List of works by Varinder Aggarwal

(−)-Cytisine: Access to a stereochemically defined and functionally flexible piperidine scaffold

scientific article published on 01 August 2018

1,2-Boron Shifts of β-Boryl Radicals Generated from Bis-boronic Esters Using Photoredox Catalysis

scientific article published on 03 September 2019

1,3-Difunctionalizations of [1.1.1]Propellane via 1,2-Metallate Rearrangements of Boronate Complexes

scientific article published on 28 January 2020

50 Years of Zweifel Olefination: A Transition-Metal-Free Coupling

scientific article published on 11 July 2017

A Formal Asymmetric Synthesis of (+)-Anatoxin-a Using an Enantioselective Deprotonation Strategy on an Eight-Membered Ring

scientific article (publication date: 12 July 1999)

A concise asymmetric route to the bridged bicyclic tropane alkaloid ferruginine using enyne ring-closing metathesis

scientific article published on 01 April 2004

A new manifold for the Morita reaction: diene synthesis from simple aldehydes and acrylates/acrylonitrile mediated by phosphines

scientific article published on 26 July 2007

A new method for the preparation of silyl enol ethers from carbonyl compounds and (trimethylsilyl)diazomethane in a regiospecific and highly stereoselective manner

scientific article published in September 2002

A new protocol for the in situ generation of aromatic, heteroaromatic, and unsaturated diazo compounds and its application in catalytic and asymmetric epoxidation of carbonyl compounds. Extensive studies to map out scope and limitations, and rationa

scientific article published in September 2003

A novel one-pot method for the preparation of pyrazoles by 1,3-dipolar cycloadditions of diazo compounds generated in situ

scientific article

A palladium catalysed cyclisation-carbonylation of bromodienes: control in carbonylation over facile beta-hydride elimination

scientific article published on 01 May 2002

A simpler route for making nitrogen-alkene rings. [corrected].

scientific article

Activation of the SN2 Reaction by Adjacent π Systems: The Critical Role of Electrostatic Interactions and of Dissociative Character

scientific article published on 12 January 2016

Alkynyl Moiety for Triggering 1,2-Metallate Shifts: Enantiospecific sp2 -sp3 Coupling of Boronic Esters with p -Arylacetylenes

scientific article published on 12 July 2017

Alkynyl Moiety for Triggering 1,2-Metallate Shifts: Enantiospecific sp2 -sp3 Coupling of Boronic Esters with p-Arylacetylenes

scientific article published on 15 June 2017

Aminals as substrates for sulfur ylides: a synthesis of functionalized aziridines and N-heterocycles

scientific article published on 28 April 2007

An annulation reaction for the synthesis of morpholines, thiomorpholines, and piperazines from beta-heteroatom amino compounds and vinyl sulfonium salts

scientific article published in January 2008

An efficient synthesis of imidazolinium salts using vinyl sulfonium salts

scientific article published on 19 May 2011

Application of Chiral Sulfides to Catalytic Asymmetric Aziridination and Cyclopropanation with In Situ Generation of the Diazo Compound We thank Avecia (M.P.), the EPSRC (M.F.), the EU for a Marie Curie Fellowship (E.A.; HPMF-CT-1999-00076), Lu'an T

scientific article published on 01 April 2001

Application of furyl-stabilized sulfur ylides to a concise synthesis of 8a-epi-swainsonine

scientific article published in January 2008

Application of the Lithiation−Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemist

scientific article published on 01 March 2010

Application of the Lithiation−Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent in Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemist

scientific article published in 2010

Application of the chiral acyl anion equivalent, trans-1,3-dithiane 1,3-dioxide, to an asymmetric synthesis of (R)-salbutamol

scientific article

Application of the lithiation–borylation reaction to the rapid and enantioselective synthesis of the bisabolane family of sesquiterpenes

scientific article published on 21 May 2012

Assembly-line synthesis of organic molecules with tailored shapes

scientific article

Asymmetric Synthesis of Secondary and Tertiary Boronic Esters

scientific article published on 18 May 2017

Asymmetric Synthesis of Tertiary Alcohols and Thiols via Nonstabilized Tertiary α-Oxy- and α-Thio-Substituted Organolithium Species

scientific article

Asymmetric Synthesis of Tertiary Alcohols and Thiols via Nonstabilized Tertiary α-Oxy- and α-Thio-Substituted Organolithium Species

scientific article published on 7 August 2017

Asymmetric Synthesis of Tertiary and Quaternary Allyl- and Crotylsilanes via the Borylation of Lithiated Carbamates

scientific article published on 18 February 2011

Asymmetric Ylide Reactions: Epoxidation, Cyclopropanation, Aziridination, Olefination, and Rearrangement.

