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List of works by Heikki M. Tuononen

1-Phenyl-3-(pyrid-2-yl)benzo[e][1,2,4]triazinyl: the first "Blatter radical" for coordination chemistry.

scientific article

77Se NMR spectroscopic, DFT MO, and VBT investigations of the reversible dissociation of solid (Se6I2)[AsF6]2.2SO2 in Liquid SO2 to solutions containing 1,4-Se6I2(2+) in equilibrium with Se(n)2+ (n = 4, 8, 10) and seven binary selenium iodine cation

scientific article published on 01 March 2009

A Cation-Captured Palladium(0) Anion: Synthesis, Structure, and Bonding of [PdBr(PPh3)2]− Ligated by an N-Heterocyclic Phosphenium Cation

scientific article

A Monomeric Aluminum Imide (Iminoalane) with Al–N Triple-Bonding: Bonding Analysis and Dispersion Energy Stabilization

scientific article

A germanium isocyanide complex featuring (n → π*) back-bonding and its conversion to a hydride/cyanide product via C-H bond activation under mild conditions

scientific article published on 22 February 2012

A sigma-donor with a planar six-pi-electron B2N2C2 framework: anionic N-heterocyclic carbene or heterocyclic terphenyl anion?

scientific article published on 01 September 2006

A simple complex on the verge of breakdown: isolation of the elusive cyanoformate ion

scientific article (publication date: 4 April 2014)

Addition of ethylene or hydrogen to a main-group metal cluster under mild conditions

scientific article published on 28 January 2015

Addition/Correction to “High-Level Ab Initio Predictions of Thermochemical Properties of Organosilicon Species: Critical Evaluation of Experimental Data and a Reliable Benchmark Database for Extending Group Additivity Approaches”

scientific article published in 2022

Ammonia Activation by a Nickel NCN-Pincer Complex featuring a Non-Innocent N-Heterocyclic Carbene: Ammine and Amido Complexes in Equilibrium.

scientific article

An unusual ditelluride: synthesis and molecular and electronic structures of the dimer of the tellurium-centered radical [TePiPr2NiPr2PTe]

scientific article published on 01 August 2005

Assembly of a planar, tricyclic B4N8 framework with s-indacene structure

scientific article published on 6 September 2007

Benson group additivity values of phosphines and phosphine oxides: Fast and accurate computational thermochemistry of organophosphorus species

scientific article published on 01 January 2019

Bi-, tetra-, and hexanuclear AuI and binuclear AgI complexes and AgI coordination polymers containing phenylaminobis(phosphonite), PhN{P(OC6H4OMe-o)2}2, and pyridyl ligands

scientific article published on 13 February 2008

Bond stretching and redox behavior in coinage metal complexes of the dichalcogenide dianions [(SPh2P)2CEEC(PPh2S)2]2- (E=S, Se): diradical character of the dinuclear copper(I) complex (E=S) ⬇️

scientific article published on 05 September 2011

Boron-Nitrogen Doped Dihydroindeno[1,2-b]fluorene Derivatives as Acceptors in Organic Solar Cells

scientific article published in July 2019

Boron-nitrogen substituted dihydroindeno[1,2-b]fluorene derivatives as acceptors in organic solar cells

scientific article published on 28 August 2019

Characterization of beta-B-agostic isomers in zirconocene amidoborane complexes

scientific article published on 01 May 2009

Cleavage of Ge–Ge and Sn–Sn Triple Bonds in Heavy Group 14 Element Alkyne Analogues (EAriPr4)2 (E = Ge, Sn; AriPr4 = C6H3-2,6(C6H3-2,6-iPr2)2) by Reaction with Group 6 Carbonyls

scientific article

Coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization in the first lanthanide complex of a 1,2,4-benzotriazinyl radical.

scientific article published on 21 September 2017

Comment on "crystallographic snapshot of an arrested intermediate in the biomimetic activation of CO2 ".

scientific article published on 3 June 2015

Computational Analysis of n→π* Back-Bonding in Metallylene–Isocyanide Complexes R2MCNR′ (M = Si, Ge, Sn; R = tBu, Ph; R′ = Me, tBu, Ph)

