOR Spectroscopy Combined with Quantum Chemical Calculations Reveals the Structure of Nitrogenase Janus Intermediate E4(4H)

scientific article published on 16 July 2019

Hydride Conformers of the Nitrogenase FeMo-cofactor Two-Electron Reduced State E2(2H), Assigned Using Cryogenic Intra Electron Paramagnetic Resonance Cavity Photolysis.

scientific article published on 24 March 2018

Mechanism of Nitrogenase H2 Formation by Metal-Hydride Protonation Probed by Mediated Electrocatalysis and H/D Isotope Effects.

scientific article published on 29 August 2017

Mechanism of Radical Initiation in the Radical S-Adenosyl-l-methionine Superfamily

article

Metal Selectivity of a Cd-, Co-, and Zn-Transporting P1B-type ATPase

scientific article published on 21 December 2016

Mo-, V-, and Fe-Nitrogenases Use a Universal Eight-Electron Reductive-Elimination Mechanism To Achieve N2 Reduction

scientific article published on 19 July 2019

Monovalent Cation Activation of the Radical SAM Enzyme Pyruvate Formate-Lyase Activating Enzyme

scientific article published on 2 August 2017

Organometallic and radical intermediates reveal mechanism of diphthamide biosynthesis.

scientific article published in March 2018

Paradigm Shift for Radical S-Adenosyl-l-methionine Reactions: The Organometallic Intermediate Ω Is Central to Catalysis

scientific article published on 06 July 2018

Particulate methane monooxygenase contains only mononuclear copper centers

scientific article published on 01 May 2019

Photoinduced Electron Transfer in a Radical SAM Enzyme Generates an S-Adenosylmethionine Derived Methyl Radical

scientific article published on 26 September 2019

Photoinduced Reductive Elimination of H2 from the Nitrogenase Dihydride (Janus) State Involves a FeMo-cofactor-H2 Intermediate

scientific article published on 8 February 2017

Reduction of Substrates by Nitrogenases

scientific article published on 16 March 2020

Spectroscopic Description of the E1 State of Mo Nitrogenase Based on Mo and Fe X-ray Absorption and Mössbauer Studies

scientific article published on 23 August 2019

Structural and spectroscopic characterization of an Fe(VI) bis(imido) complex

scientific article

Substrate-Dependent Cleavage Site Selection by Unconventional Radical S-Adenosylmethionine Enzymes in Diphthamide Biosynthesis

scientific article published on 6 April 2017

The Elusive 5'-Deoxyadenosyl Radical: Captured and Characterized by Electron Paramagnetic Resonance and Electron Nuclear Double Resonance Spectroscopies

scientific article published on 22 July 2019

The Mechanism of N2 Reduction Catalyzed by Fe-Nitrogenase Involves Reductive Elimination of H2.

scientific article

The Soybean Lipoxygenase-Substrate Complex: Correlation between the Properties of Tunneling-Ready States and ENDOR-Detected Structures of Ground States

scientific article published on 05 February 2020

Time-Resolved EPR Study of H2 Reductive Elimination from the Photoexcited Nitrogenase Janus E4(4H) Intermediate

scientific article published on 08 October 2019

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