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List of works by Herbert Mayr

"Carbocation watching" in solvolysis reactions

scientific article published on 01 January 2008

(R,E)-3-(4-Chlorophenyl)-1-phenylallyl 4-nitrobenzoate ⬇️

scientific article published on July 25, 2012

(Z)-2-[Meth-oxy(phen-yl)methyl-idene]-3,4,5-trimethyl-2,3-dihydro-1,3-thia-zole.

scientific article published on 4 August 2012

1-[2,2-Bis(phenyl-sulfon-yl)ethen-yl]-4-meth-oxy-benzene

scientific article published on 21 January 2012

2-(4-Meth-oxy-benzyl-idene)-2H-1,3-benzodithiole 1,1,3,3-tetra-oxide.

scientific article published on 4 February 2012

4,4'-Bis(dimethyl-amino)benzhydryl phenyl sulfone

scientific article published on 7 November 2009

4-[4-(Dimethylamino)benzylidene]-2,6-dimethylcyclohexa-2,5-dienone ⬇️

scientific article published on August 8, 2009

5-[(E)-Meth-oxy(phen-yl)methyl-idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole.

scientific article published on 10 November 2012

A comprehensive microscopic picture of the benzhydryl radical and cation photogeneration and interconversion through electron transfer.

scientific article published on 28 March 2013

A practical guide for estimating rates of heterolysis reactions

scientific article published on 17 November 2010

A quantitative approach to nucleophilic organocatalysis ⬇️

scientific article published on September 5, 2012

Ambident Reactivity of Acetyl- and Formyl-Stabilized Phosphonium Ylides

scientific article published on 24 August 2016

Ambident Reactivity of Phenolate Anions Revisited: A Quantitative Approach to Phenolate Reactivities

scientific article published on 26 June 2019

Ambident Reactivity of the Thiocyanate Anion Revisited: Can the Product Ratio Be Explained by the Hard Soft Acid Base Principle? ⬇️

scientific article published on November 19, 2003

Ambident reactivities of formaldehyde N,N-dialkylhydrazones

scientific article published on 19 September 2013

Ambident reactivities of methylhydrazines

scientific article published on 23 December 2011

Ambident reactivities of pyridone anions.

scientific article published on November 2010

Ambident reactivity of the cyanate anion

scientific article published in January 2008

Ambident reactivity of the cyanide ion: a failure of the HSAB principle

scientific article

Ambident reactivity of the nitrite ion revisited

scientific article published on 01 July 2005

Basicities and Nucleophilicities of Pyrrolidines and Imidazolidinones Used as Organocatalysts

scientific article published on 08 January 2020

Benzhydryl phenyl sulfone.

scientific article published on 28 November 2009

Can one predict changes from S(N)1 to S(N)2 mechanisms?

scientific article

Carbocationic n-endo-trig cyclizations

scientific article

Characterization of the nucleophilic reactivities of thiocarboxylate, dithiocarbonate and dithiocarbamate anions

scientific article

Copper(I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and aryl magnesium reagents

scientific article published on 01 January 2007

Corrigendum: The Nucleophilicity of Persistent α-Monofluoromethide Anions

scientific article published on 01 November 2016

Counterion effects in iminium-activated electrophilic aromatic substitutions of pyrroles

scientific article published on 07 December 2010

Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl-spiro-[2.5]octane-1-carbaldehyde

scientific article published on 30 January 2016

Crystal structure of 2-[chloro-(4-meth-oxy-phen-yl)meth-yl]-2-(4-meth-oxy-phen-yl)-5,5-di-methyl-cyclo-hexane-1,3-dione.

scientific article published on 06 February 2016

DABCO and DMAP--why are they different in organocatalysis?

scientific article published on 01 January 2007

Determination of the electrophilicity parameters of diethyl benzylidenemalonates in dimethyl sulfoxide: reference electrophiles for characterizing strong nucleophiles

scientific article

Di- and triarylmethylium ions as probes for the ambident reactivities of carbanions derived from 5-benzylated Meldrum's acid

scientific article published on 05 August 2014

Direct observation of the intermediate in vicarious nucleophilic substitutions of hydrogen

scientific article published on 01 June 2003

Direct observation of the ionization step in solvolysis reactions: electrophilicity versus electrofugality of carbocations

scientific article

Effect of the “Supersilyl” Group on the Reactivities of Allylsilanes and Silyl Enol Ethers ⬇️

