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List of works by Jacques Pécaut

"Chiral-at-Metal" octahedral ruthenium(II) complexes with achiral ligands: a new type of enantioselective catalyst

scientific article published in August 2003

1,2‐Dihydrotriazinyl‐N‐oxy Free Radicals ⬇️

scientific article published on August 18, 2011

A Cobalt(III) Chiroporphyrin and Its Amine Adducts. A Potential Chiral NMR Shift Reagent for Amines

scientific article published on 01 February 1998

A Fully Delocalized Mixed-Valence Bis-μ(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center

article

A Novel Dimanganese(II) Complex with Two Chloride Bridges − A Two-Electron Oxidation System

scientific article published in January 2001

A bio-inspired switch based on cobalt(II) disulfide/cobalt(III) thiolate interconversion.

scientific article published on 9 April 2014

A copper thiolate centre for electron transfer: mononuclear vs. dinuclear complexes

scientific article published on 08 February 2012

A dinuclear manganese(II) complex with the [Mn(2)(mu-O(2)CCH(3))(3)](+) core: synthesis, structure, characterization, electroinduced transformation, and catalase-like activity

scientific article

A high-frequency and high-field EPR study of new azide and fluoride mononuclear Mn(III) complexes

scientific article published in October 2003

A multifrequency high-field EPR (9–285GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes

A nitrido-centered uranium azido cluster obtained from a uranium azide

scientific article published on 01 January 2008

A structural and functional mimic of the active site of NiFe hydrogenases

scientific article published on 12 July 2010

A uranium-based UO2(+)-Mn2+ single-chain magnet assembled trough cation-cation interactions

scientific article published on 6 December 2013

A versatile route to homo- and hetero-bimetallic 5f-5f and 3d-5f complexes supported by a redox active ligand framework.

scientific article published on 26 June 2017

A zig-zag uranyl(v)-Mn(ii) single chain magnet with a high relaxation barrier

scientific article published on 01 June 2015

A {Cu2S}2+ Mixed‐Valent Core Featuring a CuCu Bond ⬇️

scientific article published on October 25, 2010

Activation of oxaziridines by lewis acids: application in enantioselective sulfoxidation

scientific article published on 01 January 2005

Air-stable Oxyallyl Patterns and a Switchable N-Heterocyclic Carbene

scientific article published on 11 April 2020

An Experimental and Theoretical Investigation on Pentacoordinated Cobalt(III) Complexes with an Intermediate S=1 Spin State: How Halide Ligands Affect their Magnetic Anisotropy

scientific article published on 26 November 2015

An Experimental and Theoretical Investigation on Pentacoordinated Cobalt(III) Complexes with an Intermediate S=1 Spin State: How Halide Ligands Affect their Magnetic Anisotropy

scientific article published on 14 December 2015

An efficient design for the rigid assembly of four bidentate chromophores in water-stable highly luminescent lanthanide complexes

scientific article

Base-driven assembly of large uranium oxo/hydroxo clusters

scientific article published on 12 May 2011

Binuclear manganese compounds of potential biological significance. 1. Syntheses and structural, magnetic, and electrochemical properties of dimanganese(II) and -(II,III) complexes of a bridging unsymmetrical phenolate ligand.

scientific article

Biologically Relevant Heterodinuclear Iron–Manganese Complexes ⬇️

scientific article published on September 18, 2012

CO2 conversion to isocyanate via multiple N-Si bond cleavage at a bulky uranium(III) complex

scientific article published on 01 October 2015

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

scientific article published on 01 February 2015

Ca K-edge XAS as a probe of calcium centers in complex systems.

scientific article published on 10 December 2014

Calcium and heterometallic manganese-calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations

scientific article published in July 2015

Calix[4]phyrin based redox architectures: towards new molecular tools for electrochemical sensing

scientific article published on 5 September 2005

Carboxylate ligands drastically enhance the rates of oxo exchange and hydrogen peroxide disproportionation by oxo manganese compounds of potential biological significance

scientific article

Catalytic asymmetric sulfoxidation by chiral manganese complexes: acetylacetonate anions as chirality switches

scientific article published in December 2003

Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step

scientific article published on 23 April 2013

Cation-cation complexes of pentavalent uranyl: from disproportionation intermediates to stable clusters.

