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List of works by Bernhard Breit

4-Acyl Pyrrole Derivatives Yield Novel Vectors for Designing Inhibitors of the Acetyl-Lysine Recognition Site of BRD4(1)

scientific article

4-Acyl Pyrroles as Dual BET-BRD7/9 Bromodomain Inhibitors Address BETi Insensitive Human Cancer Cell Lines

scientific article published on 04 December 2020

A combinatorial approach to the identification of self-assembled ligands for rhodium-catalysed asymmetric hydrogenation

scientific article published on August 22, 2010

A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis

scientific article published on 25 October 2019

A new method for the synthesis of chiral beta-branched alpha-amino acids

scientific article published on 06 September 2007

A rhodium catalyzed cycloisomerization and tandem Diels-Alder reaction for facile access to diverse bicyclic and tricyclic heterocycles.

scientific article published on 3 April 2019

A supramolecular catalyst for regioselective hydroformylation of unsaturated carboxylic acids

scientific article published on 01 January 2008

A supramolecular catalyst for the decarboxylative hydroformylation of alpha,beta-unsaturated carboxylic acids

scientific article published on 01 January 2008

A systematic investigation of coinage metal carbonyl complexes stabilized by fluorinated alkoxy aluminates

scientific article published on 29 July 2013

A unified strategy for the stereospecific construction of propionates and acetate-propionates relying on a directed allylic substitution.

scientific article published in June 2009

Alkynes as Electrophilic or Nucleophilic Allylmetal Precursors in Transition-Metal Catalysis

scientific article published on 12 June 2017

All-carbon quaternary centers via ruthenium-catalyzed hydroxymethylation of 2-substituted butadienes mediated by formaldehyde: beyond hydroformylation

scientific article published on August 2009

Allylation of N-heterocycles with allylic alcohols employing self-assembling palladium phosphane catalysts

scientific article published on 27 February 2008

Assignment of Relative Configuration of Desoxypropionates by 1H NMR Spectroscopy: Method Development, Proof of Principle by Asymmetric Total Synthesis of Xylarinic Acid A and Applications

scientific article published on April 27, 2012

Asymmetric Total Syntheses of (-)-Angustureine and (-)-Cuspareine via Rhodium-Catalyzed Hydroamination

scientific article published on 26 December 2019

Asymmetric rhodium-catalyzed addition of thiols to allenes: synthesis of branched allylic thioethers and sulfones

scientific article published on 16 January 2015

Asymmetric synthesis of N-allylic indoles via regio- and enantioselective allylation of aryl hydrazines

scientific article published on 3 July 2015

Asymmetric synthesis of allylic amines via hydroamination of allenes with benzophenone imine.

scientific article published on 9 February 2016

Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification

scientific article published on 10 November 2015

Atom-economic, regiodivergent, and stereoselective coupling of imidazole derivatives with terminal allenes

scientific article published on 20 January 2014

Beyond the BET Family: Targeting CBP/p300 with 4-Acyl Pyrroles.

scientific article published on 2 August 2017

Branched-regioselective hydroformylation with catalytic amounts of a reversibly bound directing group

scientific article published on 01 January 2008

Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes

scientific article published on 25 July 2016

Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis

scientific article published on 14 January 2013

Catalytic hydrogenation of amides to amines under mild conditions

scientific article

Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Pyridazinones with Terminal Allenes.

scientific article

Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Triazoles with Internal Alkynes and Terminal Allenes.

