List of works - Max Malacria

5-Endo-TrigRadical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes

scientific article published on 01 June 1999

A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics

scientific article published on 06 July 2015

A general strategy for ligation of organic and biological molecules to Dawson and Keggin polyoxotungstates

scientific article published on 08 September 2007

A molecular approach to self-assembly of trimethylsilylacetylene derivatives on gold.

scientific article

A new practical one-pot access to sulfonimidates

scientific article published on 01 November 2002

A stereoselective route toward polyhydoxylated piperidines. A total synthesis of (+/-)-deoxymannojirimycin

scientific article published on 01 October 2005

Activation of allenes by gold complexes: a theoretical standpoint

scientific article published on January 2011

Air-stable {(C5H5)Co} catalysts for [2+2+2] cycloadditions

scientific article published in January 2009

Alkyne versus allene activation in platinum- and gold-catalyzed cycloisomerization of hydroxylated 1,5-allenynes

scientific article published in January 2008

All-metal aromatic cationic palladium triangles can mimic aromatic donor ligands with Lewis acidic cations.

scientific article

Atroposelective [2+2+2] cycloadditions catalyzed by a rhodium(I)-chiral phosphate system.

scientific article published in September 2013

AuI-catalyzed cycloisomerization of 1,5-enynes bearing a propargylic acetate: formation of unexpected bicyclo[3.1.0]hexene

scientific article published on 13 April 2006

Bi-directional alkyne tandem isomerization via Pd(0)/carboxylic acid joint catalysis: expedient access to 1,3-dienes

scientific article published on 01 December 2018

Boosting catalyst activity in cis-selective semi-reduction of internal alkynes by tailoring the assembly of all-metal aromatic tri-palladium complexes.

scientific article published in October 2016

Boryltrihydroborate: synthesis, structure, and reactivity as a reductant in ionic, organometallic, and radical reactions

scientific article published on August 2010

CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃ ⬇️

scientific article published on August 2, 2010

Carbonyl-Inserted Organo-Hybrids of a Dawson-Type Phosphovanadotungstate: Scope and Chemoselective Oxidation Catalysis

scientific article published on 26 October 2011

Catalytic Cycloaddition Reactions

Catalytic version of enediyne cobalt-mediated cycloaddition and selective access to unusual bicyclic trienes

scientific article

Chemo- and stereoselective palladium-catalyzed allylic alkylations controlled by silicon.

scientific article published in July 2003

Chemo-, regio-, and stereoselective cobalt-mediated [2+2+2] cycloaddition of alkynyl boronates to alkenes: 1,3- and 1,4-diboryl-1,3-cyclohexadienes

scientific article

Chemoselective catalysis with organosoluble Lewis acidic polyoxotungstates

scientific article published on 01 June 2010

Chiral recognition of hybrid metal oxide by peptides

scientific article published on 01 January 2009

Cobalt(I)-mediated [2 + 2 + 2] cyclization of allenediynes toward a diastereoselective approach to 11-aryl steroid skeletons

scientific article published on 01 October 2004

Cobalt(I)-mediated preparation of polyborylated cyclohexadienes: scope, limitations, and mechanistic insight

scientific article published on 01 January 2007

Cobalt-catalyzed cyclotrimerization of alkynes: the answer to the puzzle of parallel reaction pathways

scientific article

Cobalt-mediated [2+2+2] cycloaddition versus C-H and N-H activation of 2-pyridones and pyrazinones with alkynes: a theoretical study.

