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List of works by John F. Hartwig

A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides ⬇️

scientific article published on March 25, 2011

A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds

scientific article published on 15 December 2016

A Fluorescence-Based Assay for High-Throughput Screening of Coupling Reactions. Application to Heck Chemistry

article

A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF] ⬇️

scientific article published on November 14, 2011

A Heterogeneous Nickel Catalyst for the Hydrogenolysis of Aryl Ethers without Arene Hydrogenation ⬇️

scientific article published on December 7, 2012

A Multicatalytic Approach to the Hydroaminomethylation of α-Olefins

scientific article published on 15 February 2019

A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines by Three-Coordinate Intermediates

scientific article (publication date: April 1995)

A Second-Generation Catalyst for Aryl Halide Amination: Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by (DPPF)PdCl2

article

A Simple, Multidimensional Approach to High-Throughput Discovery of Catalytic Reactions ⬇️

scientific article published on September 9, 2011

A decarboxylative approach for regioselective hydroarylation of alkynes.

scientific article

A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism

scientific article

A general, efficient, and functional-group-tolerant catalyst system for the palladium-catalyzed thioetherification of aryl bromides and iodides

scientific article published on February 2009

A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes

scientific article published in February 2006

A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes

scientific article published in February 2002

A photochemical source of dibromo- and dichlorocarbene

article

A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis

scientific article published in November 2005

Abiological catalysis by artificial haem proteins containing noble metals in place of iron

scientific article

Acceptorless, Neat, Ruthenium-Catalyzed Dehydrogenative Cyclization of Diols to Lactones

article

Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings

scientific article published in August 2002

Anti-Markovnikov hydroheteroarylation of unactivated alkenes with indoles, pyrroles, benzofurans, and furans catalyzed by a nickel-N-heterocyclic carbene system.

scientific article published on 3 September 2015

Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides

scientific article published in September 2002

Assessment of the Intermediacy of Arylpalladium Carboxylate Complexes in the Direct Arylation of Benzene: Evidence for C−H Bond Cleavage by “Ligandless” Species ⬇️

scientific article published on February 11, 2011

Autocatalytic oxidative addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br)

scientific article published on 11 April 2008

Beta-aryl eliminations from Rh(I) iminyl complexes

scientific article published in August 2005

Beyond Iron: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse Alkenes

scientific article

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations ⬇️

scientific article published on November 10, 2011

Carbon-heteroatom bond formation catalysed by organometallic complexes

scientific article

Carbon−Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides

article

Carbon−Nitrogen-Bond-Forming Reductive Elimination of Arylamines from Palladium(II) Phosphine Complexes

scientific article (publication date: September 1997)

Catalyst-Controlled Site-Selective Bond Activation.

scientific article published in March 2017

Catalytic Organometallic Reactions of Ammonia ⬇️

scientific article published on January 3, 2011

Catalytic Silylation of Unactivated C-H Bonds

scientific article published on 25 February 2015

Catalytic asymmetric addition of an amine N-H bond across internal alkenes

scientific article published on 03 November 2020

Catalytic deconstruction of waste polyethylene with ethylene to form propylene

scientific article published on 30 September 2022

Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol ⬇️

scientific article published on February 29, 2012

Catalytic hydroxylation of polypropylenes

scientific article published in January 2005

Catecholborane Bound to Titanocene. Unusual Coordination of Ligand σ-Bonds

article

Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones

scientific article published on 19 December 2013

Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C-O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments.

scientific article

Chemoselective, Enzymatic C-H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor

scientific article published on 12 January 2017

Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium

scientific article published in October 2009

Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization

scientific article published on 19 August 2019

Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion

scientific article

Controlling first-row catalysts: amination of aryl and heteroaryl chlorides and bromides with primary aliphatic amines catalyzed by a BINAP-ligated single-component Ni(0) complex

scientific article published on 21 January 2014

Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides

scientific article published on 3 July 2008

Copper(I) Enolate Complexes in α‐Arylation Reactions: Synthesis, Reactivity, and Mechanism ⬇️

scientific article published on December 8, 2011

Copper(I) phenoxide complexes in the etherification of aryl halides

scientific article

Copper-Catalyzed Defluorinative Borylation and Silylation of gem-Difluoroallyl Groups

