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List of works by Polly Arnold

A Combined Experimental and Theoretical Study of the Versatile Reactivity of an Oxocerium(IV) Complex: Concerted Versus Reductive Addition

scientific article published on 26 July 2019

A DFT study of the single electron reduction and silylation of the U–O bond of the uranyl dication in a macrocyclic environment

article by Ahmed Yahia et al published 2009 in Chemical Communications

A functional model for lanthanide doped silicate materials: synthesis of an apically substituted samarium silsesquioxane complex

article

A lanthanide-gallium complex stabilized by the N-heterocyclic carbene group

scientific article published on 6 April 2007

Abnormal N-heterocyclic carbenes

article published in 2007

Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

scientific article published on 01 January 2014

Addition-Elimination Reactions across the M−C Bond of Metal N-Heterocyclic Carbenes

article

An unsupported transition metal–lanthanide bond; synthesis and crystal structure of an Nd–Fe amido N-heterocyclic carbene complex

Anionic Amido N-Heterocyclic Carbenes: Synthesis of Covalently Tethered Lanthanide–Carbene Complexes

scientific article published on 01 December 2003

Anionic tethered N-heterocyclic carbene chemistry

scientific article

Applications of boroxide ligands in supporting small molecule activation by U(iii) and U(iv) complexes

scientific article published on 01 April 2019

Arene complexation of Sm, Eu, Tm and Yb atoms: a variable temperature spectroscopic investigation

Arene-Bridged Diuranium Complexes:  Inverted Sandwiches Supported by δ Backbonding

scientific article published in 2000

Arene-ligated heteroleptic terphenolate complexes of thorium

scientific article published on 01 December 2014

Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis

scientific article

Author Correction: Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines

scientific article published on 14 May 2020

Axially Symmetric U-O-Ln- and U-O-U-Containing Molecules from the Control of Uranyl Reduction with Simple f-Block Halides

scientific article published on 7 July 2017

Axially Symmetric U−O−Ln- and U−O−U-Containing Molecules from the Control of Uranyl Reduction with Simple f-Block Halides

Bent metal carbene geometries in amido N-heterocyclic carbene complexes

scientific article

Bifunctional yttrium(III) and titanium(IV) NHC catalysts for lactide polymerisation

scientific article published on 25 January 2006

Bis(η-heteroarene) titanium complexes derived from 2,4,6-tri-tert-butylpyridine and 2,4,6-tri-tert-butylphosphorin: Conformational preference in solution and redox activity

scholarly article by Polly Arnold et al published February 1997 in Journal of Organometallic Chemistry

C-H bond activation by f-block complexes

scientific article

C3-symmetric lanthanide tris(alkoxide) complexes formed by preferential complexation and their stereoselective polymerization of rac-lactide

scientific article published in January 2008

CALCIUM, STRONTIUM, GERMANIUM, TIN, AND LEAD BIS(TRIMETHYLSILYL)AMIDO DERIVATIVES AND 2,2,6,6-TETRAMETHYLPIPERIDIDO AND N -ISOPROPYLPHENYLAMIDO DERVATIVES OF POTASSIUM AND CALCIUM

Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes

scientific article published on 27 November 2012

Carbon monoxide coupling and functionalisation at a simple uranium coordination complex

article

Carbon–Silicon and Carbon–Carbon Bond Formation by Elimination Reactions at Metal N-Heterocyclic Carbene Complexes ⬇️

scientific article published on 07 July 2011

Catalytic one-electron reduction of uranyl(VI) to Group 1 uranyl(V) complexes via Al(III) coordination

scientific article published on 02 March 2015

Cation o' nine tails

scientific article published in Nature

Characterizing pressure-induced uranium C-H agostic bonds

scientific article published on 16 April 2015

Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Ligand for PdII/IVC−H Bond Functionalization Catalysis

scientific article published on 01 October 2009

Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper

scientific article published in 2001

Chiral indium alkoxide complexes as initiators for the stereoselective ring-opening polymerization of rac-lactide

scientific article published in January 2010

Co-linear, double-uranyl coordination by an expanded Schiff-base polypyrrole macrocycle

scientific article published on 30 April 2012

Comparisons between yttrium and titanium N-heterocyclic carbene complexes in the search for early transition metal NHC backbonding interactions

scientific article published on 4 September 2008

Computational Density Functional Study of Polypyrrolic Macrocycles: Analysis of Actinyl-Oxo to 3d Transition Metal Bonding

article

Computational analysis of M–O covalency in M(OC6H5)4 (M = Ti, Zr, Hf, Ce, Th, U)

scientific article published on 01 February 2019

Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand

scholarly article by Polly Arnold et al published 2010 in Chemical Communications