scientific article

Asymmetric addition of chiral boron-ate complexes to cyclic iminium ions

article

Asymmetric hydroboration of 1,1-disubstituted alkenes

scientific article

Asymmetric lithiation-substitution of amines involving rearrangement of borates

scientific article published on 11 December 2007

Asymmetric sulfonium ylide mediated cyclopropanation: stereocontrolled synthesis of (+)-LY354740.

scientific article published in December 2005

Asymmetric sulfur ylide mediated aziridination: application in the synthesis of the side chain of taxol

scientific article published on 01 October 2003

Asymmetric sulfur ylide reactions with boranes: scope and limitations, mechanism and understanding

scientific article published on 7 November 2007

Asymmetric synthesis of 1-heteroaryl-1-arylalkyl tertiary alcohols and 1-pyridyl-1-arylethanes by lithiation-borylation methodology

scientific article published on 05 March 2013

Asymmetric synthesis of allylsilanes by the borylation of lithiated carbamates: formal total synthesis of (-)-decarestrictine D.

scientific article published in June 2010

Asymmetric synthesis of alpha-substituted allyl boranes and their application in the synthesis of iso-agatharesinol

scientific article published on 01 January 2007

Asymmetric total synthesis of solandelactone E: stereocontrolled synthesis of the 2-ene-1,4-diol core through a lithiation-borylation-allylation sequence

scientific article published on September 2010

Asymmetrische Synthese sekundärer und tertiärer Boronsäureester

scientific article published on 9 August 2017

Ate complexes of secondary boronic esters as chiral organometallic-type nucleophiles for asymmetric synthesis

scientific article published on 04 October 2011

BF3.OEt2 and TMSOTf: A synergistic combination of Lewis acids

scientific article published on 14 September 2006

Benzylic boron reagents behaving as allylic boron reagents towards aldehydes: a new asymmetric reaction leading to homoallylic alcohols with concomitant dearomatisation

scientific article published in August 2010

Bromoethylsulfonium salt--a more effective annulation agent for the synthesis of 6- and 7-membered 1,4-heterocyclic compounds

scientific article published on 01 January 2009

CD1b Tetramers Identify T Cells that Recognize Natural and Synthetic Diacylated Sulfoglycolipids from Mycobacterium tuberculosis

scientific article published on 29 January 2018

Carbopalladation of C–C σ-bonds enabled by strained boronate complexes

scientific article published on 10 December 2018

Carboxylate-stabilised sulfur ylides (thetin salts) in asymmetric epoxidation for the synthesis of glycidic acids. Mechanism and implications

scientific article published on 18 March 2005

Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer

scientific article published on 14 March 2019

Catalytic Asymmetric Synthesis of Epoxides from Aldehydes Using Sulfur Ylides with In Situ Generation of Diazocompounds We thank the EPSRC (K.M.L., M.J.P., J.R.S.), Avecia for the support of a studentship (M.P.), the EU for a Marie Curie Fellowship

scientific article published on 01 April 2001

Catalytic asymmetric Nazarov reactions promoted by chiral Lewis acid complexes

scientific article

Catalytic, Asymmetric Sulfur Ylide-Mediated Epoxidation of Carbonyl Compounds:  Scope, Selectivity, and Applications in Synthesis

scientific article (publication date: August 2004)

Chalcogenides as Organocatalysts

scientific article (publication date: December 2007)

Chiral Aniline Synthesis via Stereospecific C(sp)-C(sp) Coupling of Boronic Esters with Aryl Hydrazines

scientific article

Complete stereoretention in the rhodium-catalyzed 1,2-addition of chiral secondary and tertiary alkyl potassium trifluoroborate salts to aldehydes

scientific article published on 01 January 2009

Complex Boron-Containing Molecules through a 1,2-Metalate Rearrangement/anti-S N 2′ Elimination/Cycloaddition Reaction Sequence