scientific article published on December 2010

Cation-controlled self-assembly of a hexameric europium wheel

scientific article published in August 2002

Cation-mediated conversion of the state of charge in uranium arene inverted-sandwich complexes

scientific article published on 08 November 2013

Chiral-at-metal ruthenium complex as a metalloligand for asymmetric catalysis

scientific article published on 26 May 2007

Cobalt and nickel diimine-dioxime complexes as molecular electrocatalysts for hydrogen evolution with low overvoltages

scientific article

Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species

scientific article published on 25 June 2019

Cobalt(III) tetraaza-macrocyclic complexes as efficient catalyst for photoinduced hydrogen production in water: Theoretical investigation of the electronic structure of the reduced species and mechanistic insight.

scientific article

Comparative structural studies of iodide complexes of uranium(III) and lanthanide(III) with hexadentate tetrapodal neutral N-donor ligands

scientific article

Comparison of two tetrapodal N,O ligands: impact of the softness of the heterocyclic N-donors pyridine and pyrazine on the selectivity for Am(III) over Eu(III).

scientific article

Controlled O2 reduction at a mixed-valent (II,I) Cu2S core

scientific article published on 23 July 2020

Controlled hydrolysis of lanthanide complexes of the N-donor tripod tris(2-pyridylmethyl)amine versus bisligand complex formation

scientific article

Controlled thermolysis of uranium (alkoxy)siloxy complexes: a route to polymetallic complexes of low-valent uranium.

scientific article

Correction to "Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid".

scientific article

Crystal Structure and Solution Fluxionality of Lanthanide Complexes of 2,4,6,-Tris-2-pyridyl-1,3,5-triazine

scientific article published on 01 July 1999

Crystal structure of a chiral binaphthyl porphyrin

Crystallization-induced asymmetric transformation of chiral-at-metal ruthenium(II) complexes bearing achiral ligands

scientific article

CuAAC-based assembly and characterization of a ruthenium-copper dyad containing a diimine-dioxime ligand framework.

scientific article

Cyclopentadienyl ruthenium-nickel catalysts for biomimetic hydrogen evolution: electrocatalytic properties and mechanistic DFT studies

scientific article published in September 2009

Definition of Magneto-Structural Correlations for the MnIIIon

Deprotonation in Mixed-Valent Diiron(II,III) Complexes with Aniline or Benzimidazole Ligands

scientific article published on 19 June 2015

Diamine Bis(phenolate) as Supporting Ligands in Organoactinide(IV) Chemistry. Synthesis, Structural Characterization, and Reactivity of Stable Dialkyl Derivatives

article by Elsa Mora et al published 18 December 2012 in Organometallics

Diastereoselective self-assembly of a homochiral europium triangle from a bipyoxazoline-carboxylate ligand

scientific article published on 01 June 2010

Dioxygen Activation and Catalytic Reduction to Hydrogen Peroxide by a Thiolate-Bridged Dimanganese(II) Complex with a Pendant Thiol.

scientific article published on 29 June 2015

Effect of substituents on redox, spectroscopic and structural properties of conjugated diaryltetrazines--a combined experimental and theoretical study

scientific article published on 09 December 2010

Effect of the Metal on Disulfide/Thiolate Interconversion: Manganese versus Cobalt

scientific article published on 09 November 2015

Efficient sensitization of lanthanide luminescence by tetrazole-based polydentate ligands.