scientific article published in January 2007

Cobalt-mediated [2+2+2] cycloaddition versus C-H and N-H activation of pyridones and pyrazinones with alkynes: an experimental study

scientific article published on 01 January 2007

Cobalt-mediated cyclic and linear 2:1 cooligomerization of alkynes with alkenes: a DFT study

scientific article published on 01 July 2006

Cobalt-mediated linear 2:1 co-oligomerization of alkynes with enol ethers to give 1-alkoxy-1,3,5-trienes: a missing mode of reactivity

scientific article published on August 2010

Cobalt-mediated regio- and stereoselective assembly of dienamides by hydroaminative alkyne coupling of alpha,omega-diynes

scientific article

Combination of gold catalysis and Selectfluor for the synthesis of fluorinated nitrogen heterocycles

scientific article published on 7 October 2011

Complexes of borane and N-heterocyclic carbenes: a new class of radical hydrogen atom donor

scientific article published on 9 July 2008

Conjugate Additions to Alkylidene Bis(Sulfoxides)

article

Convergent preparation of enantiomerically pure polyalkylated cyclopropane derivatives

scientific article published in January 2008

Diastereoselective cobalt-mediated [2 + 2 + 2] cycloadditions of substituted linear enediynes phosphine oxides: scope and limitations

scientific article published on 01 January 2003

Diastereoselective synthesis of dibenzoazepines through chelation on palladium(IV) intermediates

scientific article published on 31 December 2013

Diastereoselective synthesis of enantiopure acyclic beta,beta'-disubstituted vinylsulfoxides

scientific article published on 12 April 2008

EPR studies of the generation, structure, and reactivity of n-heterocyclic carbene borane radicals

scientific article published in February 2010

Efficient copper-mediated reactions of nitrenes derived from sulfonimidamides

scientific article published on 01 September 2004

Efficient preparation of functionalized hybrid organic/inorganic Wells-Dawson-type polyoxotungstates

scientific article published on 01 May 2005

Electron paramagnetic resonance and computational studies of radicals derived from boron-substituted N-heterocyclic carbene boranes

scientific article published on 14 June 2011

Enantioselective Ir(I)-catalyzed carbocyclization of 1,6-enynes by the chiral counterion strategy

scientific article published on 03 November 2011

Estimated rate constants for hydrogen abstraction from N-heterocyclic carbene-borane complexes by an alkyl radical

scientific article published in July 2010

Exception to the ortho effect in palladium/norbornene catalysis

scientific article published on 21 October 2011

Expeditious Synthesis of Phenanthridines from Benzylamines via Dual Palladium Catalysis

scientific article published on 17 November 2010

First Tandem Radical Cyclization/Intramolecular Diels-Alder Reaction

Fixation of the Two Tabun Isomers in Acetylcholinesterase: A QM/MM Study

Formation of cyclic sulfinates and sulfinamides through homolytic substitution at the sulfur atom

scientific article published on 01 January 2006

From Acyclic Precursors to Linear Triquinanes through a Diastereoselective One-Pot Process. A New Illustration of the Synthetic Power of Radical Cascades

scientific article published on 01 October 1998

From PtCl(2)- and acid-catalyzed to uncatalyzed cycloisomerization of 2-propargyl anilines: access to functionalized indoles

scientific article published on 01 January 2007

Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion

article

Generation and trapping of cyclopentenylidene gold species: four pathways to polycyclic compounds

scientific article published on 01 March 2009

Generation of phosphorus-centered radicals via homolytic substitution at sulfur.

scientific article published on 23 February 2007

Gold Compounds Anchored to a Metalated Arene Scaffold: Synthesis, X-ray Molecular Structures, and Cycloisomerization of Enyne

Gold(I)- and gold(III)-catalyzed cycloisomerization of allenynes: a remarkable halide effect

scientific article published on 01 November 2006

Gold(I)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

scientific article published on 07 January 2010

Gold(I)-catalyzed cyclization of β-allenylhydrazones: an efficient synthesis of multisubstituted N-aminopyrroles

scientific article published on 01 October 2010

Gold- and platinum-catalyzed cycloisomerization of enynyl esters versus allenenyl esters: an experimental and theoretical study

scientific article published in January 2009

Gold-catalyzed 1,3-acyloxy migration/5-exo-dig cyclization/1,5-acyl migration of diynyl esters

