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List of works by Holger Braunschweig

1,2,3-Diazaborinine: A BN Analog of Pyridine by Ring Expansion of a Borole with an Organic Azide

scientific article published on 30 November 2018

1,2-Bis(dimethyl-amino)-1,2-bis-(2,4,6-triisopropyl-phen-yl)diborane(4).

scientific article published on 30 November 2010

1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group.

scientific article

1-Heteroaromatic-substituted tetraphenylboroles: π-π interactions between aromatic and antiaromatic rings through a B-C bond

scientific article published on 04 December 2012

2,2'-Bipyridyl as a Redox-Active Borylene Abstraction Agent

scientific article published on 16 July 2020

2- and 2,7-Substituted para-N-Methylpyridinium Pyrenes

scientific article published on 24 November 2020

6H,13H-Pyrazino[1,2-a;4,5-a']diindole analogs: probing the pharmacophore for allosteric ligands of muscarinic M2 receptors

scientific article published on 4 January 2006

A B-C double bond unit coordinated to platinum: an alkylideneboryl ligand that is isoelectronic to neutral aminoborylene Ligands

scientific article published on 22 January 2014

A Binuclear 1,1'-Bis(boratabenzene) Complex: Unprecedented Intramolecular Metal-Metal Communication through a B-B Bond

scientific article published on 30 May 2016

A Boradiselenirane and a Boraditellurirane: Isolable Heavy Analogs of Dioxiranes and Dithiiranes

scientific article published on 27 August 2018

A Combined Experimental and Theoretical Study on the Isomers of 2,3,4,5-Tetracarba-nido-Hexaborane(6) Derivatives and Their Photophysical Properties

scientific article published on 28 October 2014

A New Class of Neutral Boron-Based Diradicals Spanned by a Two-Carbon-Atom Bridge

scientific article published on 11 January 2019

A New Perspective on Borane Chemistry: the Nucleophilicity of the B-H Bonding Pair Electrons

article

A T-shaped platinum(II) boryl complex as the precursor to a platinum compound with a base-stabilized borylene ligand

scientific article published on 01 September 2005

A boryl bridged complex: an unusual coordination mode of the BR2 ligand

scientific article published on 01 February 2005

A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode

scientific article published on 01 March 2013

A facile and selective route to remarkably inert monocyclic NHC-stabilized boriranes

scientific article published on 01 January 2015

A linear, anionic dimetalloborylene complex

scientific article published on 01 January 2008

A metal-mediated boron-centred isomerisation reaction via C-H activation.

scientific article published in November 2015

A paramagnetic heterobimetallic polymer: synthesis, reactivity, and ring-opening polymerization of tin-bridged homo- and heteroleptic vanadoarenophanes

scientific article published on 21 January 2015

A selective route to aryl-triphosphiranes and their titanocene-induced fragmentation

scientific article published on 30 July 2019

A theoretical study of the aromaticity in neutral and anionic borole compounds

scientific article published on 01 April 2015

A trimetallic gold boride complex with a fluxional gold-boron bond

scientific article published on 01 January 2009

Abnormal Tin-Boron Exchange in the Attempted Synthesis of a Borylated Borole.

scientific article published on 28 September 2017

Activation of boryl-, borylene and metalloborylene complexes by isonitriles

scientific article

Alkylideneborate zwitterions and C-C coupling by atypical diboration of electron-rich alkynes.

scientific article published on 27 October 2017

Aluminum(I)/Boron(III) Redox Reactions

scientific article published on 11 February 2019

Ambient-temperature isolation of a compound with a boron-boron triple bond

scientific article

Aminoborylene complexes of group 6 elements and iron: a synthetic, structural, and quantum chemical study

scientific article published on 01 January 2007

An Isolable Radical Anion Based on the Borole Framework

scientific article published on 14 February 2012

An early-late heterobimetallic complex with an unsupported dative bond: synthesis and structure of [(Cy(3)P)(2)Pt-ZrCl(4)]

scientific article published on 07 December 2009

An electron-precise, tetrahedral μ3 boride complex

scientific article published on 3 June 2013

An iterative divergent approach to conjugated starburst borane dendrimers

scientific article published on 19 May 2020

Ansa [1]trochrocenophanes and their related unstrained 1,1'-disubstituted counterparts: synthesis and electronic structure

scientific article published on 26 June 2007

Ansa-Complexes of [Mn(η(5) -C5 H5 )(η(6) -C6 H6 )]: Preparation, Characterization, and Reactivity of [n]Manganoarenophanes (n=1, 2, 3).

scientific article published on 31 August 2015

Ansa-bridged bis(benzene) titanium complexes

scientific article

Antiaromaticity to aromaticity: from boroles to 1,2-azaborinines by ring expansion with azides

scientific article published on 25 June 2014

Axially chiral beta,beta'-bisporphyrins: synthesis and configurational stability tuned by the central metals

scientific article published on 01 December 2008

B+ in the coordination sphere of two transition metals

scientific article published on 01 January 2008

B-B Cleavage and Ring-Expansion of a 1,4,2,3-Diazadiborinine with N-Heterocyclic Carbenes

scientific article published on 19 September 2019

Base-stabilized boryl and cationic haloborylene complexes of iron

scientific article published on 19 August 2013

Base-stabilized diborenes: selective generation and η2 side-on coordination to silver(I).

scientific article published on 3 September 2012

Beryllium bis(diazaborolyl): old neighbors finally shake hands

scientific article published on 01 January 2015

Bis(μ-diisopropyl-phosphanido-κ(2)P:P)bis-[hydrido(triisopropyl-phosphane-κP)platinum(II)]

scientific article published on 26 May 2012

Bond-Strengthening Backdonation in Aminoborylene-Stabilized Aminoborylenes: At the Intersection of Borylenes and Diborenes

scientific article published on 07 August 2019

Bond-strengthening π backdonation in a transition-metal π-diborene complex

scientific article published on 09 December 2012

Bonding in a borylene complex investigated by photoionization and dissociative photoionization.