Concise Synthesis of (+)-allo-Kainic Acid via MgI2-Mediated Tandem Aziridine Ring Opening–Formal [3 + 2] Cycloaddition

scientific article published on 02 August 2013

Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling

scientific article published on 20 April 2017

Construction of Multiple, Contiguous Quaternary Stereocenters in Acyclic Molecules by Lithiation-Borylation

scientific article published on 03 December 2014

Correlation between pK(a) and reactivity of quinuclidine-based catalysts in the Baylis-Hillman reaction: discovery of quinuclidine as optimum catalyst leading to substantial enhancement of scope

scientific article

Decarboxylative Conjunctive Cross-coupling of Vinyl Boronic Esters using Metallaphotoredox Catalysis

scientific article published on 03 February 2020

Delineation of the factors governing reactivity and selectivity in epoxide formation from ammonium ylides and aldehydes

scientific article published on 20 January 2006

Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds

scientific article published on 6 July 2016

Diastereodivergent synthesis of trisubstituted alkenes through protodeboronation of allylic boronic esters: application to the synthesis of the Californian red scale beetle pheromone

scientific article published on 5 November 2012

Diastereoselective synthesis of CF3-substituted, epoxide-fused heterocycles with β-(trifluoromethyl)vinylsulfonium salts

scientific article published on 11 December 2012

Diastereoselective synthesis of cyclopropane amino acids using diazo compounds generated in situ.

scientific article published in November 2003

Divergent, Stereospecific Mono- and Difluoromethylation of Boronic Esters

scientific article published on 28 February 2020

Effect of sulfide structure on enantioselectivity in catalytic asymmetric epoxidation of aldehydes: mechanistic insights and implications.

scholarly article

Efficient synthesis of cyclopropane-fused heterocycles with bromoethylsulfonium salt

scientific article published on 10 July 2013

Enantiodivergent Synthesis of Allenes by Point-to-Axial Chirality Transfer

scientific article published on 30 May 2018

Enantiodivergent Synthesis of Allenes by Point-to-Axial Chirality Transfer.

scientific article published on 30 May 2018

Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.

scientific article

Enantioenriched synthesis of Escitalopram using lithiation–borylation methodology

Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes.

scientific article published on 30 June 2017

Enantioselective Synthesis of the Cyclopiazonic Acid Family Using Sulfur Ylides

Enantioselective Synthesis of the Cyclopiazonic Acid Family Using Sulfur Ylides.

scientific article

Enantioselective alpha-arylation of cyclohexanones with diaryl iodonium salts: application to the synthesis of (-)-epibatidine

scientific article published in August 2005

Enantioselective construction of quaternary stereogenic centers from tertiary boronic esters: methodology and applications

scientific article published on 04 March 2011

Enantioselective installation of adjacent tertiary benzylic stereocentres using lithiation-borylation-protodeboronation methodology. Application to the synthesis of bifluranol and fluorohexestrol.

scientific article published on 28 April 2015

Enantioselective syntheses of (+)-sertraline and (+)-indatraline using lithiation/borylation-protodeboronation methodology

scientific article published on 13 October 2011

Enantioselective synthesis and cross-coupling of tertiary propargylic boronic esters using lithiation-borylation of propargylic carbamates

scientific article published on 17 October 2012

Enantioselective synthesis of (R)-tolterodine using lithiation/borylation-protodeboronation methodology

scientific article published on November 2012

Enantioselective α-Arylation of Cyclohexanones with Diaryl Iodonium Salts: Application to the Synthesis of (−)-Epibatidine

Enantiospecific Alkynylation of Alkylboronic Esters

scientific article published on 2 March 2016

Enantiospecific Alkynylation of Alkylboronic Esters.

scientific article published on 2 March 2016

Enantiospecific Synthesis of ortho -Substituted 1,1-Diarylalkanes by a 1,2-Metalate Rearrangement/anti -S N 2′ Elimination/Rearomatizing Allylic Suzuki-Miyaura Reaction Sequence