scientific article published on 10 June 2011

Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle

scientific article published on 01 January 2008

Highly Diastereoselective Conjugate Addition to Alkylidene Bis(Sulfoxides): Asymmetric Synthesis of (+)‐erythro‐Roccellic Acid ⬇️

scientific article published on November 10, 2003

Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides

scientific article published on 21 June 2007

Highly efficient peptide bond formation to functionalized Wells-Dawson-type polyoxotungstates

scientific article published on 01 July 2003

Highly enantioselective rhodium-catalyzed [2+2+2] cycloaddition of diynes to sulfonimines

scientific article published on 13 March 2013

Homolytic reduction of onium salts

scientific article published on January 2012

Identification of polyoxometalates as nanomolar noncompetitive inhibitors of protein kinase CK2.

scientific article published in July 2008

Improved method for the iodine(III)-mediated preparation of aryl sulfonimidates

scientific article published on 01 January 2006

Increased Lewis acidity in hafnium-substituted polyoxotungstates

scientific article published on 01 January 2007

Insertion of amides into a polyoxometalate

scientific article published on 01 January 2009

Intramolecular anion effect in polyoxometalate-based organocatalysts: reactivity enhancement and chirality transfer by a metal oxide-organic cation interaction

scientific article published on 24 October 2014

Intramolecular homolytic substitution of sulfinates and sulfinamides

scientific article published in October 2009

Intramolecular homolytic substitution of sulfinates and sulfinamides--a computational study

scientific article published on 29 March 2011

Iodine(III)-mediated preparations of nitrogen-containing sulfur derivatives: dramatic influence of the sulfur oxidation state.

scientific article published in February 2004

Ionic and organometallic reductions with N-heterocyclic carbene boranes

scientific article published on 01 December 2009

Iron-catalyzed reductive radical cyclization of organic halides in the presence of NaBH4: evidence of an active hydrido iron(I) catalyst

scientific article published on 11 June 2012

Lanthanide complexes of the monovacant Dawson polyoxotungstate [alpha1-P2W17O61]10- as selective and recoverable Lewis acid catalysts

scientific article published on 01 May 2006

Lanthanide polyoxocationic complexes: experimental and theoretical stability studies and Lewis acid catalysis

scientific article

Lewis-acidic polyoxometalates as reusable catalysts for the synthesis of glucuronic acid esters under microwave irradiation

scientific article published on 01 November 2010

Long-range self-assembly of a polyunsaturated linear organosilane at the n-tetradecane/Au(111) interface studied by STM.

scientific article published in August 2002

Metalated-Arene-Phosphino Ligands: A Novel Approach to Open-Sided Gold Compounds

article

Molecular complexity from polyunsaturated substrates: the gold catalysis approach

scientific article published on 24 February 2014

N-Silyl-Tethered Radical Cyclizations: A New Synthesis of γ-Amino Alcohols ⬇️

scientific article published on April 17, 2003

N-heterocyclic carbene boryl radicals: a new class of boron-centered radical.

scientific article published in August 2009

N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes

scientific article published on 27 July 2011

N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation

scientific article published in May 2013

New Cobalt-Catalyzed Cycloisomerization of epsilon-Acetylenic beta-Keto Esters. Application to a Powerful Cyclization Reactions Cascade

scientific article published on 01 April 1996

New Elements on the Behaviour of a Bissulfinylmethyl Radical

New and efficient procedure for the preparation of unsymmetrical silaketals

scientific article published on 01 June 2003

New efficient construction of the ABC core of the taxoids via a sequence of consecutive cobalt(I)-mediated [2 + 2 + 2] and [4 + 2] cyclizations

scientific article published on 01 March 2002

Non-Innocent Ligands: New Opportunities in Iron Catalysis

Of the Ortho Effect in Palladium/Norbornene-Catalyzed Reactions: A Theoretical Investigation

scientific article published on 12 May 2011

Orthogonal Syntheses of 3.2.0 Bicycles from Enallenes Promoted by Visible Light

scientific article published on 05 August 2020

Oxidation of alkyl trifluoroborates: an opportunity for tin-free radical chemistry

scientific article published on 01 November 2010

Oxidation of alpha-alkoxy allenes into alpha'-alkoxy enones

scientific article published on 01 September 2010

Palladium-Catalyzed Reaction of Aryl Iodides with ortho-Bromoanilines and Norbornene/Norbornadiene: Unexpected Formation of Dibenzoazepine Derivatives