scientific article published on October 26, 2010

Electrofugalities of 1,3-Diarylallyl Cations ⬇️

scientific article published on February 13, 2013

Electrophilic Aromatic Substitutions of Aryltrifluoroborates with Retention of the BF3– Group: Quantification of the Activating and Directing Effects of the Trifluoroborate Group ⬇️

scientific article published on April 12, 2013

Electrophilic Reactivities of Azodicarboxylates ⬇️

scientific article published on September 10, 2010

Electrophilic alkylations in neutral aqueous or alcoholic solutions

scientific article published on 01 October 2004

Electrophilic alkylations of vinylsilanes: a comparison of α- and β-silyl effects

scientific article published on 16 December 2013

Electrophilic allylations and benzylations of indoles in neutral aqueous or alcoholic solutions

scientific article published on 01 October 2006

Electrophilic reactivities of 1,2-diaza-1,3-dienes.

scientific article published in October 2010

Electrophilic reactivities of alpha,beta-unsaturated iminium ions

scientific article

Electrophilicities of Benzaldehyde-Derived Iminium Ions: Quantification of the Electrophilic Activation of Aldehydes by Iminium Formation ⬇️

scientific article published on April 23, 2013

Electrophilicities of alpha-chlorinating agents used in organocatalysis

scientific article published on 01 May 2010

Electrophilicities of bissulfonyl ethylenes

scientific article published on 27 March 2012

Electrophilicities of symmetrically substituted 1,3-diarylallyl cations

scientific article published on 19 October 2011

Electrophilicities of trans-β-nitrostyrenes

scientific article published on 18 October 2011

Electrophilicity of 5-benzylidene-1,3-dimethylbarbituric and -thiobarbituric acids

scientific article published on 27 October 2007

Electrophilicity parameters for 2-benzylidene-indan-1,3-diones--a systematic extension of the benzhydrylium based electrophilicity scale

scientific article published on 09 August 2007

Electrophilicity parameters for benzylidenemalononitriles

scientific article published in September 2003

Electrophilicity parameters of 5-benzylidene-2,2-dimethyl[1,3]dioxane-4,6-diones (benzylidene Meldrum's acids).

scientific article published on 4 March 2008

Electrophilicity versus electrofugality of tritylium ions in aqueous acetonitrile

scientific article

Enhancing the catalytic activity of 4-(dialkylamino)pyridines by conformational fixation

scientific article published on 01 October 2003

Ethenesulfonyl Fluoride: The Most Perfect Michael Acceptor Ever Found?

scientific article published on 9 May 2016

Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents

scientific article published on 03 September 2018

Farewell to the HSAB Treatment of Ambident Reactivity ⬇️

scientific article published on July 11, 2011

Fine-tuning the nucleophilic reactivities of boron ate complexes derived from aryl and heteroaryl boronic esters

scientific article published on 21 January 2015

First direct observation of the two distinct steps in an S(N)1 reaction

scientific article published on 01 December 2002

Free Energy Relationships for Reactions of Substituted Benzhydrylium Ions: From Enthalpy over Entropy to Diffusion Control ⬇️

scientific article published on August 13, 2012

From Carbodiimides to Carbon Dioxide: Quantification of the Electrophilic Reactivities of Heteroallenes

scientific article published on 27 April 2020

From carbanions to organometallic compounds: quantification of metal ion effects on nucleophilic reactivities

scientific article published on 7 May 2015

Generation of α,β-unsaturated iminium ions by laser flash photolysis

scientific article

Halide Anion Activated Reactions of Michael Acceptors with Tropylium Ion

Halide Anion Triggered Reactions of Michael Acceptors with Tropylium Ion

scientific article published on 04 December 2019

Herbert Mayr ⬇️

scientific article published on January 2, 2012

How constant are Ritchie's "constant selectivity relationships"? A general reactivity scale for n-, pi-, and sigma-nucleophiles

scientific article

How does electrostatic activation control iminium-catalyzed cyclopropanations?

scientific article published on 01 January 2009

How fast do R-X bonds ionize? A semiquantitative approach

scientific article published in February 2006

How nucleophilic are diazo compounds?

scientific article published in September 2003

Hydride-donor abilities of 1,4-dihydropyridines: a comparison with pi nucleophiles and borohydride anions

scientific article published on 01 January 2009

Hydrocarbation of C≡C bonds: quantification of the nucleophilic reactivity of ynamides

scientific article published on 08 April 2014

Imidazolidinone-derived enamines: nucleophiles with low reactivity

scientific article published on 25 April 2012

Influence of the N-Substituents on the Nucleophilicity and Lewis Basicity of N-Heterocyclic Carbenes.