scientific article published on 15 March 2012

Borabicyclo[3.2.0]heptadiene: A Fused Bicyclic Isomer of Borepin

scientific article published on 13 September 2018

Boranediyl- and Diborane(4)-1,2-diyl-bridged Platinum A-Frame Complexes

scientific article published on 20 March 2020

Borido complexes via intermetallic metalloborylene transfer

scientific article published on 01 August 2011

Boron as a bridging ligand

scientific article published in October 2005

Boron as a bridging ligand

scientific article published on 01 March 2005

Boron as a powerful reductant: synthesis of a stable boron-centered radical-anion radical-cation pair.

scientific article

Boron in the coordination spheres of three transition-metal atoms: syntheses and structures of metalloborylenes stabilized by a transition-metal base

scientific article published on 01 February 2006

Boron radical cations from the facile oxidation of electron-rich diborenes.

scientific article published on 7 April 2014

Boron-Metallated Borirenes and Bis(Borirenes).

scientific article

Boron: Its Role in Energy-Related Processes and Applications

scientific article published on 18 October 2019

Boryl- and Silyl-Substituted Mixed Sandwich Compounds of Scandium

scientific article

Boryl-functionalized σ-alkynyl and vinylidene rhodium complexes: synthesis and electronic properties.

scientific article published on 20 December 2013

Borylene metathesis through [2+2] cycloaddition

scientific article published on 01 January 2007

Borylene transfer from an iron bis(borylene) complex: synthesis of 1,4-diboracyclohexadiene and 1,4-dibora-1,3-butadiene complexes

scientific article published on 22 June 2012

Borylene transfer under thermal conditions for the synthesis of rhodium and iridium borylene complexes

scientific article published on 01 January 2008

Borylene transfer under thermal conditions: synthesis and structure of a tetrarhodium bisborylene complex

scientific article published on 01 March 2006

Borylene-based direct functionalization of organic substrates: synthesis, characterization, and photophysical properties of novel pi-conjugated borirenes.

scientific article published in July 2009

Borylene-based functionalization of Pt–alkynyl complexes by photochemical borylene transfer from [(OC)5CrBN(SiMe3)2]

scientific article published on 15 October 2009

Borylene-based functionalization of iron-alkynyl-σ-complexes and stepwise reversible metal-boryl-to-borirene transformation: synthesis, characterization, and density functional theory studies

scientific article published on 16 August 2010

Bottleable Neutral Analogues of [B2 H5 ]- as Versatile and Strongly Binding η2 Donor Ligands

scientific article published on 14 March 2018

Bromination Improves the Electron Mobility of Tetraazapentacene

scientific article published on 29 June 2018

B═B and B≡E (E = N and o) multiple bonds in the coordination sphere of late transition metals

scientific article published on 16 August 2013

CO2 Binding and Splitting by Boron-Boron Multiple Bonds

scientific article published on 14 April 2018

Carbene-induced synthesis of the first borironium cations using the [(η(5)-C5Me5)Fe(CO)2](-) anion as an unlikely leaving group

scientific article published on 29 October 2015

Carbonyl complexes of platinum(0): synthesis and structure of [(Cy3P)2Pt(CO)] and [(Cy3P)2Pt(CO)2]

scientific article published on 25 January 2011

Chelated Diborenes and Their Inverse-Electron-Demand Diels-Alder Reactions with Dienes

scientific article published on 22 October 2018

Chemical reduction and dimerization of 1-chloro-2,3,4,5-tetraphenylborole

scientific article published on October 2010

Chemoselective boron-carbon bond cleavage by hydroboration of borirenes

scientific article published in November 2009

Cleavage of BN triple bonds by main group reagents

scientific article published on 01 July 2018

Closely related yet different: a borylene and its dimer are non-interconvertible but connected through reactivity.

scientific article published on 4 January 2018

Comparative analysis of electron-density and electron-localization function for dinuclear manganese complexes with bridging boron- and carbon-centered ligands

scientific article published in January 2009

Complete and partial 1,2-additions across transition metal-boron double bonds

scientific article published on 30 June 2014

Complexation and Release of N-Heterocyclic Carbene-Aminoborylene Ligands from Group VI and VIII Metals

scientific article published on 10 August 2018

Complexes with dative bonds between d- and s-block metals: synthesis and structure of [(Cy3P)2Pt-Be(Cl)X] (X = Cl, Me)

scientific article published on 01 January 2009

Computationally Guided Molecular Design to Minimize the LE/CT Gap in D-π-A Fluorinated Triarylboranes for Efficient TADF via D and π-Bridge Tuning

scientific article published on 02 June 2020

Constrained geometry complexes—Synthesis and applications

scientific article (publication date: November 2006)

Construction of Linear and Branched Tetraboranes via 1,1- and 1,2-Diboration of Diborenes

scientific article published on 05 November 2018

Controlled homocatenation of boron on a transition metal

scientific article published on 17 June 2012

Controlling Regiochemistry in the Syntheses of Boraindanes from Diborane(4) Starting Materials

scientific article published on 07 July 2016

Conversion of trans-diboran(4)yl platinum complexes into their cis-bisboryl analogues

scientific article

Correction to 2,2'-Bipyridyl as a Redox-Active Borylene Abstraction Agent

scientific article published on 25 August 2020

Correlations and Contrasts in Homo- and Heteroleptic Cyclic (Alkyl)(amino)carbene-Containing Pt(0) Complexes.

scientific article published on 4 August 2015

Crystal structure of (3S*,4R*)-4-fluoro-3-(4-meth-oxy-phen-yl)-1-oxo-2-phenyl-1,2,3,4-tetra-hydro-iso-quinoline-4-carb-oxy-lic acid

scientific article published on 23 May 2017

Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido-borylene-1:2κ(2) B:B-[1(η(5))-penta-methyl-cyclo-penta-dien-yl](tri-cyclo-hexyl-phosphane-2κP)iron(II)platinum(II) benzene monosolvate

scientific article published on 29 October 2014

CuOTf-mediated intramolecular diborene hydroarylation

scientific article published on 20 October 2017

Cyclic (amino)(imino)carbene complexes by borylene transfer to isocyanides

scientific article published in February 2013

Cyclisation of biscarbenoids - a novel mode of cyclobutadiene stabilisation

scientific article published on 01 November 2016

Cyclization of a 1,4-diborabutadiene ligand with both atoms of CO

scientific article published on 27 February 2015

Cyclodimerization of an oxoboryl complex induced by trans ligand abstraction

scientific article published on 01 August 2010

DFT Studies of Dimerization Reactions of Boroles

scientific article

DFT Studies on the reactions of boroles with alkynes.