scientific article published on 19 January 2018

Chemo-, regio-, and enantioselective synthesis of allylic nitrones via rhodium-catalyzed addition of oximes to allenes

scientific article published on 13 June 2019

Combined transition-metal- and organocatalysis: an atom economic C3 homologation of alkenes to carbonyl and carboxylic compounds

scientific article published on 01 March 2010

Concise Total Synthesis of (-)-Vermiculine through a Rhodium-Catalyzed C2 -Symmetric Dimerization Strategy

scientific article published on 12 February 2019

Cooperative Effect of a Classical and a Weak Hydrogen Bond for the Metal-Induced Construction of a Self-Assembled β-Turn Mimic

scientific article published on 01 October 2009

Cuticular Hydrocarbon Pheromones for Social Behavior and Their Coding in the Ant Antenna

scientific article published on 12 August 2015

Desymmetrizing hydroformylation with the aid of a planar chiral catalyst-directing group

scientific article published on 01 August 2004

Development of an Axial Chirality Switch

article

Development of an improved rhodium catalyst for z-selective anti-markovnikov addition of carboxylic acids to terminal alkynes.

scientific article

Diastereoselective Hydroformylation of 2,5-Cyclohexadienyl-1-carbinols with Catalytic Amounts of a Reversibly Bound Directing Group

scientific article published on January 13, 2011

Diastereoselective hydroformylation of 2-substituted allylic o-DPPB-esters-on the origin of 1,2-asymmetric induction

scientific article published on 01 January 2003

Direct assignment of the relative configuration in 1,3,n-methyl-branched carbon chains by (1)H NMR spectroscopy

scientific article published on 01 May 2010

Direct transformation of terminal alkynes to branched allylic sulfones

scientific article published on 6 November 2014

Directed reactions of organocopper reagents

scientific article published on August 2008

Directed regio- and stereoselective hydroformylation of mono- and 1,3-disubstituted allylic alcohols: a catalytic approach to the anti-aldol-retron

scientific article published on 11 November 2003

Dithioacetals as an Entry to Titanium-Alkylidene Chemistry: A New and Efficient Carbonyl Olefination

scientific article published on 01 March 1998

Divergent Regioselectivity in the Synthesis of Trisubstituted Allylic Alcohols by Nickel‐ and Ruthenium‐Catalyzed Alkyne Hydrohydroxymethylation with Formaldehyde

scientific article published on 09 May 2011

Domino Hydroformylation-Wittig Reactions

scientific article published on 01 April 1999

Domino Hydroformylation/Knoevenagel/Hydrogenation Reactions This work was supported by the Fonds der Chemischen Industrie (Fellowship to S.K.Z.) and the Deutsche Forschungsgemeinschaft, as well as an Alfried Krupp Award for Young University Teachers

scientific article published in May 2001

Dual palladium- and proline-catalyzed allylic alkylation of enolizable ketones and aldehydes with allylic alcohols

scientific article published on 01 March 2009

Efficient Synthesis of New Fluorinated Building Blocks by means of Hydroformylation

scientific article published on 01 January 2014

Enantioselective Rhodium-Catalyzed Atom-Economical Macrolactonization

scientific article

Enantioselective Rhodium-Catalyzed Dimerization of ω-Allenyl Carboxylic Acids: Straightforward Synthesis of C2-Symmetric Macrodiolides.

scientific article published on 19 April 2018

Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids

scientific article published on December 28, 2011

Enantioselective and Regiodivergent Addition of Purines to Terminal Allenes: Synthesis of Abacavir.

scientific article published on 12 January 2017

Enantioselective formation of tertiary and quaternary allylic C-N bonds via allylation of tetrazoles

scientific article published on 01 July 2015

Enantioselective hydrogenation with self-assembling rhodium phosphane catalysts: influence of ligand structure and solvent

scientific article published on 01 January 2007

Enantioselective redox-neutral Rh-catalyzed coupling of terminal alkynes with carboxylic acids toward branched allylic esters

scientific article published on 23 February 2015

Enantioselective rhodium-catalyzed synthesis of branched allylic amines by intermolecular hydroamination of terminal allenes.

scientific article

Enantioselective synthesis of 2,6-dideoxy carbasugars based on a desymmetrizing hydroformylation-carbonyl ene cyclization process

scientific article

Enantioselective total synthesis and determination of absolute configuration of vittatalactone.