Palladium-catalyzed reaction of aryl iodides with ortho-bromoanilines and norbornene/norbornadiene: unexpected formation of dibenzoazepine derivatives

scientific article published on 26 October 2011

Palladium/norbornene catalytic system: chelation as a tool to control regioselectivity of Pd(IV) reductive elimination

scientific article

Pd Catalysis in Cyanide-Free Synthesis of Nitriles from Haloarenes via Isoxazolines

scientific article published on 14 November 2016

Platinum dichloride-catalyzed cycloisomerization of ene-ynamides

scientific article published on 01 April 2004

Preparation of NHC Borane Complexes by Lewis Base Exchange with Amine− and Phosphine−Boranes ⬇️

scientific article published on October 15, 2010

Preparation of fused polycyclic vinylcyclopropanes via radical cascade reactions

scientific article published on 30 January 2007

Production and reactions of organic-soluble lanthanide complexes of the monolacunary Dawson [alpha1-P2W17O61]10- polyoxotungstate.

scientific article

PtCl 2-catalyzed cycloisomerizations of allenynes

scientific article published in March 2004

PtCl2-Catalyzed transannular cycloisomerization of 1,5-enynes: a new efficient regio- and stereocontrolled access to tricyclic derivatives

scientific article published on 01 October 2004

PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems

scientific article published on 01 July 2004

Radical Cyclization/β-Elimination Tandem Reactions: Enantiopure Sulfoxides as Temporary Chiral Auxiliaries

scientific article published on 01 August 1998

Radical Pd(III)/Pd(I) reductive elimination in palladium sequences

scientific article published in November 2013

Radical cyclization cascade involving ynamides: an original access to nitrogen-containing heterocycles

scientific article published on 01 December 2003

Radical cyclization of N-acylcyanamides: total synthesis of luotonin A

scientific article published on 01 January 2007

Radical deoxygenation of xanthates and related functional groups with new minimalist N-heterocyclic carbene boranes

scientific article published in July 2010

Radical migration of substituents of aryl groups on quinazolinones derived from N-acyl cyanamides.

scientific article published in March 2010

Radical reductions of alkyl halides bearing electron withdrawing groups with N-heterocyclic carbene boranes

scientific article published on 21 March 2011

Radical synthesis of guanidines from N-acyl cyanamides.

scientific article published in March 2010

Reactivity of beta-lactamido N-sulfonyl radicals

scientific article published on 01 March 2004

Rearrangements of N-acyl isothioureas. Alternate access to acylguanidines from cyanamides

scientific article published on 23 October 2012

Recent advances in the use of phosphorus-centered radicals in organic chemistry

scientific article

Recent progress in cobalt-mediated [2 + 2 + 2] cycloaddition reactions

scientific article

Regioselective Activation of Oxo Ligands in Functionalized Dawson Polyoxotungstates

scientific article published on 11 March 2008

Regioselective cobalt-catalyzed formation of bicyclic 3- and 4-aminopyridines

scientific article published on 17 March 2011

Rh-catalyzed [5+1] and [4+1] cycloaddition reactions of 1,4-enyne esters with CO: a shortcut to functionalized resorcinols and cyclopentenones

scientific article published on 13 April 2012

Selective Preparation of Complex Polycyclic Molecules from Acyclic Precursors via Radical Mediated- or Transition Metal-Catalyzed Cascade Reactions

scientific article published on 01 February 1996

Self-buffering hybrid gold-polyoxometalate catalysts for the catalytic cyclization of acid-sensitive substrates