scientific article published on 23 April 2018

Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base

scientific article published on 24 November 2015

Desymmetrizing Electron-Deficient Diboranes(4): Diverse Products and Their Reactivity

scientific article published on 12 August 2016

Dialumination of unsaturated species with a reactive bis(cyclopentadienyl) dialane

scientific article

Dibora[2]ferrocenophan: ein carbenstabilisiertes Diboren in einer gespanntencis-Konfiguration

article

Dibora[2]ferrocenophane: A Carbene-Stabilized Diborene in a Strained cis-Configuration.

scientific article published on 20 December 2016

Diborabutatriene: an electron-deficient cumulene.

scientific article published on 23 May 2014

Diboran(4)yl platinum(II) complexes

scientific article published on 27 June 2013

Diborane(4) Azides: High-Energy Molecules as Surprisingly Stable Sources of Transient Iminoboranes

scientific article published on 08 April 2020

Diborane(4)yl Complexes of Molybdenum and Ruthenium

Diboryldiborenes: π-Conjugated B4 Chains Isoelectronic to the Butadiene Dication

scientific article published on 15 July 2018

Dicyclohexyl(2',4',6'-triisopropylbiphenyl-2-yl)phosphine-dichlorophenylborane

scientific article published on 17 October 2009

Dilithiation of Bis(benzene)molybdenum and Subsequent Isolation of a Molybdenum-Containing Paracyclophane

scientific article published on 22 March 2007

Direct Conversion from Terminal Borylene into Terminal Phosphinidene

scientific article published on 13 September 2016

Direct access to a cAAC-supported dihydrodiborene and its dianion

scientific article published on 23 April 2018

Direct functionalization at the boron center of antiaromatic chloroborole

scientific article published on 30 July 2008

Direct hydroboration of B=B bonds: a mild strategy for the proliferation of B-B bonds

scientific article published on 19 February 2014

Direct synthetic route to functionalized 1,2-azaborinines.

scientific article published on 26 February 2014

Ditopic ambiphilicity of an anionic dimetalloborylene complex

scientific article published on 31 January 2013

Diverse reactions of N-heterocyclic carbenes with an alkynylborane and isolation of a reactive zwitterionic borataallene

scientific article published on 04 November 2013

Dynamic, Reversible Oxidative Addition of Highly Polar Bonds to a Transition Metal

scientific article published on 29 November 2016

Electron Delocalization in Reduced Forms of 2-(BMes2)pyrene and 2,7-Bis(BMes2)pyrene

scientific article published on 22 May 2015

Electron-Density Investigation of Metal–Metal Bonding in the Dinuclear “Borylene” Complex [{Cp(CO)2Mn}2(μ-BtBu)]

scholarly article by Ulrike Flierler et al published 26 May 2008 in Angewandte Chemie International Edition

Electron-Precise Coordination Modes of Boron-Centered Ligands

scientific article published on 01 July 2010

Electronic and structural effects of stepwise borylation and quaternization on borirene aromaticity

scientific article published on 24 January 2013

Electronic structure and reactivity of a [1],[1]disilamolybdenocenophane

scientific article published in March 2010

Electronically-driven regioselective iridium-catalyzed C-H borylation of donor-π-acceptor chromophores containing triarylboron acceptors

scientific article published on 08 June 2020

Elektronendichteuntersuchung der Metall-Metall-Bindung im zweikernigen “Borylen”-Komplex [{Cp(CO)2Mn}2(μ-BtBu)]

Elucidating the Reactivity of Vicinal Dicarbenoids: From Lewis Adduct Formation to B-C Bond Activation

scientific article published on 09 August 2016

Enantioselective synthesis of tricyclic amino acid derivatives based on a rigid 4-azatricyclo[5.2.1.0]decane skeleton

scientific article published on 21 December 2009

Engineering a Small HOMO-LUMO Gap and Intramolecular C-H Borylation by Diborene/Anthracene Orbital Intercalation

scientific article

Evidence for a strong trans influence of the diboran(4)yl ligand

scientific article published on 08 November 2012

Evidence for extensive single-electron-transfer chemistry in boryl anions: isolation and reactivity of a neutral borole radical

scientific article published on 09 April 2014

Exclusive π Encapsulation of Light Alkali Metal Cations by a Neutral Molecule

scientific article published on 11 September 2015

Experimental assessment of the strengths of B-B triple bonds

article

Experimental studies on the trans-influence of boryl ligands in square-planar platinum(II) complexes

scientific article published on 01 January 2007

Extending unsupported metal-only Lewis pairs to palladium

scientific article published on 03 November 2011

Facile Access to Substituted 1,4-Diaza-2,3-Diborinines

scientific article published on 21 February 2020

Facile Access to Unprecedented Electron-Precise Monohydrodiboranes(4), cis-1,2-Dihydrodiboranes(4), and a 1,1-Dihydrodiborane(5).

scientific article

Facile Synthesis of a Stable Dihydroboryl {BH2 }- Anion

scientific article published on 18 October 2018

Fashionably late: synthesis and characterization of transition-metal-fluoroborylene complexes

scientific article published on 01 May 2010

Ferrocenylalanes: solid-state and solution structures of some new aluminum-bridged ansa-ferrocenes

scientific article published on 01 July 2005

First Bis(σ)-borane Complexes of Group 6 Transition Metals: Experimental and Theoretical Studies

scientific article published on 30 May 2019

Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds

scientific article published on 10 November 2016

Formation of BN Isosteres of Azo Dyes by Ring Expansion of Boroles with Azides

scientific article published on 25 March 2015

Formation of a Trifluorophosphane Platinum(II) Complex by P-F Bond Activation of Phosphorus Pentafluoride with a Pt0 Complex

scientific article published on 4 November 2016

Formation of a stable radical by oxidation of a tetraorganoborate

scientific article

Formation, structure and reactivity of boryloxycarbyne complexes of group 6 metals

scientific article published on 01 March 2003

From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species.