Enantiospecific Synthesis of ortho -Substituted 1,1-Diarylalkanes by a 1,2-Metalate Rearrangement/anti -S N 2′ Elimination/Rearomatizing Allylic Suzuki-Miyaura Reaction Sequence

scientific article published on 21 December 2018

Enantiospecific Synthesis of ortho-Substituted Benzylic Boronic Esters by a 1,2-Metalate Rearrangement/1,3-Borotropic Shift Sequence

scientific article

Enantiospecific Three-Component Alkylation of Furan and Indole.

scientific article published on 7 February 2018

Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans

scientific article published on 18 January 2017

Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans.

scientific article published on 18 January 2017

Enantiospecific sp(2)-sp(3) coupling of secondary and tertiary boronic esters

scientific article published on 8 June 2014

Enantiospecific sp2 -sp3 Coupling of ortho - and para -Phenols with Secondary and Tertiary Boronic Esters

scientific article published on 28 November 2017

Enantiospecific, regioselective cross-coupling reactions of secondary allylic boronic esters.

scientific article published on 2 December 2013

Epoxy-annulations by reactions of alpha-amido ketones with vinyl sulfonium salts. Reagent versus substrate control and kinetic resolution

scientific article published on 13 March 2008

Full chirality transfer in the conversion of secondary alcohols into tertiary boronic esters and alcohols using lithiation-borylation reactions

scientific article published on 01 July 2010

Generation of phosphoranes derived from phosphites. A new class of phosphorus ylides leading to high E selectivity with semi-stabilizing groups in Wittig olefinations.

scientific article

Gilbert Stork (1921-2017).

scientific article published on 29 November 2017

Hemiaminals as substrates for sulfur ylides: direct asymmetric syntheses of functionalised pyrrolidines and piperidines

scientific article published on 13 April 2006

Highly Diastereoselective Epoxidation of Ketene Dithioacetal Dioxides: A New Approach to the Asymmetric Synthesis of alpha-Amino Amides

scientific article published on 01 October 1998

Highly Enantioselective Synthesis of Tertiary Boronic Esters and their Stereospecific Conversion to other Functional Groups and Quaternary Stereocentres

Highly Selective Allylborations of Aldehydes Using α,α-Disubstituted Allylic Pinacol Boronic Esters

scientific article published on 05 May 2014

Highly diastereo- and enantioselective allylboration of aldehydes using α-substituted allyl/crotyl pinacol boronic esters via in situ generated borinic esters.

scientific article published on 27 March 2013

Highly diastereoselective 1,3-dipolar cycloaddition reactions of trans-2-methylene-1,3-dithiolane 1,3-dioxide with 3-oxidopyridinium and 3-oxidopyrylium betaines: a route to the tropane skeleton.

scientific article published in June 2003

Highly diastereoselective Diels-Alder reactions of Baylis-Hillman adducts

scientific article published on 01 June 2005

Highly diastereoselective Simmons-Smith cyclopropanation of allylic amines

scientific article published on 01 November 2003

Highly diastereoselective and enantiospecific allylation of ketones and imines using borinic esters: contiguous quaternary stereogenic centers

scientific article published on 25 August 2014

Highly diastereoselective aziridination of imines with trimethylsilyldiazomethane. Subsequent silyl substitution with electrophiles, ring opening, and metalation of C-silylaziridines--a cornucopia of highly selective transformations

scientific article

Highly diastereoselective nitrone cycloaddition onto a chiral ketene equivalent: asymmetric synthesis of cispentacin

scientific article published on 01 April 2002

Highly enantioselective darzens reaction of a camphor-derived sulfonium amide to give glycidic amides and their applications in synthesis

scientific article published in August 2002

Highly enantioselective oxidations of ketene dithioacetals leading to trans bis-sulfoxides

scientific article published in May 2003

Highly enantioselective synthesis of glycidic amides using camphor-derived sulfonium salts. Mechanism and applications in synthesis

scientific article published in February 2006

Highly regioselective and diastereoselective epoxidation of allylic amines with Oxone

scientific article published on 09 June 2005

Homologation and alkylation of boronic esters and boranes by 1,2-metallate rearrangement of boronate complexes.