scientific article published on 03 September 2012

Sensing the chirality of Dawson lanthanide polyoxometalates [alpha1-LnP2W17O61]7- by multinuclear NMR spectroscopy

scientific article published in January 2008

Silicon-hydrogen bond activation and hydrosilylation of alkenes mediated by CpCo complexes: a theoretical study

scientific article published on 01 March 2009

Silver and Brønsted acid catalyzed nazarov-type cyclizations to generate benzofulvenes

scientific article published on 01 January 2009

Silver-catalyzed cycloisomerization of 1,n-allenynamides

scientific article published on 02 May 2011

Stereoselective transition metal-catalyzed and radical polycyclizations

scientific article

Study of a Radical Cyclizations Cascade Leading to Bicyclo[3.1.1]heptanes

scientific article published on 01 February 1999

Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron−Heteroatom Bonds ⬇️

scientific article published on October 27, 2010

Suzuki-Miyaura coupling of NHC-boranes: a new addition to the C-C coupling toolbox

scientific article published on 01 November 2009

Synthesis and reactions of N-heterocyclic carbene boranes

scientific article published on 07 September 2011

Synthesis of Carbolines via Palladium/Carboxylic Acid Joint Catalysis

scientific article published on 16 May 2018

Synthesis of aminopyridines and aminopyridones by cobalt-catalyzed [2+2+2] cycloadditions involving yne-ynamides: scope, limitations, and mechanistic insights

scientific article published on 01 March 2012

Synthesis of functionalized resorcinols by rhodium-catalyzed [5+1] cycloaddition reaction of 3-acyloxy-1,4-enynes with CO

scientific article published on 29 June 2010

Synthesis of fused arylboronic esters via cobalt(0)-mediated cycloaddition of alkynylboronates with alpha,omega-diynes

scientific article published on 01 September 2004

Synthesis of marmycin A and investigation into its cellular activity

scientific article published on 20 July 2015

Synthesis of triangular tripalladium cations as noble-metal analogues of the cyclopropenyl cation

scientific article published on 22 January 2014

Synthesis of tricyclic fused 3-aminopyridines through intramolecular Co(I)-catalyzed [2+2+2] cycloaddition between ynamides, nitriles, and alkynes

scientific article published in January 2009

Synthesis, Characterization, and Structure of [GaCl3(NHC)] Complexes

Tandem gold(I)-catalyzed cyclization/electrophilic cyclopropanation of vinyl allenes

scientific article published on 25 April 2007

The behavior of 1,n-enynes in the presence of transition metals

scientific article published on 01 March 2002

The effect of a hydroxy protecting group on the PtCl2-catalyzed cyclization of dienynes--a novel, efficient, and selective synthesis of carbocycles

scientific article published in June 2002

The role of bent acyclic allene gold complexes in axis-to-center chirality transfers

scientific article published on 01 January 2008

The silicon effect on the regioselectivity of the Tsuji-Trost reaction. Experimental and theoretical approaches

Titanium-mediated domino radical cyclization/beta elimination of phosphine oxides

scientific article published on 01 August 2004

Totally chemo- and regioselective cobalt(I)-mediated formal intermolecular cyclotrimerization of alkynes

scientific article published on 01 April 2004

Towards the Synthesis of 3-Silapiperidines

Transannular radical cascade as an approach to the diastereoselective synthesis of linear triquinane

scientific article published on 01 September 2002

Transition metal catalyzed cycloisomerizations of 1,n-allenynes and -allenenes

scientific article published on 01 March 2011

Unprecedented Aromatic Homolytic Substitutions and Cyclization of AmideIminyl Radicals: Experimental and Theoretical Study

Visible-Light-Promoted Polycyclizations of Dienynes

scientific article published on 08 April 2019

Visible-light-induced photoreductive generation of radicals from epoxides and aziridines

scientific article published on 12 April 2011

Water Dissociation on α1-Hafnium and Ytterbium Substituted Dawson Polyoxotungstates: A Density Functional Theory Study†

scientific article published on 01 December 2008

List of works by Max Malacria

5-Endo-TrigRadical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes

A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics

A general strategy for ligation of organic and biological molecules to Dawson and Keggin polyoxotungstates

A molecular approach to self-assembly of trimethylsilylacetylene derivatives on gold.