scientific article

Inverse solvent effects in carbocation carbanion combination reactions: the unique behavior of trifluoromethylsulfonyl stabilized carbanions

scientific article published on 18 July 2007

Ion pair dynamics: solvolyses of chiral 1,3-diarylallyl carboxylates as a case study

scientific article published on 18 December 2012

Ion-pairing of phosphonium salts in solution: C-H⋅⋅⋅halogen and C-H⋅⋅⋅π hydrogen bonds.

scientific article published on 6 September 2013

Isothiourea-mediated asymmetric O- to C-carboxyl transfer of oxazolyl carbonates: structure-selectivity profiles and mechanistic studies

scientific article published on 19 January 2012

Kinetic evidence for the formation of oxazolidinones in the stereogenic step of proline-catalyzed reactions.

scientific article published on December 2010

Kinetic studies of carbocation-carbanion combinations: key to a general concept of polar organic reactivity

scientific article published on 01 January 2002

Kinetics and Mechanism of Oxirane Formation by Darzens Condensation of Ketones: Quantification of the Electrophilicities of Ketones

scientific article published on 16 April 2018

Kinetics and Mechanisms of the Reactions of π-Allylpalladium Complexes with Nucleophiles

scientific article published on 01 February 1999

Kinetics and mechanism of organocatalytic aza-Michael additions: direct observation of enamine intermediates

scientific article published on 28 March 2012

Kinetics of Electrophilic Fluorinations of Enamines and Carbanions: Comparison of the Fluorinating Power of N-F Reagents

scientific article published on 29 August 2018

Kinetics of bromine-magnesium exchange reactions in heteroaryl bromides

scientific article published on 01 August 2009

Kinetics of bromine-magnesium exchange reactions in substituted bromobenzenes

scientific article published in April 2009

Kinetics of hydride abstractions from 2-arylbenzimidazolines

scientific article published in December 2009

Kinetics of the reactions of halide anions with carbocations: quantitative energy profiles for s(n)1 reactions

scientific article published in March 2005

Kinetics of the solvolyses of benzhydryl derivatives: basis for the construction of a comprehensive nucleofugality scale

scientific article published in February 2006

Leaving group dependence of the rates of halogen-magnesium exchange reactions

scientific article published on 09 May 2012

Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases

scientific article published on 03 March 2020

Manifestation of polar reaction pathways of 2,3-dichloro-5,6-dicyano-p-benzoquinone

scientific article published on 12 August 2013

Marcus analysis of ambident reactivity

scientific article published on 01 July 2010

Mechanisms of hydride abstractions by quinones

scientific article published on 19 September 2014

N-Heterocyclic carbene boranes are good hydride donors

scientific article published on 13 December 2011

N-heterocyclic carbenes: organocatalysts with moderate nucleophilicity but extraordinarily high Lewis basicity

scientific article published on 28 June 2011

Negishi cross-couplings compatible with unprotected amide functions

scientific article published on 01 January 2009

Negishi cross-couplings of unsaturated halides bearing relatively acidic hydrogen atoms with organozinc reagents.

scientific article

New in situ trapping metalations of functionalized arenes and heteroarenes with TMPLi in the presence of ZnCl2 and other metal salts

scientific article published on 12 June 2014

Noncovalent interactions in organocatalysis: modulating conformational diversity and reactivity in the MacMillan catalyst

scientific article published on 21 June 2013

Nucleofugality and Nucleophilicity of Fluoride in Protic Solvents ⬇️

scientific article published on March 12, 2012

Nucleophilic Reactivities of Carbanions in Water: The Unique Behavior of the Malodinitrile Anion ⬇️

scientific article published on October 22, 2003

Nucleophilic Reactivities of Hydrazines and Amines: The Futile Search for the α-Effect in Hydrazine Reactivities ⬇️

scientific article published on September 6, 2012

Nucleophilic addition of enols and enamines to α,β-unsaturated acyl azoliums: mechanistic studies

scientific article published on 13 April 2012

Nucleophilic reactivities of benzenesulfonyl-substituted carbanions

scientific article published on 2 July 2008

Nucleophilic reactivities of deoxy Breslow intermediates: how does aromaticity affect the catalytic activities of N-heterocyclic carbenes?

