List of works - Catherine Cazin

A cooperative Pd-Cu system for direct C-H bond arylation

scientific article published on 01 August 2014

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

scientific article published on November 2013

A new stable C(NHC)--CH--C(NHC)N-heterocyclic dicarbene ligand: its mono- and dinuclear Ir(I) and Ir(I)-Rh(I) complexes.

scientific article published on 30 March 2009

A novel catalytic one-pot synthesis of carbazoles via consecutive amination and C-H activation

scientific article published on 01 October 2002

A simple access to transition metal cyclopropenylidene complexes

scientific article published in 2015

A simple synthetic entryway into palladium cross-coupling catalysis

scientific article published on 01 July 2017

Activation of hydrogen by palladium(0): formation of the mononuclear dihydride complex trans-[Pd(H)2(IPr)(PCy3)].

scientific article published in January 2009

Aerobic synthesis of N-sulfonylamidines mediated by N-heterocyclic carbene copper(I) catalysts

scientific article published on 24 March 2020

An unprecedented, figure-of-eight, dinuclear iridium(I) dicarbene and new iridium(III) 'pincer' complexes

scientific article published on 01 August 2008

An unusual cationic Ru(II) indenylidene complex and its Ru(III) derivative--efficient catalysts for high temperature olefin metathesis reactions

scientific article published on 16 December 2011

Carboxylation of NH/CH Bonds Using N-Heterocyclic Carbene Copper(I) Complexes

scientific article published on 01 November 2010

Copper N-Heterocyclic Carbene Complexes As Active Catalysts for the Synthesis of 2-Substituted Oxazolines from Nitriles and Aminoalcohols

scientific article published on 01 October 2015

Copper N-heterocyclic carbene (NHC) complexes as carbene transfer reagents

scientific article published on 23 August 2010

Copper N-heterocyclic carbene complexes in catalysis

Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry”

scientific article published on 12 October 2015

Copper(i)-NHC complexes as NHC transfer agents

scientific article published on 24 November 2016

Cu-NHC azide complex: synthesis and reactivity

scientific article published on 01 October 2019

Decarboxylation of aromatic carboxylic acids by gold(i)-N-heterocyclic carbene (NHC) complexes

scientific article published on 01 April 2011

Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides

scientific article published on 22 October 2004

Electronic effects in mixed N-heterocyclic carbene/phosphite indenylidene ruthenium metathesis catalysts

scientific article published on 05 July 2019

Energetics of the ruthenium-halide bond in olefin metathesis (pre)catalysts

scientific article published in May 2013

Enthalpies of ligand substitution for [Mo(η5C5H5)(CO)2(NO)] – The role of π-bonding effects in metal–ligand bond strengths

Expedient Syntheses of Neutral and Cationic Au(I)–NHC Complexes

Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes

scientific article published on 30 May 2016

Gold(i) catalysed regio- and stereoselective intermolecular hydroamination of internal alkynes: towards functionalised azoles

scientific article published on 01 April 2019

High-Activity Catalysts for Suzuki Coupling and Amination Reactions with Deactivated Aryl Chloride Substrates: Importance of the Palladium Source

Highly Active Well-Defined Palladium Precatalysts for the Efficient Amination of Aryl Chlorides

Highly Active [Pd(μ-Cl)(Cl)(NHC)]2(NHC = N-Heterocyclic Carbene) in the Cross-Coupling of Grignard Reagents with Aryl Chlorides

Highly Active [Pd(μ-Cl)Cl(NHC)]2Complexes in the Mizoroki-Heck Reaction

Highly active catalysts for the Suzuki coupling of aryl chlorides.

scientific article published in September 2001

Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls (PCBs).

scientific article published on 7 September 2009

Homoleptic and heteroleptic bis-NHC Cu(I) complexes as carbene transfer reagents

scientific article published in March 2016

Hydrogenation of CC Multiple Bonds Mediated by [Pd(NHC)(PCy3)] (NHC=N-Heterocyclic Carbene) under Mild Reaction Conditions

scientific article published on 01 March 2009

Hydrophenoxylation of internal alkynes catalysed with a heterobimetallic Cu-NHC/Au-NHC system

scientific article published on 11 January 2017

Influence of a Very BulkyN-Heterocyclic Carbene in Gold-Mediated Catalysis

Inner-Sphere versus Outer-Sphere Coordination of BF4– in a NHC-Gold(I) Complex

Insights into the Catalytic Activity of [Pd(NHC)(cin)Cl] (NHC=IPr, IPrCl , IPrBr ) Complexes in the Suzuki-Miyaura Reaction

