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List of works by Robert Bergman

1H NMR Chemical Shift Calculations as a Probe of Supramolecular Host–Guest Geometry

scientific article published on June 29, 2011

A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation

scientific article published on 01 January 2001

A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation This work was supported by the Director, Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division

scientific article

A Nanovessel-Catalyzed Three-Component Aza-Darzens Reaction

scientific article published on 07 January 2020

A Step beyond the Feltham–Enemark Notation: Spectroscopic and Correlated ab Initio Computational Support for an Antiferromagnetically Coupled M(II)–(NO)− Description of Tp*M(NO) (M = Co, Ni)

article

A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length

scientific article published on 16 July 2019

A comprehensive investigation of the chemistry and basicity of a parent amidoruthenium complex.

scientific article published in May 2002

A direct, biomass-based synthesis of benzoic acid: formic acid-mediated deoxygenation of the glucose-derived materials quinic acid and shikimic acid

scientific article published in July 2010

A facile, metal- and solvent-free, autoxidative coupling of quinolines with indoles and pyrroles

scientific article published on March 29, 2011

A highly reactive titanium precatalyst for intramolecular hydroamination reactions

scientific article

A mechanistic investigation of the carbon-carbon bond cleavage of aryl and alkyl cyanides using a cationic RhIII silyl complex

scientific article published in August 2003

A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex

scientific article published on 21 June 2013

A supramolecular approach to combining enzymatic and transition metal catalysis

scientific article published on 6 January 2013

A supramolecular microenvironment strategy for transition metal catalysis

scientific article published on 3 December 2015

Acceleration of amide bond rotation by encapsulation in the hydrophobic interior of a water-soluble supramolecular assembly.

scientific article

Acid catalysis in basic solution: a supramolecular host promotes orthoformate hydrolysis

scientific article

Activation of white phosphorus by low-valent group 5 complexes: formation and reactivity of cyclo-P4 inverted sandwich compounds.

scientific article published on 3 December 2014

Aluminium-catalyzed intramolecular hydroamination of aminoalkenes

scientific article published on 10 May 2010

An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation.

scientific article

An iridium difluoroketene complex: synthesis and isolation

scientific article published in November 2004

An unusally diverse array of products formed upon carbonylation of a dialkylniobium complex.

scientific article published on 31 July 2008

Analysis of an unprecedented mechanism for the catalytic hydrosilylation of carbonyl compounds

scientific article published on 6 November 2007

Annulation of aromatic imines via directed C-H bond activation

scientific article

Application of Daugulis copper-catalyzed direct arylation to the synthesis of 5-aryl benzotriazepines

scientific article published on April 2009

Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives.

scientific article published on 20 March 2014

Application of physical organic methods to the investigation of organometallic reaction mechanisms.

scientific article published in May 2003

Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization

scientific article published on 01 January 2004

Asymmetric catalytic synthesis of P-stereogenic phosphines via a nucleophilic ruthenium phosphido complex

scientific article published in March 2006

Asymmetric synthesis of (-)-incarvillateine employing an intramolecular alkylation via Rh-catalyzed olefinic C-H bond activation

scientific article published on 29 April 2008

Asymmetric synthesis of α-branched amines via Rh(III)-catalyzed C-H bond functionalization

scientific article

Aza Cope rearrangement of propargyl enammonium cations catalyzed by a self-assembled "nanozyme".

scientific article published on 25 July 2008

Biaryl Reductive Elimination Is Dramatically Accelerated by Remote Lewis Acid Binding to a 2,2′-Bipyrimidyl–Platinum Complex: Evidence for a Bidentate Ligand Dissociation Mechanism

C-F sp(2) bond functionalization mediated by niobium complexes

scientific article published on 28 July 2015

C-H bond activation of hydrocarbons by an imidozirconocene complex.

scientific article

Carboamination: additions of imine C=N bonds across alkynes catalyzed by imidozirconium complexes

scientific article

Carbon monoxide, isocyanide, and nitrile complexes of cationic, d(0) vanadium bisimides: π-back bonding derived from the π symmetry, bonding metal bisimido ligand orbitals

scientific article

Carbon-carbon bond activation of R-CN (R = Me, Ar, iPr, tBu) using a cationic Rh(III) complex

scientific article published in April 2002

Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)

scientific article (publication date: 1982)

Catalysis of 6pi electrocyclizations

scientific article published in January 2008

Catalytic C−O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin-Related Polymers

scientific article (publication date: 15 September 2010)

