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List of works by Brian Stoltz

2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters

scientific article

A FISCHER INDOLIZATION STRATEGY TOWARD THE TOTAL SYNTHESIS OF (-)-GONIOMITINE.

scientific article

A New Method for the Cleavage of Nitrobenzyl Amides and Ethers

scientific article published on November 2014

A Second-Generation Synthesis of the Cyanthiwigin Natural Product Core

scientific article published on 20 October 2016

A catalytic, asymmetric formal synthesis of (+)-hamigeran B.

scientific article published on 27 January 2011

A catalytic, enantioselective formal synthesis of (+)-dichroanone and (+)-taiwaniaquinone H.

scientific article published on 9 December 2014

A comprehensive history of arynes in natural product total synthesis

scientific article published on 23 March 2012

A computational model relating structure and reactivity in enantioselective oxidations of secondary alcohols by (-)-sparteine-Pd(II) complexes

scientific article

A concise total synthesis of (-)-quinocarcin via aryne annulation

scientific article

A convergent and enantioselective synthesis of (+)-amurensinine via selective C-H and C-C bond insertion reactions

scientific article published on September 2006

A diastereodivergent synthetic strategy for the syntheses of communesin F and perophoramidine.

scientific article

A facile and modular synthesis of phosphinooxazoline ligands

scientific article

A general approach to the basiliolide/transtaganolide natural products: total syntheses of basiliolide B, epi-8-basiliolide B, transtaganolide C, and transtaganolide D.

scientific article published on 25 March 2011

A general enantioselective route to the chamigrene natural product family

scientific article published on March 2010

A ligand-free solid-supported system for Sonogashira couplings: applications in nucleoside chemistry

scientific article

A mild and efficient approach to enantioenriched α-hydroxyethyl α,β-unsaturated δ-lactams

scientific article published on May 2016

A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres

scientific article published on March 2010

A palladium-catalyzed vinylcyclopropane (3+2) cycloaddition approach to the Melodinus alkaloids.

scientific article published on 25 July 2011

A rapid and convergent synthesis of the integrastatin core

scientific article published on 16 June 2011

A scalable synthesis of the (S)-4-(tert-butyl)-2-(pyridin-2-yl)-4,5-dihydrooxazole ((S)-t-BuPyOx) ligand

scientific article published on 12 August 2013

A unified approach to the daucane and sphenolobane bicyclo[5.3.0]decane core: enantioselective total syntheses of daucene, daucenal, epoxydaucenal B, and 14-para-anisoyloxydauc-4,8-diene

scientific article published on 2 December 2013

A unified synthetic approach to the pyrazinone dragmacidins

scientific article published on 18 July 2006

Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.

scientific article published on 6 February 2017

Alkali Metal-Hydroxide-Catalyzed C(sp)-H Bond silylation

scientific article published on 27 December 2016

An Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst

scientific article published on 14 July 2015

An Unexpected Ireland-Claisen Rearrangement Cascade During the Synthesis of the Tricyclic Core of Curcusone C: Mechanistic Elucidation by Trial-and-Error and Automatic Artificial Force-Induced Reaction (AFIR) Computations

scientific article published on 23 April 2019

An experimentally derived model for stereoselectivity in the aerobic oxidative kinetic resolution of secondary alcohols by (sparteine)PdCl2.

scientific article

Aryne acyl-alkylation in the general and convergent synthesis of benzannulated macrolactone natural products: an enantioselective synthesis of (-)-curvularin

scientific article published in April 2010

Asymmetric Synthesis of All-Carbon Quaternary Spirocycles via a Catalytic Enantioselective Allylic Alkylation Strategy.