Investigating the Structure and Reactivity of Azolyl-Based Copper(I)–NHC Complexes: The Role of the Anionic Ligand

scientific article published in November 2017

Ligand-Directed Reactivity in Dioxygen and Water Binding to cis-[Pd(NHC)2(η2-O2)].

scientific article published on 27 November 2017

Mixed N-Heterocyclic Carbene/Phosphite Ruthenium Complexes: The Effect of a Bulkier NHC

Mixed N-heterocyclic carbene/phosphite ruthenium complexes: towards a new generation of olefin metathesis catalysts

scientific article published on 27 August 2010

Mixed Phosphite/N-Heterocyclic Carbene Complexes: Synthesis, Characterization and Catalytic Studies

Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki-Miyaura reactions

scientific article published on 01 May 2013

Mono- and dinuclear cobalt complexes with chelating or bridging bidentate P,N phosphino- and phosphinito-oxazoline ligands: synthesis, structures and catalytic ethylene oligomerisation.

scientific article published on 13 August 2007

N-Heterocyclic Carbene Gold(I) and Copper(I) Complexes in C–H Bond Activation ⬇️

scientific article published on December 13, 2011

N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2.

scientific article published on 30 September 2015

Neutral Dinuclear Copper(I)-NHC Complexes: Synthesis and Application in the Hydrosilylation of Ketones

scientific article published on 6 December 2016

Oxygen Binding to [Pd(L)(L′)] (L= NHC, L′ = NHC or PR3, NHC =N-Heterocyclic Carbene). Synthesis and Structure of a Paramagnetictrans-[Pd(NHC)2(η1-O2)2] Complex

scientific article published on 04 January 2011

Palladium(0) NHC complexes: a new avenue to highly efficient phosphorescence

scientific article published on 2 April 2015

Phosphite ligands in Ru-based olefin metathesis catalysts

Phosphites as ligands in ruthenium-benzylidene catalysts for olefin metathesis

scientific article published on 31 May 2011

Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(micro-Cl)Cl(NHC)]2 complex (NHC = N-heterocyclic carbene).

scientific article published on 12 May 2008

Ruthenium Olefin Metathesis Catalysts Containing Fluoride

Ruthenium indenylidene "1(st) generation" olefin metathesis catalysts containing triisopropyl phosphite

scientific article

Ruthenium-Indenylidene and Other Alkylidene Containing Olefin Metathesis Catalysts

Sequential Functionalization of Alkynes and Alkenes Catalyzed by Gold(I) and Palladium(II) N-Heterocyclic Carbene Complexes

Simple and versatile synthesis of copper and silver N-heterocyclic carbene complexes in water or organic solvents

scientific article published in May 2010

Simple mixed tricyclohexylphosphane-triarylphosphite complexes as extremely high-activity catalysts for the Suzuki coupling of aryl chlorides

scientific article published on 01 November 2002

Simple tricyclohexylphosphine-palladium complexes as efficient catalysts for the Stille coupling of deactivated aryl chlorides

scientific article

Structure and reactivity of new iridium complexes with bis(oxazoline)-phosphonito ligands

scientific article published in December 2009

Synthesis and Reactivity of Ruthenium Phosphite Indenylidene Complexes

scientific article published on 16 October 2012

Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

scientific article published on 01 June 2019

Synthesis of Homoleptic and Heteroleptic Bis-N-heterocylic Carbene Group 11 Complexes

scientific article published on 8 January 2015

Synthetic Access to Ring-Expanded N-Heterocyclic Carbene (RE-NHC) Copper Complexes and Their Performance in Click Chemistry

scientific article published in 2021

Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

scientific article published on 20 December 2012

The Isolation of [Pd{OC(O)H}(H)(NHC)(PR3)] (NHC = N-Heterocyclic Carbene) and Its Role in Alkene and Alkyne Reductions Using Formic Acid

scientific article published on 14 January 2013

The role of the metal in the dual-metal catalysed hydrophenoxylation of diphenylacetylene

scientific article published in 2018

Towards environmentally friendlier Suzuki–Miyaura reactions with precursors of Pd-NHC (NHC = N-heterocyclic carbene) complexes