Catalytic deprotection of acetals in basic solution with a self-assembled supramolecular "nanozyme".

scientific article published in January 2007

Catalytic hydroamination of alkynes and norbornene with neutral and cationic tantalum imido complexes

scientific article

ChemInform Abstract: Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound

Chiral amide directed assembly of a diastereo- and enantiopure supramolecular host and its application to enantioselective catalysis of neutral substrates.

scientific article published on 5 December 2013

Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins

scientific article published on 5 March 2008

Cobalt-mediated [3 + 2]-annulation reaction of alkenes with alpha,beta-unsaturated ketones and imines

scientific article published on August 2009

Cobalt-mediated, enantioselective synthesis of C(2) and C(1) dienes

scientific article

Conformational Selection as the Mechanism of Guest Binding in a Flexible Supramolecular Host.

scientific article published on 5 June 2017

Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing

scientific article published on 03 December 2019

Cyclopropylmethyl/cyclobutyl rearrangements on surfaces: evidence for transient cation formation near O-covered Mo(110).

scientific article published on 22 March 2007

Deconvoluting the Role of Charge in a Supramolecular Catalyst

scientific article published on 16 May 2018

Development of ruthenium catalysts for the enantioselective synthesis of P-stereogenic phosphines via nucleophilic phosphido intermediates

scientific article

Dihydrogen Activation by Titanium Sulfide Complexes

scientific article

Diniobium inverted sandwich complexes with μ-η6:η6-arene ligands: synthesis, kinetics of formation, and electronic structure

scientific article published on 13 February 2013

Direct Michael addition of alkenes via a cobalt-dinitrosyl mediated vinylic C-H functionalization reaction

scientific article published on 23 June 2011

Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation

scientific article published on 11 July 2008

Dis-assembly of a Benzylic CF3 Group Mediated by a Niobium(III) Imido Complex

scientific article published on May 20, 2013

Dissociation of carbanions from acyl iridium compounds: an experimental and computational investigation

scientific article published in December 2004

Diverse Reactivity of a Rhenium(V) Oxo Imido Complex: [2 + 2] Cycloadditions, Chalcogen Metathesis, Oxygen Atom Transfer, and Protic and Hydridic 1,2-Additions

scientific article published on 14 July 2020

Does size really matter? The steric isotope effect in a supramolecular host-guest exchange reaction

scientific article published in May 2010

Effect of polymer attachment on the equilibrium acidity of an organotransition metal hydride and an organic carboxylic acid. Synthesis and properties of a polymer-supported metal anion

scientific article published in 1980

Effects of phosphine ligand chelation on the reactivity of monomeric parent amido ruthenium complexes: synthesis and reactivity of such a complex bearing monodentate ligands

scientific article published in December 2002

Electron acceptors promote proton-hydride tautomerism in low valent rhenium β-diketiminates

scientific article published on 03 March 2020

Electron localization in a mixed-valence diniobium benzene complex.

scientific article published on 11 November 2014

Electronic Structures of Rhenium(II) β-Diketiminates Probed by EPR Spectroscopy: Direct Comparison of an Acceptor-Free Complex to Its Dinitrogen, Isocyanide, and Carbon Monoxide Adducts

scientific article published on 28 July 2020

Electronic and medium effects on the rate of arene C [bond] H activation by cationic Ir(III) complexes

scientific article published in February 2002

Elimination of R-H from iridium acyl hydrides without loss of CO: evidence for the intervention of metal cation/carbanion pairs

scientific article published in March 2004

Enabling New Modes of Reactivity via Constrictive Binding in a Supramolecular-Assembly-Catalyzed Aza-Prins Cyclization.

scientific article published on 15 July 2015

Enantioselective catalysis of the aza-Cope rearrangement by a chiral supramolecular assembly

scientific article published in December 2009

Enantioselective guest binding and dynamic resolution of cationic ruthenium complexes by a chiral metal-ligand assembly

scientific article published in March 2004

Enantioselective intramolecular hydroarylation of alkenes via directed C-H bond activation

scientific article published on 06 August 2008

Enantioselective oxidation of di-tert-butyl disulfide with a vanadium catalyst: progress toward mechanism elucidation

scientific article

Enantioselective synthesis of a PKC inhibitor via catalytic C-H bond activation

scientific article published on 01 April 2006

Encapsulated Guest−Host Dynamics: Guest Rotational Barriers and Tumbling as a Probe of Host Interior Cavity Space

scientific article published on October 26, 2010

Encapsulation of cationic ruthenium complexes into a chiral self-assembled cage.