scientific article published on 5 July 2017

Asymmetric synthesis of QUINAP via dynamic kinetic resolution

scientific article published on 4 November 2013

Atmospheric autoxidation is increasingly important in urban and suburban North America

scientific article published on 18 December 2017

Benzannulated bicycles by three-component aryne reactions

scientific article published on 11 April 2011

Biosynthesis and chemical synthesis of presilphiperfolanol natural products

scientific article published on 25 April 2014

C-H Bond Functionalizations with Palladium(II): Intramolecular Oxidative Annulations of Arenes

scientific article published on June 2008

Catalyst-Controlled Selective Functionalization of Unactivated C–H Bonds in the Presence of Electronically Activated C–H Bonds

scientific article published on 17 September 2018

Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation.

scientific article published on 27 September 2016

Catalytic C-H bond functionalization with palladiumII: aerobic oxidative annulations of indoles

scientific article published in August 2003

Catalytic C-H bond silylation of aromatic heterocycles

scientific article published on 29 October 2015

Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates

scientific article published on 02 August 2018

Catalytic Reduction of Alkyl and Aryl Bromides Using Propan-2-ol.

scientific article

Catalytic enantioselective alkylation of substituted dioxanone enol ethers: ready access to Calpha-tetrasubstituted hydroxyketones, acids, and esters

scientific article

Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone

scientific article published on January 2009

Catalytic enantioselective construction of quaternary stereocenters: assembly of key building blocks for the synthesis of biologically active molecules.

scientific article published on 25 February 2015

Catalytic enantioselective decarboxylative protonation.

scientific article

Catalytic enantioselective stereoablative alkylation of 3-halooxindoles: facile access to oxindoles with C3 all-carbon quaternary stereocenters

scientific article published in January 2009

Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis

scientific article

Catalytic enantioselective total synthesis of (+)-eucomic acid

scientific article published on 02 March 2016

Characterization of Reactive Organometallic Species via MicroED

scientific article published on 06 September 2019

Characterization of reactive organometallic species via MicroED

ChemInform Abstract: Catalytic Enantioselective Alkylation of Substituted Dioxanone Enol Ethers: Ready Access to C(α)-Tetrasubstituted Hydroxyketones, Acids, and Esters

Concise Syntheses of Δ12-Prostaglandin J Natural Products via Stereoretentive Metathesis

scientific article published on 17 December 2018

Concise total syntheses of (–)-jorunnamycin A and (–)-jorumycin enabled by asymmetric catalysis

scientific article published in Science

Construction of Tertiary Chiral Centers by Pd-catalyzed Asymmetric Allylic Alkylation of Prochiral Enolate Equivalents

scientific article published on September 2015

Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis

scientific article published on 12 July 2013

Convergency and divergency as strategic elements in total synthesis: the total synthesis of (-)-drupacine and the formal total synthesis of (+/-)-cephalotaxine, (-)-cephalotaxine, and (+)-cephalotaxine

scientific article

Convergent and diastereoselective synthesis of the polycyclic pyran core of saudin

scientific article published in October 2006

Copper-Catalyzed Enantioselective Allylic Alkylation with a γ-Butyrolactone-Derived Silyl Ketene Acetal

scientific article published on 16 December 2019

Correction to "Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp<sup>3</sup>)-C(sp<sup>3</sup>) Cross-Coupling"

scientific article published on 04 December 2020

Correction to A Comprehensive History of Arynes in Natural Product Total Synthesis

scientific article published on 03 July 2018

Correction: Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade

Corrigendum: Enantioselective Total Synthesis of the Reported Structures of (−)-9-epi-Presilphiperfolan-1-ol and (−)-Presilphiperfolan-1-ol: Structural Confirmation and Reassignment and Biosynthetic Insights

scholarly article published in Angewandte Chemie International Edition

Cyanthiwigin Natural Product Core as a Complex Molecular Scaffold for Comparative Late-Stage C-H Functionalization Studies

scientific article

Cycloadditions of Oxacyclic Allenes and a Catalytic Asymmetric Entryway to Enantioenriched Cyclic Allenes

scientific article published on 20 March 2019

Deracemization of Quaternary Stereocenters by Pd-Catalyzed Enantioconvergent Decarboxylative Allylation of Racemic β-Ketoesters

