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List of works by Rudi van Eldik

A Spectroscopic and Mechanistic Study of the Enolization and Diol Formation of Hexafluoroacetylacetone in the Presence of Water and Alcohol

scientific article (publication date: February 1989)

A comparative mechanistic study of the reversible binding of NO to a water-soluble octa-cationic Fe(III) porphyrin complex

scientific article

A complete volume profile for the reversible binding of camphor to cytochrome P450cam ⬇️

scientific article published on January 19, 2012

A detailed mechanistic study of the substitution behavior of an unusual seven-coordinate iron(III) complex in aqueous solution

scientific article published in October 2002

Activation parameters for heme-NO binding in alcaligenes xylosoxidans cytochrome c': the putative dinitrosyl intermediate forms via a dissociative mechanism

scientific article

Activation volume measurement for C[bond]H activation. Evidence for associative benzene substitution at a platinum(II) center

scientific article published in June 2002

Activation volumes for cis-to-trans isomerisation reactions of azophenols: a clear mechanistic indicator?

scientific article published on 18 December 2017

Analysis of flame retardant additives in polymer fractions of waste of electric and electronic equipment (WEEE) by means of HPLC-UV/MS and GPC-HPLC-UV.

scientific article

Analysis of flame retardants and elements of concern in printed wiring boards with respect to origin and year of construction

scientific article published on 14 July 2013

Application of high pressure laser flash photolysis in studies on selected hemoprotein reactions

scientific article

Axial ligand and spin-state influence on the formation and reactivity of hydroperoxo-iron(III) porphyrin complexes

scientific article published on 24 April 2012

Can a Nonorganometallic Ruthenium(II) Polypyridylamine Complex Catalyze Hydride Transfer? Mechanistic Insight from Solution Kinetics on the Reduction of Coenzyme NAD+ by Formate

scientific article published on 01 October 2020

Can nitrocobalamin be reduced by ascorbic acid to nitroxylcobalamin? Some surprising mechanistic findings

scientific article published on 12 February 2018

Cation-independent electron transfer between ferricyanide and ferrocyanide ions in aqueous solution

scientific article published in February 2002

Characterisation of polymer fractions from waste electrical and electronic equipment (WEEE) and implications for waste management

scientific article

Characterization of a Mixed-Valence Ru(II)/Ru(III) Ion-Pair Complex. Unexpected High-Frequency Electron Paramagnetic Resonance Evidence for Ru(III)-Ru(III) Dimer Coupling

scientific article published on 22 May 2020

Chemical composition of submicron and fine particulate matter collected in Krakow, Poland. Consequences for the APARIC project.

scientific article

Combined experimental and theoretical study on the reactivity of compounds I and II in horseradish peroxidase biomimetics

scientific article

Combined low temperature rapid scan and 1H NMR mechanistic study of the protonation and subsequent benzene elimination from a (diimine)platinum(II) diphenyl complex relevant to arene C-H activation

scientific article published in October 2009

Comparative study of the catalytic activity of [Mn(II)(bpy)2Cl2] and [Mn2(III/IV)(mu-O)2(bpy)4](ClO4)3 in the H2O2 induced oxidation of organic dyes in carbonate buffered aqueous solution

scientific article published on 11 February 2010

Complex-formation reactions of Cu(ii) and Zn(ii) 2,2′-bipyridine and 1,10-phenanthroline complexes with bicarbonate. Identification of different carbonate coordination modes

Complex-formation reactions of dicholoro(S-methyl-L-cysteine)palladium(II) with bio-relevant ligands. Labilization induced by S-donor chelates

scientific article published on 23 October 2007

Control of Iron(II) Spin States in 2,2′:6′,2″-Terpyridine Complexes through Ligand Substitution

Coordination of 1,10-phenanthroline and 2,2'-bipyridine to Li+ in different ionic liquids. How innocent are ionic liquids?