scientific article

Encapsulation of protonated diamines in a water-soluble, chiral, supramolecular assembly allows for measurement of hydrogen-bond breaking followed by nitrogen inversion/rotation.

scientific article

Enthalpy-entropy compensation reveals solvent reorganization as a driving force for supramolecular encapsulation in water

scientific article

Enzyme-like control of carbocation deprotonation regioselectivity in supramolecular catalysis of the Nazarov cyclization

scientific article published on 20 September 2011

Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation

scientific article published in May 2010

Epoxide-Opening and Group-Transfer Reactions Mediated by Monomeric Zirconium Imido Complexes

scientific article published on November 26, 2003

Equilibrium Isotope Effects on Noncovalent Interactions in a Supramolecular Host–Guest System

scientific article published on January 24, 2012

Erratum: Correction

Examination of the hydrogen-bonding networks in small water clusters (n = 2–5, 13, 17) using absolutely localized molecular orbital energy decomposition analysis

scientific article published on October 10, 2012

Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates

scientific article

Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I).

scientific article published on February 2006

Facile Activation of Triarylboranes by Rhenium(V) Oxo Imido Complexes

scientific article published on 27 April 2020

Facile Rh(III)-Catalyzed Synthesis of Fluorinated Pyridines

scientific article published on 20 May 2015

Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascade

scientific article published on 19 August 2013

Formation, reactivity, and properties of nondative late transition metal-oxygen and -nitrogen bonds

scientific article

Functionalization of an iridium–diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources

scholarly article by Allegra L. Liberman-Martin et al published September 2016 in Polyhedron

Generation of low-valent tantalum species by reversible C-H activation in a cyclometallated tantalum hydride complex

scientific article

Group 5 chemistry supported by β-diketiminate ligands

scientific article published on 21 June 2016

H2 Activation and Direct Access to Terminal Nitride and cyclo-P3 Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate

scientific article published on 24 September 2019

Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the β-Diketiminato Ligand

scientific article published on June 7, 2010

Heterocumulene metathesis by iridium guanidinate and ureylene complexes: catalysis involving reversible insertion to form six-membered metallacycles

scientific article published in August 2002

Heterogeneous Supramolecular Catalysis through Immobilization of Anionic M4L6 Assemblies on Cationic Polymers

scientific article published on 02 November 2020

Heterotetrametallic Re-Zn-Zn-Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate

scientific article published on 08 January 2019

High-Turnover Supramolecular Catalysis by a Protected Ruthenium(II) Complex in Aqueous Solution

scientific article published on July 18, 2011

High-precision measurement of isotope effects on noncovalent host-guest interactions

scientific article published in February 2010

Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade

scientific article published on February 22, 2012

Highly Efficient Aluminum-Catalyzed Hydro-amination/-hydrazination of Carbodiimides

article

Highly efficient and enantioselective cyclization of aromatic imines via directed C-H bond activation

scientific article published in June 2004

Hydroalkoxylation catalyzed by a gold(I) complex encapsulated in a supramolecular host.

scientific article published on 25 April 2011

Hydroboration Reactivity of Niobium Bis(N-heterocyclic carbene)borate Complexes.

scientific article published on 6 April 2018

Intermediacy of an N-heterocyclic carbene complex in the catalytic C-H activation of a substituted benzimidazole

scientific article published in April 2002

Intermolecular coupling of alkenes to heterocycles via C-H bond activation

scientific article published in October 2004

Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation

scientific article published in November 2002

Iridium-catalyzed H/D exchange into organic compounds in water

scientific article published on 01 March 2002

Jerome A. Berson (1924-2017).

scientific article published on 16 March 2017

Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity

scientific article published on 03 April 2007

Kinetic control and multiple mechanisms for C-H bond activation by a Zr=N complex

scientific article published on January 2007

Kinetic evidence for the formation of discrete 1,4-dehydrobenzene intermediates. Trapping by inter- and intramolecular hydrogen atom transfer and observation of high-temperature CIDNP

article

Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound

scientific article published on 16 April 2015

Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand.

scientific article

Ligand-based carbon-nitrogen bond forming reactions of metal dinitrosyl complexes with alkenes and their application to C-H bond functionalization.

scientific article published on 23 December 2013

Living ring-opening polymerization of N-sulfonylaziridines: synthesis of high molecular weight linear polyamines

scientific article published in December 2005

Making amines strong bases: thermodynamic stabilization of protonated guests in a highly-charged supramolecular host1.