scientific article published on 25 April 2008

Electrocatalytic Hydrogen Evolution with a Cobalt Complex Bearing Pendant Proton Relays: Acid Strength and Applied Potential Govern Mechanism and Stability

scientific article published on 19 December 2019

Energetics and structural consequences of axial ligand coordination in nonplanar nickel porphyrins

scientific article published in February 2005

Experimental and computational investigation of thiolate alkylation in Ni(II) and Zn(II) complexes: role of the metal on the sulfur nucleophilicity

scientific article

Ferrocene-Based Tetradentate Schiff Bases as Supporting Ligands in Uranium Chemistry

scientific article published on 26 May 2015

Fixation of atmospheric CO2 by a dimeric lanthanum hydroxide complex; assembly of an unusual hexameric carbonate

scientific article published on 14 December 2005

Fluorenone core donor–acceptor–donor π-conjugated molecules end-capped with dendritic oligo(thiophene)s: synthesis, liquid crystalline behaviour, and photovoltaic applications

article published in 2011

H(2)O(2)-Dependent Fe-Catalyzed Oxidations: Control of the Active Species We thank the EU for financial support (TMR program (ERBMRFXCT980207)

scientific article published on 01 March 2001

H2O2-Dependent Fe-Catalyzed Oxidations: Control of the Active Species

Heterometallic Fe2 (II) -U(V) and Ni2 (II) -U(V) Exchange-Coupled Single-Molecule Magnets: Effect of the 3 d Ion on the Magnetic Properties

scientific article published on 14 October 2015

High-field EPR investigation of a series of mononuclear Mn(II) complexes doped into Zn(II) hosts

High-spin chloro mononuclear MnIII complexes: a multifrequency high-field EPR study

scientific article published in March 2005

How Accurately Can Extended X-ray Absorption Spectra Be Predicted from First Principles? Implications for Modeling the Oxygen-Evolving Complex in Photosystem II.

scientific article published on 9 September 2015

Inclusion complexes of trivalent lutetium cations with an acidic derivative of per(3,6-anhydro)-alpha-cyclodextrin.

scientific article published on 10 December 2004

Influence of mixed thiolate/thioether versus dithiolate coordination on the accessibility of the uncommon +I and +III oxidation states for the nickel ion: an experimental and computational study

scientific article

Intramolecular Electron Transfers Thwart Bistability in a Pentanuclear Iron Complex

scientific article published on 2 June 2016

Isolation of a tetrameric cation-cation complex of pentavalent uranyl

scientific article published in December 2006

Lanthanide Complexes Based on β-Diketonates and a Tetradentate Chromophore Highly Luminescent as Powders and in Polymers

scientific article published on 21 November 2013

Lanthanide(II) Complexes Supported by N,O-Donor Tripodal Ligands: Synthesis, Structure, and Ligand-Dependent Redox Behavior.

scientific article

Lanthanide(III) Complexes of Tripodal N-Donor Ligands: Structural Models for the Species Involved in Solvent Extraction of Actinides(III).

scientific article

Ligand and Metal Based Multielectron Redox Chemistry of Cobalt Supported by Tetradentate Schiff Bases

scientific article published on 14 June 2017

Ligand assisted cleavage of uranium oxo-clusters

scientific article published on 25 February 2010

Metal-controlled diastereoselective self-assembly and circularly polarized luminescence of a chiral heptanuclear europium wheel.

scientific article

Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid

scientific article published on 16 February 2017

Molecular engineering of a cobalt-based electrocatalytic nanomaterial for H₂ evolution under fully aqueous conditions

scientific article published on 28 October 2012

Mononuclear Ni(II) Complexes with a S3O Coordination Sphere Based on a Tripodal Cysteine-Rich Ligand: pH Tuning of the Superoxide Dismutase Activity

scientific article published on 23 September 2019

Multielectron redox reactions involving C-C coupling and cleavage in uranium Schiff base complexes

scientific article published on 19 November 2010

Multimetallic cooperativity in uranium-mediated CO₂ activation.

scientific article published on 23 April 2014

Multiple aromatic amination mediated by a diiron complex

scientific article published on 01 January 2008

New insights into the acid mediated disproportionation of pentavalent uranyl.

