List of works - Eva Hevia

A Record-Breaking Magnesium Hydride Molecular Cluster: Implications for Hydrogen Storage

article

A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base

scientific article published in September 2004

A new polymeric alkyl/alkoxide magnesium–sodium inverse crown complex

scientific article published on 29 June 2011

A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide

scientific article

Accessing Sodium Ferrate Complexes Containing Neutral and Anionic N-Heterocyclic Carbene Ligands: Structural, Synthetic, and Magnetic Insights

scientific article published on 02 September 2015

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

article

Activation of Ancillary Ligands in the Reactions of DMAD with Phosphido and Alkylideneamido Rhenium Complexes

scholarly article by Luciano Cuesta et al published March 2005 in Organometallics

Activation of a 1,10-phenanthroline ligand on a rhenium tricarbonyl complex

scientific article published on 22 November 2004

Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates

scientific article published on 02 May 2019

Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic Molecule

article

Alkali-Metal-Mediated Zincation of Anisole: Synthesis and Structures of Three Instructive Ortho-Zincated Complexes

article

Alkali-Metal-Mediated Zincation of Ferrocene: Synthesis, Structure, and Reactivity of a Lithium Tmp/Zincate Reagent

article

Alkali-Metal-Mediated Zincation of Polycyclic Aromatic Hydrocarbons: Synthesis and Structures of Mono- and Dizincated Naphthalenes

article

Alkali-metal mediated zincation of N-heterocyclic substrates using the lithium zincate complex, (THF)Li(TMP)Zn(tBu)2 and applications in in situ cross coupling reactions

Alkali-metal-mediated manganationII of functionalized arenes and applications of ortho-manganated products in Pd-catalyzed cross-coupling reactions with iodobenzene.

scientific article published on January 2008

Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry: Zn–H exchange reactions and structural authentication of a dinuclear Au(i) complex with a NHC anion

Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali-Metal Amides under Air

scientific article published on 21 July 2020

Assessing the reactivity of sodium alkyl-magnesiates towards quinoxaline: single electron transfer (SET) vs. nucleophilic alkylation processes

article published in 2016

Assessing the reactivity of sodium zincate [(TMEDA)Na(TMP)ZntBu2] towards benzoylferrocene: deprotonative metalationvs.alkylation reactions

scientific article published on 24 October 2011

Boosting Conjugate Addition to Nitroolefins Using Lithium Tetraorganozincates: Synthetic Strategies and Structural Insights

scientific article published on 17 March 2020

Building an extended inverse crown motif via alkali-metal-mediated alpha-magnesiation of furan

scientific article published in January 2006

C-N Bond Activation and Ring Opening of a Saturated N-Heterocyclic Carbene by Lateral Alkali-Metal-Mediated Metalation

scientific article

Closer insight into the reactivity of TMP-dialkyl zincates in directed ortho-zincation of anisole: experimental evidence of amido basicity and structural elucidation of key reaction intermediates

scientific article published on February 2009

Co-complexation Syntheses, Structural Characterization, and DFT Studies of a Novel Series of Polymeric Alkali-Metal Tetraorganogallates

Combination of organocatalytic oxidation of alcohols and organolithium chemistry (RLi) in aqueous media, at room temperature and under aerobic conditions

scientific article published on 08 July 2020

Concealed cyclotrimeric polymorph of lithium 2,2,6,6-tetramethylpiperidide unconcealed: X-ray crystallographic and NMR spectroscopic studies

scientific article published on 9 September 2013

Contacted Ion-Pair Lithium Alkylamidoaluminates: Intramolecular Alumination (Al−H Exchange) Traps for TMEDA and PMDETA

article

Cover Picture: Alkali-Metal-Mediated Manganation(II) of Functionalized Arenes and Applications ofortho-Manganated Products in Pd-Catalyzed Cross-Coupling Reactions with Iodobenzene (Chem. Eur. J. 1/2008)

Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

scientific article published in October 2013

Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)3(bipy)] (R = H or Me): N–H vs. Re–N

scientific article published on 01 September 2002

Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs.Si-O bond cleavage.

scientific article published on 20 April 2009

Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation

scientific article (publication date: 2 June 2006)

Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation

article

Donor-Activated Lithiation and Sodiation of Trifluoromethylbenzene: Structural, Spectroscopic, and Theoretical Insights

article

Donor-dictated interlocking co-complexation reactions of LiNHDipp with dimethylzinc: synthesis and structures of new methyl(amido)zincates.