Control of Oxo-Group Functionalization and Reduction of the Uranyl Ion

scientific article published on 23 March 2015

Controlled Photocatalytic Hydrocarbon Oxidation by Uranyl Complexes

scholarly article by Polly Arnold et al published 28 February 2019 in ChemCatChem

Controlled deprotection and reorganization of uranyl oxo groups in a binuclear macrocyclic environment

scientific article published on 06 November 2012

Controlling uranyl oxo group interactions to group 14 elements using polypyrrolic Schiff-base macrocyclic ligands

scientific article published in 2016

Coordination of isocyanide and reduction of cyclooctatetraene by a homoleptic uranium(III) aryloxide, and characterisation of the heteroleptic uranium(III) dimer [{U(N″) 2 (thf)(μ-I)} 2 ]

scholarly article by Stephen M Mansell & Polly Arnold published September 2016 in Polyhedron

Correction: Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin.

scientific article

Correction: Waste not, want not: CO2 (re)cycling into block polymers

scientific article published on 01 July 2019

Covalency in Ce(IV) and U(IV) halide and N-heterocyclic carbene bonds

scientific article published on August 2010

Deprotonation of N-Heterocyclic Carbenes to Afford Heterobimetallic Organolanthanide Complexes

Destruction of chemical warfare agent simulants by air and moisture stable metal NHC complexes

scientific article published on 31 January 2018

Di- and Trivalent Ruthenium Complexes of Chelating, Anionic N-Heterocyclic Carbenes

scholarly article by Polly Arnold & Andrew C. Scarisbrick published May 2004 in Organometallics

Dicerium letterbox-shaped tetraphenolates: f-block complexes designed for two-electron chemistry

scientific article published on 01 January 2020

Differential uranyl(v) oxo-group bonding between the uranium and metal cations from groups 1, 2, 4, and 12; a high energy resolution X-ray absorption, computational, and synthetic study

scientific article published on 06 September 2019

Dinuclear uranium complexation and manipulation using robust tetraaryloxides

scientific article published on 01 October 2016

Double uranium oxo cations derived from uranyl by borane or silane reduction

scientific article published on 28 March 2018

Equatorial ligand substitution by hydroxide in uranyl Pacman complexes of a Schiff-base pyrrole macrocycle

scientific article

F-Block N-Heterocyclic Carbene Complexes

article published in 2009

F-block N-heterocyclic carbene complexes

scientific article published on 7 August 2006

Functionalised saturated-backbone carbene ligands: yttrium and uranyl alkoxy-carbene complexes and bicyclic carbene-alcohol adducts

scientific article

Geoff Cloke at 65: a pioneer in organometallic chemistry

scientific article published on 01 July 2018

Group I cation templated formation of luminescent mono- and bis-substituted thionaphthol heterobimetallic complexes of Pr, Nd, Eu and Tb.

scientific article published on 3 August 2006

Heterodinuclear Uranium/Molybdenum Dinitrogen Complexes

scholarly article by Aaron L. Odom et al published June 1998 in Journal of the American Chemical Society

Heterotrimetallic {LnOVPt} complexes with antiferromagnetic Ln-V coupling and magnetic memory

scientific article published on 19 August 2020

Homo- and heteroleptic alkoxycarbene f-element complexes and their reactivity towards acidic N–H and C–H bonds

scientific article published in 2014

Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin

scientific article published on 28 October 2016

Inorganic chemistry: A reducing role for boron.

scientific article

Inter- versus Intramolecular Structural Manipulation of a Dichromium(II) Pacman Complex through Pressure Variation

scientific article

Isocyanide and Phosphine Oxide Coordination in Binuclear Chromium Pacman Complexes

scientific article published on 13 November 2013

Lanthanide/actinide differentiation with sterically encumbered N-heterocyclic carbene ligands

article

Ligand recognition processes in the formation of homochiral C3-symmetric LnL3 complexes of a chiral alkoxide.

scientific article published in August 2009

Low-valent uranium iodides: straightforward solution syntheses of UI3 and UI4 etherates

scientific article published on 3 September 2008

Macrocyclic Platforms for the Construction of Tetranuclear Oxo and Hydroxo Zinc Clusters

scientific article published on 10 February 2015

Magnesium amido N-heterocyclic carbene complexes

scientific article published on 9 June 2008

Magnesium and zinc complexes of functionalised, saturated N-heterocyclic carbene ligands: carbene lability and functionalisation, and lactide polymerisation catalysis

scientific article published on 29 July 2009

Mechanistic insight into the lanthanide(III) salt catalysed monoacylation of symmetrical diols from structural models

scientific article published in October 2003

Metal Vapor Synthesis as a Straightforward Route to Group 10 Homoleptic Carbene Complexes