scientific article

Coordination of terpyridine to Li+ in two different ionic liquids

scientific article published on 4 November 2013

Cyclometalated Analogues of Platinum Terpyridine Complexes: Kinetic Study of the Strong σ-Donor Cis and Trans Effects of Carbon in the Presence of a π-Acceptor Ligand Backbone ⬇️

scientific article published on October 6, 2003

Detailed spectroscopic, thermodynamic, and kinetic studies on the protolytic equilibria of Fe(III)cydta and the activation of hydrogen peroxide

scientific article

Direct comparison of the reactivity of model complexes for Compounds 0, I, and II in oxygenation, hydrogen-abstraction, and hydride-transfer processes

scientific article published in December 2009

Direct evidence for catalase activity of [Ru(V)(edta)(O)](-).

scientific article published in December 2014

Direct measurements of rate constants and activation volumes for the binding of H2, D2, N2, C2H4, and CH3CN to W(CO)3(PCy3)2: theoretical and experimental studies with time-resolved step-scan FTIR and UV-vis spectroscopy

scientific article published in December 2006

Diverse role of conformational dynamics in carboxypeptidase A-driven peptide and ester hydrolyses: disclosing the "perfect induced fit" and "protein local unfolding" pathways by altering protein stability

scientific article

Effect of chelate dynamics on water exchange reactions of paramagnetic aminopolycarboxylate complexes

scientific article

Effect of pressure on electron transfer reactions in inorganic and bioinorganic chemistry

scientific article

Electrochemistry of Ru(edta) complexes relevant to small molecule transformations: Catalytic implications and challenges

scientific article published in June 2021

Electron transfer with azurin at Au-SAM junctions in contact with a protic ionic melt: impact of glassy dynamics

scientific article published on 13 August 2013

Electronic tuning of the lability of Pt(II) complexes through pi-acceptor effects. Correlations between thermodynamic, kinetic, and theoretical parameters

scientific article

Electronically and sterically tuned trans labilization controls the substitution behaviour of cobaloximes

scientific article published on 3 December 2003

Electrostatic Complexation and Photoinduced Electron Transfer between Zn-Cytochrome c and Polyanionic Fullerene Dendrimers

Elucidation of inorganic reaction mechanisms in ionic liquids: the important role of solvent donor and acceptor properties

scientific article published in November 2014

Elucidation of the solution structure and water-exchange mechanism of paramagnetic [Fe(II)(edta)(H(2)O)](2-).

scientific article

Equilibrium, kinetic and solvent effect studies on the reactions of [RuIII(Hedta)(H2O)] with thiols

scientific article published on 14 September 2005

Experimental and Computational Insight into the Mechanism of NO Binding to Ferric Microperoxidase. The Likely Role of Tautomerization to Account for the pH Dependence

scientific article published on 3 September 2021

Factors that affect the nature of the final oxidation products in "peroxo-shunt" reactions of iron-porphyrin complexes

scientific article published in October 2009

Fixation of CO2 by Zinc(II) Chelates in Alcoholic Medium. X-ray Structures of {[Zn(cyclen)]3(μ3-CO3)}(ClO4)4 and [Zn(cyclen)EtOH](ClO4)2 ⬇️

scientific article (publication date: September 1997)

Formation of [Ru(III)(edta)(SNO)](2-) in Ru(III)(edta)-Mediated S-Nitrosylation of Bisulfide Ion.

scientific article published on 25 April 2016

Fundamental signatures of short- and long-range electron transfer for the blue copper protein azurin at Au/SAM junctions

scientific article

Further mechanistic information on the reaction between FeIII(edta) and hydrogen peroxide: observation of a second reaction step and importance of pH.