scientific article published on 25 August 2020

Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles

scientific article

Copper-Mediated Difluoromethylation of Aryl and Vinyl Iodides ⬇️

scientific article published on March 14, 2012

Copper-Mediated Fluorination of Aryl Iodides ⬇️

scientific article published on June 22, 2012

Copper-Mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride

scientific article published on 28 January 2020

Copper-Mediated Fluorination of Arylboronate Esters. Identification of a Copper(III) Fluoride Complex ⬇️

scientific article published on February 5, 2013

Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes

scientific article published on 30 January 2014

Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes

scientific article published on 24 November 2014

Copper-mediated perfluoroalkylation of heteroaryl bromides with (phen)CuRF.

scientific article

Correction to "Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex".

scientific article published on 17 February 2017

Correction to "Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles".

scientific article

Cross-coupling by a noncanonical mechanism involving the addition of aryl halide to Cu(II)

scientific article published on 07 September 2023

Cu(I)−Amido Complexes in the Ullmann Reaction: Reactions of Cu(I)−Amido Complexes with Iodoarenes with and without Autocatalysis by CuI ⬇️

scientific article published on October 26, 2010

Cyanation of Arenes via Iridium-Catalyzed Borylation ⬇️

scientific article published on August 25, 2010

DNA binding properties of [Pt(NH3)(C6H11NH2)Cl2], a metabolite of an orally active platinum anticancer drug

article

Desymmetrization of difluoromethylene groups by C-F bond activation

scientific article published on 01 June 2020

Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolates

scientific article published on 30 October 2014

Direct measurement of the thermodynamics of vinylarene hydroamination

scientific article

Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes

scientific article published in February 2002

Direct observation of beta-aryl eliminations from Rh(I) alkoxides

scientific article published in March 2006

Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines

scientific article

Direct, intermolecular, enantioselective, iridium-catalyzed allylation of carbamates to form carbamate-protected, branched allylic amines

scientific article published on July 2009

Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols

scientific article published on January 2008

Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes ⬇️

scientific article published on November 19, 2003

Distinct Thermodynamics for the Formation and Cleavage of N−H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex ⬇️

scientific article published on November 12, 2003

Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands

scientific article published in May 2005

Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions

scientific article published on 31 January 2011

Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes through Catalytic Regioselective Hydroboration

scientific article published on 10 May 2016

Diverse functional polyethylenes by catalytic amination

scientific article published on 28 September 2023

Diverse functionalization of strong alkyl C-H bonds by undirected borylation

scientific article published on 01 May 2020

Editing the stereochemical elements in an iridium catalyst for enantioselective allylic amination

scholarly article

Effect of Ligand Structure on the Electron Density and Activity of Iridium Catalysts for the Borylation of Alkanes

scientific article published on 11 February 2020

Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes

scientific article

Effects of Bases and Halides on the Amination of Chloroarenes Catalyzed by Pd(PtBu3)2.

scientific article

Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates

scientific article published in October 2002

Electronic effects on reductive elimination to form carbon-carbon and carbon-heteroatom bonds from palladium(II) complexes

scientific article published on March 2007

Enantioselective Borylation of Aromatic C-H Bonds with Chiral Dinitrogen Ligands.

scientific article published on 16 May 2017

Enantioselective Synthesis of Tertiary Allylic Fluorides by Iridium-Catalyzed Allylic Fluoroalkylation

scientific article published on 11 September 2018

Enantioselective Total Syntheses of (−)-Taiwaniaquinone H and (−)-Taiwaniaquinol B by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric α-Arylation ⬇️

scientific article published on January 26, 2011

Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel

scientific article

Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification

scientific article

Enantioselective α-functionalizations of ketones via allylic substitution of silyl enol ethers

scientific article published on 19 November 2018

Enantioselective, iridium-catalyzed monoallylation of ammonia

scientific article published on August 2009

Evolution of C-H Bond Functionalization from Methane to Methodology

scientific article

Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides

scientific article (publication date: 18 November 2008)

Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation

scientific article published in January 2003

Femtosecond excitation energy transport in triarylamine dendrimers

scientific article published in June 2002

Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study

scientific article

Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers

scientific article published on 7 July 2016

From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction

scientific article published on 4 October 2013

Generation of reactivity from typically stable ligands: CbondC bond-forming reductive elimination from aryl palladium(II) complexes of malonate anions

scientific article published in November 2002

Generation, Characterization, and Tunable Reactivity of Organometallic Fragments Bound to a Protein Ligand

scientific article published on 23 June 2015

Highly reactive, general and long-lived catalysts for palladium-catalyzed amination of heteroaryl and aryl chlorides, bromides, and iodides: scope and structure-activity relationships

scientific article published on 30 April 2008

Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles

scientific article published in February 2005

Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides

scientific article

Hydroaminoalkylation of unactivated olefins with dialkylamines

scientific article published on 21 October 2008

Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity ⬇️

scientific article published on November 26, 2003

Influences on the Relative Rates for C−N Bond-Forming Reductive Elimination and β-Hydrogen Elimination of Amides. A Case Study on the Origins of Competing Reduction in the Palladium-Catalyzed Amination of Aryl Halides

scientific article (publication date: 1996)

Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds

scientific article published in April 2005

Intermolecular insertion of ethylene and octene into a palladium-amide bond. Spectroscopic evidence for an ethylene amido intermediate

scientific article published in May 2010

Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity

scientific article

Intermolecular, markovnikov hydroamination of vinylarenes with alkylamines

scientific article published in November 2003

Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex

scientific article published on October 2010

Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C-H Bonds.

scientific article published on 18 August 2017

Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity

scientific article published on 25 June 2015

Iridium-Catalyzed Borylation of Secondary Benzylic C–H Bonds Directed by a Hydrosilane ⬇️

scientific article published on May 24, 2013

Iridium-Catalyzed C–H Borylation of Cyclopropanes ⬇️

scientific article published on February 21, 2013

Iridium-Catalyzed Enantioselective Allylic Substitution of Aliphatic Esters with Silyl Ketene Acetals as the Ester Enolates.

scientific article

Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides

scientific article published on 06 October 2015

Iridium-Catalyzed Intermolecular Asymmetric Hydroheteroarylation of Bicycloalkenes ⬇️

scientific article published on January 30, 2013

Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles

scientific article

Iridium-Catalyzed Regioselective and Enantioselective Allylation of Trimethylsiloxyfuran ⬇️

scientific article published on September 11, 2012

Iridium-Catalyzed Silylation of C-H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis

scientific article published on 23 April 2019

Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand

scientific article published on 18 February 2020

Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C-H Bonds

scientific article published on 8 January 2016

Iridium-Catalyzed, Intermolecular Hydroetherification of Unactivated Aliphatic Alkenes with Phenols ⬇️

scientific article published on June 12, 2013

Iridium-Catalyzed, Silyl-Directed, peri-Borylation of C-H Bonds in Fused Polycyclic Arenes and Heteroarenes

scientific article published on 13 July 2018

Iridium-catalyzed C-H borylation of heteroarenes: scope, regioselectivity, application to late-stage functionalization, and mechanism

scientific article

Iridium-catalyzed C–H coupling reaction of heteroaromatic compounds with bis(pinacolato)diboron: regioselective synthesis of heteroarylboronates

scholarly article by Jun Takagi et al published August 2002 in Tetrahedron Letters

Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation

scientific article published on 15 November 2010

Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones

scientific article

Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans

scientific article published in September 2004

Iridium-catalyzed intermolecular hydroamination of unactivated aliphatic alkenes with amides and sulfonamides.

scientific article published on 16 July 2012

Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates

scientific article published on July 2010

Iridium-catalyzed oxidative olefination of furans with unactivated alkenes

scientific article

Iridium-catalyzed regio- and enantioselective N-allylation of indoles

scientific article published on January 2009

Iridium-catalyzed regio- and enantioselective allylation of ketone enolates

scientific article

Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones

scientific article

Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine

scientific article published on 24 June 2014

Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols.

scientific article published on 22 April 2014

Iridium-catalyzed, diastereoselective dehydrogenative silylation of terminal alkenes with (TMSO)2MeSiH.

scientific article published on 15 July 2013

Iridium-catalyzed, intermolecular hydroamination of unactivated alkenes with indoles.