Metal-Metal Bonding in Uranium-Group 10 Complexes

scientific article published on 16 March 2016

Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines

scientific article published on 04 May 2020

Multi-electron reduction of sulfur and carbon disulfide using binuclear uranium(iii) borohydride complexes

scientific article published on 10 March 2017

New UIII and UIV silylamides and an improved synthesis of NaN(SiMe2R)2 (R = Me, Ph)

New chemistry from an old reagent: mono- and dinuclear macrocyclic uranium(III) complexes from [U(BH4)3(THF)2]

scientific article published on 08 July 2014

Now U=C it ⬇️

scientific article published on April 1, 2009

Numerical and experimental investigation of NIR-to-visible energy up-conversion in Er3+-doped sol–gel SiO2 powders

scientific article published in 2013

Numerical and experimental investigation of near-infrared-visible luminescence in erbium doped sol-gel SiO 2

scientific article published in June 2013

Numerical and experimental investigation of upconversion in Er doped sol-gel SiO 2

scientific article published in September 2011

Organometallic Neptunium Chemistry

scientific article

Organometallic chemistry of silver and copperN-heterocyclic carbene complexes

article published in 2002

Organometallic neptunium(III) complexes

scientific article

Oxo Group Protonation and Silylation of Pentavalent Uranyl Pacman Complexes ⬇️

scientific article published on August 26, 2011

Oxo-functionalization and reduction of the uranyl ion through lanthanide-element bond homolysis: synthetic, structural, and bonding analysis of a series of singly reduced uranyl-rare earth 5f1-4f(n) complexes

scientific article published on 4 March 2013

Oxo-group-14-element bond formation in binuclear uranium(V) Pacman complexes

scientific article

Pentavalent uranyl complexes

article by Polly Arnold et al published August 2009 in Coordination Chemistry Reviews

Probing the Reactivity of the Ce═O Multiple Bond in a Cerium(IV) Oxo Complex

scientific article

Protonolysis and thermolysis reactions of functionalised NHC–carbene boranes and borates

scientific article published in 2014

Quantum chemical topology and natural bond orbital analysis of M-O covalency in M(OC6H5)4 (M = Ti, Zr, Hf, Ce, Th, Pa, U, Np)

scientific article published on 14 July 2020

Reduction and selective oxo group silylation of the uranyl dication

scientific article published in Nature

Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding

scientific article published on 30 January 2017

Regioselective C-H activation of lanthanide-bound N-heterocyclic carbenes

scientific article

Relativistic DFT and experimental studies of mono- and bis-actinyl complexes of an expanded Schiff-base polypyrrole macrocycle

scientific article published on 4 July 2016

Ring opening polymerisation of lactide with uranium(iv) and cerium(iv) phosphinoaryloxide complexes

scientific article published on 2 August 2017

Selective and catalytic carbon dioxide and heteroallene activation mediated by cerium N-heterocyclic carbene complexes

scientific article published on 10 September 2018

Selective oxo functionalization of the uranyl ion with 3d metal cations

scientific article published in August 2006

Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged UIV/UIV Pacman complex

scientific article published on 12 June 2020

Selective reduction in ring size of silsesquioxane oligomers mediated by potassium metal

Silver alkoxide and amino N-heterocyclic carbenes; syntheses and crystal structures

article published in 2005

Silver nanoparticles and polymeric medical devices: a new approach to prevention of infection?

scientific article published on 10 November 2004

Single-Electron Uranyl Reduction by a Rare-Earth Cation

article by Polly Arnold et al published 22 December 2010 in Angewandte Chemie International Edition

Single-molecule magnets: Uranyl steps in the ring

scientific article published on 01 December 2012

Small molecule activation by uranium tris(aryloxides): experimental and computational studies of binding of N2, coupling of CO, and deoxygenation insertion of CO2 under ambient conditions

scientific article published on 17 May 2011

Spontaneous reduction and C-H borylation of arenes mediated by uranium(III) disproportionation

scientific article published on 15 July 2012

Sterically demanding bi- and tridentate alkoxy-N-heterocyclic carbenes

Strongly coupled binuclear uranium-oxo complexes from uranyl oxo rearrangement and reductive silylation

scientific article published on 21 February 2012

Subtle Interactions and Electron Transfer between U(III) , Np(III) , or Pu(III) and Uranyl Mediated by the Oxo Group

scientific article

Subtle Interactions and Electron Transfer between UIII , NpIII , or PuIII and Uranyl Mediated by the Oxo Group

Sulfur-bridged phenoxide and naphthyloxide-based ligands for lanthanide chemistry and catalysis