scientific article

Gas chromatographic determination of phosphate-based flame retardants in styrene-based polymers from waste electrical and electronic equipment ⬇️

scientific article published on August 28, 2012

Generation of hydroxyl radicals and singlet oxygen by particulate matter and its inorganic components

scientific article published on 31 March 2018

Guest exchange dynamics in an M4L6 tetrahedral host

scientific article published in February 2006

Gutmann donor and acceptor numbers for ionic liquids

scientific article published on 16 July 2012

Heterogeneous electron transfer at Au/SAM junctions in a room-temperature ionic liquid under pressure

scientific article

High-Pressure Mechanistic Insight into Bioinorganic NO Chemistry

scientific article published on 16 August 2021

High-Pressure Oxygen-17 NMR Study of the Dihydroxo-Bridged Rhodium(III) Hydrolytic Dimer. Mechanistic Evidence for Limiting Dissociative Water Exchange Pathways ⬇️

scientific article published on August 10, 1998

High-pressure testing of heterogeneous charge transfer in a room-temperature ionic liquid: evidence for solvent dynamic control

scientific article published on 16 February 2008

Host-guest complexes of mixed glycol-bipyridine cryptands: prediction of ion selectivity by quantum chemical calculations, part V

scientific article published on 27 June 2013

Influence of Krakow Winter and Summer Dusts on the Redox Cycling of Vitamin B12a in the Presence of Ascorbic Acid

scientific article published on 15 August 2021

Influence of an extremely negatively charged porphyrin on the reversible binding kinetics of NO to Fe(III) and the subsequent reductive nitrosylation

scientific article

Influence of terpyridine as pi-acceptor ligand on the kinetics and mechanism of the reaction of NO with ruthenium(III) complexes

scientific article published in November 2004

Influence of the chloride concentration on ligand substitution reactions of [Pt(SMC)Cl(2)] with biologically relevant nucleophiles.

scientific article published on 22 April 2009

Inorganic reaction mechanisms. A personal journey

scientific article published on 12 March 2020

Interplay between acetate ions, peripheral groups, and reactivity of the core nitrogens in transmetalation of tetrapyrroles

scientific article

Is bis(trifluoromethylsulfonyl)amide an innocent anion? X-ray structure data and DFT calculations

scientific article

Isolation and Characterization of the First Stable Bicarbonato Complexes of Bis(1,10-phenanthroline)copper(II). Identification of Lipscomb- and Lindskog-like Intermediates

scientific article published in 2000

Kinetic and mechanistic studies on the reaction of nitric oxide with a water-soluble octa-anionic iron(III) porphyrin complex

scientific article

Kinetic and mechanistic study on the reaction of alkylcobaloximes with azoles

scientific article published on 19 October 2004

Kinetic and thermodynamic studies on ligand substitution reactions and base-on/base-off equilibria of cyanoimidazolylcobamide, a vitamin B12 analog with an imidazole axial nucleoside

scientific article published on 20 January 2005

Kinetic studies on the reactions of [Pd(dach)(X-Y)] complexes with some DNA constituents

scientific article published on 3 December 2007

Kinetic, thermodynamic, and mechanistic patterns for free (unbound) cytochrome c at Au/SAM junctions: impact of electronic coupling, hydrostatic pressure, and stabilizing/denaturing additives

scientific article published in September 2006

Kinetics and Mechanism of the Cobalt Phthalocyanine Catalyzed Reduction of Nitrite and Nitrate by Dithionite in Aqueous Solution ⬇️

scientific article published on January 27, 2003

Kinetics and Mechanism of the Reduction ofmer-Tris-picolinatoruthenium(III) byL-Ascorbic Acid

scientific article

Kinetics and mechanism of O-O bond cleavage in the reaction of [RuIII(edta)(H2O)]- with hydroperoxides in aqueous solution

scientific article published on 13 June 2008

Kinetics and mechanism of the Co(II)-assisted oxidation of L-ascorbic acid by dioxygen and nitrite in aqueous solution

scientific article published on 30 October 2009

Kinetics and mechanism of the Co(II)-assisted oxidation of thioureas by dioxygen

scientific article published on 14 February 2005

Kinetics and mechanism of the [RuIII(edta)(H2O)]−-mediated oxidation of cysteine by H2O2 ⬇️