A new practical one-pot access to sulfonimidates

A stereoselective route toward polyhydoxylated piperidines. A total synthesis of (+/-)-deoxymannojirimycin

Activation of allenes by gold complexes: a theoretical standpoint

Air-stable {(C5H5)Co} catalysts for [2+2+2] cycloadditions

Alkyne versus allene activation in platinum- and gold-catalyzed cycloisomerization of hydroxylated 1,5-allenynes

All-metal aromatic cationic palladium triangles can mimic aromatic donor ligands with Lewis acidic cations.

Atroposelective [2+2+2] cycloadditions catalyzed by a rhodium(I)-chiral phosphate system.

AuI-catalyzed cycloisomerization of 1,5-enynes bearing a propargylic acetate: formation of unexpected bicyclo[3.1.0]hexene

Bi-directional alkyne tandem isomerization via Pd(0)/carboxylic acid joint catalysis: expedient access to 1,3-dienes

Boosting catalyst activity in cis-selective semi-reduction of internal alkynes by tailoring the assembly of all-metal aromatic tri-palladium complexes.

Boryltrihydroborate: synthesis, structure, and reactivity as a reductant in ionic, organometallic, and radical reactions

CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃ ⬇️

Carbonyl-Inserted Organo-Hybrids of a Dawson-Type Phosphovanadotungstate: Scope and Chemoselective Oxidation Catalysis

Catalytic Cycloaddition Reactions

Catalytic version of enediyne cobalt-mediated cycloaddition and selective access to unusual bicyclic trienes

Chemo- and stereoselective palladium-catalyzed allylic alkylations controlled by silicon.

Chemo-, regio-, and stereoselective cobalt-mediated [2+2+2] cycloaddition of alkynyl boronates to alkenes: 1,3- and 1,4-diboryl-1,3-cyclohexadienes

Chemoselective catalysis with organosoluble Lewis acidic polyoxotungstates

Chiral recognition of hybrid metal oxide by peptides

Cobalt(I)-mediated [2 + 2 + 2] cyclization of allenediynes toward a diastereoselective approach to 11-aryl steroid skeletons

Cobalt(I)-mediated preparation of polyborylated cyclohexadienes: scope, limitations, and mechanistic insight

Cobalt-catalyzed cyclotrimerization of alkynes: the answer to the puzzle of parallel reaction pathways

Cobalt-mediated [2+2+2] cycloaddition versus C-H and N-H activation of 2-pyridones and pyrazinones with alkynes: a theoretical study.

Cobalt-mediated [2+2+2] cycloaddition versus C-H and N-H activation of pyridones and pyrazinones with alkynes: an experimental study

Cobalt-mediated cyclic and linear 2:1 cooligomerization of alkynes with alkenes: a DFT study

Cobalt-mediated linear 2:1 co-oligomerization of alkynes with enol ethers to give 1-alkoxy-1,3,5-trienes: a missing mode of reactivity

Cobalt-mediated regio- and stereoselective assembly of dienamides by hydroaminative alkyne coupling of alpha,omega-diynes

Combination of gold catalysis and Selectfluor for the synthesis of fluorinated nitrogen heterocycles

Complexes of borane and N-heterocyclic carbenes: a new class of radical hydrogen atom donor

Conjugate Additions to Alkylidene Bis(Sulfoxides)

Convergent preparation of enantiomerically pure polyalkylated cyclopropane derivatives

Diastereoselective cobalt-mediated [2 + 2 + 2] cycloadditions of substituted linear enediynes phosphine oxides: scope and limitations

Diastereoselective synthesis of dibenzoazepines through chelation on palladium(IV) intermediates

Diastereoselective synthesis of enantiopure acyclic beta,beta'-disubstituted vinylsulfoxides