scientific article published on January 2009

Homologation of Boronic Esters with Lithiated Epoxides for the Stereocontrolled Synthesis of 1,2- and 1,3-Diols and 1,2,4-Triols

scientific article published on 01 January 2009

Homologation of Boronic Esters with Organolithium Compounds: A Computational Assessment of Mechanism

scientific article published on 28 October 2014

Investigation of the Deprotonative Generation and Borylation of Diamine-Ligated α-Lithiated Carbamates and Benzoates by in Situ IR spectroscopy

scientific article published in 2018

Investigation of the Deprotonative Generation and Borylation of Diamine-Ligated α-Lithiated Carbamates and Benzoates by in Situ IR spectroscopy

scientific article published on 27 September 2018

Iridium-Catalyzed Enantioselective Synthesis of α-Chiral Bicyclo[1.1.1]pentanes by 1,3-Difunctionalization of [1.1.1]Propellane

scientific article published on 08 July 2020

Is phenyl a good migrating group in the rearrangement of organoborates generated from sulfur ylides?

scientific article published on 5 January 2006

Iterative assembly line synthesis of polypropionates with full stereocontrol

scientific article

Ligand-induced control of C-H versus aliphatic C-C migration reactions of Rh carbenoids.

scientific article published in March 2006

Lithiated carbamates: chiral carbenoids for iterative homologation of boranes and boronic esters

scientific article published on 01 January 2007

Lithiation and Reactions of Stilbene Oxides: Synthetic Utility

Lithiation and reactions of stilbene oxides: synthetic utility

scientific article published on 01 November 2004

Lithiation–Borylation Methodology and Its Application in Synthesis

scientific article published on 29 September 2014

Lithium-Boron Chemistry: A Synergistic Strategy in Modern Synthesis

Mechanism of the Morita-Baylis-Hillman reaction: a computational investigation

scientific article published on 28 November 2007

Merging Photoredox with 1,2-Metallate Rearrangements: The Photochemical Alkylation of Vinyl Boronate Complexes

scientific article published on 12 April 2017

Metal- and Ligand-Accelerated Catalysis of the Baylis-Hillman Reaction

scientific article published on 01 October 1998

Metal-free photoinduced C(sp3)-H borylation of alkanes

scientific article published on 28 October 2020

Methylenespiro[2.3]hexanes via Nickel-Catalyzed Cyclopropanations with [1.1.1]Propellane

scientific article published on 16 December 2019

New insights in the mechanism of amine catalyzed epoxidation: dual role of protonated ammonium salts as both phase transfer catalysts and activators of oxone

scientific article

Odd-even alternations in helical propensity of a homologous series of hydrocarbons

scientific article published on 02 March 2020

On the Importance of Leaving Group Ability in Reactions of Ammonium, Oxonium, Phosphonium, and Sulfonium Ylides

scientific article published on 01 August 2005

On the mechanism of ylide-mediated cyclopropanations: evidence for a proton-transfer step and its effect on stereoselectivity.

scientific article published in June 2010

On the origin of high E selectivity in the Wittig reaction of stabilized ylides: importance of dipole-dipole interactions

scientific article

One-pot synthesis of 2,3,4,5,6-pentasubstituted tetrahydropyrans using lithiation–borylation, allylation and Prins cyclisation reactions

Organic chemistry: reactions at the end of a tether

scientific article published on 01 July 2012

Organic synthesis: New uses for old building blocks

scientific article published on 01 September 2009

Palladium catalysed cyclisation-carbonylation of enynes to give cyclic gamma,delta-unsaturated acids.

scientific article published in May 2003

Palladium-catalyzed insertion of CO2 into vinylaziridines: new route to 5-vinyloxazolidinones

scientific article published on 06 June 2011

Palladium-mediated annulation of vinyl aziridines with Michael acceptors: stereocontrolled synthesis of substituted pyrrolidines and its application in a formal synthesis of (-)-α-kainic acid

scientific article published on 27 May 2011

Photoinduced Deaminative Borylation of Alkylamines

scientific article published on 21 August 2018

Photoinduced Deoxygenative Borylations of Aliphatic Alcohols

scientific article published on 11 November 2019

Photoinduced Fragmentation Borylation of Cyclic Alcohols and Hemiacetals

scientific article published on 09 September 2020

Photoinduced decarboxylative borylation of carboxylic acids.

scientific article published on 15 June 2017

Photoredox-Catalyzed Cyclobutane Synthesis by a Deboronative Radical Addition-Polar Cyclization Cascade

article

Practical and highly selective sulfur ylide mediated asymmetric epoxidations and aziridinations using an inexpensive, readily available chiral sulfide. Applications to the synthesis of quinine and quinidine.