Computational investigations of 18-electron triatomic sulfur–nitrogen anions

scientific article

Computational modeling of isotropic electron paramagnetic resonance spectra of doublet state main group radicals

scientific article

Conformations and energetics of sulfur and selenium diimides

scientific article published in April 2003

Coordination Complexes of a Neutral 1,2,4-Benzotriazinyl Radical Ligand: Synthesis, Molecular and Electronic Structures, and Magnetic Properties

scientific article published on 7 September 2015

Copper(I) complexes of bis(2-(diphenylphosphino)phenyl) ether: synthesis, reactivity, and theoretical calculations

scientific article published on 07 July 2007

Counterintuitive mechanisms of the addition of hydrogen and simple olefins to heavy group 13 alkene analogues.

scientific article published on 23 January 2013

Cubic and spirocyclic radicals containing a tetraimidophosphate dianion [P(NR)3(NR')]*2-.

scientific article published in October 2005

Dihydrogen activation by antiaromatic pentaarylboroles

scientific article published in July 2010

Direct observation of a borane-silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

scientific article published on 28 September 2014

Dispersion forces and counterintuitive steric effects in main group molecules: heavier group 14 (Si-Pb) dichalcogenolate carbene analogues with sub-90° interligand bond angles

scientific article

Divergent reactivity of nucleophilic 1-bora-7a-azaindenide anions

scientific article published on 14 December 2017

Do extremely bent allenes exist?

scientific article published on 01 July 2009

Effect of a Rigid Sulfonamide Bond on Molecular Folding: A Case Study

scientific article published on 19 May 2015

Effects of Remote Ligand Substituents on the Structures, Spectroscopic, and Magnetic Properties of Two-Coordinate Transition-Metal Thiolate Complexes

scientific article published on 10 May 2018

Electrochemical and electronic structure investigations of the [S3N3]* radical and kinetic modeling of the [S4N4]n/[S3N3]n (n = 0, -1) interconversion

scientific article

Electronic Structures and Spectroscopic Properties of 6π-Electron Ring Molecules and Ions E2N2 and E42+ (E = S, Se, Te)

scientific article

Electronic structure of the glyoxalbis(2-hydroxyanil) (gha) ligand in [Co(III)(gha)(PPh3)2]+: radical vs. non-radical states

scientific article published on 9 June 2008

Electronic structures and molecular properties of chalcogen nitrides Se2N2 and SeSN2.

scientific article published on July 2005

Electronic structures of main-group carbene analogues

scientific article published on 13 November 2007

Experimental and theoretical investigations of structural isomers of dichalcogenoimidodiphosphinate dimers: dichalcogenides or spirocyclic contact ion pairs?

scientific article published on 01 January 2007

Experimental and theoretical investigations of structural trends for selenium(IV) imides and oxides: X-ray structure of Se3(NAd)2.

scientific article published in March 2004

Experimental and theoretical investigations of tellurium(IV) diimides and imidotelluroxanes: X-ray structures of B(C6F5)3 adducts of OTe(mu-NtBu)2TeNtBu, [OTe(mu-NtBu)2Te(mu-O)]2 and tBuNH2

scientific article published on 01 January 2005

Experimental and theoretical investigations of the contact ion pairs formed by reactions of the anions [(EPR2)2N]- (R = (i)Pr, (t)Bu; E = S, Se) with the cations [(TePR2)2N]+ (R = (i)Pr, (t)Bu).

scientific article published in July 2009

Experimental and theoretical investigations of the redox behavior of the heterodichalcogenido ligands [(EP(i)Pr2)(TeP(i)Pr2)N](-) (E = S, Se): cyclic cations and acyclic dichalcogenide dimers

scientific article

Extending the Series: Synthesis and Characterization of a Dicationic N-Heterocyclic Selenium Carbene Analogue

scientific article published on 01 October 2006

Fabrication of Porous Hydrogenation Catalysts by a Selective Laser Sintering 3D Printing Technique

scientific article published on 11 July 2019

First ruthenium complex of glyoxalbis(N-phenyl)osazone (L(NHPh)H(2)): synthesis, x-ray structure, spectra, and density functional theory calculations of (L(NHPh)H(2))Ru(PPh(3))(2)Cl(2)

scientific article published on 27 June 2007

Formation, Structural Characterization, and Calculated NMR Chemical Shifts of Selenium-Nitrogen Compounds from SeCl4 and ArNHLi (Ar = supermesityl, mesityl)

scientific article

Group 13 complexes of dipyridylmethane, a forgotten ligand in coordination chemistry.