scientific article published on September 15, 2011

Kinetics and mechanism of the formation of nitroprusside from aquapentacyanoferrate(III) and NO: complex formation controlled by outer-sphere electron transfer

scientific article published in October 2002

Kinetics and mechanism of the iron phthalocyanine catalyzed reduction of nitrite by dithionite and sulfoxylate in aqueous solution

scientific article published in September 2005

Kinetics and mechanism of the reaction of [RuIII(edta)(H2O)]- with HOBr to form an intermediate RuV=O complex in aqueous solution

scientific article published on 3 August 2006

Kinetics and mechanism of the reaction of hydrogen sulfide with diaquacobinamide in aqueous solution

scientific article

Kinetics and mechanism of the substitution reactions of [PtCl(bpma)]+, [PtCl(gly-met-S,N,N)] and their aqua analogues with L-methionine, glutathione and 5'-GMP.

scientific article

Kinetics, mechanism, and spectroscopy of the reversible binding of nitric oxide to aquated iron(II). An undergraduate text book reaction revisited

scientific article

Ligand-exchange processes on solvated lithium cations: DMSO and water/DMSO mixtures

scientific article

Ligand-exchange processes on solvated zinc cations: water exchange on [Zn(H2O)4(L)]2+.2H2O (L=heterocyclic ligand).

scientific article published in June 2010

Local dense structural heterogeneities in liquid water from ambient to 300 MPa pressure: evidence for multiple liquid-liquid transitions

scientific article published in September 2004

Long-range electron transfer with myoglobin immobilized at Au/mixed-SAM junctions: mechanistic impact of the strong protein confinement.

scientific article published on 13 January 2014

Mechanistic Complications Caused by Redox Equilibration: Ascorbate Reduction of a Ruthenium(III) Complex under Low Driving Force Conditions

scientific article

Mechanistic elucidation of the substitution behavior of alkyl cobaloximes in water and methanol as solvents

scientific article published in September 2004

Mechanistic information from pressure acceleration of hydride formation via proton binding to a cobalt(I) macrocycle

scientific article published in March 2002

Mechanistic information from volume profiles for water exchange and complex-formation reactions of aquated Ni(II). pH, buffer and medium effects

scientific article published on 14 September 2009

Mechanistic information on the copper-catalysed autoxidation of mercaptosuccinic acid in aqueous solution

scientific article published on 10 December 2003

Mechanistic information on the nitrite-controlled reduction of aquacob(III)alamin by ascorbate at physiological pH.

scientific article published on 6 August 2015

Mechanistic information on the reductive elimination from cationic trimethylplatinum(IV) complexes to form carbon-carbon bonds

scientific article published in October 2005

Mechanistic information on the reversible binding of NO to selected iron(II) chelates from activation parameters

scientific article published in May 2002

Mechanistic insight from a volume profile for electron transfer between promazine and hexaaquairon(III).

scientific article

Mechanistic insight from activation parameters for the reaction of a ruthenium hydride complex with CO2 in conventional solvents and an ionic liquid

scientific article published on June 20, 2012

Mechanistic insight from thermal activation parameters for oxygenation reactions of different substrates with biomimetic iron porphyrin models for compounds I and II ⬇️

scientific article published on July 30, 2011

Mechanistic investigations of the reaction of an iron(III) octa-anionic porphyrin complex with hydrogen peroxide and the catalyzed oxidation of diammonium-2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate).

scientific article published in August 2009

Mechanistic studies on fast ligand substitution reactions of Pt(II) in different ionic liquids: role of solvent polarity and ion-pair formation

scientific article published on 12 July 2008

Mechanistic studies on the binding of nitric oxide to a synthetic heme-thiolate complex relevant to cytochrome p450.

scientific article

Mechanistic studies on the reactions of platinum(II) complexes with nitrogen- and sulfur-donor biomolecules

scientific article published on October 2012

Mechanistic studies on versatile metal-assisted hydrogen peroxide activation processes for biomedical and environmental incentives

scientific article published in November 2016

Metabolic Response of RAW 264.7 Macrophages to Exposure to Crude Particulate Matter and a Reduced Content of Organic Matter

scientific article published on 30 August 2021

Metal complex-assisted activation of small molecules. From NO to superoxide and peroxides

scientific article published on 04 July 2008

Nitrosyl- versus nitroxyl-cobalamin?