scientific article published in June 2009

Donor-influenced Structure-Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido-Monohydrido-Dialkylaluminates

scientific article published on 13 June 2018

Electronic Structure and Excited States of Rhenium(I) Amido and Phosphido Carbonyl−Bipyridine Complexes Studied by Picosecond Time-Resolved IR Spectroscopy and DFT Calculations

scientific article published on 01 November 2006

Expanding Mg-Zn Hybrid Chemistry: Inorganic Salt Effects in Addition Reactions of Organozinc Reagents to Trifluoroacetophenone and the Implications for a Synergistic Lithium-Magnesium-Zinc Activation

article

Exploiting Deep Eutectic Solvents and Organolithium Reagent Partnerships: Chemoselective Ultrafast Addition to Imines and Quinolines Under Aerobic Ambient Temperature Conditions.

scientific article published on 28 November 2016

Exploiting Synergistic Effects in Organozinc Chemistry for Direct Stereoselective C-Glycosylation Reactions at Room Temperature

scientific article published on 05 July 2018

Exposing the hidden complexity of stoichiometric and catalytic metathesis reactions by elucidation of Mg-Zn hybrids

scientific article

Heavier Alkali-metal Gallates as Platforms for Accessing Functionalized Abnormal NHC Carbene-Gallium Complexes

Innentitelbild: Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases (Angew. Chem. 42/2008)

Insertion and Cycloaddition Reactivity of a Transition-Metal N-Metalloimine

scientific article published on 01 October 2002

Insertion of unsaturated organic electrophiles into molybdenumbond-alkoxide and rheniumbond-alkoxide bonds of neutral, stable carbonyl complexes

scientific article published in October 2002

Inside Cover: Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases (Angew. Chem. Int. Ed. 42/2008)

Introducing Glycerol as a Sustainable Solvent to Organolithium Chemistry: Ultrafast Chemoselective Addition of Aryllithium Reagents to Nitriles under Air and at Ambient Temperature

scientific article published on 27 November 2017

Introducing deep eutectic solvents to polar organometallic chemistry: chemoselective addition of organolithium and Grignard reagents to ketones in air.

scientific article published on 25 April 2014

Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

scientific article published on 23 September 2004

Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry.

scientific article published on 12 October 2007

Isomeric and chemical consequences of the direct magnesiation of 1,3-benzoazoles using β-diketiminate-stabilized magnesium bases

article

Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane

article

LiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

scientific article published on 29 June 2017

LiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

article

Ligand-induced reactivity of β-diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C-H or C-F bond activations

scientific article published on 5 October 2017

Lithium Dimethyl(amido)zinc Complexes: Contrasting Zincate (Amido = TMP) and Inverse Zincate (Amido = HMDS) Structures on Addition of TMEDA

article

Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

scientific article published on 16 January 2018

Lithium-mediated Ferration of Fluoroarenes

scientific article published on 01 November 2020

Magnesium-Mediated Benzothiazole Activation: A Room-Temperature Cascade of CH Deprotonation, CC Coupling, Ring-Opening, and Nucleophilic Addition Reactions

article

Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes

scientific article published on 01 April 2019

Manganese(I) and Rhenium(I) Tricarbonyl (Alkylthio)methyl and Alkylidenesulfonium Complexes

scholarly article by Eva Hevia et al published November 2002 in Organometallics

Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

scientific article published on 06 September 2011

Metalation of 2,4,6-Trimethylacetophenone Using Organozinc Reagents: The Role of the Base in Determining Composition and Structure of the Developing Enolate

article

Molecular Manipulations of a Utility Nitrogen-Heterocyclic Carbene by Sodium Magnesiate Complexes and Transmetallation Chemistry with Gold Complexes

scientific article published on 19 June 2018

Mono- and Dimetallic Cyano Complexes with {Mo(η3-allyl)(CO)2(N−N)} Fragments

article published in 2003

New Octahedral Rhenium(I) Tricarbonyl Amido Complexes

scholarly article by Eva Hevia et al published April 2002 in Organometallics

New expeditions in polar organometallic chemistry

scientific article published on 01 October 2014

New insights into addition reactions of dialkylzinc reagents to trifluoromethyl ketones: structural authentication of a beta-hydride elimination product containing a tetranuclear zinc chain

scientific article published on 10 September 2009

New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation

scientific article published on 11 January 2012

New supramolecular assemblies in heterobimetallic chemistry: synthesis of a homologous series of unsolvated alkali-metal zincates

scientific article published in October 2014

New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands

scientific article

Organolithium-Initiated Polymerization of Olefins in Deep Eutectic Solvents under Aerobic Conditions

scientific article published on 02 May 2019

Organozinc pivalate reagents: segregation, solubility, stabilization, and structural insights

scientific article published on 31 January 2014

Polar organometallic strategies for regioselective C-H metallation of N-heterocyclic carbenes.