Deracemization of quaternary stereocenters by Pd-catalyzed enantioconvergent decarboxylative allylation of racemic beta-ketoesters

scientific article

Development of (trimethylsilyl)ethyl ester protected enolates and applications in palladium-catalyzed enantioselective allylic alkylation: intermolecular cross-coupling of functionalized electrophiles

scientific article published on 11 April 2014

Development of a catalytic enantioselective synthesis of the guanacastepene and heptemerone tricyclic core

scientific article published on 27 February 2019

Development of a palladium-catalyzed decarboxylative cross-coupling of (2-azaaryl)carboxylates with aryl halides

scientific article published on July 2013

Development of an enantiodivergent strategy for the total synthesis of (+)- and (-)-dragmacidin f from a single enantiomer of quinic Acid.

scientific article published in April 2005

Direct oxidative Heck cyclizations: intramolecular Fujiwara-Moritani arylations for the synthesis of functionalized benzofurans and dihydrobenzofurans

scientific article published in November 2004

Effects of a modified dye-labeled nucleotide spacer arm on incorporation by thermophilic DNA polymerases

scientific article published in January 2006

Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis

scientific article published on 24 May 2010

Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters

scientific article published on 6 November 2013

Enantioconvergent catalysis

scientific article

Enantioselective Alkynylation of Trifluoromethyl Ketones Catalyzed by Cation-Binding Salen Nickel Complexes

scientific article published on 02 December 2019

Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A.

scientific article

Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.

scientific article published on 19 June 2017

Enantioselective Iridium-Catalyzed Allylic Alkylation Reactions of Masked Acyl Cyanide Equivalents.

scientific article published on 14 March 2017

Enantioselective Pd-Catalyzed Allylic Alkylation Reactions of Dihydropyrido[1,2-a]indolone Substrates: Efficient Syntheses of (-)-Goniomitine, (+)-Aspidospermidine, and (-)-Quebrachamine

scientific article published on 26 September 2016

Enantioselective Pd-Catalyzed Decarboxylative Allylic Alkylation of Thiopyranones. Access to Acyclic, Stereogenic α-Quaternary Ketones.

scientific article published on 13 September 2017

Enantioselective Synthesis of 15-Deoxy-Δ12,14-Prostaglandin J2

scientific article published on 06 December 2019

Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation

scientific article published on 19 July 2017

Enantioselective Synthesis of Caprolactam and Enone Precursors to the Heterocyclic DEFG Ring System of Zoanthenol.

scientific article published on 19 April 2016

Enantioselective Synthesis of Vicinal All-Carbon Quaternary Centers via Iridium-Catalyzed Allylic Alkylation

scientific article published on 11 June 2018

Enantioselective Total Synthesis of (–)-Myrifabral A and B

Enantioselective Total Synthesis of Nigelladine A via Late-Stage C-H Oxidation Enabled by an Engineered P450 Enzyme.

scientific article published on 19 July 2017

Enantioselective Tsuji allylations

scientific article published on December 2007

Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams

scientific article published on 18 December 2011

Enantioselective construction of the tricyclic core of curcusones A-D via a cross-electrophile coupling approach

scientific article published on 01 October 2019

Enantioselective construction of α-quaternary cyclobutanones by catalytic asymmetric allylic alkylation

scientific article published on 17 May 2013

Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies

scientific article

Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids

Enantioselective protonation

scientific article

Enantioselective synthesis of a hydroxymethyl-cis-1,3-cyclopentenediol building block

scientific article published on 26 October 2012

Enantioselective synthesis of dialkylated N-heterocycles by palladium-catalyzed allylic alkylation

scientific article published on 25 February 2015

Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation.