scientific article published on 22 June 2017

From an electron-rich bis(boraketenimine) to an electron-poor diborene

scientific article published on 17 February 2015

From classical to nonclassical metal-boron bonds: synthesis of a novel metallaborane

scientific article published on 01 April 2002

Functionalization of N2 via Formal 1,3-Haloboration of a Tungsten(0) σ-Dinitrogen Complex

scientific article published on 06 July 2020

Fundamental Differences between Group 8 Metals: Unexpected Oxidation State Preferences and Mechanisms in Ruthenium Borylene Complex Formation.

scientific article

Generation of 1,2-azaboretidines via reduction of ADC borane adducts.

scientific article published on 16 April 2015

Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.

scientific article published on 12 October 2016

Generation of a carbene-stabilized bora-borylene and its insertion into a C-H bond

scientific article published on 04 November 2011

Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials

scientific article published on 15 November 2007

Half-Sandwich Complexes of an Extremely Electron-Donating, Redox-Active η6-Diborabenzene Ligand.

scientific article

Heterodiatomic Multiple Bonding in Group 13: A Complex with a Boron-Aluminum π Bond Reduces CO2

scientific article published on 07 June 2019

Heterodinuclear bridged borylene complexes

scientific article published on 01 February 2005

Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers

scientific article published on 18 February 2011

Heteroleptic [n]chromoarenophanes: ansa complexes derived from [Cr(η(5)-C5H5)(η(6)-C6H6)].

scientific article published on 23 November 2012

Hexahalodiborate Dianions: A New Family of Binary Boron Halides

scientific article published on 23 August 2019

High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex

scientific article published on 03 February 2012

High-Yield Synthesis of a Hybrid 2,3,4,5-Tetracarba-1,6-nido-hexaborane(6) Cluster with an exo-Polyhedral Boracycle

High-performance air-stable n-channel organic thin film transistors based on halogenated perylene bisimide semiconductors

scientific article

Highly Strained Heterocycles Constructed from Boron-Boron Multiple Bonds and Heavy Chalcogens

scientific article published on 30 March 2016

Highly stable, readily reducible, fluorescent, trifluoromethylated 9-borafluorenes

scientific article published on 30 January 2020

Hole Transfer Processes in meta- and para-Conjugated Mixed Valence Compounds: Unforeseen Effects of Bridge Substituents and Solvent Dynamics.

scientific article published on 12 April 2017

Hydridoborylene complexes and di-, tri-, and tetranuclear borido complexes with hydride ligands

scientific article published on 11 November 2013

Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties

scientific article published on 25 November 2019

Impact of Molecular Flexibility on Binding Strength and Self-Sorting of Chiral π-Surfaces

scientific article published on 26 May 2011

Increasing the Reactivity of Diborenes: Derivatization of NHC-Supported Dithienyldiborenes with Electron-Donor Groups.

scientific article published on 25 October 2017

Interaction between d- and p-block metals: synthesis and structure of platinum-alane adducts

scientific article published on 01 January 2007

Interaction of (benzylidene-hydrazono)-1,4-dihydropyridines with beta-amyloid, acetylcholine, and butyrylcholine esterases

scientific article published on 15 January 2010

Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron.

scientific article published on 8 July 2016

Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species

scientific article published on 25 November 2020

Intramolecular activation of a disila[2]molybdenocenophanedihydride: synthesis and structure of a [1],[1]metalloarenophane

scientific article published on 01 January 2008

Intriguing migrations in transient iminoborane adducts: two new pathways to aminoboranes

scientific article published on 01 August 2018

Introducing [Mn(CO)3(tpa-κ(3)N)](+) as a novel photoactivatable CO-releasing molecule with well-defined iCORM intermediates - synthesis, spectroscopy, and antibacterial activity

scientific article published on 01 July 2014

Iridium-catalysed dehydrocoupling of aryl phosphine-borane adducts: synthesis and characterisation of high molecular weight poly(phosphinoboranes).

scientific article

Isolation and Characterization of Crystalline, Neutral Diborane(4) Radicals

scientific article published on 21 June 2018

Isolation and Reactivity of an s-Block Metal Antiaromatic

scientific article published on 19 November 2020

Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst-Free Spontaneous Cyclopropanation Step at 0 °C.

scientific article

Isolation of a neutral boron-containing radical stabilized by a cyclic (alkyl)(amino)carbene.

scientific article published on 10 June 2014

Isolation of diborenes and their 90°-twisted diradical congeners.

scientific article

Jozimine A2: the first dimeric Dioncophyllaceae-type naphthylisoquinoline alkaloid, with three chiral axes and high antiplasmodial activity

scientific article published on 5 December 2012

Late-transition-metal complexes as tunable Lewis bases

scientific article published on 01 October 2010

Lewis Acid Binding and Transfer as a Versatile Experimental Gauge of the Lewis Basicity of Fe(0) , Ru(0) , and Pt(0) Complexes

scientific article published on 11 November 2015

Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions

scientific article published on 11 October 2019

Lewis-Base-Induced Disproportionation of a Dialane

scientific article published on 18 July 2018

Lithiumboryl--a synthon for a nucleophilic boryl anion

scientific article published on 01 January 2007

Low-coordinate boride ligands: a true trimetalloborane

scientific article published on 01 January 2009

Luminescent Mono-, Di-, and Triradicals: Bridging Polychlorinated Triarylmethyl Radicals by Triarylamines and Triarylboranes

scientific article published on 19 November 2019

Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron.