scientific article published on 7 February 2018

Post-Metalation Structural Insights into the Use of Alkali-Metal-Mediated Zincation for Directedortho-Metalation of a Tertiary Aromatic Amide

article

Potassium-alkyl magnesiates: synthesis, structures and Mg–H exchange applications of aromatic and heterocyclic substrates

article

Pre-Metalation Structural Insights into the Use of Alkali-Metal-Mediated Zincation for Directedortho-Metalation of a Tertiary Aromatic Amide

article

Preparation of Polyfunctional Arylzinc Organometallics in Toluene by Halogen/Zinc Exchange Reactions

scientific article published on 19 July 2019

Probing the metallating ability of a polybasic sodium alkylmagnesiate supported by a bulky bis(amido) ligand: deprotomagnesiation reactions of nitrogen-based aromatic substrates.

scientific article published in March 2014

Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights† †Dedicated to the memory of Paul von R. Schleyer. ‡ ‡Electronic supplementary information (ESI) available: CIF files gi

scientific article published on 3 July 2015

Reactive Alkoxide Complexes of Groups 6 and 7 Metals

Reactivity of Molybdenum and Rhenium Hydroxo Complexes toward Organic Electrophiles: Reactions that Afford Carboxylato Products§

article

Reactivity of Polar Organometallic Compounds in Unconventional Reaction Media: Challenges and Opportunities

Reactivity of Polar Organometallic Compounds in Unconventional Reaction Media: Challenges and Opportunities (Eur. J. Org. Chem. 31/2015)

Reactivity of molybdenum and rhenium hydroxo-carbonyl complexes toward organic electrophiles

scientific article published in April 2004

Reactivity of the Amido Complex [Re(NHpTol)(CO)3(bipy)] toward Neutral Organic Electrophiles

Regioselective Bromine/Magnesium-Exchange for Selective Functionalization of Polyhalogenated Aromatics and Heterocycles

scientific article published on 20 October 2020

Regioselective magnesiation of N-heterocyclic molecules: securing insecure cyclic anions by a β-diketiminate-magnesium clamp

scientific article published on 19 January 2017

Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation

scientific article published in May 2005

Shedding New Light on ZnCl2-Mediated Addition Reactions of Grignard Reagents to Ketones: Structural Authentication of Key Intermediates and Diffusion-Ordered NMR Studies

article

Sodium dialkyl-amidozincates: alkyl or amido bases? An experimental and theoretical case study

scientific article published in May 2005

Solvent-Free and TMEDA-Solvated Mixed Alkali Metal-Magnesium Tris-diisopropylamides

article

Split Personality of Lithium Chloride: Recent Salt Effects in Organometallic Recipes

article

Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

article

Structural and Magnetic Diversity in Alkali-Metal Manganate Chemistry: Evaluating Donor and Alkali-Metal Effects in Co-complexation Processes

scientific article

Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines

scientific article published on 27 October 2016

Structural and Synthetic Insights into Pyridine Homocouplings Mediated by a β-Diketiminato Magnesium Amide Complex

scientific article published on 07 September 2018

Structural and reactivity insights in Mg–Zn hybrid chemistry: Zn–I exchange and Pd-catalysed cross-coupling applications of aromatic substrates

article

Structural basis for regioisomerization in the alkali-metal-mediated zincation (AMMZn) of trifluoromethyl benzene by isolation of kinetic and thermodynamic intermediates.