scientific article published on 31 October 2018

Enantioselective synthesis of the 5-6-7 carbocyclic core of the gagunin diterpenoids

scientific article published on 26 June 2013

Enantioselective synthesis of α-quaternary Mannich adducts by palladium-catalyzed allylic alkylation: total synthesis of (+)-sibirinine

scientific article published on 20 January 2015

Enantioselective synthesis of α-secondary and α-tertiary piperazin-2-ones and piperazines by catalytic asymmetric allylic alkylation

scientific article

Enantioselective total synthesis of (+)-cassiol

scientific article published in January 2009

Enantioselective total synthesis of the reported structures of (-)-9-epi-presilphiperfolan-1-ol and (-)-presilphiperfolan-1-ol: structural confirmation and reassignment and biosynthetic insights

scientific article published on 22 August 2012

Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

scientific article

Enantioselective, Convergent Synthesis of the Ineleganolide Core by a Tandem Annulation Cascade

scientific article published on 17 August 2016

Evolution of a unified, stereodivergent approach to the synthesis of communesin F and perophoramidine.

scientific article

Exceedingly Efficient Synthesis of (±)-Grandifloracin and Acylated Analogues

scientific article published on 10 June 2015

Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketones

scientific article published on 27 February 2013

Expedient synthesis of 3-hydroxyisoquinolines and 2-hydroxy-1,4-naphthoquinones via one-pot aryne acyl-alkylation/condensation

scientific article published on 6 October 2009

Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation

scientific article

Gas phase production and loss of isoprene epoxydiols

scientific article

Gas-phase synthesis of charged copper and silver Fischer carbenes from diazomalonates: mechanistic and conformational considerations in metal-mediated wolff rearrangements.

scientific article published in April 2003

General and Practical Potassium Methoxide/Disilane-Mediated Dehalogenative Deuteration of (Hetero)Arylhalides

scientific article published on 22 August 2018

Global Diastereoconvergence in the Ireland-Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids

scientific article published on 15 December 2020

Heterogeneous reductive isomerization reaction using catalytic Pd/C and H2.

scientific article published in June 2005

High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates ⬇️

scientific article published on January 1, 2010

Highly functionalized donor-acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids

scientific article published on June 2015

Homogeneous pd-catalyzed enantioselective decarboxylative protonation

scientific article published on 28 February 2008

Incorporation of a chiral gem-disubstituted nitrogen heterocycle yields an oxazolidinone antibiotic with reduced mitochondrial toxicity

scientific article published on 16 July 2019

Intermolecular Stereoselective Iridium-Catalyzed Allylic Alkylation: An Evolutionary Account

scientific article published on 15 August 2018

Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals

scientific article published on 07 January 2019

Ionic and Neutral Mechanisms for C-H Bond Silylation of Aromatic Heterocycles Catalyzed by Potassium tert-Butoxide.

scientific article published on 2 May 2017

Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates

scientific article

Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride.

scientific article published on 28 November 2016

Isocanthine Synthesis via Rh(III)-Catalyzed Intramolecular C-H Functionalization.

scientific article

Label-free detection of single nanoparticles and biological molecules using microtoroid optical resonators

scientific article published on 01 January 2016

Lewis acid mediated (3 + 2) cycloadditions of donor-acceptor cyclopropanes with heterocumulenes

scientific article published on 9 October 2012

Mechanism and enantioselectivity in palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones: insights from computation and experiment

scientific article published on 27 September 2013

Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones

scientific article

Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps.

scientific article

Molecular mousetraps: gas-phase studies of the covalent coupling of noncovalent complexes initiated by reactive carbenes formed by controlled activation of diazo precursors.

scientific article

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

article

Natural products as inspiration for the development of asymmetric catalysis

scientific article published on September 2008

New directions in natural product synthesis

scientific article published on 01 October 2018

Ni-Catalyzed Enantioselective C-Acylation of α-Substituted Lactams

scientific article published on 3 July 2016

Nickel-Catalyzed Intramolecular C-O Bond Formation: Synthesis of Cyclic Enol Ethers.

scientific article published on 9 May 2016

Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols.