scientific article

Halogen and Hydrogen Bonded Complexes of 5-Iodouracil

scientific article

Haptotropism in a Nickel Complex with a Neutral, π‐Bridging cyclo‐P4 Ligand Analogous to Cyclobutadiene

scientific article

Heptacoordinated molybdenum(VI) complexes of phenylenediamine bis(phenolate): a stable molybdenum amidophenoxide radical.

scientific article published on 29 April 2013

High-Level Ab Initio Predictions of Thermochemical Properties of Organosilicon Species: Critical Evaluation of Experimental Data and a Reliable Benchmark Database for Extending Group Additivity Approaches

scientific article published in 2022

Homoleptic Pnictogen–Chalcogen Coordination Complexes

scientific article published on 27 July 2012

Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene

scientific article published on 01 February 2014

Identification of mixed bromidochloridotellurate anions in disordered crystal structures of (bdmim)2[TeX2Y4] (X, Y=Br, Cl; bdmim=1-butyl-2,3-dimethylimidazolium) by combined application of Raman spectroscopy and solid-state DFT calculations.

scientific article

In search of the [PhB(mu-N(t)Bu)2]2As. radical: experimental and computational investigations of the redox chemistry of group 15 bis-boraamidinates

scientific article published on 9 April 2008

Insights into the decomposition pathway of a lutetium alkylamido complex via intramolecular C–H bond activation

scientific article

Isolation of Free Phenylide-like Carbanions with N-Heterocyclic Carbene Frameworks

scientific article

Isolation of a stable, acyclic, two-coordinate silylene.

scientific article published on 6 April 2012

Low‐Valent Germanylidene Anions: Efficient Single‐Site Nucleophiles for Activation of Small Molecules

scientific article

Mechanistic studies on the metal-free activation of dihydrogen by antiaromatic pentarylboroles.

scientific article published on 4 January 2013

Mechanistic study of stepwise methylisocyanide coupling and C-H activation mediated by a low-valent main group molecule.

scientific article published on 12 April 2013

Molecular Complexes Featuring Unsupported Dispersion-Enhanced Aluminum-Copper and Gallium-Copper Bonds

scientific article published on 10 November 2020

Mono- and Bis(imidazolidinium ethynyl) Cations and Reduction of the Latter To Give an Extended Bis-1,4-([3]Cumulene)-p -carboquinoid System

Mono- and Bis(imidazolidinium ethynyl) Cations and Reduction of the Latter To Give an Extended Bis-1,4-([3]Cumulene)-p-carboquinoid System

scientific article published on 19 November 2017

More electron rich than cyclopentadienyl: 1,2-diaza-3,5-diborolyl as a ligand in ferrocene and ruthenocene analogs

scientific article published on 24 June 2011

N-heterocyclic carbenes with inorganic backbones: electronic structures and ligand properties

scientific article published in January 2008

NMR spectroscopic evidence for the intermediacy of XeF(3)(-) in XeF(2)/F(-) exchange, attempted syntheses and thermochemistry of XeF(3)(-) salts, and theoretical studies of the XeF(3)(-) anion

scientific article published in October 2010

Nature of bonding in group 13 dimetallenes: a delicate balance between singlet diradical character and closed shell interactions

scientific article published on 04 November 2010

New insights into the chemistry of imidodiphosphinates from investigations of tellurium-centered systems

scientific article published on 01 August 2010

New tellurium-containing ring systems

scientific article

New tetraphosphane ligands {(X2P)2NC6H4N(PX2)2} (X = Cl, F,OMe, OC6H4OMe-o): synthesis, derivatization, group 10 and 11 metal complexes and catalytic investigations. DFT calculations on intermolecular P...P interactions in halo-phosphines

scientific article published on 8 July 2008

Nickel as a Lewis Base in a T-Shaped Nickel(0) Germylene Complex Incorporating a Flexible Bis(NHC) Ligand

scholarly article by Chris Gendy et al published 8 November 2018 in Angewandte Chemie