Novel dinuclear platinum(II) complexes containing mixed nitrogen-sulfur donor ligands

scientific article

Novel iron(III) porphyrazine complex. Complex speciation and reactions with NO and H2O2.

scientific article

Oxidation of hydroxyurea with oxovanadium(V) ions in acidic aqueous solution

scientific article

Physicochemical Analysis of Water Extracts of Particulate Matter from Polluted Air in the Area of Kraków, Poland

scientific article published on 28 April 2021

Post-combustion syntheses of PCDD/F and PBDD/F from halogen-rich fuel is suppressed by a pebble heater technology

scientific article published on September 2007

Preface

Preparation of reference materials for the determination of RoHS-relevant flame retardants in styrenic polymers

scientific article

Rapid identification of RoHS-relevant flame retardants from polymer housings by ultrasonic extraction and RP-HPLC/UV.

scientific article

Rapid ligand substitution reactions in ionic liquids studied by stopped-flow technique

scientific article published on 11 September 2007

Reaction mechanisms relevant to the formation and utilization of [Ru(edta)(NO)] complexes in aqueous media

scientific article published in December 2021

Reaction of [RuIII(edta)(H2O)]- with H2O2 in aqueous solution. Kinetic and mechanistic investigation

scientific article published on 30 January 2007

Reactivity of a Cytostatic Active N,N-Donor-Containing Dinuclear Pt(II) Complex with Biological Relevant Nucleophiles ⬇️

scientific article published on February 22, 2012

Reactivity of aquacobalamin and reduced cobalamin toward S-nitrosoglutathione and S-nitroso-N-acetylpenicillamine

scientific article published in February 2006

Redox Equilibration Observed for the Reduction of a Ruthenium(III) Complex by Ascorbate under Low-Driving-Force Conditions

scientific article

Redox reactions of a Ru(III)-edta complex with thioamino acids. Kinetic and mechanistic studies

scientific article published on 4 January 2011

Reduction of some Pt(IV) complexes with biologically important sulfur-donor ligands

scientific article published on 9 May 2013

Reduction pathway of end-on terminally coordinated dinitrogen. V. N-N bond cleavage in Mo/W hydrazidium complexes with diphosphine coligands. Comparison with triamidoamine systems

scientific article published in May 2005

Reinvestigation of the formation of a mononuclear Fe(III) hydroperoxido complex using high pressure kinetics

scientific article published on 21 July 2010

Release of NO from reduced nitroprusside ion. Iron-dinitrosyl formation and NO-disproportionation reactions

scientific article published in April 2005

Remarkably high catalytic activity of the RuIII(edta)/H2O2 system towards degradation of the azo-dye Orange II ⬇️

scientific article published on July 27, 2011

Reply to the Comment on the article "Gutmann donor and acceptor numbers for ionic liquids" (Chem. Eur. J. 2012, 18, 10969-10982) by J.-F. Gal and C. Laurence.

scientific article

Ru(III)(EDTA) mediated S-nitrosylation of cysteine by nitrite

scientific article published on 29 October 2014

Ru(III)(edta) mediated oxidation of azide in the presence of hydrogen peroxide. Azide versus peroxide activation

scientific article published in February 2014

Ru(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere outer-sphere mechanism

scientific article published on 15 June 2021

Selective oxidation of thiourea with H2O2 catalyzed by [RuIII(edta)(H2O)]−: kinetic and mechanistic studies ⬇️

scientific article published on 01 April 2013

Simplicity within the complexity: bilateral impact of DMSO on the functional and unfolding patterns of α-chymotrypsin.