scientific article published in November 2009

Enantioselective total synthesis and determination of the absolute configuration of the 4,6,8,10,16,18-hexamethyldocosane from Antitrogus parvulus

scientific article published in August 2005

Enantioselective total synthesis of the unnatural and the natural stereoisomers of vittatalactone

scientific article published in July 2010

Formation of quaternary carbon centers by highly regioselective hydroformylation with catalytic amounts of a reversibly bound directing group

scientific article published on 04 July 2011

Functional characterization of three specific acyl-coenzyme A synthetases involved in anaerobic cholesterol degradation in Sterolibacterium denitrificans Chol1S.

scientific article published on 26 January 2018

Hexaphosphapentaprismane: a new gateway to organophosphorus cage compound chemistry

scientific article published on 01 June 2002

Hydroformylation of homoallylic azides: a rapid approach toward alkaloids

scientific article published on 01 January 2009

Hydrogen bonding as a construction element for bidentate donor ligands in homogeneous catalysis: regioselective hydroformylation of terminal alkenes

scientific article published in June 2003

Hydrogen-bond and solvent dynamics in transition metal complexes: a combined simulation and NMR-investigation

scientific article published on 29 November 2012

Inducing Axial Chirality in a Supramolecular Catalyst.

scientific article published on 6 March 2018

Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system

scientific article published on May 12, 2011

Ionic-liquid-modified CMK-3 as a support for the immobilization of molybdate ions (MoO42-): Heterogeneous nanocatalyst for selective oxidation of sulfides and benzylic alcohols

scientific article published on 07 January 2020

Iterative deoxypropionate synthesis based on a copper-mediated directed allylic substitution

scientific article published on 01 July 2004

Iterative deoxypropionate synthesis based on a copper-mediated directed allylic substitution: formal total synthesis of borrelidin (C3-C11 fragment)

scientific article published on 01 August 2006

Iterative synthesis of (oligo)deoxypropionates via zinc-catalyzed enantiospecific sp3-sp3 cross-coupling

scientific article published on 01 October 2009

Ligand self-assembling through complementary hydrogen-bonding in the coordination sphere of a transition metal center: the 6-diphenylphosphanylpyridin-2(1H)-one system.

scientific article

Ligand-Mediated Regioselective Rhodium-Catalyzed Benzotriazole-Allene Coupling: Mechanistic Exploration and Quantum Chemical Analysis

scientific article published on 04 February 2020

Mechanistic insight into the ruthenium-catalysed anti-Markovnikov hydration of alkynes using a self-assembled complex: a crucial role for ligand-assisted proton shuttle processes

scientific article published on 15 May 2014

Mechanistic insights into a supramolecular self-assembling catalyst system: evidence for hydrogen bonding during rhodium-catalyzed hydroformylation

scientific article published on 28 September 2012

Mechanistic investigations of the rhodium catalyzed propargylic CH activation

scientific article published on 08 January 2014

Needle ball-like nanostructured mixed Cu-Ni-Co oxides: Synthesis, characterization and application to the selective oxidation of sulfides to sulfoxides

scientific article published on 30 May 2019

One-pot desymmetrizing hydroformylation/carbonyl ene cyclization process: straightforward access to highly functionalized cyclohexanols

scientific article published on 01 December 2008

Palladium- and Rhodium-Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes Towards Chiral Pyrazoles

scientific article published on 29 January 2019

Palladium-Catalyzed Direct C-H Allylation of Electron-Deficient Polyfluoroarenes with Alkynes

scientific article published on 14 March 2018

Palladium-Catalyzed Stereoselective Cyclization of in Situ Formed Allenyl Hemiacetals: Synthesis of Rosuvastatin and Pitavastatin

scientific article published on 17 May 2018

Palladium-catalyzed trisallylation of benzoxazoles and 2-aryl-1,3,4-oxadiazoles with alkyne

scientific article published on 01 January 2019

Paraformaldehyde and methanol as C1  feedstocks in metal-catalyzed C-C couplings of π-unsaturated reactants: beyond hydroformylation