Nickel as a Lewis Base in a T-Shaped Nickel(0) Germylene Complex Incorporating a Flexible Bis(NHC) Ligand

scholarly article by Chris Gendy et al published 27 November 2018 in Angewandte Chemie

Non-Innocent Base Properties of 3- and 4-Pyridyl-dithia- and Diselenadiazolyl Radicals: The Effect of N-Methylation

article

Oligoamide Foldamers as Helical Chloride Receptors-the Influence of Electron-Withdrawing Substituents on Anion-Binding Interactions

scientific article published on 07 February 2019

Oxidative ortho-C-N fusion of aniline by OsO4. Isolation, characterization of oxo-amido Osmium(VI) complexes, and their catalytic activities for oxidative C-C bond cleavage of unsaturated hydrocarbons

scientific article published in December 2008

Paramagnetic aluminium β-diketiminate

scientific article published on 30 July 2012

Phospha-Fischer Carbenes: Synthesis, Structure, Bonding, and Reactions of Pd(0)− and Pt(0)−Phosphenium Complexes

scientific article

Phosphorus-Chalcogen Ring Expansion and Metal Coordination

scientific article published on 13 October 2017

Polymorphism in a π stacked Blatter radical: structures and magnetic properties of 3-(phenyl)-1-(pyrid-2-yl)-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl

scientific article

Porous 3D Printed Scavenger Filters for Selective Recovery of Precious Metals from Electronic Waste

scientific article

Preparation and Characterization of P2 BCh Ring Systems (Ch=S, Se) and Their Reactivity with N-Heterocyclic Carbenes.

scientific article

Pyrazolium- and 1,2-Cyclopentadiene-Based Ligands as σ-Donors: a Theoretical Study of Electronic Structure and Bonding ⬇️

scientific article published on 07 February 2012

Reaction of LiArMe6 (ArMe6= C6H3-2,6-(C6H2-2,4,6-Me3)2) with indium(I)chloride yields three m-terphenyl stabilized mixed-valent organoindium subhalides

scientific article

Reactions of Alkenes and Alkynes with an Acyclic Silylene and Heavier Tetrylenes under Ambient Conditions

Reactions of Terphenyl-Substituted Digallene AriPr4GaGaAriPr4 (AriPr4 = C6H3-2,6-(C6H3-2,6-iPr2)2) with Transition Metal Carbonyls and Theoretical Investigation of the Mechanism of Addition

scientific article

Reactions of m-Terphenyl-Stabilized Germylene and Stannylene with Water and Methanol: Oxidative Addition versus Arene Elimination and Different Reaction Pathways for Alkyl- and Aryl-Substituted Species

scientific article

Reversible complexation of ethylene by a silylene under ambient conditions

scientific article

Role of Weak Hydrogen Bonds and Halogen Bonds in 5-Halo-1,3-dimethyluracils and Their Cocrystals—A Combined Experimental and Computational Study

scientific article

Room-Temperature Magnetic Bistability in a Salt of Organic Radical Ions

scientific article

Sensing of human plasma fibrinogen on polished, chemically etched and carbon treated titanium surfaces by diffractive optical element based sensor

scientific article published in July 2008

Side-on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel

scientific article published on 27 October 2020

Stable spirocyclic neutral radicals: aluminium and gallium boraamidinates

scientific article published on 11 July 2005

Structural and spectroscopic studies of the PCP-bridged heavy chalcogen-centered monoanions [HC(PPh(2)E)(PPh(2))](-) (E = Se, Te) and [HC(PR(2)E)(2)](-) (E = Se, Te, R = Ph; E = Se, R = (i)Pr): homoleptic Group 12 complexes and one-electron oxidatio

scientific article published in December 2009

Structurally simple complexes of CO2.