scientific article

Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates

scientific article published on January 2010

Iridium-catalyzed, silyl-directed borylation of nitrogen-containing heterocycles

scientific article published in March 2010

Iridium-catalyzed, β-selective C(sp3)-H silylation of aliphatic amines to form silapyrrolidines and 1,2-amino alcohols

scientific article published on 13 December 2018

Kumada coupling of aryl and vinyl tosylates under mild conditions

scientific article

Late Stage Azidation of Complex Molecules

scientific article published on 07 October 2016

Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides

scientific article published on 2 June 2007

Ligandless, anionic, arylpalladium halide intermediates in the Heck reaction

scientific article published on January 2010

Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes

scientific article published on 15 September 2014

Mechanism of Ni-Catalyzed Oxidations of Unactivated C(sp3)-H Bonds

scientific article published on 28 October 2020

Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands. Evidence for the Reaction of Iodoarenes With Ligated Anionic CuI Intermediates

scientific article

Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes

scientific article

Mechanism of the rhodium-catalyzed silylation of arene C-H bonds

scientific article published on 14 August 2014

Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands

scientific article published on 8 November 2017

Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes.

scientific article published on 8 August 2017

Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia

scientific article published on 18 June 2018

Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through pi-Arene Complexes

scientific article

Mechanistic Studies on Direct Arylation of Pyridine N-Oxide: Evidence for Cooperative Catalysis between Two Distinct Palladium Centers ⬇️

scientific article published on February 17, 2012

Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C-H Bonds

scientific article

Mechanistic study of beta-hydrogen elimination from organoplatinum(II) enolate complexes

scientific article published on 28 October 2008

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution ⬇️

scientific article published on September 28, 2010

Meta Halogenation of 1,3-Disubstituted Arenes via Iridium-Catalyzed Arene Borylation

scientific article published on 21 November 2007

Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization

scientific article

Mild Iridium-Catalyzed Borylation of Arenes. High Turnover Numbers, Room Temperature Reactions, and Isolation of a Potential Intermediate ⬇️

scientific article published on January 23, 2002

Mild palladium-catalyzed selective monoarylation of nitriles

scientific article published in November 2005

Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines

scientific article published on 10 January 2008

New "Cats" in the House: Chemistry Meets Biology in Artificial Metalloenzymes and Repurposed Metalloenzymes

scientific article published on 01 May 2019

Nickel-Catalyzed Asymmetric α-Arylation and Heteroarylation of Ketones with Chloroarenes: Effect of Halide on Selectivity, Oxidation State, and Room-Temperature Reactions ⬇️

scientific article published on September 27, 2011

Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions

scientific article published on 10 February 2020

Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts

scientific article published on 25 February 2015

Noble-Metal Substitution in Hemoproteins: An Emerging Strategy for Abiological Catalysis

scientific article published on 29 January 2019

N−H Activation of Hydrazines by Iridium(I). Double N−H Activation To Form Iridium Aminonitrene Complexes ⬇️

scientific article published on August 25, 2010

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition‐Metal Complexes ⬇️

scientific article published on March 5, 2012

One-Pot Anti-Markovnikov Hydroamination of Unactivated Alkenes by Hydrozirconation and Amination ⬇️

scientific article published on August 27, 2013

One-pot synthesis of unsymmetrical diaryl thioethers by palladium-catalyzed coupling of two aryl bromides and a thiol surrogate

scientific article

Origin of the Difference in Reactivity between Ir Catalysts for the Borylation of C-H Bonds

scientific article published on 03 October 2019

Origins of Regioselectivity in Iridium Catalyzed Allylic Substitution

scientific article

Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes

scientific article published on 7 May 2012

Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes

scientific article published in March 2010

Oxidation of Hindered Allylic C–H Bonds with Applications to the Functionalization of Complex Molecules.

scientific article

Oxidative addition of ammonia to form a stable monomeric amido hydride complex

scientific article

Oxidative addition of an alkyl halide to form a stable Cu(III) product

scientific article published on 07 September 2023

Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature

scientific article

Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate

scientific article (publication date: March 1997)

Palladium-Catalyzed Arylation of Fluoroalkylamines

scientific article published on 29 June 2015

Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile

scientific article

Palladium-Catalyzed Cross-Coupling of Ethyl Bromodifluoroacetate with Aryl Bromides or Triflates and Cross-Coupling of Ethyl Bromofluoroacetate with Aryl Iodides.