scientific article published on 27 November 2014

Phosphabarrelene-rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes

scientific article published on 13 February 2004

Phosphabarrelenes as ligands in rhodium-catalyzed hydroformylation of internal alkenes essentially free of alkene isomerization

scientific article published on 01 September 2006

Phosphorylation of Tip60 by GSK-3 determines the induction of PUMA and apoptosis by p53

scientific article

Potent inhibitors of malarial aspartic proteases, the plasmepsins, by hydroformylation of substituted 7-azanorbornenes

scientific article published on 19 November 2012

Preparation data of the bromodomains BRD3(1), BRD3(2), BRD4(1), and BRPF1B and crystallization of BRD4(1)-inhibitor complexes.

scientific article

Preparation of Alkylmagnesium Reagents from Alkenes through Hydroboration and Boron–Magnesium Exchange

scientific article published on April 23, 2012

Probing o-diphenylphosphanyl benzoate (o-DPPB)-directed C-C bond formation: total synthesis of dictyostatin

scientific article published on 18 December 2014

Reagent directing group controlled organic synthesis: total synthesis of (R,R,R)-alpha-tocopherol

scientific article published in January 2007

Realistic energy surfaces for real-world systems: an IMOMO CCSD(T):DFT scheme for rhodium-catalyzed hydroformylation with the 6-DPPon ligand

scientific article published on 14 October 2013

Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

scientific article published on 03 February 2011

Regio- and Enantioselective Rhodium-Catalyzed Addition of 1,3-Diketones to Allenes: Construction of Asymmetric Tertiary and Quaternary All Carbon Centers

scientific article published on 11 January 2017

Regio- and enantioselective synthesis of N-substituted pyrazoles by rhodium-catalyzed asymmetric addition to allenes

scientific article published on 29 April 2015

Regioconvergent and Enantioselective Rhodium-Catalyzed Hydroamination of Internal and Terminal Alkynes: A Highly Flexible Access to Chiral Pyrazoles

scientific article published on 01 April 2016

Regiodivergent Hydroaminoalkylation of Alkynes and Allenes by a Combined Rhodium and Photoredox Catalytic System

scientific article published on 29 January 2019

Regioselective Rhodium-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Terminal Alkynes

scientific article published on 18 December 2015

Remote control of regio- and diastereoselectivity in the hydroformylation of bishomoallylic alcohols with catalytic amounts of a reversibly bound directing group

scientific article published on 01 January 2010

Removable Directing Groups in Organic Synthesis and Catalysis

scientific article published on March 7, 2011

Rhodium-Catalyzed Asymmetric Allylation of Malononitriles as Masked Acyl Cyanide with Allenes: Efficient Access to β,γ-Unsaturated Carbonyls

scientific article published on 13 September 2018

Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Allenes

scientific article published on 21 June 2019

Rhodium-Catalyzed Asymmetric N-H Functionalization of Quinazolinones with Allenes and Allylic Carbonates: The First Enantioselective Formal Total Synthesis of (-)-Chaetominine.

scientific article published on 4 November 2017

Rhodium-Catalyzed Cyclisation of Terminal and Internal Allenols: An Atom Economic and Highly Stereoselective Access Towards Tetrahydropyrans Johannes P. Schmidt, Bernhard Breit

scientific article published on 17 September 2020

Rhodium-Catalyzed Diastereo- and Enantioselective Tandem Spirocyclization/Reduction of 3-Allenylindoles: Access to Functionalized Vinylic Spiroindolines

scientific article published on 26 November 2019

Rhodium-Catalyzed Diastereoselective Cyclization of Allenyl-Sulfonylcarbamates: A Stereodivergent Approach to 1,3-Aminoalcohol Derivatives.

scientific article

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Allylation of Phenols and 2-Hydroxypyridines.