scientific article published in February 2010

Practical and highly selective sulfur ylide-mediated asymmetric epoxidations and aziridinations using a cheap and readily available chiral sulfide: extensive studies to map out scope, limitations, and rationalization of diastereo- and enantioselecti

scientific article

Profile. Varinder Aggarwal

scientific article published in February 2003

Prostaglandin Total Synthesis Enabled by the Organocatalytic Dimerization of Succinaldehyde

scientific article published on 16 July 2020

Protodeboronation of tertiary boronic esters: asymmetric synthesis of tertiary alkyl stereogenic centers

scientific article published on 16 November 2010

QM and QM/MM studies of selectivity in organic and bioorganic chemistry

Radical Addition to Strained σ-Bonds Enables the Stereocontrolled Synthesis of Cyclobutyl Boronic Esters

scientific article published on 05 June 2019

Rate acceleration of the Baylis-Hillman reaction in polar solvents (water and formamide). Dominant role of hydrogen bonding, not hydrophobic effects, is implicated

scientific article published in January 2002

Reactions of iminium ions with Michael acceptors through a Morita-Baylis-Hillman-type reaction: enantiocontrol and applications in synthesis

scientific article published on 01 January 2007

Reactions of silyl-stabilised sulfur ylides with organoboranes: enantioselectivity, mechanism, and understanding

scientific article published on 28 February 2008

Reactivity and selectivity in the Wittig reaction: a computational study

scientific article published in February 2006

Readily synthesized chiral sulfides as reagents for asymmetric epoxidation

scientific article published on 01 September 2006

Reagent controlled addition of chiral sulfur ylides to chiral aldehydes

scientific article published on 26 August 2005

Reagent-Controlled Lithiation–Borylation

Reevaluation of the Mechanism of the Baylis-Hillman Reaction: Implications for Asymmetric Catalysis

scientific article published on 01 March 2005

Regio- and Stereoselective Homologation of 1,2-Bis(Boronic Esters): Stereocontrolled Synthesis of 1,3-Diols and Sch 725674

scientific article published on 26 October 2016

Regio- and Stereoselective Homologation of 1,2-Bis(Boronic Esters): Stereocontrolled Synthesis of 1,3-Diols and Sch 725674

Remote chiral induction in vinyl sulfonium salt-mediated ring expansion of hemiaminals into epoxide-fused azepines

scientific article published on 23 December 2010

Reoptimization of the Organocatalyzed Double Aldol Domino Process to a Key Enal Intermediate and Its Application to the Total Synthesis of Δ -Prostaglandin J

scientific article published on 06 June 2018

Revising the structure of a new eicosanoid from human platelets to 8,9-11,12-diepoxy-13-hydroxyeicosadienoic acid.

scientific article published in 2019

Ring-Expansion Induced 1,2-Metalate Rearrangements: Highly Diastereoselective Synthesis of Cyclobutyl Boronic Esters

scientific article published on 12 March 2020

Ring-Opening Lithiation-Borylation of 2-Trifluoromethyl Oxirane: A Route to Versatile Tertiary Trifluoromethyl Boronic Esters

scientific article published on 02 December 2019

Selective uni- and bidirectional homologation of diborylmethane

scientific article published on 9 February 2017

Short Convergent Synthesis of the Mycolactone Core Through Lithiation-Borylation Homologations

scientific article published on 01 September 2015

Short Enantioselective Total Synthesis of Tatanan A and 3-epi-Tatanan A Using Assembly-Line Synthesis

scientific article published on 16 November 2016

Short Enantioselective Total Synthesis of Tatanan A and 3-epi-Tatanan A Using Assembly-Line Synthesis.

scientific article published on 16 November 2016

Short stereoselective synthesis of the Phytophthora universal mating hormone α1 using lithiation/borylation reactions

scientific article published on 14 March 2014

Stereo- and Regiocontrolled Methylboration of Terminal Alkynes.

scientific article published on 9 May 2018

Stereocontrolled Synthesis of 1,5-Stereogenic Centers through Three-Carbon Homologation of Boronic Esters

scientific article published on 15 July 2014

Stereocontrolled Synthesis of Polypropionate Fragments based on a Building Block Assembly Strategy using Lithiation-Borylation Methodologies.