scientific article published on 26 February 2013

Solvation largely accounts for the effect of N-alkylation on the properties of nickel(II/I) and chromium(III/II) cyclam complexes

scientific article published in June 2002

Solvent and pressure effects on the motions of encapsulated guests: tuning the flexibility of a supramolecular host

scientific article

Solvent tuning of the substitution behavior of a seven-coordinate iron(III) complex

scientific article published in February 2006

Spectroscopic Evidence for Ligand Substitution Reactions at the Solid-Liquid Interface of a Sub-micrometer Gold(I) Carbene Complex

scientific article

Spectroscopic and Kinetic Evidence for the Crucial Role of Compound 0 in the P450cam -Catalyzed Hydroxylation of Camphor by Hydrogen Peroxide

scientific article published on 10 September 2015

Spectroscopic, thermodynamic, kinetic studies and oxidase/antioxidant biomimetic catalytic activities of tris(3,5-dimethylpyrazolyl)borate Cu(II) complexes

scientific article

Steric and electronic tuning of the reactivity of [RuII(terpy)(N^N)Cl]Cl complexes

scientific article published in May 2020

Structural and Kinetic Studies on the Formation of Platinum(II) and Palladium(II) Complexes with l-Cysteine-Derived Ligands ⬇️

scientific article published on August 24, 1998

Structural and kinetic study of reversible CO2 fixation by dicopper macrocyclic complexes. From intramolecular binding to self-assembly of molecular boxes

scientific article published on 3 October 2007

Structural and mechanistic information on the reaction of bicarbonate with Cu(II) and Zn(II) complexes of tris(2-aminoethyl)amine. Identification of intermediate and product species

Structural, spectroscopic, and kinetic investigation of the molybdenum dialkylhydrazido complexes [MoBr(NNC5H10)(dppe)2]Br and [Mo(NNC5H10)(dppe)2]: activation parameters and revised mechanism for N-N cleavage

scientific article published in March 2009

Structure and reactivity of [RuII(terpy)(N^N)Cl]Cl complexes: consequences for biological applications.

scientific article published on 24 July 2017

Structures of Carbonato and Bicarbonato Complexes of Bis(1,10-phenanthroline)Zinc(II): Experiment and Theory

Structures of Vanadium(III)-Ethylenediamine-N,N′-diacetato-N,N′-di-3-propionato Complexes. Critical Role of pπ-dπ Donation in Determining the Coordination Number ⬇️

scientific article published on December 29, 2010

Studies on Pd(1,4-bis(2-hydroxyethyl)piperazine)-dicarboxylic acid complexes as models for carboplatin with structural features enhancing the interaction with DNA

scientific article published on 18 June 2019

Studies on the Reaction of Iron(II) with NO in a Noncoordinating Ionic Liquid

scientific article

Studies on the reactions of [AuCl4](-) with different nucleophiles in aqueous solution

scientific article published in June 2014

Substitution behaviour of amine-bridged dinuclear Pt(II) complexes with bio-relevant nucleophiles

scientific article published in May 2008

Substitution behaviour of novel dinuclear Pt(ii) complexes with bio-relevant nucleophiles ⬇️

scientific article published on 08 November 2011

Substitution reactions of [Pt(terpy)X]2+ with some biologically relevant ligands. Synthesis and crystal structure of [Pt(terpy)(cyst-S)](ClO4)2.0.5H2O and [Pt(terpy)(guo-N7)](ClO4)2.0.5guo.1.5H2O.