scientific article published on 13 September 2016

Rhodium-Catalyzed Enantioselective Cyclization of 3-Allenyl-indoles: Access to Functionalized Tetrahydrocarbazoles

scientific article published on 28 May 2019

Rhodium-Catalyzed Enantioselective Decarboxylative Alkynylation of Allenes with Arylpropiolic Acids

scientific article published on 05 February 2018

Rhodium-Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Alkynes with Alcohols: Synthesis of Branched Allylic Ethers.

scientific article published on 31 May 2016

Rhodium-Catalyzed Hydroformylation of 1,1-Disubstituted Allenes Employing the Self-Assembling 6-DPPon System

scientific article published on 27 April 2015

Rhodium-Catalyzed Parallel Kinetic Resolution of Racemic Internal Allenes Towards Enantiopure Allylic 1,3-Diketones

scientific article published on 06 June 2019

Rhodium-Catalyzed Regio- and Enantioselective Addition of N-Hydroxyphthalimide to Allenes: A Strategy To Synthesize Chiral Allylic Alcohols.

scientific article published on 27 December 2017

Rhodium-Catalyzed Regioselective Domino Azlactone-Alkyne Coupling/Aza-Cope Rearrangement: Facile Access to 2-Allyl-3-oxazolin-5-ones and Trisubstituted Pyridines

scientific article published on 17 May 2017

Rhodium-Catalyzed Selective anti-Markovnikov Addition of Carboxylic Acids to Alkynes

scientific article published on 04 November 2010

Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones

scientific article published on 01 May 2017

Rhodium-catalyzed asymmetric intramolecular hydroarylation of allenes: access to functionalized benzocycles

scientific article published on 10 September 2019

Rhodium-catalyzed chemo- and regioselective decarboxylative addition of β-ketoacids to alkynes.

scientific article

Rhodium-catalyzed chemo- and regioselective decarboxylative addition of β-ketoacids to allenes: efficient construction of tertiary and quaternary carbon centers

scientific article published on 09 January 2014

Rhodium-catalyzed chemo-, regio-, and enantioselective addition of 2-pyridones to terminal allenes

scientific article published on 08 October 2014

Self-assembled bidentate ligands for Ru-catalyzed anti-Markovnikov hydration of terminal alkynes

scientific article published on 01 February 2006

Self-assembled bidentate ligands for the nickel-catalyzed hydrocyanation of alkenes

scientific article published on 01 January 2009

Self-assembly of bidentate ligands for combinatorial homogeneous catalysis based on an A-T base-pair model

scientific article published in March 2005

Self-assembly of bidentate ligands for combinatorial homogeneous catalysis: asymmetric rhodium-catalyzed hydrogenation

scientific article

Self-assembly of bidentate ligands for combinatorial homogeneous catalysis: methanol-stable platforms analogous to the adenine-thymine base pair

scientific article published on 01 January 2007

Short access to (+)-lupinine and (+)-epiquinamide via double hydroformylation

scientific article published in February 2010

Stereodivergent and Protecting-Group-Free Synthesis of the Helicascolide Family: A Rhodium-Catalyzed Atom-Economical Lactonization Strategy.

scientific article published on 4 April 2016

Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines

scientific article published on 06 September 2011

Stereoselective synthesis of trisubstituted olefins by a directed allylic substitution strategy

scientific article published on 02 September 2011

Stereospecific and stereodivergent construction of quaternary carbon centers through switchable directed/nondirected allylic substitution

scientific article published on 01 July 2004

Stereospecific and stereodivergent construction of tertiary and quaternary carbon centers through switchable directed/nondirected allylic substitution

scientific article published on 01 October 2006

Structural characterization of O- and C-glycosylating variants of the landomycin glycosyltransferase LanGT2

scientific article published on 7 January 2015

Supramolecular PhanePhos-analogous ligands through hydrogen-bonding for asymmetric hydrogenation

scientific article published on 18 December 2007

Supramolecular approaches to generate libraries of chelating bidentate ligands for homogeneous catalysis

scientific article published in October 2005

Supramolecular bidentate ligands by metal-directed in situ formation of antiparallel beta-sheet structures and application in asymmetric catalysis.