EPR studies of the generation, structure, and reactivity of n-heterocyclic carbene borane radicals

Efficient copper-mediated reactions of nitrenes derived from sulfonimidamides

Efficient preparation of functionalized hybrid organic/inorganic Wells-Dawson-type polyoxotungstates

Electron paramagnetic resonance and computational studies of radicals derived from boron-substituted N-heterocyclic carbene boranes

Enantioselective Ir(I)-catalyzed carbocyclization of 1,6-enynes by the chiral counterion strategy

Estimated rate constants for hydrogen abstraction from N-heterocyclic carbene-borane complexes by an alkyl radical

Exception to the ortho effect in palladium/norbornene catalysis

Expeditious Synthesis of Phenanthridines from Benzylamines via Dual Palladium Catalysis

First Tandem Radical Cyclization/Intramolecular Diels-Alder Reaction

Fixation of the Two Tabun Isomers in Acetylcholinesterase: A QM/MM Study

Formation of cyclic sulfinates and sulfinamides through homolytic substitution at the sulfur atom

From Acyclic Precursors to Linear Triquinanes through a Diastereoselective One-Pot Process. A New Illustration of the Synthetic Power of Radical Cascades

From PtCl(2)- and acid-catalyzed to uncatalyzed cycloisomerization of 2-propargyl anilines: access to functionalized indoles

Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion

Generation and trapping of cyclopentenylidene gold species: four pathways to polycyclic compounds

Generation of phosphorus-centered radicals via homolytic substitution at sulfur.

Gold Compounds Anchored to a Metalated Arene Scaffold: Synthesis, X-ray Molecular Structures, and Cycloisomerization of Enyne

Gold(I)- and gold(III)-catalyzed cycloisomerization of allenynes: a remarkable halide effect

Gold(I)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

Gold(I)-catalyzed cyclization of β-allenylhydrazones: an efficient synthesis of multisubstituted N-aminopyrroles

Gold- and platinum-catalyzed cycloisomerization of enynyl esters versus allenenyl esters: an experimental and theoretical study

Gold-catalyzed 1,3-acyloxy migration/5-exo-dig cyclization/1,5-acyl migration of diynyl esters

Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle

Highly Diastereoselective Conjugate Addition to Alkylidene Bis(Sulfoxides): Asymmetric Synthesis of (+)‐erythro‐Roccellic Acid ⬇️

Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides

Highly efficient peptide bond formation to functionalized Wells-Dawson-type polyoxotungstates

Highly enantioselective rhodium-catalyzed [2+2+2] cycloaddition of diynes to sulfonimines

Homolytic reduction of onium salts

Identification of polyoxometalates as nanomolar noncompetitive inhibitors of protein kinase CK2.

Improved method for the iodine(III)-mediated preparation of aryl sulfonimidates

Increased Lewis acidity in hafnium-substituted polyoxotungstates

Insertion of amides into a polyoxometalate

Intramolecular anion effect in polyoxometalate-based organocatalysts: reactivity enhancement and chirality transfer by a metal oxide-organic cation interaction

Intramolecular homolytic substitution of sulfinates and sulfinamides

Intramolecular homolytic substitution of sulfinates and sulfinamides--a computational study

Iodine(III)-mediated preparations of nitrogen-containing sulfur derivatives: dramatic influence of the sulfur oxidation state.

Ionic and organometallic reductions with N-heterocyclic carbene boranes

Iron-catalyzed reductive radical cyclization of organic halides in the presence of NaBH4: evidence of an active hydrido iron(I) catalyst

Lanthanide complexes of the monovacant Dawson polyoxotungstate [alpha1-P2W17O61]10- as selective and recoverable Lewis acid catalysts

Lanthanide polyoxocationic complexes: experimental and theoretical stability studies and Lewis acid catalysis

Lewis-acidic polyoxometalates as reusable catalysts for the synthesis of glucuronic acid esters under microwave irradiation