scientific article published on 18 October 2010

New polydentate ligand and catalytic properties of the corresponding ruthenium complex during sulfoxidation and alkene epoxidation

scientific article published on 28 May 2008

New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionation

scientific article published on 01 December 2011

Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase.

scientific article published on 18 July 2016

Origin of the red shifts in the optical absorption bands of nonplanar tetraalkylporphyrins

scientific article

Origin of the zero-field splitting in mononuclear octahedral dihalide MnII complexes: an investigation by multifrequency high-field electron paramagnetic resonance and density functional theory.

scientific article

Oxidation chemistry of uranium(III) complexes of Tpa: synthesis and structural studies of oxo, hydroxo, and alkoxo complexes of uranium(IV).

scientific article published in September 2003

Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

scientific article published on 19 February 2009

Phosphoester hydrolysis: the incoming substrate turns the bridging hydroxido nucleophile into a terminal one.

scientific article

Phosphorescent Binuclear Iridium Complexes Based on Terpyridine–Carboxylate: An Experimental and Theoretical Study

scientific article published on 10 August 2011

Polynuclear cation-cation complexes of pentavalent uranyl: relating stability and magnetic properties to structure

scientific article

Practical synthetic routes to solvates of U(OTf)3: X-ray crystal structure of [U(OTf)3(MeCN)3]n, a unique U(III) coordination polymer

scientific article published in August 2005

Redox-Induced μ-Acetato and μ-Oxo Core Interconversions in Dinuclear Manganese Tris(2-methylpyridyl)amine (tpa) Complexes: Isolation and Characterization of [Mn2III(μ-O)(μ-O2CCH3)(tpa)2]3+

Redox-Innocent Metal-Assisted Cleavage of S-S Bond in a Disulfide-Containing Ligand.

scientific article

Relating structural and thermodynamic effects of the Pb(II) lone pair: a new picolinate ligand designed to accommodate the Pb(II) lone pair leads to high stability and selectivity

scientific article published on 06 April 2007

Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes

scientific article published in September 2009

Reversible apical coordination of imidazole between the Ni(III) and Ni(II) oxidation states of a dithiolate complex: a process related to the Ni superoxide dismutase

scientific article published in July 2010

Selective self-assembly of hexameric homo- and heteropolymetallic lanthanide wheels: synthesis, structure, and photophysical studies

scientific article published on 01 February 2007

Self-assembly of a 3d-5f trinuclear single-molecule magnet from a pentavalent uranyl complex

scientific article published on 05 October 2014

Self-assembly of highly luminescent lanthanide complexes promoted by pyridine-tetrazolate ligands

scientific article

Self-assembly of polyoxo clusters and extended frameworks by controlled hydrolysis of low-valent uranium

scientific article published on 01 January 2007

Self-assembly properties of semiconducting donor-acceptor-donor bithienyl derivatives of tetrazine and thiadiazole-effect of the electron accepting central ring.

scientific article

Seven Reversible Redox Processes in a Self-Assembled Cobalt Pentanuclear Bis(triple-stranded helicate): Structural, Spectroscopic, and Magnetic Characterizations in the CoICoII4, CoII5, and CoII3CoIII2 Redox States

scientific article published on 24 June 2020

Siloxides as supporting ligands in uranium(III)-mediated small-molecule activation

scientific article published on 04 November 2012

Solid-state and solution properties of cationic lanthanide complexes of a new neutral heptadentate N4O3 tripodal ligand

scientific article published in December 2003

Spectroscopic and electrochemical characterization of an aqua ligand exchange and oxidatively induced deprotonation in diiron complexes

scientific article

Stable Di- and Tri-coordinated Carbon(II) Supported by an Electron-Rich β-Diketiminate Ligand.