scientific article published on 3 December 2003

Synthesis and detailed characterization ofcis-dichloridobispicolinatoruthenate(III) as solid and in solution

scientific article published on 10 July 2016

Systematic tuning of the reactivity of [RuII(terpy)(N^N)Cl]Cl complexes

scientific article published on 3 July 2018

Temperature- and pressure-dependent stopped-flow kinetic studies of jack bean urease. Implications for the catalytic mechanism

scientific article

The classic "brown-ring" reaction in a new medium: kinetics, mechanism, and spectroscopy of the reversible binding of nitric oxide to iron(II) in an ionic liquid

scientific article

The impact of tripodal chelates on water exchange kinetics and mechanisms: a variable temperature and pressure 17O NMR study to clarify the structure-reactivity relationship in [Fe(II)(L)(H2O2](-) complexes

scientific article

The oxidative degradation of dibenzoazepine derivatives by cerium(IV) complexes in acidic sulfate media

scientific article published on 29 November 2011

The reduction of (ImH)[trans-RuIIICl4(dmso)(Im)] under physiological conditions: preferential reaction of the reduced complex with human serum albumin.

scientific article published on 26 April 2008

Thermodynamic and kinetic behaviour of [Pt(2-methylthiomethylpyridine)(OH2)2]2+.

scientific article

Thermodynamic and kinetic studies on novel dinuclear platinum(II) complexes containing bidentate N,N-donor ligands

scientific article published in August 2011

Thermodynamic and kinetic studies on reactions of Fe(III)(meso-[tetra(3-sulfonatomesityl)porphin]) with NO in an ionic liquid. Trace impurities can change the mechanism!

scientific article

Thermodynamic and kinetic studies on reactions of Pt(II) complexes with biologically relevant nucleophiles

scientific article

Thermodynamic and kinetic studies on the interaction of RuIII(edta) with NO in an ionic liquid ⬇️

scientific article published on March 18, 2011

Thermodynamic, electrochemical, high-pressure kinetic, and mechanistic studies of the formation of oxo Fe(IV)-TAML species in water.

scientific article published on 18 November 2010

Thermodynamics of the interaction of ruthenium(III) polyaminecarboxylate complexes with bio-relevant ligands. Deactivation of the complexes as NO scavengers by thiol ligands

scientific article published in November 2012

Transition state characterization for the reversible binding of dihydrogen to bis(2,2'-bipyridine)rhodium(I) from temperature- and pressure-dependent experimental and theoretical studies

scientific article published in February 2006

Triggering water exchange mechanisms via chelate architecture. Shielding of transition metal centers by aminopolycarboxylate spectator ligands

scientific article

Tuning the lability of a series of Ru(II) polypyridyl complexes: a comparison of experimental-kinetic and DFT-predicted reaction mechanisms

scientific article published on 19 January 2021

Tuning the reactivity of chelated dinuclear Pt(II) complexes through a flexible diamine linker. A detailed kinetic and mechanistic study

scientific article published on 12 February 2010

Understanding chemical reaction mechanisms in ionic liquids: successes and challenges

scientific article

Unusual mechanism for the short-range electron transfer within gold-alkanethiol-ionic-liquid films of subnanometer thickness

scientific article published on 4 December 2009

Versatile and fast gas chromatographic determination of frequently used brominated flame retardants in styrenic polymers

scientific article published on 19 July 2008

Volume profile analysis for the reversible binding of superoxide to form iron(II)-superoxo/Iron(III)-peroxo porphyrin complexes

scientific article published on 8 November 2010

Water Exchange Controls the Complex-Formation Mechanism of Water-Soluble Iron(III) Porphyrins: Conclusive Evidence for Dissociative Water Exchange from a High-Pressure (17)O NMR Study The authors gratefully acknowledge financial support from the Deu

scientific article

Which oxidant is really responsible for P450 model oxygenation reactions? A kinetic approach

scientific article published in January 2008

[FeIII(tmdta)]--twist-boat/half-chair conformer ratio reliably deduced from DFT-calculated Raman spectra

scientific article published on 20 August 2007

[Ru(III)(edta)(H(2)O)](-) mediated oxidation of hydroxyurea with H(2)O(2). Kinetic and mechanistic investigation

scientific article published on 15 December 2009

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