scientific article published on 24 January 2018

Non-carbonyl-stabilized metallocarbenoids in synthesis: the development of a tandem rhodium-catalyzed bamford-stevens/thermal aliphatic claisen rearrangement sequence

scientific article published in October 2002

Orthogonal synthesis of indolines and isoquinolines via aryne annulation

scientific article published on 15 January 2008

Oxidative Fragmentations and Skeletal Rearrangements of Oxindole Derivatives.

scientific article published on 14 February 2017

Oxidative cyclizations in a nonpolar solvent using molecular oxygen and studies on the stereochemistry of oxypalladation

scientific article published on December 2005

PREPARATION OF (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-).

scientific article

PREPARATION OF (S)-tert-ButylPHOX (Oxazole, 4-(1,1-dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro- (4S)-)

scientific article

Palladium(II)-catalyzed allylic C-H oxidation of hindered substrates featuring tunable selectivity over extent of oxidation

scientific article published on 31 July 2015

Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate

scientific article published on 18 October 2016

Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters

scientific article published on December 2011

Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Cyclic Electrophiles

scientific article published on 02 July 2015

Palladium-Catalyzed Construction of Quaternary Stereocenters by Enantioselective Arylation of γ-Lactams with Aryl Chlorides and Bromides

scientific article published on 22 February 2019

Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (-)-Aspewentins A, B, and C.

scientific article published on 29 July 2015

Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins

scientific article

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of 1,4-Diazepan-5-ones

scientific article published on 31 October 2019

Palladium-Catalyzed Enantioselective Csp3-Csp3 Cross-Coupling for the Synthesis of (Poly)fluorinated Chiral Building Blocks

scientific article published on 05 September 2018

Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α-N-Pyrrolyl/Indolyl Ketones

scientific article published on 18 May 2020

Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones

scientific article

Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to five-, six-, and seven-membered β-substituted cyclic enones: enantioselective construction of all-carbon quaternary stereocenters.

scientific article

Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to heterocyclic acceptors.

scientific article published on 03 December 2012

Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters ⬇️

scientific article

Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates

scientific article published on 17 May 2019

Palladium-catalyzed enantioselective oxidation of alcohols: a dramatic rate acceleration by Cs2CO3/t-BuOH

scientific article published on 01 March 2003

Palladium-catalyzed enantioselective oxidation of chiral secondary alcohols: access to both enantiomeric series

scientific article published on January 2008

Palladium-catalyzed oxidative kinetic resolution with ambient air as the stoichiometric oxidation gas.

scientific article published in January 2004

Palladium-catalyzed oxidative wacker cyclizations in nonpolar organic solvents with molecular oxygen: a stepping stone to asymmetric aerobic cyclizations.

scientific article

Palladium-catalyzed α,β-dehydrogenation of acyclic ester equivalents promoted by a novel electron deficient phosphinooxazoline ligand

scientific article published on 01 June 2019

Particle-phase accretion forms dimer esters in pinene secondary organic aerosol

scientific article published on 16 November 2023

Pd-catalyzed enantioselective aerobic oxidation of secondary alcohols: applications to the total synthesis of alkaloids

scientific article published on 18 September 2008

Polycyclic Furanobutenolide-Derived Cembranoid and Norcembranoid Natural Products: Biosynthetic Connections and Synthetic Efforts.

scientific article published on 18 May 2017

Potassium tert-Butoxide-Catalyzed Dehydrogenative C-H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study.

scientific article published on 12 April 2017

Preparation of (S)-2-Allyl-2-Methylcyclohexanone

Preparation of (S)-tert-ButylPHOX

Preparation of (S)-tert-ButylPyOx and Palladium-catalyzed Asymmetric Conjugate Addition of Arylboronic Acids

scientific article published on 04 March 2016

Preparation of 1,5-Dioxaspiro[5.5]undecan-3-one

scientific article

Preparation of 1,5-Dioxaspiro[5.5]undecan-3-one

Probing Trends in Enantioinduction via Substrate Design: Palladium-Catalyzed Decarboxylative Allylic Alkylation of α-Enaminones

scientific article published on 16 June 2020

Production and Fate of C4 Dihydroxycarbonyl Compounds from Isoprene Oxidation.