scientific article published on July 2010

Structural variations in bimetallic sodium–magnesium and sodium–zinc ketimides, and a sodium–zinc alkide–alkoxide–amide: connections to ring-stacking, ring-laddering, and inverse crown concepts

article

Structurally Defined Reactions of Sodium TMP–Zincate with Nitrile Compounds: Synthesis of a Salt-Like Sodium Sodiumdizincate and Other Unexpected Ion-Pair Products

article

Structurally Defined Zincated and Aluminated Complexes of Ferrocene Made by Alkali-Metal Synergistic Syntheses

article

Structurally defined potassium-mediated zincation of pyridine and 4-R-substituted pyridines (R = Et, iPr, tBu, Ph, and Me2N) by using dialkyl-TMP-zincate bases

scientific article published on July 2009

Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation

article

Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines

scientific article published on 16 May 2008

Synergic Monodeprotonation of Bis(benzene)chromium by Using Mixed Alkali Metal-Magnesium Amide Bases and Structural Characterization of the Heterotrimetallic Products

article

Synergic Para-Directed Monometalation of Bis(toluene)chromium by Alkali-Metal-Mediated Magnesiation

article

Synergic Synthesis of Benzannulated Zincabicyclic Complexes, α-Zincated N Ylides, through Sodium-TMEDA-Mediated Zincation of a Haloarene

article

Synthesis and Characterization of New Mixed-Metal Sodium−Magnesium Enolates Derived from 2,4,6-Trimethylacetophenone†

article

Synthesis and Crystal Structure of[{nBuMg(μ-TMP)}2] and of a Homometallic Inverse Crown in Tetranuclear[{nBuMg2[μ-N(H)Dipp]2(μ3-OnBu)}2]

article

Synthesis and Reactivity of New (Methoxy)methyl Complexes of Manganese(I) and Rhenium(I)

Synthesis and Structural Elucidation of Alkyl, Amido, and Mixed Alkyl−Amido “Highly-Coordinated” Zincates

Synthesis and characterisation of a series of alkylmagnesium amide and related oxygen-contaminated "alkoxy" compounds

scientific article published on 8 March 2005

Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetylides: structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates.

scientific article published on 14 February 2008

Synthesis and characterization of an infinite sheet of metal–alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

article

Synthesis and structural elucidation of solvent-free and solvated lithium dimethyl (HMDS) zincates

scientific article

Synthesis of Mixed Alkali-Metal−Zinc Enolate Complexes Derived from 2,4,6-Trimethylacetophenone: New Inverse Crown Structures

article

Synthesis of beta-lactams from a N-rhenaimine: effect of the transition metal on the energetic profile of the Staudinger reaction

scientific article published in April 2003

Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†

article

Synthesis, Structural Elucidation, and Diffusion-Ordered NMR Studies of Homoleptic Alkyllithium Magnesiates: Donor-Controlled Structural Variations in Mixed-Metal Chemistry

article

Synthesis, Structure and Solution Studies on Mixed Aryl/Alkyl Lithium Zincates

Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation

scientific article published in January 2009

Synthetic, structural and magnetic implications of introducing 2,2'-dipyridylamide to sodium-ferrate complexes.

scientific article published in May 2017

TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases: lithium-mediated alumination or lithiation–alkylaluminium-trapping reagents?

article

Tandem Mn-I exchange and homocoupling processes mediated by a synergistically operative lithium manganate

scientific article published on 22 October 2020

The Future of Polar Organometallic Chemistry Written in Bio-Based Solvents and Water

scientific article published on 20 September 2018

Towards a Paradigm Shift in Polar Organometallic Chemistry

scientific article published on 01 September 2020

Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C-H Functionalizations.

scientific article published on 9 May 2017

Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.

scientific article

Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping

scientific article published on 20 September 2016

Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping

article

Trapping, stabilization, and characterization of an enolate anion of a 1,6-adduct of benzophenone chelated by a sodium alkylamidozincate cation

scientific article published in September 2005

Two alternative approaches to access mixed hydride-amido zinc complexes: synthetic, structural and solution implications

scientific article

Ultrafast amidation of esters using lithium amides under aerobic ambient temperature conditions in sustainable solvents

scientific article published on 30 April 2020

Understanding the Subtleties of Frustrated Lewis Pair Activation of Carbonyl Compounds by N-Heterocyclic Carbene/Alkyl Gallium Pairings.

scientific article published on 26 September 2016

Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

article

Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

Untangling the Complexity of Mixed Lithium/Magnesium Alkyl/Alkoxy Combinations Utilised in Br/Mg Exchange Reactions

scientific article published on 06 January 2021

Utilising Sodium-Mediated Ferration for Regioselective Functionalisation of Fluoroarenes via C-H and C-F Bond Activations.