Transition Metal-Catalyzed Carboxylation of Organic Substrates with Carbon Dioxide

Transition metal bifluorides

[Pd(IPr*)(cinnamyl)Cl]: An Efficient Pre-catalyst for the Preparation of Tetra-ortho-substituted Biaryls by Suzuki-Miyaura Cross-Coupling

scientific article published on 13 March 2012

[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen

scientific article published on 01 October 2012

[Pd(μ-Cl)Cl(IPr*)]2: a highly hindered pre-catalyst for the synthesis of tetra-ortho-substituted biaryls via Grignard reagent cross-coupling

scientific article published on 26 June 2014

List of works by Catherine Cazin

A cooperative Pd-Cu system for direct C-H bond arylation

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

A new stable C(NHC)--CH--C(NHC)N-heterocyclic dicarbene ligand: its mono- and dinuclear Ir(I) and Ir(I)-Rh(I) complexes.

A novel catalytic one-pot synthesis of carbazoles via consecutive amination and C-H activation

A simple access to transition metal cyclopropenylidene complexes

A simple synthetic entryway into palladium cross-coupling catalysis

Activation of hydrogen by palladium(0): formation of the mononuclear dihydride complex trans-[Pd(H)2(IPr)(PCy3)].

Aerobic synthesis of N-sulfonylamidines mediated by N-heterocyclic carbene copper(I) catalysts

An unprecedented, figure-of-eight, dinuclear iridium(I) dicarbene and new iridium(III) 'pincer' complexes

An unusual cationic Ru(II) indenylidene complex and its Ru(III) derivative--efficient catalysts for high temperature olefin metathesis reactions

Carboxylation of NH/CH Bonds Using N-Heterocyclic Carbene Copper(I) Complexes

Copper N-Heterocyclic Carbene Complexes As Active Catalysts for the Synthesis of 2-Substituted Oxazolines from Nitriles and Aminoalcohols

Copper N-heterocyclic carbene (NHC) complexes as carbene transfer reagents

Copper N-heterocyclic carbene complexes in catalysis

Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry”

Copper(i)-NHC complexes as NHC transfer agents

Cu-NHC azide complex: synthesis and reactivity

Decarboxylation of aromatic carboxylic acids by gold(i)-N-heterocyclic carbene (NHC) complexes

Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides

Electronic effects in mixed N-heterocyclic carbene/phosphite indenylidene ruthenium metathesis catalysts

Energetics of the ruthenium-halide bond in olefin metathesis (pre)catalysts

Enthalpies of ligand substitution for [Mo(η5C5H5)(CO)2(NO)] – The role of π-bonding effects in metal–ligand bond strengths

Expedient Syntheses of Neutral and Cationic Au(I)–NHC Complexes

Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes

Gold(i) catalysed regio- and stereoselective intermolecular hydroamination of internal alkynes: towards functionalised azoles

High-Activity Catalysts for Suzuki Coupling and Amination Reactions with Deactivated Aryl Chloride Substrates: Importance of the Palladium Source

High-Activity Catalysts for Suzuki Coupling and Amination Reactions with Deactivated Aryl Chloride Substrates: Importance of the Palladium Source

Highly Active Well-Defined Palladium Precatalysts for the Efficient Amination of Aryl Chlorides

Highly Active [Pd(μ-Cl)(Cl)(NHC)]2(NHC = N-Heterocyclic Carbene) in the Cross-Coupling of Grignard Reagents with Aryl Chlorides

Highly Active [Pd(μ-Cl)Cl(NHC)]2Complexes in the Mizoroki-Heck Reaction

Highly active catalysts for the Suzuki coupling of aryl chlorides.

Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls (PCBs).