scientific article

Structures and EPR spectra of binary sulfur–nitrogen radicals from DFT calculations

scientific article

Syntheses and structures of magnesium and zinc boraamidinates: EPR and DFT investigations of Li, Mg, Zn, B, and In complexes of the [PhB(NtBu)2].- anion radical

scientific article published in March 2006

Syntheses, X-ray structures, and redox behaviour of the group 14 bis-boraamidinates M[PhB(μ-N-t-Bu)2]2 (M = Ge, Sn) and Li2M[PhB(μ-N-t-Bu)2]2 (M = Sn, Pb)

scientific article

Synthesis and Redox Behaviour of the Chalcogenocarbonyl Dianions [(E)C(PPh2S)2]2−: Formation and Structures of Chalcogen–Chalcogen Bonded Dimers and a Novel Selone ⬇️

scientific article published on November 15, 2010

Synthesis and characterisation of p-block complexes of biquinoline at different ligand charge states.

scientific article published on 16 January 2017

Synthesis and structures of aluminum and magnesium complexes of tetraimidophosphates and trisamidothiophosphates: EPR and DFT investigations of the persistent neutral radicals {Me2Al[(mu-NR)(mu-NtBu)P(mu-NtBu)2]Li(THF)2}(*) (R = SiMe3, tBu)

scientific article published on 01 August 2005

Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2](-): structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes

scientific article published on 25 July 2016

Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement

scientific article published on 8 November 2017

Synthesis, reactivity, and computational analysis of halophosphines supported by dianionic guanidinate ligands

scientific article published on 09 March 2012

Synthesis, spectroscopic, and structural investigation of the cyclic [N(PR2E)2]+ cations (E = Se, Te; R = iPr, Ph): the effect of anion and R-group exchange

scientific article published on 01 December 2006

Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes

scientific article published in January 2015

Tellurium(II)-centered dications from the pseudohalide "Te(OTf)2".

scientific article published on January 2009

Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C-C bond activation

scientific article published on 10 March 2022

The Instability of Ni{N(SiMe3 )2 }2 : A Fifty Year Old Transition Metal Silylamide Mystery

scientific article published on 2 September 2015

The Instability of Ni{N(SiMe3)2}2: A Fifty Year Old Transition Metal Silylamide Mystery

The Monomeric Alanediyl :AlAriPr8 (AriPr8 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2): An Organoaluminum(I) Compound with a One-Coordinate Aluminum Atom

scientific article published on 23 November 2020

The Nature of Transannular Interactions in E4N4 and E8(2+) (E = S, Se).

scientific article published on 5 October 2012

The Role of Orbital Symmetries in Enforcing Ferromagnetic Ground State in Mixed Radical Dimers

scientific article published on 19 June 2018

The cyclic [N(PiPr2E)2]+ (E = Se, Te) cations: a new class of inorganic ring system

scientific article published on 10 March 2006

The influence of electron delocalization upon the stability and structure of potential N-heterocyclic carbene precursors with 1,3-diaryl-imidazolidine-4,5-dione skeletons

scientific article

Theoretical investigation of paramagnetic diazabutadiene gallium(III)-pnictogen complexes: insights into the interpretation and simulation of electron paramagnetic resonance spectra

scientific article published in November 2005

Theoretical investigation of paramagnetic group 13 diazabutadiene radicals: insights into the prediction and interpretation of EPR spectroscopy parameters

scientific article published on 11 January 2006

Trapping Rare and Elusive Phosphinidene Chalcogenides

scientific article published on 10 January 2017

Tridentate C–I⋯O−–N+ halogen bonds

scientific article

Unusual B4N2C2 ligand in a ruthenium pseudo-triple-decker sandwich complex displaying three reversible electron-transfer steps

scientific article published on 01 January 2008

Weak interactions between trivalent pnictogen centers: computational analysis of bonding in dimers X3E...EX3 (E = pnictogen, X = halogen)

scientific article published on 01 July 2009

Wiener bounds for complex permittivity in terahertz spectroscopy: case study of two-phase pharmaceutical tablets

scientific article published in January 2010

Zirconocene-Based Methods for the Preparation of BN-Indenes: Application to the Synthesis of 1,5-Dibora-4a,8a-diaza-1,2,3,5,6,7-hexaaryl-4,8-dimethyl-s-indacenes

scientific article

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