scientific article published on 25 October 2017

Utilising Sodium-Mediated Ferration for Regioselective Functionalisation of Fluoroarenes via C−H and C−F Bond Activations

Zincate-Mediated Arylation Reactions of Acridine: Pre- and Postarylation Structural Insights

s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols

scientific article published on 14 May 2019

List of works by Eva Hevia

A Record-Breaking Magnesium Hydride Molecular Cluster: Implications for Hydrogen Storage

A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base

A new polymeric alkyl/alkoxide magnesium–sodium inverse crown complex

A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide

Accessing Sodium Ferrate Complexes Containing Neutral and Anionic N-Heterocyclic Carbene Ligands: Structural, Synthetic, and Magnetic Insights

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

Activation of Ancillary Ligands in the Reactions of DMAD with Phosphido and Alkylideneamido Rhenium Complexes

Activation of a 1,10-phenanthroline ligand on a rhenium tricarbonyl complex

Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates

Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic Molecule

Alkali-Metal-Mediated Zincation of Anisole: Synthesis and Structures of Three Instructive Ortho-Zincated Complexes

Alkali-Metal-Mediated Zincation of Ferrocene: Synthesis, Structure, and Reactivity of a Lithium Tmp/Zincate Reagent

Alkali-Metal-Mediated Zincation of Polycyclic Aromatic Hydrocarbons: Synthesis and Structures of Mono- and Dizincated Naphthalenes

Alkali-metal mediated zincation of N-heterocyclic substrates using the lithium zincate complex, (THF)Li(TMP)Zn(tBu)2 and applications in in situ cross coupling reactions

Alkali-metal-mediated manganationII of functionalized arenes and applications of ortho-manganated products in Pd-catalyzed cross-coupling reactions with iodobenzene.

Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry: Zn–H exchange reactions and structural authentication of a dinuclear Au(i) complex with a NHC anion

Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali-Metal Amides under Air

Assessing the reactivity of sodium alkyl-magnesiates towards quinoxaline: single electron transfer (SET) vs. nucleophilic alkylation processes

Assessing the reactivity of sodium zincate [(TMEDA)Na(TMP)ZntBu2] towards benzoylferrocene: deprotonative metalationvs.alkylation reactions

Boosting Conjugate Addition to Nitroolefins Using Lithium Tetraorganozincates: Synthetic Strategies and Structural Insights

Building an extended inverse crown motif via alkali-metal-mediated alpha-magnesiation of furan

C-N Bond Activation and Ring Opening of a Saturated N-Heterocyclic Carbene by Lateral Alkali-Metal-Mediated Metalation

Closer insight into the reactivity of TMP-dialkyl zincates in directed ortho-zincation of anisole: experimental evidence of amido basicity and structural elucidation of key reaction intermediates

Co-complexation Syntheses, Structural Characterization, and DFT Studies of a Novel Series of Polymeric Alkali-Metal Tetraorganogallates

Combination of organocatalytic oxidation of alcohols and organolithium chemistry (RLi) in aqueous media, at room temperature and under aerobic conditions

Concealed cyclotrimeric polymorph of lithium 2,2,6,6-tetramethylpiperidide unconcealed: X-ray crystallographic and NMR spectroscopic studies

Contacted Ion-Pair Lithium Alkylamidoaluminates: Intramolecular Alumination (Al−H Exchange) Traps for TMEDA and PMDETA

Cover Picture: Alkali-Metal-Mediated Manganation(II) of Functionalized Arenes and Applications ofortho-Manganated Products in Pd-Catalyzed Cross-Coupling Reactions with Iodobenzene (Chem. Eur. J. 1/2008)

Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)3(bipy)] (R = H or Me): N–H vs. Re–N

Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs.Si-O bond cleavage.

Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation

Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation

Donor-Activated Lithiation and Sodiation of Trifluoromethylbenzene: Structural, Spectroscopic, and Theoretical Insights

Donor-dictated interlocking co-complexation reactions of LiNHDipp with dimethylzinc: synthesis and structures of new methyl(amido)zincates.