scientific article

Mechanism of the Rhodium(III)-Catalyzed Arylation of Imines via C–H Bond Functionalization: Inhibition by Substrate

scientific article published on January 17, 2012

Mechanisms of allene stereoinversion by imidozirconium complexes

scientific article

Mechanistic Investigation of Cycloreversion/Cycloaddition Reactions between Zirconocene Metallacycle Complexes and Unsaturated Organic Substrates

scientific article

Mechanistic investigation of the staudinger ligation

scientific article (publication date: 2 March 2005)

Mechanistic investigations of the acid-catalyzed cyclization of a vinyl ortho-quinone methide

scientific article

Mechanistic study of the oxidative coupling of styrene with 2-phenylpyridine derivatives catalyzed by cationic rhodium(III) via C-H activation

scientific article published on 16 April 2013

Memes=Trisun, Mason, and the rest of amery

scientific article published on 10/8/2018 by the dro1d himself.

Microwave-Assisted C−H Bond Activation:  A Rapid Entry into Functionalized Heterocycles

article

Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation

scientific article published in February 2006

Molecular recognition and self-assembly special feature: Encapsulation and characterization of proton-bound amine homodimers in a water-soluble, self-assembled supramolecular host

scientific article

Molecular recognition and stabilization of iminium ions in water

scientific article

Monomeric Cyclopentadienylnickel Methoxo and Amido Complexes: Synthesis, Characterization, Reactivity, and Use for Exploring the Relationship between H−X and M−X Bond Energies

scientific article published in 1997

Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions

scientific article published on July 2006

New Regio- and Stereoselective Cascades via Unstabilized Azomethine Ylide Cycloadditions for the Synthesis of Highly Substituted Tropane and Indolizidine Frameworks.

scientific article published on 19 September 2016

New routes to transition metal-carbido species: synthesis and characterization of the carbon-centered trigonal prismatic clusters [W(6)CCl(18)](n)(-) (n = 1, 2, 3).

scientific article published in September 2003

Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes

scientific article published on 23 December 2015

Nitro and Nitroso Metathesis Reactions with Monomeric Zirconium Imido Complexes

scientific article published on August 2004

Nucleophilic substitution catalyzed by a supramolecular cavity proceeds with retention of absolute stereochemistry

scientific article published on 7 October 2014

Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand.

scientific article

Olefination and group transfer reactions of an electron deficient tantalum methylidene complex

scientific article published on 14 November 2005

Organometallic chemistry: C-H activation

scientific article published in March 2007

Origins of large rate enhancements in the Nazarov cyclization catalyzed by supramolecular encapsulation

scientific article published on 25 February 2014

Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium β-Diketiminate Complex.

scientific article

Oxygen-centered hexatantalum tetradecaimido cluster complexes

scientific article

Ozonolysis-based route to the in situ formation of aldehyde-bearing self-assembled monolayer surfaces

scientific article published on 6 February 2008

Pd-catalyzed dynamic kinetic enantioselective arylation of silylphosphines

scientific article published on 16 November 2007

Phosphine-catalyzed hydration and hydroalkoxylation of activated olefins: use of a strong nucleophile to generate a strong base

scientific article published in July 2003

Photo-activation of d(0) niobium imido azides: en route to nitrido complexes

scientific article published in April 2016

Platinum-catalyzed phenyl and methyl group transfer from tin to iridium: evidence for an autocatalytic reaction pathway with an unusual preference for methyl transfer

scientific article

Preparation and physical properties of early-late heterobimetallic compounds featuring Ir–M bonds (M = Ti, Zr, Hf)

scientific article published on October 21, 2011

Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids

scientific article published on 4 February 2016

Protein-like proton exchange in a synthetic host cavity

scientific article

Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis

scientific article published on February 8, 2013

Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: a dramatic effect of counteranions on reaction efficiency

scientific article published on October 2005

Proton-mediated chemistry and catalysis in a self-assembled supramolecular host.

scientific article published in October 2009

Pt-catalyzed C-C activation induced by C-H activation

scientific article published on 20 August 2013

Reaction of (bisimido)niobium(V) complexes with organic azides: [3 + 2] cycloaddition and reversible cleavage of β-diketiminato ligands involving nitrene transfer

scientific article

Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes

scientific article published on May 2004

Reactivity of Zirconocene Azametallacyclobutenes: Insertion of Aldehydes, Carbon Monoxide, and Formation of α,β-Unsaturated Imines. Formation and Trapping of [Cp2ZrO] in a [4 + 2] Retrocycloaddition1

scientific article published on July 12, 1996

Rearrangements and stereomutations of metallacycles derived from allenes and imidozirconium complexes.