scientific article published on 15 December 2015

Progress toward the Enantioselective Synthesis of Curcusones A-D via a Divinylcyclopropane Rearrangement Strategy

scientific article published on 25 November 2019

Progress toward the Synthesis of garsubellin A and related phloroglucins: the direct diastereoselective synthesis of the bicyclo[3.3.1]nonane core

scientific article published in May 2002

Progress toward the synthesis of the basiliolides and transtaganolides: an intramolecular pyrone Diels-Alder entry into a novel class of natural products

scientific article published on 7 December 2007

Progress toward the total synthesis of saudin: development of a tandem Stille-oxa-electrocyclization reaction

scientific article published in June 2005

Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides.

scientific article published on October 2010

Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp3)-C(sp3) Cross-Coupling

scientific article published on 08 July 2020

Regioselective reactions of highly substituted arynes

scientific article published on 01 March 2010

Reversible inhibitor of p97, DBeQ, impairs both ubiquitin-dependent and autophagic protein clearance pathways

scientific article

Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes

scientific article

Selective nucleic acid capture with shielded covalent probes

scientific article published on 18 June 2013

Selective syntheses of leuconolam, leuconoxine, and mersicarpine alkaloids from a common intermediate through regiocontrolled cyclizations by Staudinger reactions†Electronic supplementary information (ESI) available: Experimental details and procedu

scientific article

Sequential Ruthenium Catalysis for Olefin Isomerization and Oxidation: Application to the Synthesis of Unusual Amino Acids.

scientific article

Short Enantioselective Formal Synthesis of (–)-Platencin

scientific article published on 23 July 2018

Side chain chemistry mediates backbone fragmentation in hydrogen deficient peptide radicals

scientific article

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

scientific article (publication date: 4 February 2015)

Small-Scale Procedure for Acid-Catalyzed Ketal Formation

scientific article published on 22 August 2019

Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters

scientific article published on June 2015

Stereoselective Lewis acid mediated (3+2) cycloadditions of N-H- and N-sulfonylaziridines with heterocumulenes

scientific article

Stereospecific Overman Rearrangement of Substituted Cyclic Vinyl Bromides: Access to Fully Substituted α-Amino Ketones

scientific article published on 30 October 2019

Structural features and reactivity of (sparteine)PdCl2: a model for selectivity in the oxidative kinetic resolution of secondary alcohols

scientific article published on November 2008

Substituent effects and nearly degenerate transition states: rational design of substrates for the tandem Wolff-Cope reaction

scientific article

Synergistic O + OH oxidation pathway to extremely low-volatility dimers revealed in β-pinene secondary organic aerosol

article published in the Proceedings of the National Academy of Sciences of the United States of America

Synthesis and Exploration of Electronically Modified (R)-5,5-Dimethyl-(p-CF3)3-i-PrPHOX in Palladium-Catalyzed Enantio- and Diastereoselective Allylic Alkylation: A Practical Alternative to (R)-(p-CF3)3-t-BuPHOX.

scientific article published in August 2015

Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate

scientific article (publication date: 8 June 2006)

Synthesis of 2-Quinuclidonium by Eliminating Water:  Experimental Quantification of the High Basicity of Extremely Twisted Amides

scientific article (publication date: February 2007)

Synthesis of Aryl Ketoamides via Aryne Insertion into Imides

scientific article published on 7 June 2016

Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol

scientific article published on 19 August 2020

Synthesis of diverse β-quaternary ketones via palladium-catalyzed asymmetric conjugate addition of arylboronic acids to cyclic enones

scientific article

Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork-Danheiser approach: preparation of mono-, bi-, and tricyclic systems

scientific article

Synthesis of the carbocyclic core of zoanthenol: implementation of an unusual acid-catalyzed cyclization

scientific article

Synthetic Applications and Methodological Developments of Donor-Acceptor Cyclopropanes and Related Compounds.