Donor-influenced Structure-Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido-Monohydrido-Dialkylaluminates

Electronic Structure and Excited States of Rhenium(I) Amido and Phosphido Carbonyl−Bipyridine Complexes Studied by Picosecond Time-Resolved IR Spectroscopy and DFT Calculations

Expanding Mg-Zn Hybrid Chemistry: Inorganic Salt Effects in Addition Reactions of Organozinc Reagents to Trifluoroacetophenone and the Implications for a Synergistic Lithium-Magnesium-Zinc Activation

Exploiting Deep Eutectic Solvents and Organolithium Reagent Partnerships: Chemoselective Ultrafast Addition to Imines and Quinolines Under Aerobic Ambient Temperature Conditions.

Exploiting Synergistic Effects in Organozinc Chemistry for Direct Stereoselective C-Glycosylation Reactions at Room Temperature

Exposing the hidden complexity of stoichiometric and catalytic metathesis reactions by elucidation of Mg-Zn hybrids

Heavier Alkali-metal Gallates as Platforms for Accessing Functionalized Abnormal NHC Carbene-Gallium Complexes

Innentitelbild: Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases (Angew. Chem. 42/2008)

Insertion and Cycloaddition Reactivity of a Transition-Metal N-Metalloimine

Insertion of unsaturated organic electrophiles into molybdenumbond-alkoxide and rheniumbond-alkoxide bonds of neutral, stable carbonyl complexes

Inside Cover: Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases (Angew. Chem. Int. Ed. 42/2008)

Introducing Glycerol as a Sustainable Solvent to Organolithium Chemistry: Ultrafast Chemoselective Addition of Aryllithium Reagents to Nitriles under Air and at Ambient Temperature

Introducing deep eutectic solvents to polar organometallic chemistry: chemoselective addition of organolithium and Grignard reagents to ketones in air.

Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry.

Isomeric and chemical consequences of the direct magnesiation of 1,3-benzoazoles using β-diketiminate-stabilized magnesium bases

Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane

LiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

LiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

Ligand-induced reactivity of β-diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C-H or C-F bond activations

Lithium Dimethyl(amido)zinc Complexes: Contrasting Zincate (Amido = TMP) and Inverse Zincate (Amido = HMDS) Structures on Addition of TMEDA

Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

Lithium-mediated Ferration of Fluoroarenes

Magnesium-Mediated Benzothiazole Activation: A Room-Temperature Cascade of CH Deprotonation, CC Coupling, Ring-Opening, and Nucleophilic Addition Reactions

Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes

Manganese(I) and Rhenium(I) Tricarbonyl (Alkylthio)methyl and Alkylidenesulfonium Complexes

Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

Metalation of 2,4,6-Trimethylacetophenone Using Organozinc Reagents: The Role of the Base in Determining Composition and Structure of the Developing Enolate

Molecular Manipulations of a Utility Nitrogen-Heterocyclic Carbene by Sodium Magnesiate Complexes and Transmetallation Chemistry with Gold Complexes

Mono- and Dimetallic Cyano Complexes with {Mo(η3-allyl)(CO)2(N−N)} Fragments

New Octahedral Rhenium(I) Tricarbonyl Amido Complexes

New expeditions in polar organometallic chemistry

New insights into addition reactions of dialkylzinc reagents to trifluoromethyl ketones: structural authentication of a beta-hydride elimination product containing a tetranuclear zinc chain

New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation

New supramolecular assemblies in heterobimetallic chemistry: synthesis of a homologous series of unsolvated alkali-metal zincates

New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands

Organolithium-Initiated Polymerization of Olefins in Deep Eutectic Solvents under Aerobic Conditions

Organozinc pivalate reagents: segregation, solubility, stabilization, and structural insights

Polar organometallic strategies for regioselective C-H metallation of N-heterocyclic carbenes.

Post-Metalation Structural Insights into the Use of Alkali-Metal-Mediated Zincation for Directedortho-Metalation of a Tertiary Aromatic Amide

Potassium-alkyl magnesiates: synthesis, structures and Mg–H exchange applications of aromatic and heterocyclic substrates

Pre-Metalation Structural Insights into the Use of Alkali-Metal-Mediated Zincation for Directedortho-Metalation of a Tertiary Aromatic Amide

Preparation of Polyfunctional Arylzinc Organometallics in Toluene by Halogen/Zinc Exchange Reactions

Probing the metallating ability of a polybasic sodium alkylmagnesiate supported by a bulky bis(amido) ligand: deprotomagnesiation reactions of nitrogen-based aromatic substrates.