List of works - Adrian Chaplin

2,6-Bis[1-(2,4,6-tri-methyl-phenyl-imino)-eth-yl]pyridine.

scientific article

A case for linear agostic interactions: identification by DFT calculation in a complex of Ta containing a uniquely caged triphenylmethyl C-H hydrogen.

scientific article published on 28 July 2004

A convenient method for the generation of {Rh(PNP)} and {Rh(PONOP)} fragments: reversible formation of vinylidene derivatives

scientific article published on 01 February 2019

A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes

scientific article published on 22 January 2020

Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate

scientific article published on 19 November 2008

Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes

scientific article published on 01 February 2010

Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes

scientific article published on 10 October 2008

Amino-borane oligomers bound to a Rh(I) metal fragment

scientific article published on 23 March 2010

Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling

scientific article published on 07 February 2012

B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes

scientific article published on 01 January 2010

Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center

scientific article published on 01 January 2009

C-C activation in the solid state in an organometallic σ-complex.

scientific article published on 28 July 2011

C-F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene.

scientific article published on 22 December 2016

Catalytic Activity of Bis-phosphine Ruthenium(II)−Arene Compounds: Chemoselective Hydrogenation and Mechanistic Insights

Catalytic Activity of Bis-phosphine Ruthenium(II)−Arene Compounds: Structure−Activity Correlations

Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H3B·NMeHBH2·NMeH2Bound to Iridium

scientific article published on 01 July 2011

Conformational flexibility in 2,2'-Dioxybiphenyl-chloro-cyclotetraphosphazenes and its relevance to polyphosphazene analogues

scientific article published on 03 March 2007

Coordination chemistry of a calix[4]arene-based NHC ligand: dinuclear complexes and comparison to I(i)Pr2Me2

scientific article published on 10 May 2016

Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment

scientific article published on 25 May 2011

Electrochemical synthesis of polypyrrole in ionic liquids

article

Gold(I) and platinum(II) complexes with a new diphosphine ligand based on the cyclotriphosphazene platform

scientific article published on 23 December 2005

Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation

scientific article published on 29 June 2011

Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(κ2-triphos)(p-cymene)]PF6

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.

scientific article published on 2 March 2012

Isolation and structural characterisation of rhodium(iii) η2-fluoroarene complexes: experimental verification of predicted regioselectivity

scientific article published on 21 April 2020

Linked Metal-cluster Systems: Isolation and Characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

Low-coordinate iridium NHC complexes derived from selective and reversible C-H bond activation of fluoroarenes

scientific article published on 01 March 2015

Mechanistic Studies on the Formation of η2-Diphosphine (η6-p-cymene)ruthenium(II) Compounds

Monomeric and oligomeric amine-borane sigma-complexes of rhodium. intermediates in the catalytic dehydrogenation of amine-boranes

scientific article published on 01 October 2009

NHC-based pincer ligands: carbenes with a bite.

scientific article

On the Influence of “Arm-on, Arm-off” Processes on Alkene Hydrogenation Catalysed by a Rhodium Triphos Complex

scholarly article by Adrian B Chaplin & Paul J. Dyson published November 2007 in European Journal of Inorganic Chemistry

One-Electron Oxidation of [M(P(t) Bu3 )2 ] (M=Pd, Pt): Isolation of Monomeric [Pd(P(t) Bu3 )2 ](+) and Redox-Promoted C-H Bond Cyclometalation

scientific article published on 16 February 2016

Organometallic chemistry using partially fluorinated benzenes

scientific article

Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

scientific article published on 20 October 2020

Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)

scientific article published on 07 September 2018

Pendant−Bridging−Chelating−Cleavage: A Series of Bonding Modes in Ruthenium(II)-BINAPO Complexes

Potassium Binding Adjacent to Cationic Transition-Metal Fragments: Unusual Heterobimetallic Adducts of a Calix[4]arene-Based Thione Ligand

scientific article published on 2 November 2017

Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study

scientific article published on 23 August 2019

Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all

scientific article published on 11 November 2020

Reactivity and catalytic activity of a robust ruthenium(II)-triphos complex

scientific article published on 29 November 2007

Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation.

scientific article published on July 2010

Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation

scientific article published on 12 July 2010

Revisiting the Electronic Structure of Phosphazenes

scientific article published on 01 November 2005

Rhodium(I) Pincer Complexes of Nitrous Oxide

scientific article published on 12 September 2019

Rhodium(III) Complexes Featuring Coordinated CF 3 Appendages

scientific article published on 09 April 2019

Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen

scientific article published on 09 October 2018

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch

scientific article published on 19 April 2011

Rotaxane synthesis exploiting the M(i)/M(iii) redox couple

scientific article published on 24 August 2017

Solution, solid-state, and computational analysis of agostic interactions in a coherent set of low-coordinate rhodium(III) and iridium(III) complexes

scientific article published on 26 January 2018

Solvent promoted reversible cyclometalation in a tethered NHC iridium complex

scientific article published on 27 November 2013

Synthesis and Characterization of Organometallic Ionic Liquids and a Heterometallic Carbene Complex Containing the Chromium Tricarbonyl Fragment