scientific article published on 19 January 2017

Maximizing coordinative and electronic unsaturation: three-coordinate dicationic platinum complexes.

scientific article published on 31 January 2013

Me CAAC=N- : A Cyclic (Alkyl)(Amino)Carbene Imino Ligand

scientific article published on 09 January 2020

Metal-free binding and coupling of carbon monoxide at a boron-boron triple bond.

scientific article

Metal-mediated diboration of alkynes with [2]borametalloarenophanes under stoichiometric, homogeneous, and heterogeneous conditions

scientific article published on 01 December 2006

Metal-mediated synthesis of 1,4-di-tert-butyl-1,4-azaborine

Metal-only Lewis pairs by reversible insertion of ruthenium and osmium fragments into metal-boron double bonds

scientific article published on 12 March 2014

Metal-only Lewis pairs with transition metal lewis bases

scientific article published on 22 May 2012

Metallomimetic Chemistry of Boron

scientific article published on 14 January 2019

Metathesis reactions of a manganese borylene complex with polar heteroatom-carbon double bonds: a pathway to previously inaccessible carbene complexes.

scientific article published on 31 May 2013

Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex

scientific article published on 15 March 2016

Mild synthesis of diboryldiborenes by diboration of B-B triple bonds

scientific article published on 11 June 2019

Molecular Structure of [CpFe(CO)2]2AlAr (Ar = 2-[(Dimethylamino)methyl]phenyl): An Alanediyl Complex with Two Fe−Al Bonds

scientific article published on 01 December 1996

Molecular structure and cluster formation of a tert-butylborylene complex

scientific article published on 01 June 2006

Mono- and Dianion of a Bis(benzobuta)tetraazapentacene Derivative

scientific article published on 03 July 2019

Monohaloboryls (BHX-) as bridging ligands: observable dinuclear σ-(halo)boranyl intermediates in the synthesis of metalloborylenes

scientific article published on 20 January 2012

Monomeric 16-Electron π-Diborene Complexes of Zn(II) and Cd(II).

scientific article published on 26 July 2017

Monomeric CpAl(i): synthesis, reactivity, and the concept of valence isomerism

scientific article published on 14 January 2019

Multiple complexation of CO and related ligands to a main-group element

scientific article published in June 2015

Multiple reduction of 2,5-bis(borolyl)thiophene: isolation of a negative bipolaron by comproportionation.

scientific article published on 9 October 2013

N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D-π-A Compounds

scientific article published on 26 September 2019

N-Heterocyclic Silylenes in Boron Chemistry: Facile Formation of Silylboranes and Silaborinines

scientific article published on 06 October 2016

NHC-stabilized 1-hydro-1H-borole and its nondegenerate sigmatropic isomers

scientific article published on 11 April 2011

Nature of bonding in terminal borylene, alylene, and gallylene complexes of vanadium and niobium [(η(5)-C5H5)(CO)3M(ENR2)] (M = V, Nb; E = B, Al, Ga; R = CH3, SiH3, CMe3, SiMe3): a DFT study

scientific article published on 28 December 2010

Near-Infrared Quadrupolar Chromophores Combining Three-Coordinate Boron-Based Superdonor and Superacceptor Units

scientific article published on 03 April 2019

Neutral Diboron Analogues of Archetypal Aromatic Species by Spontaneous Cycloaddition.

scientific article published on 4 July 2016

Neutral and anionic transition-metal-base-stabilized metalloborylene complexes

scientific article published on 01 September 2010

Neutral zero-valent s-block complexes with strong multiple bonding

article

New Outcomes of Beryllium Chemistry: Lewis Base Adducts for Salt Elimination Reactions

scientific article published on 01 February 2019

New metal-only Lewis pairs: elucidating the electronic influence of N-heterocyclic carbenes and phosphines on the dative Pt-Al bond

scientific article published on 01 May 2012

New outcomes of Lewis base addition to diboranes(4): electronic effects override strong steric disincentives

scientific article published on 14 March 2016

Ni-catalyzed traceless, directed C3-selective C-H borylation of indoles

scientific article published on 27 June 2020

Nitrogen fixation and reduction at boron

scientific article published in February 2018

Non-iron [n]metalloarenophanes

scientific article published in March 2010

Novel organocycloborates via Grignard reagentsElectronic supplementary information (ESI) available: experimental details and 1H, 13C and 11B NMR data for 1, 2, 3and 4, single crystal X-ray data and additional figures for 3and 4. See http://www.rsc.or

Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor

scientific article published on 4 August 2017

O,N,B-Containing eight-membered heterocycles by ring expansion of boroles with nitrones.

scientific article published on 17 August 2015

Observation of elementary steps in the catalytic borane dehydrocoupling reaction

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Oligo(borolyl)benzenes--synthesis and properties

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On the Reactivity of Phosphaalumenes towards C−C Multiple Bonds

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On the relation of energy and electron transfer in multidimensional chromophores based on polychlorinated triphenylmethyl radicals and triarylamines

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One-pot, room-temperature conversion of dinitrogen to ammonium chloride at a main-group element

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Organometallic Chemistry in Europe

Organometallic Probe for the Electronics of Base-Stabilized Group 11 Metal Cations

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Ortho-methylated tribenzotriquinacenes--paving the way to curved carbon networks

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Outstanding Short-Circuit Currents in BHJ Solar Cells Based on NIR-Absorbing Acceptor-Substituted Squaraines

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Oxidation, Coordination and Nickel-Mediated Deconstruction of a Highly Electron-Rich Diboron Analogue of 1,3,5-Hexatriene

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Oxidative addition of arsenic halides to platinum(0)

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Oxidative addition of boron trifluoride to a transition metal

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Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)2{BiCl2}]

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Oxoboryl complexes: boron-oxygen triple bonds stabilized in the coordination sphere of platinum

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Paracyclophanes as model compounds for strongly interacting π-systems, part 3: influence of the substitution pattern on photoabsorption properties

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Perylene Bisimide Radicals and Biradicals: Synthesis and Molecular Properties