scientific article

Reassignment of the configuration of salvianolic acid B and establishment of its identity with lithospermic acid B.

scientific article published in August 2006

Redox-Initiated Reactivity of Dinuclear β-Diketiminatoniobium Imido Complexes.

scientific article published on 18 January 2017

Regio- and Diastereoselective Synthesis of Highly Substituted, Oxygenated Piperidines from Tetrahydropyridines

scientific article published on 22 June 2015

Regio- and stereoselective 1,2-dihydropyridine alkylation/addition sequence for the synthesis of piperidines with quaternary centers

scientific article

Regio- and stereospecific formation of protected allylic alcohols via zirconium-mediated S(N)2' substitution of allylic chlorides

scientific article published on 31 October 2007

Reproducibility in Chemical Research

scientific article published on 25 August 2016

Rh(I)-Catalyzed Cycloisomerization of 1,6-Enynes

scientific article

Rh(I)-Catalyzed Direct Arylation of Azines

scientific article published on October 29, 2010

Rh(I)-catalyzed alkylation of quinolines and pyridines via C-H bond activation

scientific article published on 6 April 2007

Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight

scientific article published on 02 February 2008

Rh(I)-catalyzed direct arylation of pyridines and quinolines

scientific article published on 15 October 2008

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation

scientific article published on December 22, 2010

Rhenium-Catalyzed Didehydroxylation of Vicinal Diols to Alkenes Using a Simple Alcohol as a Reducing Agent

scientific article published on August 25, 2010

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

scientific article published on December 8, 2011

Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C-H bond activation

scientific article published on 02 June 2009

Rhodium(III)-Catalyzed Arylation of Boc-Imines via C−H Bond Functionalization

scientific article published on January 4, 2011

Rhodium(III)-catalyzed indazole synthesis by C-H bond functionalization and cyclative capture

scientific article published on 3 May 2013

Rhodium(III)‐Catalyzed Alkenyl CH Bond Functionalization: Convergent Synthesis of Furans and Pyrroles

scientific article published on November 22, 2012

Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes

scientific article published on January 1, 2012

Rhodium-Catalyzed Synthesis of Branched Amines by Direct Addition of Benzamides to Imines

scientific article published on April 13, 2012

Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation

scientific article

Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline.

scientific article published in March 2006

Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes

scientific article published on 01 May 2004

Ronald Breslow (1931-2017).

scientific article

Safe Preparation and Purification of Sodium Tetrakis[(3,5-trifluoromethyl)phenyl]borate (NaBArF 24 ): Reliable and Sensitive Analysis of Water in Solutions of Fluorinated Tetraarylborates

scientific article

Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis

scientific article

Scope and mechanism of formal S(N)2' substitution reactions of a monomeric imidozirconium complex with allylic electrophiles

scientific article published on 8 March 2008

Scope and mechanism of the C-H bond activation reactivity within a supramolecular host by an iridium guest: a stepwise ion pair guest dissociation mechanism

scientific article

Selective C-H bond activation by a supramolecular host-guest assembly

scientific article published in February 2004

Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution

article

Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels

scientific article

Selective monoterpene-like cyclization reactions achieved by water exclusion from reactive intermediates in a supramolecular catalyst.

scientific article published on 22 October 2012

Selective transformations of organic compounds by imidozirconocene complexes

scientific article published in January 2002

Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts

scientific article published on 01 October 2018

Solvent and pressure effects on the motions of encapsulated guests: tuning the flexibility of a supramolecular host

scientific article

Some problems in the oxidative addition and binding of ethylene to a transition-metal center

article

Stabilization of Reactive Organometallic Intermediates Inside a Self-Assembled Nanoscale Host

scientific article (publication date: 23 January 2006)

Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation

scientific article published on May 2006

Stoichiometric and catalytic H/D incorporation by cationic iridium complexes: a common monohydrido-iridium intermediate

scientific article published in October 2004

Stoichiometric and catalytic deuterium and tritium labeling of "unactivated" organic substrates with cationic Ir(III) complexes

scientific article published on 01 January 2004

Structural consequences of anionic host-cationic guest interactions in a supramolecular assembly

scientific article published on 01 January 2009

Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal-carbon bonds

scientific article published on 01 October 2019

Sub-Picosecond IR Study of the Reactive Intermediate in an Alkane C−H Bond Activation Reaction by CpRh(CO)2

scientific article published in August 1998

Supramolecular Ga4L6(12-) Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer.