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes.

scientific article published on 22 May 2019

Synthesis and reactivity of NHC-based rhodium macrocycles

scientific article published on 10 December 2014

Synthesis, structure and dynamics of NHC-based palladium macrocycles.

scientific article

Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching

scientific article published on 20 August 2018

The Synthesis and Characterisation of Bis(phosphane)-Linked (6-p-Cymene)ruthenium(II)-Borane Compounds

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

scientific article published on 03 February 2011

Tuning the hydrophobicity of ruthenium(II)-arene (RAPTA) drugs to modify uptake, biomolecular interactions and efficacy

scientific article published on 26 September 2007

UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex.

scientific article

Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).

scientific article published on 18 December 2009

Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles

scientific article published on 9 May 2016

[Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2

scientific article published on 14 February 2011

List of works by Adrian Chaplin

2,6-Bis[1-(2,4,6-tri-methyl-phenyl-imino)-eth-yl]pyridine.

A case for linear agostic interactions: identification by DFT calculation in a complex of Ta containing a uniquely caged triphenylmethyl C-H hydrogen.

A convenient method for the generation of {Rh(PNP)} and {Rh(PONOP)} fragments: reversible formation of vinylidene derivatives

A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes

Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate

Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes

Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes

Amino-borane oligomers bound to a Rh(I) metal fragment

Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling

B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes

Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center

C-C activation in the solid state in an organometallic σ-complex.

C-F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene.

Catalytic Activity of Bis-phosphine Ruthenium(II)−Arene Compounds: Chemoselective Hydrogenation and Mechanistic Insights

Catalytic Activity of Bis-phosphine Ruthenium(II)−Arene Compounds: Structure−Activity Correlations

Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H3B·NMeHBH2·NMeH2Bound to Iridium

Conformational flexibility in 2,2'-Dioxybiphenyl-chloro-cyclotetraphosphazenes and its relevance to polyphosphazene analogues

Coordination chemistry of a calix[4]arene-based NHC ligand: dinuclear complexes and comparison to I(i)Pr2Me2

Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment

Electrochemical synthesis of polypyrrole in ionic liquids

Gold(I) and platinum(II) complexes with a new diphosphine ligand based on the cyclotriphosphazene platform

Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation

Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(κ2-triphos)(p-cymene)]PF6

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.

Isolation and structural characterisation of rhodium(iii) η2-fluoroarene complexes: experimental verification of predicted regioselectivity

Linked Metal-cluster Systems: Isolation and Characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

Low-coordinate iridium NHC complexes derived from selective and reversible C-H bond activation of fluoroarenes

Mechanistic Studies on the Formation of η2-Diphosphine (η6-p-cymene)ruthenium(II) Compounds

Monomeric and oligomeric amine-borane sigma-complexes of rhodium. intermediates in the catalytic dehydrogenation of amine-boranes

NHC-based pincer ligands: carbenes with a bite.

On the Influence of “Arm-on, Arm-off” Processes on Alkene Hydrogenation Catalysed by a Rhodium Triphos Complex

One-Electron Oxidation of [M(P(t) Bu3 )2 ] (M=Pd, Pt): Isolation of Monomeric [Pd(P(t) Bu3 )2 ](+) and Redox-Promoted C-H Bond Cyclometalation

Organometallic chemistry using partially fluorinated benzenes

Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)

Pendant−Bridging−Chelating−Cleavage: A Series of Bonding Modes in Ruthenium(II)-BINAPO Complexes

Potassium Binding Adjacent to Cationic Transition-Metal Fragments: Unusual Heterobimetallic Adducts of a Calix[4]arene-Based Thione Ligand

Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study

Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all

Reactivity and catalytic activity of a robust ruthenium(II)-triphos complex

Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation.

Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation

Revisiting the Electronic Structure of Phosphazenes

Rhodium(I) Pincer Complexes of Nitrous Oxide

Rhodium(III) Complexes Featuring Coordinated CF 3 Appendages

Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch

Rotaxane synthesis exploiting the M(i)/M(iii) redox couple

Solution, solid-state, and computational analysis of agostic interactions in a coherent set of low-coordinate rhodium(III) and iridium(III) complexes

Solvent promoted reversible cyclometalation in a tethered NHC iridium complex

Synthesis and Characterization of Organometallic Ionic Liquids and a Heterometallic Carbene Complex Containing the Chromium Tricarbonyl Fragment

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes.

Synthesis and reactivity of NHC-based rhodium macrocycles

Synthesis, structure and dynamics of NHC-based palladium macrocycles.

Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching

The Synthesis and Characterisation of Bis(phosphane)-Linked (6-p-Cymene)ruthenium(II)-Borane Compounds

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

Tuning the hydrophobicity of ruthenium(II)-arene (RAPTA) drugs to modify uptake, biomolecular interactions and efficacy

UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex.

Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).

Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles

[Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2