scientific article published on 3 May 2017

Palladium-Catalyzed C−O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination To Form the C−O Bond in Diaryl Ethers

scientific article (publication date: April 1999)

Palladium-Catalyzed Enantioselective α-Arylation of α-Fluoroketones

scientific article

Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles

article

Palladium-Catalyzed Methylation of Aryl, Heteroaryl, and Vinyl Boronate Esters

scientific article published on 14 February 2019

Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles ⬇️

scientific article (publication date: April 2003)

Palladium-Catalyzed α-Arylation of Carboxylic Acids and Secondary Amides via a Traceless Protecting Strategy

scientific article published on 16 July 2019

Palladium-Catalyzed α-Arylation of Zinc Enolates of Esters: Reaction Conditions and Substrate Scope ⬇️

scientific article published on August 21, 2013

Palladium-Catalyzed, Enantioselective α-Arylation of α-Fluorooxindoles

scientific article published on 6 March 2017

Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation

scientific article published on 31 October 2016

Palladium-catalyzed addition of mono- and dicarbonyl compounds to conjugated dienes

scientific article published in October 2004

Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions

scientific article

Palladium-catalyzed amination of aromatic C-H bonds with oxime esters

scientific article published in March 2010

Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature

scientific article published on 24 September 2008

Palladium-catalyzed amination of aryl chlorides and bromides with ammonium salts

scientific article

Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands

scientific article published in January 2002

Palladium-catalyzed arylation of trimethylsilyl enolates of esters and imides. High functional group tolerance and stereoselective synthesis of alpha-aryl carboxylic acid derivatives

scientific article published in April 2004

Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines

scientific article

Palladium-catalyzed equilibrium addition of acidic OH groups across dienes

scientific article published in January 2003

Palladium-catalyzed formation of carbon-nitrogen bonds. Reaction intermediates and catalyst improvements in the hetero cross-coupling of aryl halides and tin amides

scientific article (publication date: June 1994)

Palladium-catalyzed gamma-arylation of alpha,beta-unsaturated esters from silyl ketene acetals

scientific article published on August 2010

Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents

article

Palladium-catalyzed α-arylation for the addition of small rings to aromatic compounds

scientific article published on 09 September 2019

Pd-catalyzed α-arylation of trimethylsilyl enolates of α,α-difluoroacetamides

scientific article published on 3 October 2014

Pd-catalyzed α-arylation of α,α-difluoroketones with aryl bromides and chlorides. A route to difluoromethylarenes

scientific article published on 10 March 2014

Polysilylether: A Degradable Polymer from Biorenewable Feedstocks

scientific article published on 30 August 2016

Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives

scientific article published on January 2007

Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds

scientific article published on 20 August 2009

Pushing the σ‐Donor Strength in Iridium Pincer Complexes: Bis(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands ⬇️

scientific article published on October 16, 2012

Reaktivität von Wolframocen gegenüber B-B und B-H-Bindungen im Vergleich zu C-H-Bindungen

Recent advances in the discovery of organometallic catalysts using high-throughput screening assays

scientific article

Reductive Elimination from Arylpalladium Cyanide Complexes ⬇️

scientific article published on March 8, 2012

Reductive Elimination from Phosphine-Ligated Alkylpalladium(II) Amido Complexes To Form sp3 Carbon-Nitrogen Bonds.

scientific article published on 14 March 2018

Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides

scientific article published on January 2007

Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes

scientific article published in March 2006

Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes

scientific article

Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex

scientific article

Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides

scientific article published in March 2003

Regioselective borylation of the C-H bonds in alkylamines and alkyl ethers. Observation and origin of high reactivity of primary C-H bonds beta to nitrogen and oxygen

scientific article

Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes

scientific article published on 23 November 2015

Regioselectivity of the borylation of alkanes and arenes

scientific article published on 18 February 2011

Resting state and elementary steps of the coupling of aryl halides with thiols catalyzed by alkylbisphosphine complexes of palladium