scientific article published on 27 January 2016

Synthetic efforts toward cyathane diterpenoid natural products

scientific article published on 16 March 2009

The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

scientific article

The CryoEM Method MicroED as a Powerful Tool for Small Molecule Structure Determination

scientific article published on 02 November 2018

The CryoEM Method MicroED as a Powerful Tool for Small Molecule Structure Determination

The CryoEM Method MicroED as a Powerful Tool for Small Molecule Structure Determination

The Development of a Facile Tandem Wolff/Cope Rearrangement for the Synthesis of Fused Carbocyclic Skeletons ⬇️

scientific article published on November 12, 2003

The Development of a Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Asymmetric Formation of the Polycyclic Norditerpenoid Carbocyclic Core by Tandem Annulation Cascade

scientific article published on 21 February 2018

The Total Synthesis of (-)-Scabrolide A

scientific article published on 30 March 2020

The Total Synthesis of (–)-Scabrolide a

scholarly article published 4 March 2020

The Transition Metal Catalyzed [π2s + π2s + σ2s + σ2s] Pericyclic Reaction: Woodward-Hoffmann Rules, Aromaticity, and Electron Flow

scientific article published on 27 October 2020

The biology and chemistry of the zoanthamine alkaloids.

scientific article published on January 2008

The catalytic asymmetric total synthesis of elatol

scientific article published on 29 December 2007

The catalytic enantioselective total synthesis of (+)-liphagal

scientific article published on 10 June 2011

The catalytic enantioselective, protecting group-free total synthesis of (+)-dichroanone.

scientific article

The direct acyl-alkylation of arynes

scientific article

The enantioselective Tsuji allylation

scientific article published in November 2004

The first total synthesis of dragmacidin d.

scientific article published in November 2002

The inner-sphere process in the enantioselective Tsuji allylation reaction with (S)-t-Bu-phosphinooxazoline ligands.

scientific article published on 8 September 2007

The palladium-catalyzed aerobic kinetic resolution of secondary alcohols: reaction development, scope, and applications.

scientific article published on December 2009

The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation

scientific article published on 6 November 2012

The synthesis of C-3β functionalized indoles via a hydroboration/Suzuki-Miyaura coupling sequence

scientific article published on November 2006

The total syntheses of basiliolide C, epi-basiliolide C, and protecting-group-free total syntheses of transtaganolides C and D.

scientific article published on 6 October 2014

The total synthesis of (+)-dragmacidin F.

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The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation

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The total synthesis of (--)-lemonomycin

scientific article published in December 2003

Total Synthesis and Characterization of 7-Hypoquinuclidonium Tetrafluoroborate and 7-Hypoquinuclidone BF3 Complex

scientific article (publication date: 27 January 2016)

Total Synthesis of (+)- and (-)-K252a

scientific article published in 1995

Total Synthesis of (±)-Phomoidride D.

scientific article published on 29 December 2017

Total Synthesis of the Norhasubanan Alkaloid Stephadiamine

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Total syntheses of (-)-transtaganolide A, (+)-transtaganolide B, (+)-transtaganolide C, and (-)-transtaganolide D and biosynthetic implications

scientific article published on 16 May 2013

Total syntheses of cyanthiwigins B, F, and G.

scientific article

Toward a symphony of reactivity: cascades involving catalysis and sigmatropic rearrangements

scientific article published on March 2014

Unified Enantioselective, Convergent Synthetic Approach toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Synthesis of a Series of Ineleganoloids by Oxidation-State Manipulation of the Carbocyclic Core

scientific article published on 10 June 2019

Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones

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Use of a palladium(II)-catalyzed oxidative kinetic resolution in synthetic efforts toward bielschowskysin

scientific article published in September 2013

Welwitindolinone C synthetic studies. Construction of the welwitindolinone carbon skeleton via a transannular nitrone cycloaddition ⬇️

scientific article published on August 14, 2010

Wolff/Cope Approach to the AB Ring of the Sesterterpenoid Variecolin.

scientific article published on 4 January 2018

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