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Phenylpyridyl-fused Boroles: A Unique Coordination Mode and Weak B-N Coordination-Induced Dual Fluorescence

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Phosphine adducts of 1,2-dibromo-1,2-dimesityldiborane(4): between bridging halides and rearrangement processes

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Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds

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Phosphine-triggered co-catenation of :BR and CO on an iron atom

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Photoionization and pyrolysis of a 1,4-azaborinine: retro-hydroboration in the cation and identification of novel organoboron ring systems

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Planar cyclopenten-4-yl cations - highly delocalized π aromatics stabilized by hyperconjugation

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Planar four-coordinate boron: a single, flat boron atom as a ligand for four metals

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Platinum complexes containing pyramidalized germanium and tin dihalide ligands bound through σ,σ M=E multiple bonds

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Platinum oxoboryl complexes as substrates for the formation of 1:1, 1:2, and 2:1 Lewis acid-base adducts and 1,2-dipolar additions

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Platinum substituted boroles

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Platinum trans-Bis(borirene) complexes displaying coplanarity and communication across a platinum metal center.

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Preparation and Characterization of a π-Conjugated Donor-Acceptor System Containing the Strongly Electron-Accepting Tetraphenylborolyl Unit

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Preparation and structural characterization of transition-metal complexes featuring the cymantrenyl(bromo)boryl ligand

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Preparation, Properties, and Structures of the Radical Anions and Dianions of Azapentacenes

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Pseudodiborenes: hydride-bridged diboranes(5) as two-electron reductants of chalcogens

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Pyrene Molecular Orbital Shuffle-Controlling Excited State and Redox Properties by Changing the Nature of the Frontier Orbitals.

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Quaternizing diboranes(4): highly divergent outcomes and an inorganic Wagner-Meerwein rearrangement

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Reaction of Dihalodiboranes(4) with a N-Heterocyclic Silylene: Facile Construction of 1-Aryl-2-Silyl-1,2-Diboraindanes

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Reactions of Digallanes with p- and d-Block Lewis Bases: Adducts, Bis(gallyl) Complexes, and Naked Ga+ as Ligand

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Reactivity Enhancement of a Zerovalent Diboron Compound by Desymmetrization

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Reactivity of Lewis basic platinum complexes towards fluoroboranes

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Reactivity of Pt0 complexes toward gallium(III) halides: synthesis of a platinum gallane complex and oxidative addition of gallium halides to Pt0

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Reactivity of Tetrahalo- and Difluorodiboranes(4) toward Lewis Basic Platinum(0): Bis(boryl), Borylborato, and Doubly Boryl-Bridged Platinum Complexes

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Reactivity of Transition-Metal Borylene Complexes: Recent Advances in B–C and B–B Bond Formation via Borylene Ligand Coupling

Reactivity of [1],[1]disilamolybdenocenophane toward zerovalent platinum complexes

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Reactivity of a Dihydrodiborene with CO: Coordination, Insertion, Cleavage, and Spontaneous Formation of a Cyclic Alkyne

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Reactivity of a platinum iminoboryl complex toward Lewis and Brønsted acids

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Reactivity of a platinum-substituted borirene

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Reactivity of a terminal chromium borylene complex towards olefins: insertion of a borylene into a C-H bond

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Reactivity of an oxoboryl complex toward fluorinated aryl boron reagents

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Recent developments in the chemistry of antiaromatic boroles

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Reduction and Rearrangement of a Boron(I) Carbonyl Complex

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Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling

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Reductive Insertion of Elemental Chalcogens into Boron-Boron Multiple Bonds

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Reductive borylene-CO coupling with a bulky arylborylene complex.

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Regioselective Catalytic and Stepwise Routes to Bulky, Functional-Group-Appended, and Luminescent 1,2-Azaborinines

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Release of Isonitrile- and NHC-Stabilized Borylenes from Group VI Terminal Borylene Complexes

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Reversible insertion of platinum into coinage group metal-halogen bonds

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Reversible intramolecular coupling of the terminal borylene and a carbonyl ligand of [Cp(CO)2Mn=B-tBu].

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Reversible photochemical and thermal isomerization of azaboratabisnorcaradiene to azaborabenzotropilidene

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Reversible sigma-borane-to-borylene transformation: a little something for everyone

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Ring Expansions of Boroles with Diazo Compounds: Steric Control of C or N Insertion and Aromatic/Nonaromatic Products

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Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum-nitrogen heterocycles

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Rydberg state mediated multiphoton ionization of (η7-C7H7)(η5-C5H5)Cr: DFT-supported experimental insights into the molecular and electronic structures of excited sandwich complexes

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Scope of the Thermal Ring-Expansion Reaction of Boroles with Organoazides.

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Selective Photocatalytic C–F Borylation of Polyfluoroarenes by Rh/Ni Dual Catalysis Providing Valuable Fluorinated Arylboronate Esters

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Selective dilithiation of [Ti(η(5)-C5H5)(η(8)-C8H8)] and subsequent conversion into neutral and cationic ansa-complexes

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Selective dimetalation of [Mn(eta5-C5H5)(eta6-C6H6)]: crystal structure and conversion to strained [n]metalloarenophanes

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Selective mono- and dimetallation of a group 3 sandwich complex

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Selective one- and two-electron reductions of a haloborane enabled by a π-withdrawing carbene ligand

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Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments

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Silver(I) and thallium(I) cations as unsupported bridges between two metal bases

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Simple solution-phase syntheses of tetrahalodiboranes(4) and their labile dimethylsulfide adducts

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Simultaneous fragmentation and activation of white phosphorus.

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Single and Double Hydroboration of B-B Triple Bonds and Convergent Routes to a Cationic Tetraborane

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Single and double activation of acetone by isolobal B[triple bond, length as m-dash]N and B[triple bond, length as m-dash]B triple bonds.