Symmetric and asymmetric samarium alkoxide derivatives of bridging sulfur biphenolate and binaphtholate ligands; synthetic, structural, and catalytic studies

Synthesis and NHC Lability of d0Lithium, Yttrium, Titanium, and Zirconium Amido Bis(N-heterocyclic carbene) Complexes

scholarly article by Ian S. Edworthy et al published July 2007 in Organometallics

Synthesis and characterisation of yttrium complexes supported by the beta-diketiminate ligand {ArNC(CH3)CHC(CH3)NAr}- (Ar = 2,6-Pr(i)2C6H3).

scientific article published on 20 June 2007

Synthesis and luminescence studies of mono- and C3-symmetric, tris(ligand) complexes of Sm(III), Y(III) and Eu(III) with sulfur-bridged binaphtholate ligands

scientific article published on 11 October 2004

Synthesis and reactivity of neodymium(III) amido-tethered N-heterocyclic carbene complexes

scholarly article by Polly Arnold & Stephen Liddle published June 2008 in Comptes Rendus Chimie

Synthesis and small molecule reactivity of uranium(IV) alkoxide complexes with both bound and pendant N-heterocyclic carbene ligands

scientific article

Synthesis and structural characterisation of an yttrium-alkyl-alkylidene

scientific article published on 8 February 2008

Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis

article

Synthesis of Heteroleptic Cerium(III) Anionic Amido-Tethered N-Heterocyclic Carbene Complexes

scholarly article by Stephen Liddle & Polly Arnold published May 2005 in Organometallics

Synthesis of mono- and di-potassium salts and methoxy adducts of sulfur-bridged biphenols by selective deprotonationElectronic supplementary information (ESI) available: full characterisation for all complexes described and packing diagrams for 3 and

article by Polly Arnold et al published 21 February 2003 in Dalton Transactions

Tetravalent cerium carbene complexes

scholarly article by Ian J. Casely et al published 2007 in Chemical Communications

The Effect of the Equatorial Environment on Oxo-Group Silylation of the Uranyl Dication: A Computational Study

scientific article published on 01 April 2010

The First Example of a Formal Scandium(I) Complex:  Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring

article

The first stable scandocene: synthesis and characterisation of bis(η-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)

scholarly article by Polly Arnold et al published 1998 in Chemical Communications

The first structurally authenticated zerovalent heteroarene complex of a lanthanide; synthesis and X-ray structure of bis(2,4,6-tri-tert-butyl- phosphorin)holmium(O)

Theoretical exploration of uranyl complexes of a designed polypyrrolic macrocycle: structure/property effects of hinge size on Pacman-shaped complexes ⬇️

scientific article published on June 20, 2012

Theoretical predictions of cofacial bis(actinyl) complexes of a stretched Schiff-base calixpyrrole ligand ⬇️

scientific article published on April 12, 2011

Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [UVIO2]2

scientific article published on 12 August 2019

Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes

scientific article published on 3 February 2005

Thorium Mono- and Bis(imido) Complexes Made by Reprotonation of cyclo-Metalated Amides

scientific article published on 12 August 2015

Thorium(IV) and Uranium(IV) trans-Calix[2]benzene[2]pyrrolide Alkyl and Alkynyl Complexes: Synthesis, Reactivity, and Electronic Structure

scholarly article by Markéta Suvova et al published 16 October 2017 in Organometallics

Thoroughly enthralling thulium

scientific article published in November 2017

Titanium(III) Alkoxy-N-heterocyclic Carbenes and a Safe, Low-Cost Route to TiCl3(THF)3

scholarly article by Natalie A. Jones et al published January 2007 in Organometallics

Titanium(IV) Alkoxy-N-heterocyclic Carbenes:  Structural Preferences of Alkoxide and Bromide Adducts

scholarly article by Shaheed A. Mungur et al published April 2006 in Organometallics

Tuning the catalytic properties of rare earth borohydrides for the polymerisation of isoprene

scientific article

Uranium rhodium bonding in heterometallic complexes

scientific article published on 3 February 2017

Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts

scientific article published on 10 April 2013

Uranium-mediated activation of small molecules

scientific article

Uranium-nitrogen multiple bonding: isostructural anionic, neutral, and cationic uranium nitride complexes featuring a linear U=N=U core

scientific article published in March 2010

Uranyl complexation by a schiff-base, polypyrrolic macrocycle

scientific article

Uranyl oxo activation and functionalization by metal cation coordination

article by Polly Arnold et al published 23 November 2010 in Nature Chemistry

Uranyl to Uranium(IV) Conversion through Manipulation of Axial and Equatorial Ligands

scientific article published on 18 February 2018

Waste not, want not: CO2 (re)cycling into block polymers

scientific article published on 01 June 2019

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