scientific article published on 20 November 2017

Stereocontrolled Synthesis of β-Amino Alcohols from Lithiated Aziridines and Boronic Esters

scientific article published on 01 January 2009

Stereocontrolled Total Synthesis of (-)-Stemaphylline

scientific article published on 18 January 2017

Stereocontrolled Total Synthesis of (−)-Stemaphylline

scientific article published on 18 January 2017

Stereocontrolled asymmetric synthesis of syn-E-1,4-diol-2-enes using allyl boronates and its application in the total synthesis of solandelactone F

scientific article published on 18 January 2012

Stereocontrolled organocatalytic synthesis of prostaglandin PGF2α in seven steps

scientific article

Stereocontrolled synthesis of adjacent acyclic quaternary-tertiary motifs: application to a concise total synthesis of (-)-filiformin

scientific article published on 22 April 2014

Stereocontrolled synthesis of carbon chains bearing contiguous methyl groups by iterative boronic ester homologations: application to the total synthesis of (+)-faranal

scientific article published on 01 January 2009

Stereodivergent Olefination of Enantioenriched Boronic Esters

scientific article published on 13 December 2016

Stereodivergent Olefination of Enantioenriched Boronic Esters

Stereoselective synthesis of trans-β-lactams by palladium-catalysed carbonylation of vinyl aziridines

scientific article published on 27 November 2009

Stereoselective total synthesis of (+)-giganin and its C10 epimer by using late-stage lithiation-borylation methodology

scientific article

Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles.

scientific article published on 13 October 2017

Stereospecific Coupling of Boronic Esters with N-Heteroaromatic Compounds

scientific article published on 21 August 2015

Stereospecific Couplings of Secondary and Tertiary Boronic Esters

scientific article published on 20 November 2014

Stereospecific conversion of alcohols into pinacol boronic esters using lithiation–borylation methodology with pinacolborane

scientific article published on 01 April 2014

Stereospecific functionalizations and transformations of secondary and tertiary boronic esters

scientific article published on 11 April 2017

Strain Release of Donor-Acceptor Cyclopropyl Boronate Complexes

scientific article published on 24 April 2019

Strain-Release-Driven Homologation of Boronic Esters: Application to the Modular Synthesis of Azetidines

scientific article published on 11 March 2019

Structure and reactivity of boron-ate complexes derived from primary and secondary boronic esters

scientific article published on 14 May 2015

Stuart Warren (24 Dec 1938-22 Mar 2020)

scientific article published on 16 September 2020

Studies on the Asymmetric Oxidation of Ester Derivatives of 1,3-Dithiane-2-carboxylates. Asymmetric Synthesis of trans-1,3-Dithiane 1,3-Dioxide

scientific article published on 01 October 1998

Sulfur-ylide-mediated synthesis of functionalized and trisubstituted epoxides with high enantioselectivity; application to the synthesis of CDP-840.

scientific article

Synergy of synthesis, computation and NMR reveals correct baulamycin structures.

scientific article published in July 2017

Synthesis and application of easily recyclable thiomorpholines for use in sulfur ylide mediated asymmetric epoxidation of aldehydes

scientific article published in September 2008

Synthesis and applications of chiral organoboranes generated from sulfonium ylides

scientific article published in February 2005

Synthesis of 6- and 7-Membered N-Heterocycles Using α-Phenylvinylsulfonium Salts

scientific article published on 30 September 2015

Synthesis of Alfaprostol and PGF2α through 1,4-Addition of an Alkyne to an Enal Intermediate as the Key Step

scientific article published on 24 October 2017

Synthesis of Enantioenriched Alkylfluorides by the Fluorination of Boronate Complexes

scientific article published on 05 August 2015

Synthesis of Functionalized Alkenes by a Transition-Metal-Free Zweifel Coupling

scientific article published on 28 April 2017

Synthesis of Functionalized Cyclopropanes from Carboxylic Acids by a Radical Addition-Polar Cyclization Cascade

scientific article published on 19 November 2018

Synthesis of Functionalized Cyclopropanes from Carboxylic Acids by a Radical Addition-Polar Cyclization Cascade

scientific article published on 25 October 2018

Synthesis of enantioenriched tertiary boronic esters by the lithiation/borylation of secondary alkyl benzoates

scientific article published on 18 October 2013

Synthesis of enantioenriched tertiary boronic esters from secondary allylic carbamates. Application to the synthesis of C30 botryococcene

scientific article published on 23 April 2012

Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners

scientific article published on 01 July 2002

Synthesis of highly enantioenriched C-tertiary amines from boronic esters: application to the synthesis of igmesine

scientific article published on 29 December 2010

Synthesis of hydroxyphthioceranic acid using a traceless lithiation-borylation-protodeboronation strategy.