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Single, Double, Triple Bonds and Chains: The Formation of Electron‐Precise BB Bonds

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Spontaneous Metal-Free Transfer Hydrogenation of Iminoboranes with Ammonia Borane and Amine Boranes

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Spontaneous trans-Selective Transfer Hydrogenation of Apolar B=B Double Bonds

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Spying on the boron-boron triple bond using spin-spin coupling measured from 11B solid-state NMR spectroscopy

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Stabilization of delphinidin in a complex with sulfobutylether-β-cyclodextrin allows for antinociception in inflammatory pain

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Stable Lewis Base Adducts of Tetrahalodiboranes: Synthetic Methods and Structural Diversity

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Stable Organic (Bi)Radicals by Delocalization of Spin Density into the Electron-Poor Chromophore Core of Isoindigo.

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Stable actinide π complexes of neutral 1,4-diborabenzene

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Stepwise intermetal borylene transfer: synthesis and structure of mono- and dinuclear cobalt-borylene complexes

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Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum

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Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes

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Sterically demanding hetero-substituted [2]borametallocenophanes of group IV metals: synthesis, structure and reactivity

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Stoichiometric and homogeneous-catalytic diboration of the n=n double bond of azobenzene

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Strongly Phosphorescent Transition Metal π-Complexes of Boron-Boron Triple Bonds.

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Structural evidence for antiaromaticity in free boroles

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Structure and bonding energy analysis of M-Ga bonds in dihalogallyl complexes trans-[X(PMe3)2M(GaX2)] (M = Ni, Pd, Pt; X = Cl, Br, I).

scientific article published in August 2010

Structure and reactivity of distanna[2]metallocenophanes of ruthenium and osmium

scientific article published on 22 July 2013

Syntheses of Group 4 ansa-Trovacene Complexes and Conversion of [1]Silatrovacenophanes into Paramagnetic Metallopolymers by Ring-Opening Polymerization

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Syntheses of mono- and dinuclear diiodoboryl complexes of platinum

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Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes

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Synthesis and Structure of Novel Organocycloborates

Synthesis and Structure of [1]Borametallocenophanes of Titanium, Zirconium, and Hafnium

scholarly article by Holger Braunschweig et al published November 1999 in European Journal of Inorganic Chemistry

Synthesis and Structure of [1]Borametallocenophanes of Titanium, Zirconium, and Hafnium

scholarly article by Holger Braunschweig et al published November 1999 in European Journal of Inorganic Chemistry

Synthesis and Structure of the First Terminal Borylene Complexes

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Synthesis and Structure of the First Transition Metal Borylene Complexes

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Synthesis and Structure of the First [1]Boratitanocenophanes

Synthesis and Trapping of Iminoboranes by M=B/C=N Bond Metathesis.

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Synthesis and characterization of a mercury-containing trimetalloboride

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Synthesis and characterization of palladium and platinum iminoboryl complexes

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Synthesis and coordination chemistry of 1-cymantrenyl-2,3,4,5-tetraphenylborole

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Synthesis and electronic structure of a ferroborirene

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Synthesis and electronic structure of a terminal alkylborylene complex

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Synthesis and reactions of {o-{[bis(dimethylamino)boryl]methyl}phenyl}diphenylphosphane

Synthesis and reactivity of boron-, silicon-, and tin-bridged ansa-cyclopentadienyl-cycloheptatrienyl titanium complexes (troticenophanes).

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Synthesis and reactivity studies of iminoboryl complexes

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Synthesis and reduction chemistry of mixed-Lewis-base-stabilised chloroborylenes.

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Synthesis and structure of a carbene-stabilized boraallene coordinated to rhodium.

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Synthesis and structure of a carbene-stabilized pi-boryl anion

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Synthesis and structure of a cationic platinum borylene complex

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Synthesis and structure of a ferrocenylboron dication

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Synthesis and structure of aminobis(η1-cyclopentadienyl)boranes and related compounds

Synthesis and structure of boron-bridged constrained geometry complexes of titanium

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Synthesis and structure of distanna and tristanna ansa half-sandwich complexes of ruthenium and nickel

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Synthesis and structure of heterodinuclear rhodium and iridium borylene complexes

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Synthesis and structure of the first boron-bridged constrained geometry complexes

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Synthesis and structure of the first heterodinuclear bis(borylene) complexes.

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Synthesis and structure-activity relationships of new quinolone-type molecules against Trypanosoma brucei

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Synthesis and structures of [Yb {?5-(C5H4)B(NiPr2)NHtBu}2 {N(SiMe3)2} ] and [Zr {?5-(C9H6)B(N(SiMe3)2)(C9H7)} Cl2]

Synthesis of 1-aza-2-borabutatriene rhodium complexes by thermal borylene transfer from [(OC)5Mo=BN(SiMe3)2]

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Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron-Boron Triple Bond

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Synthesis of Complex Boron-Nitrogen Heterocycles Comprising Borylated Triazenes and Tetrazenes Under Mild Conditions

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Synthesis of Functionalized 1,4-Azaborinines by the Cyclization of Di-tert-butyliminoborane and Alkynes

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Synthesis of Functionalized Hydrazines: Facile Homogeneous (N-Heterocyclic Carbene)-Palladium(0)-Catalyzed Diboration and Silaboration of Azobenzenes

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Synthesis of Unsymmetrical Diboron(5) Compounds and Their Conversion to Diboron(5) Cations

Synthesis of a Paramagnetic Polymer by Ring-Opening Polymerization of a Strained [1]Vanadoarenophane

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Synthesis of a bicyclic diborane by selective boron carbon bond formation

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Synthesis of a bimetallic platinum-tungsten complex with a bridging micro-diboranyl-oxycarbyne moiety

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Synthesis of ansa-[2]boracyclopentadienylcycloheptatrienylchromium and its reaction to the ansa-platinabis(boryl) complex by oxidative addition of the boron-boron bond

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Synthesis of ansa-[n]silacyclopentadienyl-cycloheptatrienyl-chromium complexes (n = 1, 2): novel precursors for polymers bearing chromium in the backbone

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Synthesis of borirenes by photochemical borylene transfer from [(OC)5M==BN(SiMe3)2] (M=Cr, Mo) to alkynes

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Synthesis of catechol-, pinacol-, and neopentylglycolborane through the heterogeneous catalytic B-B hydrogenolysis of diboranes(4).