scientific article

Supramolecular catalyst for aldehyde hydrogenation and tandem hydroformylation-hydrogenation.

scientific article

Syntheses of Thailandepsin B Pseudo-Natural Products: Access to new highly potent HDAC Inhibitors via Late Stage Modification

scientific article published on 29 July 2020

Synthesis of 2-(Isoquinolin-1-yl)prop-2-en-1-ones via Silver(I)-Catalyzed One-Pot Tandem Reaction of ortho-Alkynylbenzaldoximes with Propargylic Alcohols

scientific article published on 09 September 2019

Synthetic Aspects of Stereoselective Hydroformylation

scientific article published on April 1, 2003

Tandem Regioselective Hydroformylation-Hydrogenation of Internal Alkynes Using a Supramolecular Catalyst

scientific article published on 12 October 2018

Tandem decarboxylative hydroformylation-hydrogenation reaction of α,β-unsaturated carboxylic acids toward aliphatic alcohols under mild conditions employing a supramolecular catalyst system

scientific article published on 01 October 2013

Tandem rhodium-catalyzed hydroformylation-hydrogenation of alkenes by employing a cooperative ligand system

scientific article published on 30 January 2012

The Total Synthesis of Epothilone D as a Yardstick for Probing New Methodologies.

scientific article published on 28 October 2016

Tofacitinib and analogs as inhibitors of the histone kinase PRK1 (PKN1).

scientific article

Total Synthesis of (-)-Cylindrocyclophane F: A Yardstick for Probing New Catalytic C-C Bond-Forming Methodologies

scientific article published on 22 October 2018

Total synthesis of (+)-bourgeanic acid utilizing o-DPPB-directed allylic substitution

scientific article published on 01 August 2009

Total synthesis of (+)-clavolonine, (-)-deacetylfawcettiine, and (+)-acetylfawcettiine

scientific article published in March 2010

Total synthesis of (18S)- and (18R)-homolargazole by rhodium-catalyzed hydrocarboxylation

scientific article published on 29 January 2014

Transition metal catalyzed stereodivergent synthesis of - and -δ-vinyl-lactams: formal total synthesis of (-)-cermizine C and (-)-senepodine G

scientific article published on 24 January 2019

Transition-Metal-Catalyzed Regiodivergent and Stereoselective Access to Branched and Linear Allylated 4-Pyridones.

scientific article published on 28 March 2017

Transition-state stabilization by a secondary substrate-ligand interaction: a new design principle for highly efficient transition-metal catalysis

scientific article

Unlocking the N(2)  selectivity of benzotriazoles: regiodivergent and highly selective coupling of benzotriazoles with allenes

scientific article published on 23 May 2014

Urea-substituted Tetramethylcyclopentadienyl Ligands for Supramolecularly Accelerated Rh(III)-catalyzed ortho-C-H Olefination of Benzoic Acid Derivatives

scientific article published on 09 December 2020

Visible-Light-Driven Intermolecular Reductive Ene-Yne Coupling by Iridium/Cobalt Dual Catalysis for C(sp3 )-C(sp2 ) Bond Formation

scientific article published on 08 November 2019

Z-Selective Hydrothiolation of Racemic 1,3-Disubstituted Allenes: An Atom-Economic Rhodium-Catalyzed Dynamic Kinetic Resolution

scientific article published on 29 September 2015

Zinc-catalyzed enantiospecific sp3-sp3 cross-coupling of alpha-hydroxy ester triflates with Grignard reagents

scientific article published on 01 January 2008

o-DPPB-directed copper-mediated and -catalyzed allylic substitution with Grignard reagents

scientific article published on 01 August 2006

ortho-Diphenylphosphanylbenzoyl-Directed Cuprate Addition to Acyclic Enoates

scientific article published on 01 March 1998

μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)

scientific article published on December 6, 2007