scientific article published on 27 July 2014

Synthesis of prostaglandin analogues, latanoprost and bimatoprost, using organocatalysis via a key bicyclic enal intermediate

scientific article published on 12 January 2015

Synthesis of α-substituted vinylsulfonium salts and their application as annulation reagents in the formation of epoxide- and cyclopropane-fused heterocycles

scientific article published on 13 October 2014

Tandem Allylboration-Prins Reaction for the Rapid Construction of Substituted Tetrahydropyrans: Application to the Total Synthesis of (-)-Clavosolide A.

scientific article published on 14 January 2016

Tandem Allylboration-Prins Reaction for the Rapid Construction of Substituted Tetrahydropyrans: Application to the Total Synthesis of (−)-Clavosolide A

scientific article published on 14 January 2016

Tandem formation and [2,3] rearrangement of methylene ammonium ylides derived from amines and the Simmons-Smith reagent

scientific article published on 01 May 2003

The Story behind "Synergy of Synthesis, Computation, and NMR Reveals Correct Baulamycin Structures".

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The complexity of catalysis: origins of enantio- and diastereocontrol in sulfur ylide mediated epoxidation reactions

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The use of enantiomerically pure ketene dithioacetal bis(sulfoxides) in highly diastereoselective intramolecular nitrone cycloadditions. Application in the total synthesis of the beta-amino acid (-)-cispentacin and the first asymmetric synthesis of

The use of vinyl sulfonium salts in the stereocontrolled asymmetric synthesis of epoxide- and aziridine-fused heterocycles: application to the synthesis of (-)-balanol

scientific article published on 01 October 2006

Total Synthesis of Thromboxane B2 via a Key Bicyclic Enal Intermediate

scientific article published on 07 August 2020

Total synthesis of (+)-erogorgiaene using lithiation-borylation methodology, and stereoselective synthesis of each of its diastereoisomers

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Toward ideality: the synthesis of (+)-kalkitoxin and (+)-hydroxyphthioceranic acid by assembly-line synthesis.

scientific article published on 27 January 2015

Trapping‐Enrichment Multi‐dimensional Liquid Chromatography with On‐Line Deuterated Solvent Exchange for Streamlined Structure Elucidation at the Microgram Scale

Unexpected side reactions of imidazolium-based ionic liquids in the base-catalysed Baylis-Hillman reaction

scientific article published on 01 August 2002

Unraveling the mechanism of epoxide formation from sulfur ylides and aldehydes

scientific article published on May 2002

Use of alkyl 2,4,6-triisopropylbenzoates in the asymmetric homologation of challenging boronic esters

scientific article published on 05 September 2011

Vinylidene Homologation of Boronic Esters and its Application to the Synthesis of the Proposed Structure of Machillene

scientific article published on 18 September 2019

Visible-Light-Driven Strain-Increase Ring Contraction Allows the Synthesis of Cyclobutyl Boronic Esters

scientific article published on 31 January 2020

Visible-Light-Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ-Amino Boronic Esters

article

Visible-Light-Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ-Amino Boronic Esters.

scientific article published on 8 January 2018

ortho -Directing Chromium Arene Complexes as Efficient Mediators for Enantiospecific C(sp2 )-C(sp3 ) Cross-Coupling Reactions

scientific article published on 3 January 2018

ortho-Directing Chromium Arene Complexes as Efficient Mediators for Enantiospecific C(sp2 )-C(sp3 ) Cross-Coupling Reactions

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α-Sulfinyl Benzoates as Precursors to Li and Mg Carbenoids for the Stereoselective Iterative Homologation of Boronic Esters.

scientific article published on 16 August 2017

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