Homoleptic and heteroleptic bis-NHC Cu(I) complexes as carbene transfer reagents

Hydrogenation of CC Multiple Bonds Mediated by [Pd(NHC)(PCy3)] (NHC=N-Heterocyclic Carbene) under Mild Reaction Conditions

Hydrophenoxylation of internal alkynes catalysed with a heterobimetallic Cu-NHC/Au-NHC system

Influence of a Very BulkyN-Heterocyclic Carbene in Gold-Mediated Catalysis

Inner-Sphere versus Outer-Sphere Coordination of BF4– in a NHC-Gold(I) Complex

Insights into the Catalytic Activity of [Pd(NHC)(cin)Cl] (NHC=IPr, IPrCl , IPrBr ) Complexes in the Suzuki-Miyaura Reaction

Investigating the Structure and Reactivity of Azolyl-Based Copper(I)–NHC Complexes: The Role of the Anionic Ligand

Ligand-Directed Reactivity in Dioxygen and Water Binding to cis-[Pd(NHC)2(η2-O2)].

Mixed N-Heterocyclic Carbene/Phosphite Ruthenium Complexes: The Effect of a Bulkier NHC

Mixed N-heterocyclic carbene/phosphite ruthenium complexes: towards a new generation of olefin metathesis catalysts

Mixed Phosphite/N-Heterocyclic Carbene Complexes: Synthesis, Characterization and Catalytic Studies

Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki-Miyaura reactions

Mono- and dinuclear cobalt complexes with chelating or bridging bidentate P,N phosphino- and phosphinito-oxazoline ligands: synthesis, structures and catalytic ethylene oligomerisation.

N-Heterocyclic Carbene Gold(I) and Copper(I) Complexes in C–H Bond Activation ⬇️

N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2.

Neutral Dinuclear Copper(I)-NHC Complexes: Synthesis and Application in the Hydrosilylation of Ketones

Oxygen Binding to [Pd(L)(L′)] (L= NHC, L′ = NHC or PR3, NHC =N-Heterocyclic Carbene). Synthesis and Structure of a Paramagnetictrans-[Pd(NHC)2(η1-O2)2] Complex

Palladium(0) NHC complexes: a new avenue to highly efficient phosphorescence

Phosphite ligands in Ru-based olefin metathesis catalysts

Phosphites as ligands in ruthenium-benzylidene catalysts for olefin metathesis

Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(micro-Cl)Cl(NHC)]2 complex (NHC = N-heterocyclic carbene).

Ruthenium Olefin Metathesis Catalysts Containing Fluoride

Ruthenium indenylidene "1(st) generation" olefin metathesis catalysts containing triisopropyl phosphite

Ruthenium-Indenylidene and Other Alkylidene Containing Olefin Metathesis Catalysts

Sequential Functionalization of Alkynes and Alkenes Catalyzed by Gold(I) and Palladium(II) N-Heterocyclic Carbene Complexes

Simple and versatile synthesis of copper and silver N-heterocyclic carbene complexes in water or organic solvents

Simple mixed tricyclohexylphosphane-triarylphosphite complexes as extremely high-activity catalysts for the Suzuki coupling of aryl chlorides

Simple tricyclohexylphosphine-palladium complexes as efficient catalysts for the Stille coupling of deactivated aryl chlorides

Structure and reactivity of new iridium complexes with bis(oxazoline)-phosphonito ligands

Synthesis and Reactivity of Ruthenium Phosphite Indenylidene Complexes

Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

Synthesis of Homoleptic and Heteroleptic Bis-N-heterocylic Carbene Group 11 Complexes

Synthetic Access to Ring-Expanded N-Heterocyclic Carbene (RE-NHC) Copper Complexes and Their Performance in Click Chemistry

Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

The Isolation of [Pd{OC(O)H}(H)(NHC)(PR3)] (NHC = N-Heterocyclic Carbene) and Its Role in Alkene and Alkyne Reductions Using Formic Acid

The role of the metal in the dual-metal catalysed hydrophenoxylation of diphenylacetylene

Towards environmentally friendlier Suzuki–Miyaura reactions with precursors of Pd-NHC (NHC = N-heterocyclic carbene) complexes

Transition Metal-Catalyzed Carboxylation of Organic Substrates with Carbon Dioxide

Transition metal bifluorides

[Pd(IPr*)(cinnamyl)Cl]: An Efficient Pre-catalyst for the Preparation of Tetra-ortho-substituted Biaryls by Suzuki-Miyaura Cross-Coupling

[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen

[Pd(μ-Cl)Cl(IPr*)]2: a highly hindered pre-catalyst for the synthesis of tetra-ortho-substituted biaryls via Grignard reagent cross-coupling