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Synthesis of cyclic diborenes with unprecedented cis-configuration

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Synthesis of eta1-borazine complexes of palladium and platinum

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Synthesis of fused B,N-heterocycles by alkyne cleavage, NHC ring-expansion and C-H activation at a diboryne

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Synthesis of polyheterocyclic 1,1-diboryltriazenes by γ-nitrogen insertion of azides into activated B-B single bonds

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Synthesis of the first heteroaryl-substituted boryl complexes: strong stabilizing effects of boron-aryl π-conjugation

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Synthesis of unsymmetrical B2E2 and B2E3 heterocycles by borylene insertion into boradichalcogeniranes

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Synthesis of zwitterionic cobaltocenium borate and borata-alkene derivatives from a borole-radical anion

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Synthesis, Electronic Structure, and Novel Reactivity of Strained, Boron-Bridged [1]Ferrocenophanes

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Synthesis, Photophysical and Electronic Properties of Mono-, Di-, Tri-Amino-Substituted Ortho-Perylenes, and Comparison to the Tetra-Substituted Derivative

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Synthesis, Photophysical and Electronic Properties of New Red-to-NIR Emitting Donor-Acceptor Pyrene Derivatives

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Synthesis, Photophysical, and Electrochemical Properties of Pyrenes Substituted with Donors or Acceptors at the 4- or 4,9-Positions

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Synthesis, coordination behavior, and reduction chemistry of cymantrenyl-1,3-bis(2,3,4,5-tetraphenyl)borole

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Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-substituted ortho-perylenes displaying four reversible oxidations or reductions

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Synthesis, structure and reactivity of disila- and distanna ansa half-sandwich complexes of molybdenum and tungsten

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Synthesis, structure, and bonding of novel homodinuclear cobalt and nickel borylene complexes

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Synthesis, structure, and reactivity of borole-functionalized ferrocenes

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T-shaped platinum boryl complexes: synthesis and structure

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Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles

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Terminal Borylene Complexes as a Source for the Borylene B-N(SiMe(3))(2): Alternative Synthesis and Structure of

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Terminal borylene complexes stabilized by a transition-metal base

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Tetraiododiborane(4) (B2 I4 ) is a Polymer Based on sp3 Boron in the Solid State

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The Triboracyclopropenyl Dianion: The Lightest Possible Main-Group-Element Hückel π Aromatic

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The first silyl- and germylboryl complexes: synthesis from novel (dichloro)silyl- and (dichloro)germylboranes, structure and reactivity

The pentaphenylborole-2,6-lutidine adduct: a system with unusual thermochromic and photochromic properties

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The reactivities of iminoboranes with carbenes: BN isosteres of carbene-alkyne adducts

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The reduction chemistry of ferrocenylborole

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The reductive coupling of dinitrogen

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Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II)

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Toward Transition-Metal-Templated Construction of Arylated B4 Chains by Dihydroborane Dehydrocoupling

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Towards Homoleptic Borylene Complexes: Incorporation of Two Borylene Ligands into a Mononuclear Iridium Species

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Transition metals as Lewis bases: “Z-type” boron ligands and metal-to-boron dative bonding

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Transition-Metal π-Ligation of a Tetrahalodiborane

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Transition-metal complexes of boron-new insights and novel coordination modes

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Transition-metal-carbene-like intermolecular insertion of a borylene into C-H bonds

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Transition-metal-catalyzed synthesis of diboranes(4)

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Transmetallation between metal-only Lewis pairs: a new rhodium alane complex

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Trapping the elusive parent borylene

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Trihapto ligation of a borirene to a single metal atom: a heterocyclic analogue of the η³-cyclopropenyl ligand

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Two derivatives of phenylpyridyl-fused boroles with contrasting electronic properties: decreasing and enhancing the electron accepting ability

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Uncatalyzed Hydrogenation of First-Row Main Group Multiple Bonds

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Unexpected bonding mode of the diboran(4)yl ligand: combining the boryl motif with a dative Pt-B interaction

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Unexpected cluster formation upon hydroboration of a neutral diborene with 9-BBN.

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Unexpected generation of diastereomers by double diboration of a dialkyne

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Unexpected luminescence behavior of coinage metal π-diborene complexes

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Unprecedented Borane, Diborane(3), Diborene, and Borylene Ligands via Pt-Mediated Borane Dehydrogenation

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Unprecedented oxidative addition and metal-only Lewis pair chemistry of antimony trihalides

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Unprecedented reactivity of the bridged borylene complexes [mu-BCl((eta(5)-C(5)H(4)Me)Mn(CO)(2))(2)] toward pyridine

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Unravelling the Dramatic Electrostructural Differences Between N-Heterocyclic Carbene- and Cyclic (Alkyl)(amino)carbene-Stabilized Low-Valent Main Group Species

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Unsupported boron–carbon σ-coordination to platinum as an isolable snapshot of σ-bond activation

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Unsymmetrical, Cyclic Diborenes and Thermal Rearrangement to a Borylborylene.

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[(Eta5-C5H5)(OC)3V=B=N(SiMe3)2: a half-sandwich complex with a terminal borylene ligand

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[(OC)5 Cr=BSi(SiMe3 )3 ]: A Terminal Borylene Complex with an Electronically Unsaturated Boron Atom

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[2]borametallocenophanes of group 4 metals: synthesis and structure

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cyclo-Tri-μ-oxido-tris-{[(η,η)-1,2-bis-(cyclo-penta-dien-yl)-1,1,2,2-tetra-methyl-disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene

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sp2–sp3 diboranes: astounding structural variability and mild sources of nucleophilic boron for organic synthesis

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{N',N''-Bis[2,6-bis-(1-methyl-ethyl)phen-yl]-N,N-dimethyl-guanidinato-κN',N''}dibromido-borane

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σ-Coordination of metal-boryl bonds to gold(I)

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σ-Donor-σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt(0) and Pb(II) fragments

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