scientific article published on 20 December 2016

Stable pentavalent uranyl species and selective assembly of a polymetallic mixed-valent uranyl complex by cation-cation interactions

scientific article published on 01 January 2009

Structural Snapshots of Cluster Growth from {U6 } to {U38 } During the Hydrolysis of UCl4

scientific article published on 21 January 2019

Structural and density functional studies of uranium(III) and lanthanum(III) complexes with a neutral tripodal N-donor ligand suggesting the presence of a U-N back-bonding interaction

scientific article published in May 2002

Structural and photophysical properties of trianionic nine-coordinated near-IR emitting 8-hydroxyquinoline-based complexes

scientific article

Structural and photophysical studies of highly stable lanthanide complexes of tripodal 8-hydroxyquinolinate ligands based on 1,4,7-triazacyclononane

scientific article

Structural characterization and electronic properties determination by high-field and high-frequency EPR of a series of five-coordinated Mn(II) complexes

scientific article published in October 2004

Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex – the reactivity toward S-alkylation: an experimental and theoretical study

scientific article published on 01 October 2012

Structure, stability, dynamics, high-field relaxivity and ternary-complex formation of a new tris(aquo) gadolinium complex

scientific article

Synthesis and SMM behaviour of trinuclear versus dinuclear 3d-5f uranyl(v)-cobalt(ii) cation-cation complexes

scientific article published on 17 January 2017

Synthesis and Structure of a Stable Pentavalent-Uranyl Coordination Polymer

scientific article published on 01 June 2006

Synthesis and reactivity of a terminal uranium(iv) sulfide supported by siloxide ligands

scientific article published on 10 May 2016

Synthesis and structural characterization of five-, six-, and seven-coordinate mononuclear manganese(II) complexes with N-tridentate ligands

article published in 2004

Synthesis of electron-rich uranium(IV) complexes supported by tridentate Schiff base ligands and their multi-electron redox chemistry.

scientific article published on 4 June 2013

Synthesis, electrochemical and photophysical properties of heterodinuclear Ru-Mn and Ru-Zn complexes bearing ambident Schiff base ligand

scientific article published on 18 May 2010

Synthesis, structure, and bonding of stable complexes of pentavalent uranyl

scientific article published in January 2010

The effect of pyridinecarboxylate chelating groups on the stability and electronic relaxation of gadolinium complexes

scientific article published on 10 February 2005

The important effect of ligand architecture on the selectivity of metal ion recognition in An(III)/Ln(III) separation with N-donor extractants

scientific article published in December 2002

Thermically and electrochemically induced isomerization of a (bis(ferrocene)-cyclam)copper(II) complex

scientific article published in April 2003

Tuning lanthanide reactivity towards small molecules with electron-rich siloxide ligands.

scientific article published on 30 July 2014

Tuning uranium-nitrogen multiple bond formation with ancillary siloxide ligands

scientific article published on 5 August 2013

Two new terpyridine dimanganese complexes: a manganese(III,III) complex with a single unsupported oxo bridge and a manganese(III,IV) complex with a dioxo bridge. Synthesis, structure, and redox properties.

scientific article published in March 2002

Two-electron versus one-electron reduction of chalcogens by uranium(iii): synthesis of a terminal U(v) persulfide complex

scholarly article by Clément Camp et al published 2014 in Chemical Science

Unique crown thioether complexes of f elements: the crystal structure of U(III) and La(III) complexes of 1,4,7-trithiacyclononane

scientific article

Uranium and manganese assembled in a wheel-shaped nanoscale single-molecule magnet with high spin-reversal barrier.

scientific article published on 11 November 2012

Valence Localization at a Bio-inspired Mixed-Valent {Cu2 S}2+ Motif upon Solvation in Acetonitrile: Effect on Nitrous Oxide Reductase (N2 Or) Activity.

scientific article

Versatile pyridine-2,6-bis-tetrazolate scaffolds for the formation of highly luminescent lanthanide complexes

scientific article published on 21 January 2016

X-ray photoreduction of a di(mu-oxo)Mn(III)Mn(IV) complex occurs at temperatures as low as 20 K

scientific article published on 01 November 2006

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