scientific article published on 09 May 2012

Nucleophilic reactivities of imide and amide anions.

scientific article published on August 2010

Nucleophilic reactivities of indoles

scientific article published on 01 November 2006

Nucleophilic reactivities of sulfur ylides and related carbanions: comparison with structurally related organophosphorus compounds

scientific article published on 01 August 2010

Nucleophilic reactivities of the anions of nucleobases and their subunits

scientific article published on 08 December 2011

Nucleophilicities and Lewis basicities of imidazoles, benzimidazoles, and benzotriazoles

scientific article published in April 2010

Nucleophilicities and Lewis basicities of isothiourea derivatives

scientific article published on 26 May 2011

Nucleophilicities and carbon basicities of DBU and DBN.

scientific article published on 13 March 2008

Nucleophilicities and carbon basicities of pyridines

scientific article published in January 2007

Nucleophilicities of amino acids and peptides

scientific article published on 16 October 2007

Nucleophilicities of nitroalkyl anions

scientific article published in October 2004

Nucleophilicities of primary and secondary amines in water

scientific article published on 6 April 2007

Nucleophilicities of the anions of arylacetonitriles and arylpropionitriles in dimethyl sulfoxide

scientific article published in January 2009

Nucleophilicity Parameters of Arylsulfonyl-Substituted Halomethyl Anions.

scientific article published on 20 January 2017

Nucleophilicity Parameters of Stabilized Iodonium Ylides for Characterizing Their Synthetic Potential

scientific article published on 02 August 2016

Nucleophilicity and Electrophilicity Parameters for Predicting Absolute Rate Constants of Highly Asynchronous 1,3-Dipolar Cycloadditions of Aryldiazomethanes

scientific article published on 16 November 2018

Nucleophilicity and nucleofugality of phenylsulfinate (PhSO(2)(-)): a key to understanding its ambident reactivity

scientific article

Nucleophilicity of Alkyl Zirconocene and Titanocene Precatalysts, and Kinetics of Activation by Carbenium Ions and by B(C6 F5 )3.

scientific article published in June 2016

Nucleophilicity parameters for alkyl and aryl isocyanides

scientific article published on 01 January 2007

Nucleophilicity parameters for phosphoryl-stabilized carbanions and phosphorus ylides: implications for Wittig and related olefination reactions

scientific article

Nucleophilicity parameters of enamides and their implications for organocatalytic transformations

scientific article published on 27 March 2012

Nucleophilicity parameters of pyridinium ylides and their use in mechanistic analyses

scientific article published on 25 September 2013

Organocatalytic activity of cinchona alkaloids: which nitrogen is more nucleophilic?

scientific article published in September 2009

Philicities, Fugalities, and Equilibrium Constants

scientific article

Photogeneration of Benzhydryl Cations by Near-UV Laser Flash Photolysis of Pyridinium Salts ⬇️

scientific article published on August 14, 2012

Photolytic generation of benzhydryl cations and radicals from quaternary phosphonium salts: how highly reactive carbocations survive their first nanoseconds.

scientific article

Pi-nucleophilicity in carbon-carbon bond-forming reactions

scientific article published on 01 January 2003

Potassium [1-(tert-butoxycarbonyl)-1H-indol-3-yl]trifluoroborate hemihydrate ⬇️

scientific article published on April 6, 2012

Predicting Absolute Rate Constants for Huisgen Reactions of Unsaturated Iminium Ions with Diazoalkanes

scientific article published on 07 April 2020

Quantification and Theoretical Analysis of the Electrophilicities of Michael Acceptors

scientific article published on 18 September 2017

Quantification of ion-pairing effects on the nucleophilic reactivities of benzoyl- and phenyl-substituted carbanions in dimethylsulfoxide

scientific article published on 10 November 2014

Quantification of the Electrophilic Reactivities of Aldehydes, Imines, and Enones ⬇️

scientific article published on May 5, 2011

Quantification of the Electrophilicity of Benzyne and Related Intermediates

scientific article

Quantification of the ambident electrophilicities of halogen-substituted quinones

scientific article published on 05 August 2014

Rate-equilibrium relationships in hydride transfer reactions: the role of intrinsic barriers

scientific article published on 01 April 2002

Rates and equilibria of the reactions of tertiary phosphanes and phosphites with benzhydrylium ions

scientific article published in January 2005

Reactions of carbocations with unsaturated hydrocarbons: electrophilic alkylation or hydride abstraction?