scientific article

Rhodium boryl complexes in the catalytic, terminal functionalization of alkanes

scientific article

Rhodium phosphine-π-arene intermediates in the hydroamination of alkenes

scientific article

Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes ⬇️

scientific article published on May 14, 2003

Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds

scientific article published on 2 June 2016

Rhodium-Catalyzed Regioselective Silylation of Alkyl C-H Bonds for the Synthesis of 1,4-Diols

scientific article published on 2 January 2018

Rhodium-catalyzed enantioselective silylation of arene C-H bonds: desymmetrization of diarylmethanols

scientific article published on 20 May 2015

Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol

scientific article published in February 2014

Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt

scientific article published in February 2002

Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent

scientific article published in December 2003

Ruthenium-Catalyzed Hydroamination of Unactivated Terminal Alkenes with Stoichiometric Amounts of Alkene and an Ammonia Surrogate by Sequential Oxidation and Reduction

scientific article published on 24 December 2020

Ruthenium-Catalyzed Regiospecific Borylation of Methyl C−H Bonds

scientific article (publication date: October 2006)

Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes

scientific article published in March 2004

Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides

scientific article published in April 2003

Selective C-H fluorination of pyridines and diazines inspired by a classic amination reaction

scientific article

Sequential Xanthalation and O-Trifluoromethylation of Phenols: A Procedure for the Synthesis of Aryl Trifluoromethyl Ethers

scientific article published on 22 November 2019

Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes

scientific article published on 22 May 2008

Site-Selective Functionalization of (sp3 )C-H Bonds Catalyzed by Artificial Metalloenzymes Containing an Iridium-Porphyrin Cofactor

scientific article published on 21 August 2019

Site-selective oxidation, amination and epimerization reactions of complex polyols enabled by transfer hydrogenation

scientific article

Slow reductive elimination from arylpalladium parent amido complexes

scientific article published on September 2010

Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions

scientific article published on July 2017

Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis.

scientific article published on 10 January 2018

Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis

scientific article published on 15 December 2016

Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts

scientific article published on 07 August 2019

Sterically Controlled Alkylation of Arenes through Iridium‐Catalyzed CH Borylation ⬇️

scientific article published on December 11, 2012

Sterically Controlled, Palladium-Catalyzed Intermolecular Amination of Arenes ⬇️

scientific article published on May 28, 2013

Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates

article

Synthesis and late-stage functionalization of complex molecules through C-H fluorination and nucleophilic aromatic substitution

scientific article published on July 2014

Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling

scientific article published on March 2016

Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides

scientific article published on 4 October 2012

Synthesis of difluoromethyl ethers with difluoromethyltriflate

scientific article published on 10 January 2013

Synthesis, Characterization, and Reactivity of Palladium Fluoroenolate Complexes.

scientific article

Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles

scientific article published in August 2002

Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand

scientific article published in August 2002

Synthesis, structure, theoretical studies, and Ligand exchange reactions of monomeric, T-shaped arylpalladium(II) halide complexes with an additional, weak agostic interaction

scientific article published in February 2004

Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes

scientific article published on 13 July 2016

Time-resolved IR studies on the mechanism for the functionalization of primary C-H bonds by photoactivated Cp*W(CO)3(Bpin).

scientific article published in February 2010

Traceless Silylation of β-C(sp3)-H Bonds of Alcohols via Perfluorinated Acetals.

scientific article published on 28 December 2017

Transfer of amido groups from isolated rhodium(I) amides to alkenes and vinylarenes

scientific article published in August 2005

Transition-Metal-Catalyzed Selective Functionalization of C(sp3)-H Bonds in Natural Products

scientific article published on 11 December 2017

Trifluoromethylation of Arylsilanes with [(phen)CuCF3 ]

scientific article published on 23 May 2016

Trimethylphosphate as a Methylating Agent for Cross Coupling: A Slow-Release Mechanism for the Methylation of Arylboronic Esters

scientific article published on 28 November 2018

Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities

scientific article

Unparalleled Rates for the Activation of Aryl Chlorides and Bromides: Coupling with Amines and Boronic Acids in Minutes at Room Temperature

article

Unusual Electronic Effects of Ancillary Ligands on the Perfluoroalkylation of Aryl Iodides and Bromides Mediated by Copper(I) Pentafluoroethyl Complexes of Substituted Bipyridines

scientific article published on 02 December 2019

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