The synthesis of [Ru5C(CO)15] by the carbonylation of [Ru6C(CO)17] and the reactions of the pentanuclear cluster with a variety of small molecules: the X-ray structure analyses of [Ru5C(CO)15], [Ru5C(CO)15(MeCN)], [Ru5C(CO)14(PPh3)], [Ru5C(CO)13(PPh3