scientific article published on 10 August 2015

Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics

scientific article published on 22 January 2019

Supramolecular catalysis in metal-ligand cluster hosts

scientific article published on 21 April 2015

Supramolecular catalysis of a unimolecular transformation: aza-Cope rearrangement within a self-assembled host

scientific article published in December 2004

Supramolecular catalysis of orthoformate hydrolysis in basic solution: an enzyme-like mechanism

scientific article

Supramolecular catalysis of unimolecular rearrangements: substrate scope and mechanistic insights

scientific article published in August 2006

Synthesis and coordination chemistry of tri-substituted benzamidrazones

scientific article published on November 25, 2010

Synthesis and investigation of [Cp(PMe(3))Rh(H)(H(2))](+) and its partially deuterated and tritiated isotopomers: evidence for a hydride/dihydrogen structure

scientific article published in May 2002

Synthesis and properties of oxygen-centered tetradecaimido hexatantalum clusters

scientific article published on January 2007

Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and β-diketiminato ligands.

scientific article published on 27 April 2011

Synthesis and reactivity of the first structurally characterized heterobimetallic complex containing an unsupported bridging sulfur atom

article published in 1989

Synthesis and reactivity of the hydrido- and alkylrhenium methylidene complexes Cp*(PMe3)2(R)Re=CH2 (R = H, CH3).

scientific article published in November 2004

Synthesis and reactivity of the monomeric late-transition-metal parent amido complex [Ir(Cp*)(PMe3)(Ph)(NH2)].

scientific article

Synthesis of Iridium(III) Carboxamides via the Bimetallic Reaction between Cp*(PMe3)IrPh(OH) and [Cp*(PMe3)Ir(Ph)NCR]+

scientific article published on October 18, 1999

Synthesis of Isoquinuclidines from Highly Substituted Dihydropyridines via the Diels–Alder Reaction

scientific article published on January 15, 2013

Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors

scientific article

Synthesis of [RuCl2(NO)2(THF)] and its double C-N bond-forming reactions with alkenes

scientific article published on 7 April 2011

Synthesis of a Benzodiazepine-Derived Rhodium NHC Complex by C−H Bond Activation

scientific article published on May 26, 2008

Synthesis of a Tricyclic Mescaline Analogue by Catalytic C−H Bond Activation

scientific article published on April 17, 2003

Synthesis of a first-row transition metal parent amido complex and carbon monoxide insertion into the amide N-H bond

scientific article

Synthesis of dihydropyridines and pyridines from imines and alkynes via C-H activation

scientific article

Synthesis of mono-substituted 2,2'-bipyridines

scientific article

Synthesis of multicyclic pyridine and quinoline derivatives via intramolecular C-H bond functionalization

scientific article

Synthesis of potent bicyclic bisarylimidazole c-Jun N-terminal kinase inhibitors by catalytic C-H bond activation

scientific article published on January 2007

Synthesis of pyridines from ketoximes and terminal alkynes via C-H bond functionalization

scientific article published on 14 February 2012

Synthesis of trinuclear alkylidyne complexes from dinuclear alkyne complexes and metal hydrides. CIDNP evidence for vinyl radical intermediates in the hydrogenolysis of these clusters

Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)Nb(III) Imido Complexes

scientific article

Synthesis, structural characterization, and quantitative basicity studies of lithium zirconimidate complexes

scientific article published on January 2008

Synthetic and Mechanistic Studies of Strained Heterocycle Opening Reactions Mediated by Zirconium(IV) Imido Complexes

scientific article published in March 2005

The acid hydrolysis mechanism of acetals catalyzed by a supramolecular assembly in basic solution

scientific article

The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations.

scientific article

The hydrophobic effect drives the recognition of hydrocarbons by an anionic metal-ligand cluster

scientific article published on 19 September 2007

The stereoselective formation of bicyclic enamines with bridgehead unsaturation via tandem C-H bond activation/alkenylation/electrocyclization

scientific article

The thermodynamic driving force for CH activation at iridium

scholarly article by Page O. Stoutland et al published January 1988 in Polyhedron

Theoretical study of the rhenium-alkane interaction in transition metal-alkane sigma-complexes

scholarly article

Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination.

scientific article published on 11 September 2017

Total synthesis of (+)-lithospermic acid by asymmetric intramolecular alkylation via catalytic C-H bond activation

scientific article

Ultrafast UV pump/IR probe studies of C-H activation in linear, cyclic, and aryl hydrocarbons.

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