scientific article published on 01 April 2002

Reactions of nitroheteroarenes with carbanions: bridging aromatic, heteroaromatic, and vinylic electrophilicity

scientific article published in January 2008

Regio- and stereoselective ring-opening reactions of epoxides with indoles and pyrroles in 2,2,2-trifluoroethanol

scientific article published in January 2008

Relationships between carbocation stabilities and electrophilic reactivity parameters, E: quantum mechanical studies of benzhydryl cation structures and stabilities

scientific article published in September 2002

Relative rates of bromine-magnesium exchange reactions in substituted bromobenzene derivatives

scientific article published in January 2008

Role of electron-transfer processes in reactions of diarylcarbenium ions and related quinone methides with nucleophiles

scientific article published in September 2003

Rolf Huisgen (1920-2020)

scientific article published on 06 July 2020

S(N)1 reactions with inverse rate profiles

scientific article published on 01 April 2004

SN2' versus SN2 reactivity: control of regioselectivity in conversions of Baylis-Hillman adducts

scientific article published in January 2010

Scales of Lewis basicities toward C-centered Lewis acids (carbocations)

scientific article published on 20 January 2015

Scales of Nucleophilicity and Electrophilicity: A System for Ordering Polar Organic and Organometallic Reactions

article

Scope and limitations of cyclopropanations with sulfur ylides.

scientific article published on 29 November 2010

Solvatation als Ursache für die unerwartete Nucleophilie-Reihung von Peroxid-Anionen

Solvation Accounts for the Counterintuitive Nucleophilicity Ordering of Peroxide Anions.

scientific article published on 16 August 2017

Solvent nucleophilicity

scientific article

Stabilities of trityl-protected substrates: the wide mechanistic spectrum of trityl ester hydrolyses

scientific article published in July 2010

Stereoselective synthesis and reactions of secondary alkyllithium reagents functionalized at the 3-position

scientific article published on 12 January 2015

Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles.

scientific article published on 13 October 2017

Structure and Reactivity of Indolylmethylium Ions: Scope and Limitations in Synthetic Applications

scientific article published on 18 August 2015

Structure and reactivity of boron-ate complexes derived from primary and secondary boronic esters

scientific article published on 14 May 2015

Structure-nucleophilicity relationships for enamines

scientific article published in May 2003

Structure-reactivity relationships in negishi cross-coupling reactions

scientific article published on 01 January 2010

Structures and ambident reactivities of azolium enolates

scientific article published on 29 July 2013

Structures and reactivities of 2-Trityl- and 2-(Triphenylsilyl)pyrrolidine-derived enamines: evidence for negative hyperconjugation with the trityl group

scientific article published on 24 September 2014

Structures and reactivities of O-methylated Breslow intermediates.

scientific article

Suppression of common-ion return by amines: a method to measure rates of fast S(N)1 reactions

scientific article published in October 2009

Synthesis and reactivity of highly nucleophilic pyridines

scientific article published on 27 December 2010

Synthesis of γ-lactones from alkenes employing p-methoxybenzyl chloride as +CH2CO−2 equivalent

The DMAP-catalyzed acetylation of alcohols--a mechanistic study (DMAP = 4-(dimethylamino)pyridine).

scientific article

The Influence of Perfluorinated Substituents on the Nucleophilic Reactivities of Silyl Enol Ethers ⬇️

scientific article published on July 25, 2012

The Nucleophilicity of Persistent α-Monofluoromethide Anions

scientific article published on 15 September 2016

The Reactivity–Selectivity Principle: An Imperishable Myth in Organic Chemistry

scientific article (publication date: 13 March 2006)

Thermodynamic stability and reactivity of silylated bis(oxy)iminium ions

scientific article published on 31 October 2007

Towards a Comprehensive Hydride Donor Ability Scale ⬇️

scientific article published on November 30, 2012

Towards a General Scale of Nucleophilicity?

scientific article published on 01 June 2006

Transition-metal-free homocoupling of organomagnesium compounds

scientific article published on 01 July 2006

Unexpected gas-phase reactivity of the CH3OH adduct of Michler's hydrol blue: proton-shuttle catalysis and stepwise radical expulsions.

scientific article published on 25 August 2007

Which Factors Control the Nucleophilic Reactivities of Enamines?

scientific article published in February 2018

Why Are Vinyl Cations Sluggish Electrophiles?

scientific article

trans-2-(2-Nitro-1-phenylethyl)cyclohexanone ⬇️

scientific article published on November 13, 2010

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